原位合成钴/还原氧化石墨烯纳米粒子催化氨硼烷制氢

doi:10.3866/PKU.WHXB201404141

Abstract

Abstract:

Cobalt nanoparticles (NPs) supported on reduced graphene oxide (RGO) were synthesized by a one-step in situ co-reduction of an aqueous solution of cobalt(Ⅱ) chloride and graphene oxide (GO) using ammonia borane (AB) as the sole reductant under ambient conditions. The as-synthesized Co/RGO catalysts exhibited high catalytic activity for the hydrolytic dehydrogenation of AB at room temperature. The assynthesized Co/RGO nanocatalysts exhibited much higher catalytic activity than the RGO-free Co counterpart. Compared with the nanocatalysts reduced by NaBH4, the Co/RGO nanocatalysts generated by the milder reductant AB exhibited superior catalytic activity. Moreover, kinetic studies indicate that the catalytic hydrolysis of AB by Co/RGO has zero order kinetics with respect to the substrate concentration. The hydrolysis activation energy is estimated to be about 27.10 kJ·mol^-1, which is lower than most reported data for the same reaction conusing non-noble metal catalysts and some noble metal containing catalysts. Furthermore, the RGO-supported Co NPs show good recyclability and magnetic reusability for hydrogen generation from an aqueous solution of AB, which enables the practical reuse of the catalysts. Hence, this general method indicates that AB can be used as both a potential hydrogen storage material and an efficient reducing agent, and can be easily extended to the facile preparation of other RGO-based metallic systems.

Key words: Energy storage material, Reduced graphene oxide, Co nanoparticle, Ammonia borane, Hydrogen generation

MSC2000:

O643

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YANG Yu-Wen, FENG Gang, LU Zhang-Hui, HU Na, ZHANG Fei, CHEN Xiang-Shu. In situ Synthesis of Reduced Graphene Oxide Supported Co Nanoparticles as Efficient Catalysts for Hydrogen Generation from NH₃BH₃[J].Acta Phys. -Chim. Sin., 2014, 30(6): 1180-1186.

