Please wait a minute...
Acta Phys. Chim. Sin.  2014, Vol. 30 Issue (9): 1720-1726    DOI: 10.3866/PKU.WHXB201407021
CATALYSIS AND SURFACE SCIENCE     
Facile Synthesis of Graphene-Cobalt Hydroxide Nanocomposite and Application in Degradation of Acid Orange 7
LI Jie-Bing1, YI Yu1, SHI Peng-Hui2, WANG Qian1, LI Deng-Xin1, ASIF Hussain1, YANG Ming1,3
1. State Environmental Protection Engineering Center for Pollution Treatment and Control in Textile Industry, College of Environmental Science and Engineering, Donghua University, Shanghai 201620, P. R. China;
2. College of Environmental and Chemical Engineering, Shanghai University of Electric Power, Shanghai 200090, P. R. China;
3. Research Center for Analysis & Measurement, Donghua University, Shanghai 201620, P. R. China
Download:   PDF(907KB) Export: BibTeX | EndNote (RIS)      

Abstract  

In this study, a cobalt hydroxide-reduced graphene oxide (Co(OH)2/rGO) composite was synthesized by one-step self-assembly, and used as a catalyst in dye degradation. The catalyst was characterized using X-ray diffraction (XRD), Raman spectroscopy, transmission electron microscopy (TEM), energy-dispersive Xray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS). The catalyst had well-distributed Co(OH)2 nanoparticles on the reduced graphene oxide surface. The catalytic performance of this hybrid material was investigated for the activation of peroxymonosulfate (PMS), and used to degrade acid orange 7 (AO7) dye in aqueous solution. The experimental results showed that the composite had high catalytic activity in the degradation of AO7, and 100% decomposition was achieved in less than 12 min. Total organic carbon (TOC) experiments indicated a high degree of mineralization, suggesting excellent catalytic activity. Stability tests showed that the catalyst was stable in the degradation of AO7 over several runs. AO7 was completely degraded in 16 min in the third run.



Key wordsAdvanced oxidation      Peroxymonosulfate      Cobalt hydroxide      Graphene      Acid Orange 7     
Received: 14 April 2014      Published: 02 July 2014
MSC2000:  O643.32  
Fund:  

The project was supported by the Innovation Program of Shanghai Municipal Education Commission, China (12ZZ069), Shanghai Municipal Natural Science Foundation, China (11ZR1400400), Shanghai Tongji Gao Tingyao Environmental Science & Technology Development Foundation, China (STGEF), and State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, China (LK1203).

Corresponding Authors: LI Deng-Xin     E-mail: lidengxin@dhu.edu.cn
Cite this article:

LI Jie-Bing, YI Yu, SHI Peng-Hui, WANG Qian, LI Deng-Xin, ASIF Hussain, YANG Ming. Facile Synthesis of Graphene-Cobalt Hydroxide Nanocomposite and Application in Degradation of Acid Orange 7. Acta Phys. Chim. Sin., 2014, 30(9): 1720-1726.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB201407021     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2014/V30/I9/1720

