ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2014,Vol.30>> Issue(7)>> 1267-1273     doi: 10.3866/PKU.WHXB201405052         中文摘要
Synthesis and Electrocatalytic Properties of Pt Nanoparticles on Nitrogen-Doped Reduced Graphene Oxide for Methanol Oxidation
WANG Li1, MA Jun-Hong1,2
1. College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, P. R. China;
2. Key Laboratory of Advanced Functional Materials, Autonomous Region, Institute of Applied Chemistry, Xinjiang University, Urumqi 830046, P. R. China
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Nitrogen-doped reduced graphene oxide materials (N-RGO) derived from pyrolysis of graphene oxide (GO)/polyaniline composites were used as a support for the immobilization of Pt nanoparticles. The morphologies and structures of N-RGO and Pt/N-RGO were comprehensively characterized by transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and Raman spectroscopy. The electrocatalytic activities of the as-prepared catalysts for CO stripping and methanol oxidation were investigated by cyclic voltammetry and chronoamperometry. The results showed that GO was reduced to multilayer graphene by thermal annealing accompanied with successful incorporation of N atoms into RGO. Moreover, the presence of the doped N atoms enhanced the surface defects and electrical conductivity of the RGO materials. Pt nanoparticles on N-RGO were more evenly dispersed, had better CO tolerance, and had higher activity/stability for methanol oxidation than those on RGO without N doping.

Keywords: Polyaniline   Reduced graphene oxide   Nitrogen-doped   Platinum electrocatalyst   Methanol oxidation  
Received: 2014-03-22 Accepted: 2014-05-05 Publication Date (Web): 2014-05-05
Corresponding Authors: MA Jun-Hong Email:

Fund: The project was supported by the Doctoral Scientific Research Starting Foundation of Xinjiang University, China (BS100110), Open Project Program of Xinjiang Laboratory of Advanced Functional Materials, China (XJDX0902-2010-06), and National Natural Science Foundation of China (21201146).

Cite this article: WANG Li, MA Jun-Hong. Synthesis and Electrocatalytic Properties of Pt Nanoparticles on Nitrogen-Doped Reduced Graphene Oxide for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2014,30 (7): 1267-1273.    doi: 10.3866/PKU.WHXB201405052

(1) Wei, D.; Liu, Y.;Wang, Y.; Zhang, H.; Huang, L.; Yu, G. Nano Lett. 2009, 9, 1752. doi: 10.1021/nl803279t
(2) Yang, Z.; Yao, Z.; Li, G.; Fang, G.; Nie, H.; Liu, Z.; Zhou, X.; Chen, X.; Huang, S. ACS Nano 2012, 6, 205. doi: 10.1021/nn203393d
(3) Shao, Y. Y.; Sui, J. H.; Yin, G. P.; Gao, Y. Z. Appl. Catal. B 2008, 79 (1), 89. doi: 10.1016/j.apcatb.2007.09.047
(4) Xiong, B.; Zhou, Y. K.; O′Hayre, R.; Shao, Z. P. Appl. Surf. Sci. 2013, 266, 433. doi: 10.1016/j.apsusc.2012.12.053
(5) Wu, J.; Hu, F.; Hu, X.;Wei, Z. D.; Shen, P. K. Electrochimica Acta 2008, 53 (28), 8341. doi:10.1016/j.electacta.2008.06.051
(6) Zhou, C.W.; Kong, J.; Yenilmez, E.; Dai, H. J. Science 2000, 290, 1552. doi: 10.1126/science.290.5496.1552
(7) He, D. P.; Jiang, Y. L.; Lv, H. F.; Pan, M.; Mu, S. C. Applied Catalysis B: Environmental 2013, 132 -133, 379.
(8) Xiao, X.; Zhou, Y. K.; Lu, J. M.; Tian, X. H.; Zhu, H. X.; Liu, J. G. Electrochimica Acta 2014, 120, 439. doi: 10.1016/j. electacta.2013.12.062
(9) Zhang, L. S.; Liang, X. Q.; Song,W. G.;Wu, Z. Y. Phys. Chem. Chem. Phys. 2010, 12, 12055. doi: 10.1039/c0cp00789g
(10) Sun, L.;Wang, L.; Tian, G. G.; Tan, T. X.; Xie, Y.; Shi, K. Y.; Li, M. T.; Fu, H. G. RSC Adv. 2012, 2, 4498. doi: 10.1039/c2ra01367c
(11) Wang, Y.; Shao, Y. Y.; Matson, D.W.; Li, J. H.; Lin, Y. H. ACS Nano 2010, 4, 1790.