References

(1) Schlapbach, L.; Züttel, A. Nature 2001, 414, 353. doi: 10.1038/35104634
(2) Grochala,W.; Edwards, P. P. Chem. Rev. 2004, 104, 1283. doi: 10.1021/cr030691s
(3) Graetz, J. Chem. Soc. Rev. 2009, 38, 73. doi: 10.1039/b718842k
(4) Suh, M. P.; Park, H. J.; Prasad, T. K.; Lim, D.W. Chem. Rev. 2012, 112, 782. doi: 10.1021/cr200274s
(5) Staubitz, A.; Robertson, A. P. M.; Manners, I. Chem. Rev. 2010, 110, 4079. doi: 10.1021/cr100088b
(6) Chen, P.; Zhu, M. Mater. Today 2008, 11, 36.
(7) Lu, Z. H.; Xu, Q. Funct. Mater. Lett. 2012, 5, 1230001. doi: 10.1142/S1793604712300010
(8) Yadav, M.; Xu, Q. Energy Environ. Sci. 2012, 5, 9698. doi: 10.1039/c2ee22937d
(9) Lu, Z. H.; Yao, Q. L.; Zhang, Z. J.; Yang, Y.W.; Chen, X. S. J. Nanomater. 2014, 729029.
(10) Rakap, M.; Kalu, E. E.; Özkar, S. J. Power Sources 2012, 210, 184. doi: 10.1016/j.jpowsour.2012.03.025
(11) Yan, J. M.;Wang, Z. L.;Wang, H. L.; Jiang, Q. J. Mater. Chem. 2012, 22, 10990. doi: 10.1039/c2jm31042b
(12) Yang, Y.W.; Zhang, F.;Wang, H. L.; Yao, Q. L.; Chen, X. S.; Lu, Z. H. J. Nanomater. 2014, 294530.
(13) Cheng, F. Y.; Ma, H.; Li, Y. M.; Chen, J. Inorg. Chem. 2007, 46, 788. doi: 10.1021/ic061712e
(14) Basu, S.; Brockman, A.; Gagare, P.; Zheng, Y.; Ramachandran, P. V.; Delgass,W. N.; Gore, J. P. J. Power Sources 2009, 188, 238. doi: 10.1016/j.jpowsour.2008.11.085
(15) Du, Y. S.; Cao, N.; Yang, L.; Luo,W.; Cheng, G. Z. New J. Chem. 2013, 37, 3035. doi: 10.1039/c3nj00552f
(16) Xi, P. X.; Chen, F. J.; Xie, G. Q.; Ma, C.; Liu, H.Y.; Shao, C. W.;Wang, J.; Xu, Z. H.; Xu, X. M.; Zeng, Z. Z. Nanoscale 2012, 4, 5597. doi: 10.1039/c2nr31010d
(17) Chandra, M.; Xu, Q. J. Power Sources 2007, 168, 135. doi: 10.1016/j.jpowsour.2007.03.015
(18) Yang, L.; Luo,W.; Cheng, G. E. ACS Appl. Mater. Interfaces 2013, 5, 8231. doi: 10.1021/am402373p
(19) Rachiero, G. P.; Demirci, U. B.; Miele, P. Int. J. Hydrog. Energy 2011, 36, 7051. doi: 10.1016/j.ijhydene.2011.03.009
(20) Simagia, V. I.; Komova, O. V.; Ozerova, A. M.; Netskina, O. V.; Odegova, G. V.; Kelleman, D. G.; Bulavcheoko, O. V.; Ishchenko, A. V. Appl. Catal. A: Gen. 2011, 384, 86.
(21) Yan, L.; Su, J.; Meng, X. Y.; Luo,W.; Cheng, G. Z. J. Mater. Chem. A 2013, 1, 10016. doi: 10.1039/c3ta11835e
(22) Lu, Z. H.; Li, J. P.; Zhu, A. L.; Yao, Q. L.; Huang,W.; Zhou, R. Y.; Zhou, R. F.; Chen, X. S. Int. J. Hydrog. Energy 2013, 38, 5330. doi: 10.1016/j.ijhydene.2013.02.076
(23) Lu, Z. H.; Jiang, H. L.; Yadav, M.; Aranishi, K.; Xu, Q. J. Mater. Chem. 2012, 22, 5065. doi: 10.1039/c2jm14787d
(24) Rakap, M.; Özkar, S. Int. J. Hydrog. Energy 2010, 35, 3341. doi: 10.1016/j.ijhydene.2010.01.138
(25) Metin, Ö.; Özkar, S. Int. J. Hydrog. Energy 2011, 36, 1424.
(26) Yao, Q. L.; Shi,W. M.; Feng, G.; Lu, Z. H.; Zhang, X. L.; Tao, D. J.; Kong, D. J.; Chen, X. S. J. Power Sources 2014, 257, 293. doi: 10.1016/j.jpowsour.2014.01.122
(27) Yang, Y.W.; Lu, Z. H.; Hu, Y. J.; Zhang, Z. J.; Shi,W. M.; Chen, X. S.;Wang, T. T. RSC Advances 2014, 4, 13749. doi: 10.1039/c3ra47023g