(1) Neyens, E.; Baeyens, J. J. Hazard. Mater. 2003, 98 (1-3), 33.
(2) Andreozzi, R.; Caprio, V.; Insola, A.; Marotta, R. Catal. Today 1999, 53 (1), 51. doi: 10.1016/S0920-5861(99)00102-9
(3) Hu, L.; Yang, F.; Lu,W.; Hao, Y.; Yuan, H. Appl. Catal. B 2013, 134 -135 (2), 7.
(4) Melero, J. A.; Calleja, G.; Martínez, F.; Molina, R.; Pariente, M. I. Chem. Eng. J. 2007, 131 (1-3), 245.
(5) Chen, X.; Chen, J.; Qiao, X.;Wang, D.; Cai, X. Appl. Catal. B 2008, 80 (1-2), 116.
(6) Yao, Y.; Yang, Z.; Zhang, D.; Peng,W.; Sun, H.;Wang, S. Ind. Eng. Chem. Res. 2012, 51 (17), 6044. doi: 10.1021/ie300271p
(7) Anipsitakis, G. P.; Dionysiou, D. D. Environ. Sci. Technol. 2004, 38 (13), 3705. doi: 10.1021/es035121o
(8) Chan, K. H.; Chu,W. Water Res. 2009, 43 (9), 2513. doi: 10.1016/j.watres.2009.02.029
(9) Anipsitakis, G. P.; Dionysiou, D. D. Environ. Sci. Technol. 2003, 37 (20), 4790. doi: 10.1021/es0263792
(10) Shi, P.; Dai, X.; Zheng, H.; Li, D.; Yao,W.; Hu, C. Chem. Eng. J. 2014, 240 (5), 264.
(11) Anipsitakis, G. P.; Stathatos, E.; Dionysiou, D. D. J. Phys. Chem. B 2005, 109 (27), 13052. doi: 10.1021/jp052166y
(12) Zhang, Z.; Edwards, J. O. Inorg. Chem. 1992, 31 (17), 3514. doi: 10.1021/ic00043a007
(13) Kim, J.; Edwards, J. O. Inorg. Chim. Acta 1995, 235 (1-2), 9.
(14) Muller, J. G.; Zheng, P.; Rokita, S. E.; Burrows, C. J. J. Am. Chem. Soc. 1996, 118 (10), 2320. doi: 10.1021/ja952518m
(15) Zhang,W.; Tay, H. L.; Lim, S. S.;Wang, Y.; Zhong, Z.; Xu, R. Appl. Catal. B 2010, 95 (1-2), 93.
(16) Shukla, P.;Wang, S.; Singh, K.; Ang, H. M.; Tadé, M. O. Appl. Catal. B 2010, 99 (1-2), 163. doi: 10.1016/j.apcatb.2010.06.013
(17) Shukla, P. R.;Wang, S.; Sun, H.; Ang, H. M.; Tadé, M. Appl. Catal. B 2010, 100 (3-4), 529.
(18) Shukla, P.; Sun, H.;Wang, S.; Ang, H. M.; Tadé, M. O. Catal. Today 2011, 175 (1), 380. doi: 10.1016/j.cattod.2011.03.005
(19) Shukla, P.; Sun, H.;Wang, S.; Ang, H. M.; Tadé, M. O. Sep. Purif. Technol. 2011, 77 (2), 230. doi: 10.1016/j.seppur.2010.12.011
(20) Shi, P.; Su, R.; Zhu, S.; Zhu, M.; Li, D.; Xu, S. J. Hazard. Mater. 2012, 229 -230 (30), 331.
(21) Shi, P.; Su, R.;Wan, F.; Zhu, M.; Li, D.; Xu, S. Appl. Catal. B 2012, 123 -124 (23), 265.
(22) Yang, Q. J.; Choi, H.; Dionysiou, D. D. Appl. Catal. B 2007, 74 (1-2), 170. doi: 10.1016/j.apcatb.2007.02.001
(23) Zhao, J.; Zou, Y.; Zou, X.; Bai, T.; Liu, Y.; Gao, R.;Wang, D.; Li, G. D. Nanoscale 2014, 6 (13), 7255. doi: 10.1039/c4nr00002a
(24) Hu, Z. A.; Xie, Y. L.;Wang, Y. X.; Xie, L. J.; Fu, G. R.; Jin, X. Q.; Zhang, Z. Y.; Yang, Y. Y.;Wu, H. Y. The Journal of Physical Chemistry C 2009, 113 (28), 12502.
