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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2014,Vol.30>> Issue(9)>> 1650-1658     doi: 10.3866/PKU.WHXB201406181         中文摘要
ELECTROCHEMISTRY AND NEW ENERGY
Fe3O4/Graphene Composites with a Porous 3D Network Structure Synthesized through Self-Assembly under Electrostatic Interactions as Anode Materials of High-Performance Li-Ion Batteries
LIU Jian-Hua1, LIU Bin-Hong2, LI Zhou-Peng2
1. Depatment of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, P. R. China;
2. Department of Chemical & Biological Engineering, Zhejiang University, Hangzhou 310027, P. R. China
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Fe3O4/graphene composites with a conductive, porous three-dimensional (3D) graphene network were synthesized through a facile method. In the preparation process, Fe(OH)3 colloid was formed in situ by adding FeCl3 solution to a boiling graphene oxide (GO) suspension, with Fe(OH)3/GO precipitated because of the electrostatic interaction between the two components. The precipitate was separated and added to a second GO suspension to achieve additional GO encapsulation. This self-assembled Fe(OH)3/GO precursor was then hydrothermally and heat treated, resulting in the formation of Fe3O4/graphene composites. X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and Raman spectroscopy results revealed that the Fe3O4/graphene composites possess a favorable 3D porous graphene network embedding 50- to 100-nm-sized Fe3O4 nanoparticles. The Fe3O4/graphene composites exhibit good electrochemical performance as an anode material for Li-ion batteries. The electrode composed of the Fe3O4/graphene composite delivered a capacity of 1390 mAh·g-1 for the first lithiation and retained a capacity of 819 mAh·g-1 after 50 cycles. The electrodes also exhibited good rate capability. The present results demonstrate that the electrochemical performance of the Fe3O4/graphene composite is highly sensitive to its preparation procedure and to the resulting nanostructure. Each of the four preparation procedures was experimentally shown to be important for achieving the final nanostructure and good electrochemical performance. A formation mechanism for the Fe3O4/graphene composite is also proposed.



Keywords: Fe3O4/graphene composite   Self-assembly   Anode material for Li-ion battery   Cyclic stability   Rate capability  
Received: 2014-03-27 Accepted: 2014-06-17 Publication Date (Web): 2014-06-18
Corresponding Authors: LIU Bin-Hong Email: liubh@zju.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (51271164, 21276229), Natural Science Foundation of Zhejiang Province, China (Z4110126), and Fund for the Key Science and Technology Innovation Team of Zhejiang Province, China (2010R50013).

Cite this article: LIU Jian-Hua, LIU Bin-Hong, LI Zhou-Peng. Fe3O4/Graphene Composites with a Porous 3D Network Structure Synthesized through Self-Assembly under Electrostatic Interactions as Anode Materials of High-Performance Li-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2014,30 (9): 1650-1658.    doi: 10.3866/PKU.WHXB201406181

(1) Tarascon, J. M.; Armand, M. Nature 2001, 414, 359. doi: 10.1038/35104644
(2) Armand, M.; Tarascon, J. M. Nature 2008, 451, 652. doi: 10.1038/451652a
(3) Goodenough, J. B.; Kim, Y. Chem. Mater. 2010, 22, 587. doi: 10.1021/cm901452z
(4) Gao, B.; Sinha, S.; Fleming, L.; Zhou, O. Adv. Mater. 2001, 13, 816. doi: 10.1002/1521-4095(200106)13:11<816::AIDADMA816>3.0.CO;2-P
(5) Lee, K. T.; Jung, Y. S.; Oh, S. M. J. Am. Chem. Soc. 2003, 125, 5652. doi: 10.1021/ja0345524
(6) Poizot, P.; Laruelle, S.; Grugeon, S.; Dupont, L.; Tarascon, J. M. Nature 2000, 407, 496. doi: 10.1038/35035045
(7) Park, C. M.; Kim, J. H.; Kim, H.; Sohn, H. J. Chem. Soc. Rev. 2010, 39, 3115. doi: 10.1039/b919877f
(8) Cabana, J.; Monconduit, L.; Larcher, D.; Palacin, M. R. Adv. Mater. 2010, 22, E170.
