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Acta Phys. -Chim. Sin.  2014, Vol. 30 Issue (9): 1641-1649    DOI: 10.3866/PKU.WHXB201406172
ELECTROCHEMISTRY AND NEW ENERGY     
Preparation and Electrochemical Performances of Li1.2Mn0.54-xNi0.13Co0.13ZrxO2 Cathode Materials for Lithium-Ion Batteries
REN Xiang-Zhong, LIU Tao, SUN Ling-Na, ZHANG Pei-Xin
College of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518060, Guangdong Province, P. R. China
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Abstract  

To improve the cycling performance of lithium-rich cathode materials, Li1.2Mn0.54Ni0.13Co0.13O2 and Li1.2Mn0.54-xNi0.13Co0.13ZrxO2 (x=0.00, 0.01, 0.02, 0.03, and 0.06) were synthesized by a combustion method. The structure and morphology were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The electrochemical performances were examined by cyclic voltammetry (CV), electrochemical AC impedance spectroscopy, and galvanostatic charge-discharge cycling. The results indicate that all of the doped samples have a layer of α-NaFeO2. When charged and discharged at 0.1C and 1.0C (1.0C=180 mA·g-1) in the voltage range of 2.0-4.8 V, the initial discharge capacities of Li1.2Mn0.52Ni0.13Co0.13Zr0.02O2 were 280.3 and 206.4 mAh·g-1, respectively. Moreover, the capacity retention after 50 cycles improved from 73.2% to 88.9% at 1.0C at room temperature. Meanwhile, this system delivered a higher discharge capacity of 76.5 mAh·g-1 than that of the bare materials (15 mAh·g-1) at 5.0C after 50 cycles. Electrochemical performances of the doped samples were improved at a 2.0C rate at different temperatures (50, 25, and -10 ℃). Furthermore, compared with the undoped material, the specific discharge capacity increased by 61.1% at -10 ℃ after 50 cycles.



Key wordsCombustion method      Lithium-ion battery      Cathode material      Lithium-rich material      Doping     
Received: 18 April 2014      Published: 17 June 2014
MSC2000:  O646  
Fund:  

The project was supported by the National Natural Science Foundation of China (21000174), Shenzhen Strategic Emerging Industry Development Funds, China (JCYJ20120613163733279, JCYJ20130329113849606).

Corresponding Authors: REN Xiang-Zhong     E-mail: renxz@szu.edu.cn
Cite this article:

REN Xiang-Zhong, LIU Tao, SUN Ling-Na, ZHANG Pei-Xin. Preparation and Electrochemical Performances of Li1.2Mn0.54-xNi0.13Co0.13ZrxO2 Cathode Materials for Lithium-Ion Batteries. Acta Phys. -Chim. Sin., 2014, 30(9): 1641-1649.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB201406172     OR     http://www.whxb.pku.edu.cn/Y2014/V30/I9/1641

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