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Acta Phys. Chim. Sin.  2014, Vol. 30 Issue (7): 1267-1273    DOI: 10.3866/PKU.WHXB201405052
ELECTROCHEMISTRY AND NEW ENERGY     
Synthesis and Electrocatalytic Properties of Pt Nanoparticles on Nitrogen-Doped Reduced Graphene Oxide for Methanol Oxidation
WANG Li1, MA Jun-Hong1,2
1. College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, P. R. China;
2. Key Laboratory of Advanced Functional Materials, Autonomous Region, Institute of Applied Chemistry, Xinjiang University, Urumqi 830046, P. R. China
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Abstract  

Nitrogen-doped reduced graphene oxide materials (N-RGO) derived from pyrolysis of graphene oxide (GO)/polyaniline composites were used as a support for the immobilization of Pt nanoparticles. The morphologies and structures of N-RGO and Pt/N-RGO were comprehensively characterized by transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and Raman spectroscopy. The electrocatalytic activities of the as-prepared catalysts for CO stripping and methanol oxidation were investigated by cyclic voltammetry and chronoamperometry. The results showed that GO was reduced to multilayer graphene by thermal annealing accompanied with successful incorporation of N atoms into RGO. Moreover, the presence of the doped N atoms enhanced the surface defects and electrical conductivity of the RGO materials. Pt nanoparticles on N-RGO were more evenly dispersed, had better CO tolerance, and had higher activity/stability for methanol oxidation than those on RGO without N doping.



Key wordsPolyaniline      Reduced graphene oxide      Nitrogen-doped      Platinum electrocatalyst      Methanol oxidation     
Received: 22 March 2014      Published: 05 May 2014
MSC2000:  O646  
Fund:  

The project was supported by the Doctoral Scientific Research Starting Foundation of Xinjiang University, China (BS100110), Open Project Program of Xinjiang Laboratory of Advanced Functional Materials, China (XJDX0902-2010-06), and National Natural Science Foundation of China (21201146).

Corresponding Authors: MA Jun-Hong     E-mail: junhong@xju.edu.cn
Cite this article:

WANG Li, MA Jun-Hong. Synthesis and Electrocatalytic Properties of Pt Nanoparticles on Nitrogen-Doped Reduced Graphene Oxide for Methanol Oxidation. Acta Phys. Chim. Sin., 2014, 30(7): 1267-1273.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB201405052     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2014/V30/I7/1267

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