(9) Ji, L.W.; Lin, Z.; Alcoutlabi, M.; Zhang, X.W. Energy Environ. Sci. 2011, 4, 2683.
(10) Zhang, L. S.; Jiang, L. Y.; Yan, H. J.;Wang,W. D.;Wang,W.; Song,W. G.; Guo, Y. G.;Wan, L. J. J. Mater. Chem. 2010, 20, 5462. doi: 10.1039/c0jm00672f
(11) Chen, J.; Huang, K. L.; Liu, S. Q. Chin. J. Inorg. Chem. 2008, 24, 621. [陈洁, 黄可龙, 刘素琴. 无机化学学报, 2008, 24, 621.]
(12) Cheng, F.; Huang, K. L.; Liu, S. Q.; Fang, X. S.; Zhang, X. Acta Phys. -Chim. Sin. 2011, 27 (6), 1439. [程风, 黄可龙, 刘素琴, 房雪松, 张新. 物理化学学报, 2011, 27 (6), 1439.] doi: 10.3866/PKU.WHXB20110607
(13) Liang, J. F.; Zhou, J.; Guo, L. Science Foundation in China 2013, 21 (1), 59.
(14) Tang, Y. P.;Wang, S. M.; Hou, G. Y.; Zheng, G. Q. Battery Bimonthly 2014, 44 (1), 50. [唐谊平, 王诗明, 侯广亚, 郑国渠. 电池, 2014, 44 (1), 50.]
(15) Sun, J.; Zhao, D. L.; Liu, H.; Jing, L.; Chi,W. D.; Shen, Z. M. J. Function Materials 2012, 43 (15), 2027. [孙杰, 赵东林,刘辉, 景磊, 迟伟东, 沈曾民. 功能材料, 2012, 43 (15), 2027.]
(16) Ban, C. M.;Wu, Z. C.; Gillaspie, D. T.; Chen, L.; Yan, Y. F.; Blackburn, J. L.; Dillon, A. C. Adv. Mater. 2010, 22, E145.
(17) Ma, Y.; Zhang, C.; Ji, G.; Lee, J. Y. J. Mater. Chem. 2012, 22, 7845. doi: 10.1039/c2jm30422h
(18) Su, J.; Cao, M. H.; Ren, L., Hu, C.W. J. Phys. Chem. C 2011, 115, 14469.
(19) Lee, J. K.; Smith, K. B.; Hayner, C. M.; Kung, H. H. Chem. Commun. 2010, 46, 2025. doi: 10.1039/b919738a
(20) Chen, S. Q.;Wang, Y. J. Mater. Chem. 2010, 20, 9735. doi: 10.1039/c0jm01573c
(21) Wu, Z. S.; Zhou, G.; Yin, L. C.; Ren,W.; Li, F., Chen, H. M. Nano Energy 2012, 1, 107.