(25) El-Batlouni, H.; El-Rassy, H.; Al-Ghoul, M. J. Phys. Chem. A 2008, 112 (34), 7755. doi: 10.1021/jp804569b
(26) Yao, Y.; Xu, C.; Miao, S.; Sun, H.;Wang, S. J. Colloid Interface Sci. 2013, 402 (15), 230.
(27) Gan, Y. P.; Qin, H. P.; Huang, H.; Tao, X. Y.; Fang, J.W.; Zhang, W. K. Acta Phys. -Chim. Sin. 2013, 29 (2), 403. [甘永平, 秦怀鹏, 黄辉, 陶新永, 方俊武, 张文魁. 物理化学学报, 2013, 29(2) 403.] doi: 10.3866/PKU.WHXB201211022
(28) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80 (6), 1339. doi: 10.1021/ja01539a017
(29) He, Y. S.; Bai, D.W.; Yang, X.; Chen, J.; Liao, X. Z.; Ma, Z. F. Electrochem. Commun. 2010, 12 (4), 570. doi: 10.1016/j.elecom.2010.02.002
(30) Gupta, V.; Kusahara, T.; Toyama, H.; Gupta, S.; Miura, N. Electrochem. Commun. 2007, 9 (9), 2315. doi: 10.1016/j.elecom.2007.06.041
(31) Salavati-Niasari, M.; Bazarganipour, M. Transition Met. Chem. 2009, 34 (6), 605. doi: 10.1007/s11243-009-9237-5
(32) Ferrari, A. C. Solid State Commun. 2007, 143 (1-2), 47.
(33) Tuinstra, F.; Koenig, J. L. The Journal of Chemical Physics 1970, 53, 1126. doi: 10.1063/1.1674108
(34) Ferrari, A.; Meyer, J.; Scardaci, V.; Casiraghi, C.; Lazzeri, M.; Mauri, F.; Piscanec, S.; Jiang, D.; Novoselov, K.; Roth, S. Phys. Rev. Lett. 2006, 97 (18), 187401. doi: 10.1103/PhysRevLett.97.187401
(35) Kaniyoor, A.; Baby, T. T.; Ramaprabhu, S. J. Mater. Chem. 2010, 20 (39), 8467. doi: 10.1039/c0jm01876g
(36) Ramesha, G. K.; Sampath, S. J. Phys. Chem. C 2009, 113 (19), 7985. doi: 10.1021/jp811377n
(37) Stankovich, S.; Dikin, D. A.; Piner, R. D.; Kohlhaas, K. A.; Kleinhammes, A.; Jia, Y.;Wu, Y.; Nguyen, S. T.; Ruoff, R. S. Carbon 2007, 45 (7), 1558. doi: 10.1016/j.carbon.2007.02.034
(38) Zsoldos, Z.; Guczi, L. The Journal of Physical Chemistry 1992, 96 (23), 9393. doi: 10.1021/j100202a061
(39) Khassin, A. A.; Yurieva, T. M.; Kaichev, V. V.; Bukhtiyarov, V. I.; Budneva, A. A.; Paukshtis, E. A.; Parmon, V. N. J. Mol. Catal. A: Chem. 2001, 175 (1-2), 189.
(40) Perera, S. D.; Mariano, R. G.; Vu, K.; Nour, N.; Seitz, O.; Chabal, Y.; Balkus, K. J. ACS Catalysis 2012, 2 (6), 949. doi: 10.1021/cs200621c
(41) Li, D.; Muller, M. B.; Gilje, S.; Kaner, R. B.;Wallace, G. G. Nat. Nano 2008, 3 (2), 101.
(42) Sun, H.; Liu, S.; Zhou, G.; Ang, H. M.; Tadé, M. O.;Wang, S. ACS Applied Materials & Interfaces 2012, 4 (10), 5466. doi: 10.1021/am301372d
(43) Kusic, H.; Koprivanac, N.; Srsan, L. J. Photochem. Photobiol. A: Chem. 2006, 181 (2-3), 195.
(44) Sun, H.; Liang, H.; Zhou, G.;Wang, S. J. Colloid Interface Sci. 2013, 394 (1), 394.