(12) Hassan, F. M.; Chabot, V.; Li, J. D.; Kim, B. K.; Ricardez-Sandoval, L.; Yu, A. P. J. Mater. Chem. A 2013, 1, 2904.
(13) Xu, X.; Zhou, Y. K.; Yuan, T.; Li, Y.W. Electrochimica Acta 2013, 112, 587. doi: 10.1016/j.electacta.2013.09.038
(14) Lin, Z. Y.;Waller, G.; Liu, Y.; Liu, M. L.;Wong, C. P. Adv. Energy Mater. 2012, 2 (7), 884.
(15) Lin, Z.Y.; Song, M. K.; Ding, Y.; Liu, Y.; Liu, M. L.;Wong, C. P. Phys. Chem. Chem. Phys. 2012, 14, 3381. doi: 10.1039/c2cp00032f
(16) Sheng, Z. H.; Shao, L.; Chen, J. J.; Bao,W. J.;Wang, F. B.; Xia, X. H. ACS Nano 2011, 5, 4350. doi: 10.1021/nn103584t
(17) Lin, Z. Y.;Waller, G.; Liu, Y.; Liu, M. L.;Wong, C. P. Nano Energy 2013, 2, 241. doi: 10.1016/j.nanoen.2012.09.002
(18) Lai, L. F.; Potts, J. R.; Zhan, D.;Wang, L.; Poh, C. K.; Tang, C. H.; Gong, H.; Shen, Z. X.; Lin, J. Y.; Rodney, S. R. Energy Environ. Sci. 2012, 5, 7936. doi: 10.1039/c2ee21802j
(19) Wu, G.; Mack, N. H.; Gao,W.; Ma, S. G.; Zhong, R. Q.; Han, J. T.; Baldwin, J. K.; Zelenay, P. ACS Nano 2012, 6 (11), 9764. doi: 10.1021/nn303275d
(20) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80, 1339. doi: 10.1021/ja01539a017
(21) Wu, G.; Swaidan, R. J.; Li, D. Y.; Li, N. Electrochimica Acta 2008, 53, 7622. doi: 10.1016/j.electacta.2008.03.082
(22) Stankovicha, S.; Dikina, D. A.; Piner, R. D.; Kohlhaas, K. A.; Kleinhammes, A.; Jia, Y. Y.;Wu, Y.; Nguyen, S. B. T.; Ruoff, R. S. Carbon 2007, 45 (7), 1558. doi: 10.1016/j.carbon.2007.02.034
(23) Liu, S.;Wang, J.; Zeng, J.; Ou, J.; Li, Z.; Liu, X.; Yang, S. G. J. Power Sources 2010, 195 (15), 4628. doi: 10.1016/j. jpowsour.2010.02.024
(24) Ferrari, A. C.; Meyer, J. C.; Scardaci, V.; Casiraghi, C.; Lazzeri, M.; Mauri, F.; Piscanec, S.; Jiang, D.; Novoselov, K. S.; Roth, S.; Geim, A. K. Phys. Rev. Lett. 2006, 97, 187401. doi: 10.1103/PhysRevLett.97.187401
(25) Kudin, K. N.; Ozbas, B.; Schniepp, H. C.; Prud′homme, R. K.; Aksay, I. A.; Car, R. Nano Lett. 2008, 8, 36. doi: 10.1021/nl071822y
(26) Xin, Y. C.; Liu, J. G.; Zhou, Y.; Liu,W. M.; Gao, J.; Xie, Y.; Yin, Y.; Zou, Z. G. Electrochimica Acta 2012, 60, 354. doi: 10.1016/j.electacta.2011.11.062
(27) Kuo, P. L.; Chen,W. F.; Huang, H. Y.; Chang, I. C.; Dai, S. A. J. Phys. Chem. B 2006, 110, 3071.