(22) Xu, C.; Xu, B.; Gu, Y.; Xiong, Z.; Sun, J.; Zhao, X. S. Energy Environ. Sci. 2013, 6, 1388. doi: 10.1039/c3ee23870a
(23) Chen, S., Zhu, J.W.;Wu, X. D.; Han, Q. F.;Wang, X. ACS Nano 2010, 4, 2822. doi: 10.1021/nn901311t
(24) Zhou, G.;Wang, D.W.; Li, F.; Zhang, L.; Li, N.;Wu, Z. S.; Wen, L.; Lu, G. Q.; Chen, H. M. Chem. Mater. 2010, 22, 5306. doi: 10.1021/cm101532x
(25) Zhang, M.; Lei, D. N.; Yin, X. M.; Chen, L. B.; Li, Q. H.;Wang, Y. G.;Wang, T. H. J. Mater. Chem. 2010, 20, 5538. doi: 10.1039/c0jm00638f
(26) Behera, S. K. Chem. Commun. 2011, 47, 10371. doi: 10.1039/c1cc13218k
(27) Li, B. J.; Cao, H. Q.; Shao, J.; Qu, M. Z.;Warner, J. H. J. Mater. Chem. 2011, 21, 5069. doi: 10.1039/c0jm03717f
(28) Chen, Y.; Song, B. H.; Tang, X. S.; Lu, L.; Xu, J. M. J. Mater. Chem. 2012, 22, 17656. doi: 10.1039/c2jm32057f
(29) Zhu, X.; Zhu, Y.; Murali, S.; Stroller, M. D.; Ruoff, R. S. ACS Nano 2011, 5, 3333. doi: 10.1021/nn200493r
(30) Zai, J. T .; Yu, C.; Zou, Q.; Tao, L. Q.;Wang, K. X.; Han, Q. Y.; Li, B.; Xiao, Y. L.; Qian, X. F.; Qi, R. R. RSC Adv. 2012, 2, 4397. doi: 10.1039/c2ra20319g
(31) Fan, Z.; Yan, J.;Wei, T.; Zhi, L.; Ning, G.; Li, T.;Wei, F. Adv. Func. Mater. 2011, 11, 2905.
(32) Zhou, J.; Song, H.; Ma, L.; Chen, X. RSC Adv. 2011, 1, 782. doi: 10.1039/c1ra00402f
(33) Xu, Y.; Sheng, K.; Li, C.; Shi, G. ACS Nano 2010, 4, 4324. doi: 10.1021/nn101187z
(34) Yang, S.; Feng, X.; Ivanovici, S.; Mullen, K. Angew. Chem. Int. Edit. 2010, 49, 8408. doi: 10.1002/anie.201003485
(35) Wei,W.; Yang, S.; Zhou, H.; Lieberwirth, I.; Feng, X.; Mullen, K. Adv. Mater. 2013, 25, 2909. doi: 10.1002/adma.v25.21
(36) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80, 1339. doi: 10.1021/ja01539a017
(37) Armelao, L.; Bertoncello, R.; Crociani, L.; Depaoli, G.; Granozzi, G.; Tondello, E.; Bettinelli, M. J. Mater. Chem. 1995, 5, 79. doi: 10.1039/jm9950500079
(38) Qu, J.; Yin, Y. X.;Wang, Y. Q.; Yan, Y.; Guo, Y. G.; Song,W. G. ACS Appl. Mater. Interfaces 2013, 5, 3932.
(39) Anderson, M. A.; Rubin, A. J. Adsorption of Inorganics at Solid-Liquid Interfaces; Ann Arbor Science Publishers, Inc.: Ann Arbor, USA, 1981.
(40) Wang, T. Q.;Wang, X. L.; Lu, Y.; Xiong, Q. Q.; Zhao, X. Y.; Cai, J. B.; Huang, S.; Gu, C. D.; Tu, J. P. RSC Adv. 2014, 4, 322. doi: 10.1039/c3ra45268a

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61. SU Zhao-Hui; CHEN Qi-Yuan; LI Jie; LIU Shi-Jun.Preparation and Characterization of Mesoporous Silicon Dioxide Doped with Tungsten[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1760-1764
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63. SUN Wei; YANG Mao-Xia; ZHONG Jiang-Hua; JIAO Kui.Electrochemical Behaviors of Brilliant Cresyl Blue on DNA Modified Gold Electrode[J]. Acta Phys. -Chim. Sin., 2007,23(04): 499-502
64. GAO Li-Ning;LU Feng-Ting;HU Jing; FANG; Yu.Progress in the Studies of Fluorescent Film Sensors[J]. Acta Phys. -Chim. Sin., 2007,23(02): 274-284
