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Acta Phys. -Chim. Sin.  2015, Vol. 31 Issue (1): 153-158    DOI: 10.3866/PKU.WHXB201411175
CATALYSIS AND SURFACE SCIENCE     
Preparation of NiS-Modified Cd1-xZnxS by a Hydrothermal Method and Its Use for the Efficient Photocatalytic H2 Evolution
LIN Cai-Fang, CHEN Xiao-Ping, CHEN Shu, SHANGGUAN Wen-Feng
Research Center for Combustion and Environment Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China
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Abstract  

NiS-modified Cd1-xZnxS has been prepared using a simple hydrothermal method. Notably, the H2 evolution rate of 0.5% (y, molar fraction) NiS/Cd0.3Zn0.7S(1840 μmol·h-1) was found to be 2.1- and 1.3-fold greater than those of Cd0.3Zn0.7S(884 μmol·h-1) and 0.5% (w, mass fraction) Pt (1390 μmol·h-1), respectively, when 0.35 mol·L-1 Na2SO3 and 0.25 mol·L-1 Na2Swere used as sacrificial agents. The apparent quantumefficiency of 0.5% (y) NiS/Cd0.3Zn0.7S at 420 nm was 36.8%. The characterization of this material by X-ray diffraction (XRD), ultraviolet-visible diffuse reflection spectroscopy (UV-Vis DRS), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) showed that the NiS particles provided the active sites required for H2 evolution and transferring the photo generated electrons, and therefore enhanced the photocatalytic activity of the catalyst towards H2 production.



Key wordsCd1-xZnxS      NiS      Hydrothermal method      Photocatalytic activity      Hydrogen production     
Received: 08 October 2014      Published: 17 November 2014
MSC2000:  O643  
Fund:  

The project was supported by the National High Technology Research and Development Programof China (863) (2012AA051501) and International Cooperation Project of Shanghai Municipal Science and Technology Commission, China (12160705700).

Corresponding Authors: SHANGGUAN Wen-Feng     E-mail: shangguan@sjtu.edu.cn
Cite this article:

LIN Cai-Fang, CHEN Xiao-Ping, CHEN Shu, SHANGGUAN Wen-Feng. Preparation of NiS-Modified Cd1-xZnxS by a Hydrothermal Method and Its Use for the Efficient Photocatalytic H2 Evolution. Acta Phys. -Chim. Sin., 2015, 31(1): 153-158.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB201411175     OR     http://www.whxb.pku.edu.cn/Y2015/V31/I1/153

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