Acta Phys. -Chim. Sin. ›› 2015, Vol. 31 ›› Issue (2): 285-290.doi: 10.3866/PKU.WHXB201412241

• ELECTROCHEMISTRY AND NEW ENERGY • Previous Articles     Next Articles

Synthesis of CH3NH3SrxPb(1-x)I3 with Less Pb Content and Its Application in All-Solid Thin Film Solar Cells

BAI Xiao-Gong1, SHI Yan-Tao1, WANG Kai1, DONG Qing-Shun1, XING Yu-Jin1, ZHANG Hong1, WANG Liang1, MA Ting-Li1,2   

  1. 1. State Key Laboratory of Fine Chemicals, College of Chemistry, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China;
    2. Graduate School of Life Science and Systems Engineering, Kyushu Institute of Technology, Kitakyushu 808-0196, Fukuoka, Japan
  • Received:2014-09-29 Revised:2014-12-23 Published:2015-01-26
  • Contact: SHI Yan-Tao, MA Ting-Li E-mail:shiyantao@dlut.edu.cn;tinglima@dlut.edu.cn
  • Supported by:

    The project was supported by the National Natural Science Foundation of China (51402036, 51273032, 91333104) and International Science & Technology Cooperation Program of China (2013DFA51000).

Abstract:

Hybrid organic-inorganic lead halide perovskite solar cells (PSCs) have recently undergone rapid progress and exhibit high photoelectric conversion efficiencies of up to 19.3%. As light-absorber in PSCs, the hybrid organic-inorganic lead halide perovskite cannot be used in large-scale applications because of its high Pb content. In this work, we replaced some Pb with Sr to synthesize a novel perovskite CH3NH3SrxPb(1-x)I3 and used it as a light-absorber in PSCs. Compared with CH3NH3PbI3, CH3NH3Sr0.3Pb0.7I3 is a better light-absorber but the corresponding photovoltaic performance in PSCs decreased obviously.

Key words: Perovskite solar cell, Less Pb, Sr replacing, CH3NH3SrxPb(1-x)I3

MSC2000: 

  • O644