65. YANG Zhao-Hui;ZHANG Mao-Feng;CAO Wei-Xiao.Self-assembly Films of Poly(4-diazosulfonate Styrene-co-4-vinylpyridine) with Polyaniline and Their Photoelectric Conversion Properties[J]. Acta Phys. -Chim. Sin., 2007,23(01): 1-5
66. YU Zhi- Hui;TIAN Mi;JIAO Qing-Ying;XIA Ding- Guo.Self-assembling Nanobimetallic Particles of Au-Pt on Glassy Carbon Electrode[J]. Acta Phys. -Chim. Sin., 2006,22(08): 1015-1020
67. DIAO Yu-Xia;ROHDE Dirk;WAN Li-Jun.Ordered Self-assembled Monolayers of β-dicarbonyl Derivatives Studied by STM[J]. Acta Phys. -Chim. Sin., 2006,22(06): 691-695
68. XU Meng-Qing; ZUO Xiao-Xi; LI Wei-Shan; ZHOU Hao-Jie; LIU Jian-Sheng; YUAN Zhong-Zhi.Effect of Butyl Sultone on the Li-ion Battery Performance and Interface of Graphite Electrode[J]. Acta Phys. -Chim. Sin., 2006,22(03): 335-340
69. ZHU Jian-Hua; SHI Jin-Xia; LI Heng; HE Ping-Sheng.Self-assembling of Microsphere through Template[J]. Acta Phys. -Chim. Sin., 2006,22(03): 350-354
70. GAN Zhi-ping; GUAN Jian-guo.Chemical Self-assembly Route to Fabricate Hollow Barium Ferrite Submicrospheres[J]. Acta Phys. -Chim. Sin., 2006,22(02): 189-192
71. SHI Jian-zhen; FANG Jing-huai; MU Ren-wang; LI Ya-li.Preparation of Au Core-Ag Shell Nanoparticles Film and Its SERS Activity Study[J]. Acta Phys. -Chim. Sin., 2006,22(02): 135-140
72. ZHAO Jian-wei; KAN Rong-rong; ZHANG Yan; CHEN Hong-yuan.Applications of Scanning Probe Microscopy in Nanolithography on Alkanethiol Self-assembled Monolayers[J]. Acta Phys. -Chim. Sin., 2006,22(01): 124-130
73. DENG Xiang-Hui;KAN Xian-Wen;YU Yan;ZHANG Wen-Zhi;LIU Hong-Ying;FANG Bin.Electrochemical and Catalytic Properties of Ferrocene/L-cysteine Modified Electrode[J]. Acta Phys. -Chim. Sin., 2005,21(12): 1399-1402
74. ZHOU Xiao-shun; XU Xiaomi; ZHONG Hui-ping; LONG La-sheng; HUANG Rong-bin; XIE Zhao-xiong; ZHENG Lan-sun; MAO Bing-wei.Adsorption of Metal-Organic Complex Molecule on Au(111) Surface[J]. Acta Phys. -Chim. Sin., 2005,21(09): 949-951
75. AN Shi-yan; XU Shan-dong; ZENG Qing-dao; TAN Zhong-yin; WANG Chen; WAN Li-jun; BAI Chun-li.The Self-assembly Structure of Pyrazine Derivative on Highly Oriented Pyrolytic Graphite[J]. Acta Phys. -Chim. Sin., 2005,21(08): 925-928
76. MA Hui-ru; GUAN Jian-guo; LU Guo-jun; YUAN Run-zhang.The Preparation and Characterization of PAn-PEG-PAn Rod-coil Triblock Copolymers[J]. Acta Phys. -Chim. Sin., 2005,21(06): 627-631
77. CAO Jie-Ming; CHANG Xin; ZHENG Ming-Bo; HUANG Hai-Bin; JI Hong-Mei; LIU Jin-Song; KE Xing-Fei.Three-dimensional Silica Opals Templating for Synthesis of ZnS Photonic Crystals via Solvothermal Approach[J]. Acta Phys. -Chim. Sin., 2005,21(05): 560-564
78. DIAO Peng; MEI Gang; HOU Qun-Chao; YU Feng; XIANG Min; ZHANG Qi.Electrochemical Properties of Thiol Monolayers Prepared by Constant-Potential Assembly[J]. Acta Phys. -Chim. Sin., 2005,21(03): 291-295