(28) Wu, G.; Li, D.; Dai, C.;Wang, D.; Li, N. Langmuir 2008, 24, 3566. doi: 10.1021/la7029278
(29) Groves, M. N.; Chan, A. S.W.; Malardier, J. C.; Jugroot, M. Chem. Phys. Lett. 2009, 481, 214. doi: 10.1016/j.cplett.2009.09.074
(30) Zhou, Y.; Neyerlin, K.; Olson, T. S.; Pylypenko, S.; Bult, J.; Dinh, H. N.; Gennett, T.; Shao, Z. P.; O'Hayre, R. Energy Environ. Sci. 2010, 3 (10), 1437. doi: 10.1039/c003710a
(31) Wang, S. Y.; Jiang, S. P.;Wang, X.; Guo, J. Electrochimica Acta 2011, 56, 1563. doi: 10.1016/j.electacta.2010.10.055
(32) Zheng, S. F.; Hu, J. S.; Zhong, L. S.;Wan, L. J.; Song,W. G. J. Phys. Chem. C 2007, 111, 11174. doi: 10.1021/jp0727042
(33) Zheng, B.; Zheng,W. T.; Zhang, K.;Wen, Q. B.; Zhu, J. Q.; Meng, S. H.; He, X. D.; Han, J. C. Carbon 2006, 44, 962. doi: 10.1016/j.carbon.2005.10.009

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61. Fang Kun;Li Shou-Ping;Tao Xue-Yu;Wang Qing-Lu;Mao Wei-Min;Wu Qi-Ye.Preparation by Dispersion Polymerization and Characterization of Soluble and Stable Colloidal Polyaniline Microparticles[J]. Acta Phys. -Chim. Sin., 2004,20(01): 103-106
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66. Mu Shao-Lin;Yang Yi-Fei;Tan Zhi-An.The Electrocatalytic Oxidation of Hydrogen Peroxide on Polyaniline Doped with Ferrocenesulfonic Acid[J]. Acta Phys. -Chim. Sin., 2003,19(07): 588-592
67. Wei Jian-Hong;Shi Jing;Guan Jian-Guo;Yuan Run-Zhang.Surface Modification of PAn Particles[J]. Acta Phys. -Chim. Sin., 2003,19(07): 657-660
68. Wei Zi-Dong;Miki Atsushi;Ohmori Tadayoshi;Osawa Masatoshi.Methanol Electroxidation on Upd - Sn Modified Platinum Electrodes[J]. Acta Phys. -Chim. Sin., 2002,18(12): 1120-1124
69. Chen Di-Zhao;Liang Yi-Zeng;Xu Cheng-Jian.Rank Analysis on Two-dimensional Kinetic Data and Its Related Application[J]. Acta Phys. -Chim. Sin., 2002,18(10): 924-929
70. Wei Jian-Hong;Guan Jian-Guo;Chen Wen-Yi;Yuan Run-Zhang.Preparation and Characteristics of Polyaniline - Barium Titanate Nanocomposite Particles[J]. Acta Phys. -Chim. Sin., 2002,18(07): 653-656
71. Dai Li-Zong;Xu Yi-Ting;Jean-Yves Gal;Wu Hui-Huang.Studies on the Structure of the Aggregated State of Ringsubstituted Polyaniline[J]. Acta Phys. -Chim. Sin., 2002,18(03): 237-242
72. Liao Chuan-Ping;Gu Ming-Yuan.Mixied-Potential for Autocatalytic Polymerization of Aniline[J]. Acta Phys. -Chim. Sin., 2001,17(10): 904-907
73. Kan Jin-Qing;Hou Jun-Hua;Mu Shao-Lin.Bioelectrochemical Characters of Doping-coating Polyanilineuricase Electrode[J]. Acta Phys. -Chim. Sin., 2001,17(01): 32-36
74. Mu Shao-Lin, Yang Yi-Fei.Polyaniline Used as An Electron Transfer Mediator for the Catalyzed Dehydrogenating Renction of Alcohol[J]. Acta Phys. -Chim. Sin., 2000,16(09): 830-834
75. Huo Li-Hua, Wang Dong-Mei, Zeng Guang-Fu, Xi Shi-Quan.Preparation and Properties of Conducting Polymer of Doped Polyaniline LB Film[J]. Acta Phys. -Chim. Sin., 2000,16(07): 632-635
