非晶态镍硼酸盐结构的EXAFS研究

doi:10.3866/PKU.WHXB201409251

Abstract

Abstract:

In this work, two amorphous hydrated nickel borates were synthesized with nickel chloride hexahydrate and borax as reactants at mole ratios of 1:2 and 1:8, respectively. The chemical compositions of these nickel borates were determined to be NiO·0.8B₂O₃·4.5H₂O and NiO·B₂O₃·3H₂O through thermogravimetryderivative thermogravimetry (TG-DTG) and chemical analysis, in which the main anions were determined to be B₃O₃(OH)₅^2- and B₂O(OH)₆^2-, respectively, by Raman spectroscopy. The local structure of these samples was studied by synchrotron radiation extended X-ray absorption fine structure (EXAFS). Based on the processing and fitting of the EXAFS experimental data, the neighboring coordination atoms type, the interatomic distances, and the atom-pair numbers of Ni were determined. The fitting results of the amorphous nickel borate show that the local structure around the Ni atom has a similar structure to that of the Ni₃B₂O₆ crystal. The neighboring coordination atoms of Ni in these amorphous nickel borates are O, B, and Ni. For NiO·0.8B₂O₃·4.5H₂O, the interatomic distances for Ni―O, Ni―B, and Ni―Ni are 0.208, 0.263, and 0.311 nm, and the atom-pair numbers are 5.7, 3.8, and 3.8, respectively. The interatomic distances of NiO·B₂O₃·3H₂O are 0.207, 0.262, and 0.310 nm, and the atom-pair numbers are 6.0, 4.0, and 4.0, respectively. The first shells of Ni²⁺ in NiO·0.8B₂O₃·4.5H₂O and NiO·B₂O₃·3H₂O are octahedral with six oxygen atoms.

Key words: Nickel borate, Nickel hydroxide, Extended X-ray absorption fine structure, Local structure, Coordination atom

MSC2000:

O641

LIU Hong-Yan, FANG Chun-Hui, FANG Yan, ZHOU Yong-Quan, ZHU Fa-Yan, GE Hai-Wen, YANG Zi-Xiang, TANG Yu-Ling. EXAFS Study of the Structure of Amorphous Nickel Borate[J].Acta Phys. -Chim. Sin., 2014, 30(11): 1979-1986.

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EXAFS Study of the Structure of Amorphous Nickel Borate

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