79. Chen Zhi-Chun;Xu Shan-Hao;Lin Han-Feng;Yang Shao-Ming;Lin Xian-Fu.Glucose Oxidase Modified Electrode Fabricated by Layer-by-layer Molecular Deposition[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1267-1270
80. Li Di;Li Jing-Hong.Electrochemistry of Monolayer Protected Nanoclusters[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 982-988
81. Wang Chen;Fan Xiao-Lin;Liu Yu-Hong;Wan Li-Jun;Bai Chun-Li.Recent Progress of Electrical Conductivity of Single Molecule[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 1003-1009
82. Fu Chong-Gang;Su Chang-Hua;Shan Rui-Feng.Electrochemical Properties of L-cysteine Self-assembled Membrane Modified Gold Electrode[J]. Acta Phys. -Chim. Sin., 2004,20(02): 207-210
83. Li Yang-Mei;Jiang Xiu-Ming;Chen Zhi-Chun;Fu Shui-Yu;Lin Xian-Fu.Construction of Ordered Films of Horseradish Peroxidase through Lectin-glycogenReaction and Its Application in Enzyme Electrode[J]. Acta Phys. -Chim. Sin., 2004,20(02): 216-220
84. Li Yang-Mei;Chen Zhi-Chun;Lü De-Shui;Lin Xian-Fu.Topography and Electro-catalysis Property of Horseradish Peroxidase Assembly Active Films[J]. Acta Phys. -Chim. Sin., 2003,19(05): 474-477
85. Cao Lin-You;Diao Peng;Liu Zhong-Fan.Preparation of Au (core)-Cu (shell) Nanoparticles Assembly by Electrodeposition[J]. Acta Phys. -Chim. Sin., 2002,18(12): 1062-1067
86. Wang Ning;Ding Ke-Qiang;Tong Ru-Ting;Shao Hui-Bo.The Electrochemical Behavior of Self-assembled Monolayers of Schiff Base[J]. Acta Phys. -Chim. Sin., 2002,18(09): 846-849
87. Zhu Xiao-Yang.Organic Monolayers on Silicon:Microprinting, Micromachines, and Microarrrays[J]. Acta Phys. -Chim. Sin., 2002,18(09): 855-864
88. Ding Ke-Qiang;He Xiao-Ling;Wang Qing-Fei;Jiang Dian-Lu;Bai Juan;Tong Ru-Ting;Wang Xin-Kui.The AC Impedance Study of Calmodulin Modified on Au Electrode[J]. Acta Phys. -Chim. Sin., 2002,18(08): 741-745
89. Gu Guo-Tuan;Zhang Zhi-Jun;Dang Hong-Xin.Preparation and Tribological Behavior of Perfluoroctanoxamidepropyltrioxylmethyl Silane SAM[J]. Acta Phys. -Chim. Sin., 2002,18(07): 669-672
90. Li Zhi-Wei;Zhou Jing-Fang;Zhang Zhi-Jun;Dang Hong-Xin.Preparation and Self-assembly on Glasses of Surface-functional Polystyrene Nanoparticles[J]. Acta Phys. -Chim. Sin., 2002,18(06): 550-553
91. Zhang Sheng-Mao;Gao Yong-Jian;Zhang Zhi-Jun;Dang Hong-Xin;Liu Wei-Min;Xue Qun-Ji.Preparation and Characterization of Selfassembly Nanocomposite Thin Film[J]. Acta Phys. -Chim. Sin., 2002,18(05): 451-454
92. Xu Li-Na;Xu Hong-Fei;Zhou Kai-Chang;Xu Ai-Qun;Yue Zeng-Quan;Gu Ning;Zhang Hai-Qian;Liu Ju-Zheng;Chen Kun-Ji.Study on a New Activation Method for Initiating Electroless Plating on Alumina Powders Based on SAMs Bonded Palladium[J]. Acta Phys. -Chim. Sin., 2002,18(03): 284-288