(28) Chandra, M.; Xu, Q. J. Power Sources 2006, 156, 190. doi: 10.1016/j.jpowsour.2005.05.043
(29) Rakap, M.; Kalu, E. E.; Özkar, S. Int. J. Hydrog. Energy 2011, 36, 1448. doi: 10.1016/j.ijhydene.2010.10.097
(30) Eom, K. S.; Cho, K.W.; Kwon, H. S. Int. J. Hydrog. Energy 2010, 35, 181.
(31) Garaj, S.; Hubbard,W.; Reina, A.; Kong, J.; Branton, D.; Golovchenko, J. A. Nature 2010, 467, 190. doi: 10.1038/nature09379
(32) Lee, C.;Wei, X. D.; Kysar, J.W.; Hone, J. Science 2008, 321, 385. doi: 10.1126/science.1157996
(33) Choi, B. G.; Hong, J.; Park, Y. C.; Jung, D. H.; Hong,W. H.; Hammond, P. T.; Park, H. S. ACS Nano 2011, 5, 5167. doi: 10.1021/nn2013113
(34) Hu, Y. J.; Jin, J.; Zhang, H.;Wu, P.; Cai, C. X. Acta Phys. -Chim. Sin. 2010, 26 (8), 2073. [胡耀娟, 金娟, 张卉, 吴萍, 蔡称心. 物理化学学报, 2010, 26 (8), 2073.] doi: 10.3866/PKU.WHXB20100812
(35) Li, S. M.;Wang, B.; Liu, J. H.; Yu, M.; An, J.W. Acta Phys. - Chim. Sin. 2012, 28 (11), 2754. [李松梅, 王博, 刘建华, 于美, 安军伟. 物理化学学报, 2012, 28 (11), 2754.] doi: 10.3866/PKU.WHXB201208292
(36) Li, Y. X.;Wei, Z. D.; Zhao, Q. L.; Ding,W.; Zhang, Q.; Chen, S. G. Acta Phys. -Chim. Sin. 2011, 27 (4), 858. [李云霞, 魏子栋, 赵巧玲, 丁炜, 张骞, 陈四国. 物理化学学报, 2011, 27 (4),858.] doi: 10.3866/PKU.WHXB20110411
(37) Mazumder, V.; Chi, M. F.; More, K. L.; Sun, S. H. Angew Chem. Int. Edit. 2010, 49, 9368. doi: 10.1002/anie.201003903
(38) Vinodgopal, K.; Neppolian, B.; Lightcap, I. V.; Grieser, F.; Ashokkumar, M.; Kamat, P. V. J. Am. Chem. Soc. 2010, 1, 1987.
(39) Liu, C. B.;Wang, K.; Luo, S. L.; Tang, Y. H.; Chen, L. Y. Small 2011, 7, 1203. doi: 10.1002/smll.v7.9
(40) Cao, N.; Su, J.; Luo,W.; Cheng, G. Z. Int. J. Hydrog. Energy 2014, 39, 426. doi: 10.1016/j.ijhydene.2013.10.059
(41) Roucoux, A.; Schulz, J.; Patin, H. Chem. Rev. 2002, 102, 3757. doi: 10.1021/cr010350j
(42) Yang, L.; Cao, N.; Du, C.; Dai, H. M.; Hu, K.; Luo,W.; Cheng, G. Z. Materials Letters 2014, 115, 113. doi: 10.1016/j.matlet.2013.10.039
(43) Astruc, D.; Lu, F.; Aranzaes, J. R. Angew Chem. Int. Edit. 2005, 44, 7852.
(44) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80, 1339. doi: 10.1021/ja01539a017
(45) Kovtyukhova, N. I.; Ollivier, P. J.; Martin, B. R.; Mallouk, T. E.; Chizhik, S. A.; Buzaneva, E. V.; Gorchinskiy, A. D. Chem. Mater. 1999, 11, 771. doi: 10.1021/cm981085u
(46) Chen, H. Q.; Müller, M. B.; Gilmore, K. J.;Wallace, G. G.; Li, D. Adv. Mater. 2008, 20, 3557. doi: 10.1002/adma.200800757

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In situ Synthesis of Reduced Graphene Oxide Supported Co Nanoparticles as Efficient Catalysts for Hydrogen Generation from NH₃BH₃

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In situ Synthesis of Reduced Graphene Oxide Supported Co Nanoparticles as Efficient Catalysts for Hydrogen Generation from NH3BH3

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In situ Synthesis of Reduced Graphene Oxide Supported Co Nanoparticles as Efficient Catalysts for Hydrogen Generation from NH₃BH₃