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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2014,Vol.30>> Issue(7)>> 1267-1273     doi: 10.3866/PKU.WHXB201405052         中文摘要
ELECTROCHEMISTRY AND NEW ENERGY
Synthesis and Electrocatalytic Properties of Pt Nanoparticles on Nitrogen-Doped Reduced Graphene Oxide for Methanol Oxidation
WANG Li1, MA Jun-Hong1,2
1. College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, P. R. China;
2. Key Laboratory of Advanced Functional Materials, Autonomous Region, Institute of Applied Chemistry, Xinjiang University, Urumqi 830046, P. R. China
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Nitrogen-doped reduced graphene oxide materials (N-RGO) derived from pyrolysis of graphene oxide (GO)/polyaniline composites were used as a support for the immobilization of Pt nanoparticles. The morphologies and structures of N-RGO and Pt/N-RGO were comprehensively characterized by transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and Raman spectroscopy. The electrocatalytic activities of the as-prepared catalysts for CO stripping and methanol oxidation were investigated by cyclic voltammetry and chronoamperometry. The results showed that GO was reduced to multilayer graphene by thermal annealing accompanied with successful incorporation of N atoms into RGO. Moreover, the presence of the doped N atoms enhanced the surface defects and electrical conductivity of the RGO materials. Pt nanoparticles on N-RGO were more evenly dispersed, had better CO tolerance, and had higher activity/stability for methanol oxidation than those on RGO without N doping.



Keywords: Polyaniline   Reduced graphene oxide   Nitrogen-doped   Platinum electrocatalyst   Methanol oxidation  
Received: 2014-03-22 Accepted: 2014-05-05 Publication Date (Web): 2014-05-05
Corresponding Authors: MA Jun-Hong Email: junhong@xju.edu.cn

Fund: The project was supported by the Doctoral Scientific Research Starting Foundation of Xinjiang University, China (BS100110), Open Project Program of Xinjiang Laboratory of Advanced Functional Materials, China (XJDX0902-2010-06), and National Natural Science Foundation of China (21201146).

Cite this article: WANG Li, MA Jun-Hong. Synthesis and Electrocatalytic Properties of Pt Nanoparticles on Nitrogen-Doped Reduced Graphene Oxide for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2014,30 (7): 1267-1273.    doi: 10.3866/PKU.WHXB201405052

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