93. Wang Sheng-Fu;Du Dan;Zou Qi-Chao.Electrochemical Properties of L-cysteine Self-assembled Monolayers Modified[J]. Acta Phys. -Chim. Sin., 2001,17(12): 1102-1106
94. Yu Hai-Hu;Wu Hong-Biao;Li Xiao-Fu;Zhu Yun-Zhou;Jiang De-Sheng.Self-assembly and Optical Properties of Silica Nanoparticulate Thin Films[J]. Acta Phys. -Chim. Sin., 2001,17(12): 1057-1061
95. Dong Dong;Zhang Sheng;Zhu Tao;Gan Liang-Bing;Liu Zhong-Fan.FullereneTerminated SAMs on Gold(111):Formation and Characterization[J]. Acta Phys. -Chim. Sin., 2001,17(11): 978-981
96. Li Dong-Sheng;Lu Gong-Xuan.Synthesis of Conductive Polymer/Semiconductor Nanocomposite Films by Layerbylayer Assembly Techniques[J]. Acta Phys. -Chim. Sin., 2001,17(03): 252-256
97. Ren Si-Li;Yang Sheng-Rong;Xue Qun-Ji.Perfluorodecanoic Acid Ultrathin Film on Single Crystal Silicon Substrate Coated with Polyethyleneimine[J]. Acta Phys. -Chim. Sin., 2001,17(02): 97-100
98. Chen Zhao-Hui, Ma Ying, Yao Jian-Nian.High-Efficlent Photochromic WO3-polymer/1,10-DAD Self-assembly Films Modified by Organic Molecules[J]. Acta Phys. -Chim. Sin., 2000,16(12): 1057-1061
99. Wang Zhen, Zhang Hao-Li, Li Hu-Lin.Self-assembly Behavior of Azobenzene Derivative β-Cyclodextrin Inclusion Complex on Gold[J]. Acta Phys. -Chim. Sin., 1999,15(07): 606-612
100. Zhang Hao-Li, Zhang Hua, Zhang Jin, Wu Bin, Liu Zhong-Fan, Li Hu-Lin.Fbrication and Structural Evaluation of Self-assembled Monolayer of Quinoline Derivative on Gold[J]. Acta Phys. -Chim. Sin., 1999,15(07): 657-661
101. Xu Guo-Hua, Higashitani Ko.Changes of the Surface Adhesion Forces during the Formation of OTS Self-Assembled Monolayer Investigated by AFM[J]. Acta Phys. -Chim. Sin., 1999,15(05): 458-461
102. Li Hai-Ying, Zhang Hao-Li, Zhang Jin, Liu Zhong-Fan.Preparation and Structural Characterization of Self-assembled Monolayers from a New Series of Mercapto Contained Azobenzene Derivatives[J]. Acta Phys. -Chim. Sin., 1999,15(03): 198-203
103. Fu Xiao-Yi, Mou Tao, Wang Jian, Zhu Tao, Liu Zhong-Fan.pH-Dependent Assembling of Gold Nanoparticles on p-Aminothiophenol Modified Gold Substrate[J]. Acta Phys. -Chim. Sin., 1998,14(11): 968-974
104. Shao Hui-Bo, Yu Hua-Zhong, Cheng Guang-Jun, Zhang Hao-Li, Liu Zhong-Fan.Study of the Formation Process of an Azobenzene Self-assembled Monolayer on Gold Surface[J]. Acta Phys. -Chim. Sin., 1998,14(09): 846-851
105. Shao Hui-Bo, Yu Hua-Zhong, Zhang Hao-Li, Luo Ying, Cheng Guang-Jun, Liu Zhong-Fan.State of the Tunneling Mechanism for Long Range Electron Transfer in Azobenzene Self-assembled Monolayers[J]. Acta Phys. -Chim. Sin., 1998,14(09): 772-777
106. Jiang Peng, Cheng Guang-Jun, Zhang Hao-Li, Cai Sheng-Min, Liu Zhong-Fan.Preparation of Atomically Flat Stripped-gold Substrate for Self-assembly[J]. Acta Phys. -Chim. Sin., 1998,14(07): 609-614
107. Hou Shi-Feng, Yang Ke-Sheng, Fang Hui-Qun, Chen Hong-Yuan.Electron Transfer Mechanism Characteristics of 2,3,5,6-tetrachloride-quinone Anchored on the Self-assembled Monolayers of Dithiol[J]. Acta Phys. -Chim. Sin., 1998,14(07): 640-644