[1] WANG Hai-Yan, SHI Gao-Quan. Layered Double Hydroxide/Graphene Composites and Their Applications for Energy Storage and Conversion[J]. Acta Phys. Chim. Sin., 2018, 34(1): 22-35.
[2] QIAN Hui-Hui, HAN Xiao, ZHAO Yan, SU Yu-Qin. Flexible Pd@PANI/rGO Paper Anode for Methanol Fuel Cells[J]. Acta Phys. Chim. Sin., 2017, 33(9): 1822-1827.
[3] DU Wei-Shi, Lü Yao-Kang, CAI Zhi-Wei, ZHANG Cheng. Flexible All-Solid-State Supercapacitor Based on Three-Dimensional Porous Graphene/Titanium-Containing Copolymer Composite Film[J]. Acta Phys. Chim. Sin., 2017, 33(9): 1828-1837.
[4] TIAN Ai-Hua, WEI Wei, QU Peng, XIA Qiu-Ping, SHEN Qi. One-Step Synthesis of SnS2 Nanoflower/Graphene Nanocomposites with Enhanced Lithium Ion Storage Performance[J]. Acta Phys. Chim. Sin., 2017, 33(8): 1621-1627.
[5] YANG Yi, LUO Lai-Ming, CHEN Di, LIU Hong-Ming, ZHANG Rong-Hua, DAI Zhong-Xu, ZHOU Xin-Wen. Synthesis and Electrocatalytic Properties of PtPd Nanocatalysts Supported on Graphene for Methanol Oxidation[J]. Acta Phys. Chim. Sin., 2017, 33(8): 1628-1634.
[6] WANG Lei, YU Fei, MA Jie. Design and Construction of Graphene-Based Electrode Materials for Capacitive Deionization[J]. Acta Phys. Chim. Sin., 2017, 33(7): 1338-1353.
[7] WANG Mei-Song, ZOU Pei-Pei, HUANG Yan-Li, WANG Yuan-Yuan, DAI Li-Yi. Three-Dimensional Graphene-Based Pt-Cu Nanoparticles-Containing Composite as Highly Active and Recyclable Catalyst[J]. Acta Phys. Chim. Sin., 2017, 33(6): 1230-1235.
[8] YANG Shao-Bin, LI Si-Nan, SHEN Ding, TANG Shu-Wei, SUN Wen, CHEN Yue-Hui. First-Principles Study of Na Storage in Bilayer Graphene with Double Vacancy Defects[J]. Acta Phys. Chim. Sin., 2017, 33(3): 520-529.
[9] LI Yi-Ming, CHEN Xiao, LIU Xiao-Jun, LI Wen-You, HE Yun-Qiu. Electrochemical Reduction of Graphene Oxide on ZnO Substrate and Its Photoelectric Properties[J]. Acta Phys. Chim. Sin., 2017, 33(3): 554-562.
[10] BAI Xue-Jun, HOU Min, LIU Chan, WANG Biao, CAO Hui, WANG Dong. 3D SnO2/Graphene Hydrogel Anode Material for Lithium-Ion Battery[J]. Acta Phys. Chim. Sin., 2017, 33(2): 377-385.
[11] CAO Pengfei, HU Yang, ZHANG Youwei, PENG Jing, ZHAI Maolin. Radiation Induced Synthesis of Amorphous Molybdenum Sulfide/Reduced Graphene Oxide Nanocomposites for Efficient Hydrogen Evolution Reaction[J]. Acta Phys. Chim. Sin., 2017, 33(12): 2542-2549.
[12] QUAN Quan, XIE Shun-Ji, WANG Ye, XU Yi-Jun. Photoelectrochemical Reduction of CO2 Over Graphene-Based Composites:Basic Principle,Recent Progress,and Future Perspective[J]. Acta Phys. Chim. Sin., 2017, 33(12): 2404-2423.
[13] ZHANG Yun-Long, ZHANG Yu-Zhi, SONG Li-Xin, GUO Yun-Feng, WU Ling-Nan, ZHANG Tao. Synthesis and Photocatalytic Performance of Ink Slab-Like ZnO/Graphene Composites[J]. Acta Phys. Chim. Sin., 2017, 33(11): 2284-2292.
[14] WANG Xu-Chun, LI Jin-Ze, LI Guang-Yong, WANG Jin, ZHANG Xue-Tong, GUO Qiang. Fabrication and Performance of Various Aerogel Microspheres[J]. Acta Phys. Chim. Sin., 2017, 33(11): 2141-2152.
[15] ZENG Xiang-Dong, ZHAO Xiao-Yu, WEI Hui-Ge, WANG Yan-Fei, TANG Na, SHA Zuo-Liang. Specific Capacitance and Supercapacitive Properties of Polyaniline-Reduced Graphene Oxide Composite[J]. Acta Phys. Chim. Sin., 2017, 33(10): 2035-2041.