正极集流体对可充镁电池电化学性能的影响

doi:10.3866/PKU.WHXB201411173

Abstract

Abstract:

The effects of different cathode current collectors (stainless steel, nickel, copper, and titanium) on the electrochemical performance of rechargeable magnesiumbatteries were investigated. Chevrel phase Mo₆S₈ acted as the cathode, (PhMgCl)₂- AlCl₃/tetrahydrofuran (THF) (the second generation electrolyte) as the electrolyte, and magnesium as the anode. Constant current discharge-charge results indicated that the electrochemical polarization of the electrode on stainless steel was the smallest and its cycling stability was the best, followed by nickel, copper, and titanium. Microstructure analyses for the electrodes and current collectors before and after discharge-charge were analyzed to investigate the differing electrochemical performance. The electrolyte corroded the current collectors to differing degrees. The surfaces of the electrodes differed after coating the active material on different current collectors. The corrosion potentials of the current collectors decreased after loading the active material. This resulted in the current collectors being more susceptible to corrosion by the electrolyte.

Key words: Rechargeable magnesiumbattery, Cathode, Current collector, Electrochemical performance, Corrosion

MSC2000:

O646

SU Shuo-Jian, NULI Yan-Na, FEILURE Tuerxun, YANG Jun, WANG Jiu-Lin. Effects of Cathode Current Collectors on the Electrochemical Performance of Rechargeable Magnesium Batteries[J].Acta Phys. -Chim. Sin., 2015, 31(1): 111-120.

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Effects of Cathode Current Collectors on the Electrochemical Performance of Rechargeable Magnesium Batteries

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