108. Xiao Zhong-Dang, Huang Dan, Gu Jian-Hua, Lu Zu-Hong.X-ray Photoelectron Spectroscopy Study of the Deposition of TiO2 Thin Films on Self-assembly Monolayer[J]. Acta Phys. -Chim. Sin., 1998,14(01): 57-62
109. Zhang Jin,Zhao Jiang,Zhang Hao-Li,Liu Zhong-Fan,Li Hu-Lin.Influence of End Alkyl Chain Length on the Structure of Self-assembled Monolayer of Azobenzene on Gold[J]. Acta Phys. -Chim. Sin., 1997,13(10): 868-872
110. Li Jing-Hong,Cheng Guang-Jin,Dong Shao-Jun.Electrochemical Study of the Self-exchange between Viologen-thiol Self-assembled Monolayers and Alkanethiol on Gold Electrodes[J]. Acta Phys. -Chim. Sin., 1997,13(07): 655-658
111. Zhang Hao-Li,Zhang Jin,Zhao Jiang,Wang Yong-Qiang,She Jin,Yu Hua-Zhong,Li Hu-Lin.New Approach on the Synthesis of Functionalized Alkanethiols and the Structural Characterization of Their Self-Assembled Monolayers[J]. Acta Phys. -Chim. Sin., 1997,13(06): 515-524
112. He Hui-Xin,Li Chun-Zeng,Wang Jun-Mei,Zhang Hao-Li,Xu Xiao-Jie,Liu Zhong-Fan.Force Titration of Self-Assembled Monolayer Using Chemical Force Microscopy[J]. Acta Phys. -Chim. Sin., 1997,13(04): 293-296
113. Zhao Jian-Wei,Yu Hua-Zhong,Wang Yong-Qiang,Zhang Hao-Li,Liu Z.Structure-Dependent Electron Transfer Kinetics of Azobenzene Self-Assembled Monolayers on Gold[J]. Acta Phys. -Chim. Sin., 1997,13(01): 42-47
114. Wang Jian,Zhu Tao,Liu Zhong-Fan.Fabricating SERS-Active Substrate by Assembling of Au Nanoparticles[J]. Acta Phys. -Chim. Sin., 1996,12(11): 961-964
115. Zhao Jian-Wei,Yu Hua-Zhong,Wang Yong-Qiang,Tang Ming,Cai Sheng-Min,Liu Zhong-Fan.The Adsorption Kinetics and Characterization of Azobenzene Self-Assembled Monolayers on Gold[J]. Acta Phys. -Chim. Sin., 1996,12(07): 581-588
116. Tian Hong-Jian,Zhou Qing-Fu,Shen Shu-Yin,Xu Hui-Jun.The Studies of the Supramolecular System of Porphyrin-Phthalocyanine Formed by Molecular Self-assembly and Its Photoinduced Electron Transfer Processes[J]. Acta Phys. -Chim. Sin., 1996,12(01): 44-48
117. WANG Yun-He, QIN Yuan, YAO Man, WANG Xu-Dong, LI Shu-Ying, WANG Dong, CHEN Ting.Molecular Dynamics Simulation of Chiral Self-assembly Structure on HOPG Surface Driven by Hydrogen Bonds for BIC and HA Systems[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
118. HAO Wei-Ju, ZHANG Jun-Qi, SHANG Ya-Zhuo, XU Shou-Hong, LIU Hong-Lai.Preparation of Fluoresence Labeling pH-Sensitive Micelles for Controlled Drug Release[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
119. YE Juan, SUN Kai, TAO Min-Long, TU Yu-Bing, XIE Zheng-Bo, WANG Ya-Li, HAO Shao-Jie, XIAO Hua-Fang, WANG Jun-Zhong.Chiral feature of the achiral Copper Phthalocyanine on Bi(111) Surface[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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