76. Li Jian-Chang, Xue Zeng-Quan, Zhang Hao, Zeng Yan, Liu Wei-Min, Wu Quan-De.Chiral Fractal Patterns of TCNQ Thin Films Grown by Vacuum Evaporation[J]. Acta Phys. -Chim. Sin., 2000,16(07): 579-582
77. Li Jian-Chang, Song Yan-Lin, Xue Zeng-Quan, Liu Wei-Min, Jiang Lei, Zhu Dao-Ben.Microstructure and Electric Properties of Polyaniline-TCNQ Complex Thin Film Grown by Vacuum Evaporation[J]. Acta Phys. -Chim. Sin., 2000,16(04): 289-293
78. Jiang Dian-Lu, Weng Yong-Liang, Tong Ru-Ting.Preparation and Characterization of Polyaniline/Bentonite Layered Nanocomposites[J]. Acta Phys. -Chim. Sin., 1999,15(01): 69-72
79. Chen Yi-Chi, Yin Wu-Sheng, Zhang Shu-Xiang, Wu Jin-Ping, Gu Ti-Ren.Preparation and Properties of SIS/PAn Conducting Rubber Composite[J]. Acta Phys. -Chim. Sin., 1998,14(06): 501-508
80. Tang Xiao-Hui, Li Yong-Fang, Fang Shi-Bi.Studies of Electrochemical Properties of PAn Doped with Disulfidedisulfonic Acid[J]. Acta Phys. -Chim. Sin., 1998,14(03): 214-218
81. Kan Jin-Qing,Mu Shao-Lin.Study on Inhibition of Xanthine Oxidase by Umbelliferone[J]. Acta Phys. -Chim. Sin., 1997,13(07): 650-654
82. Kan Jin-Qing,Qiao Yue-Dong,Mu Shao-Lin,Li Yong-Fang.Inhibition of Bioelectrochemical Activities of Polyaniline Uricase Electrode by Theophylline[J]. Acta Phys. -Chim. Sin., 1997,13(03): 236-241
83. Song Gen-Ping,Guo-Rong,Yan Peng-Quan.Preparation of Fine Particles of Polyaniline in O/W Microemulsion[J]. Acta Phys. -Chim. Sin., 1996,12(09): 812-815
84. Zhong Qi-Ling,Xiong Li-Hua,Zhong Zhi-Jing,Li Wu-Hu.Synergistic Effect of the Oxidation of Formic Acid at Polyaniline Electrodes Modified by Palladium Microparticles[J]. Acta Phys. -Chim. Sin., 1996,12(04): 346-352
85. Lin Xian-Jie,Xu Long-Jun.Study on the Active Mechanism of Substitution and Doping on Conductivity of Polyanilines[J]. Acta Phys. -Chim. Sin., 1996,12(02): 152-155
86. Cai Lin-Tao, Yao Shi-Bing, Zhou Shao-Min.Electrocatalytic Oxidation of Ascorbic Acid at Polyaniline Modified Electrode and the Effects of the Magnetic Field[J]. Acta Phys. -Chim. Sin., 1995,11(02): 185-188
87. Zhong Qi-Ling, Wu Wen, Li Wu-Hu, Tian Zhong-Qun.Interaction between Palladium Microparticles and Polyaniline in Electrocatalytic Process for Oxidation of Formic Acid[J]. Acta Phys. -Chim. Sin., 1994,10(09): 813-817
88. Kan Jin-Qing; Mu Shao-Lin.The Study of Properties for the Polyaniline Uricase Electrode[J]. Acta Phys. -Chim. Sin., 1993,9(03): 345-350
89. Chen Yan-Zhen; Gu Zhi-Jun; Tian Zhong-Qun.Photoelectrochemical Polymerization of Conducting Polymer Monomers[J]. Acta Phys. -Chim. Sin., 1993,9(02): 277-280
90. Zhang Sheng-Shui; Chou Wei-Hua; Liu Qing-Guo; Yang Lei-Ling.Impendance Analysis for the Interface of Polyaniline and PEO-LiClO4 Complex[J]. Acta Phys. -Chim. Sin., 1992,8(04): 515-518
91. Dong Shao-Jun; Song Fa-Yi.Electrocatalytic Oxidation of Ascorbic Acid at Polyaniline Film Modified Glassy Carbon Electrodes[J]. Acta Phys. -Chim. Sin., 1992,8(01): 82-86
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