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Acta Phys. Chim. Sin.  2014, Vol. 30 Issue (12): 2307-2314    DOI: 10.3866/PKU.WHXB201410142
Adsorption Properties of Ordered Mesoporous Silica for Butyraldehyde
HUANG Tian-Hui1, ZHAO Yu-Juan2, TIAN Zhao-Fu1, LI Xiao-Lan1, LIU Qian1, ZHAO Dong-Yuan2
1. Technology Centre, China Tobacco Guangxi Industrial Incorporation, Nanning 530001, P. R. China;
2. Department of Chemistry, Fudan University, Shanghai 200433, P. R. China
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Ordered mesoporous silica materials SBA-15, MCM-41, SBA-16, KIT-6 with different pore sizes and properties were prepared. Several SBA-15 materials were synthesized with different pore diameters by changing the hydrothermal temperature. The materials produced were characterized using small-angle X-ray scattering (SAXS), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and nitrogen adsorption/desorption. The adsorption isotherms of organic aldehyde were measured, using butyraldehyde as a model molecule. The results were compared with those for the adsorption capacity of Y-zeolite; they showed that the specific surface area originating from the mesopores was proportional to the amount of butyraldehyde adsorption. The adsorption isotherms agreed with Langmuir mode for monolayer adsorption. Mesoporous silica MCM-41 with the highest mesopore specific surface area showed the highest adsorbed amount of butyraldehyde (484 mg·g-1). The SBA-15 sample was selected for the fabrication of cigarette filters, and the results showed that SBA-15 significantly reduced the amount of Croton aldehyde released in cigarette smoke.

Key wordsMesoporous silica      Synthesis      Adsorption      Butyraldehyde      Croton aldehyde      Cigarette smoke     
Received: 08 July 2014      Published: 14 October 2014
MSC2000:  O647  

The project was supported by the Zhenlong-Fudan Joint Laboratory Project, China (20120208Y).

Corresponding Authors: ZHAO Dong-Yuan     E-mail:
Cite this article:

HUANG Tian-Hui, ZHAO Yu-Juan, TIAN Zhao-Fu, LI Xiao-Lan, LIU Qian, ZHAO Dong-Yuan. Adsorption Properties of Ordered Mesoporous Silica for Butyraldehyde. Acta Phys. Chim. Sin., 2014, 30(12): 2307-2314.

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