Register
ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2015,Vol.31>> Issue(4)>> 676-684     doi: 10.3866/PKU.WHXB201501281         中文摘要
ELECTROCHEMISTRY AND NEW ENERGY
Preparation and Supercapacitive Performance of N, S Co-Doped Activated Carbon Materials
LI Zhao-Hui, LI Shi-Jiao, ZHOU Jin, ZHU Ting-Ting, SHEN Hong-Long, ZHUO Shu-Ping
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, Shandong Province, P. R. China
Full text: PDF (3243KB) Export: BibTeX | EndNote (RIS) Supporting Info

In this work, N, S co-doped microporous carbon materials were successfully prepared using human hair and sucrose as carbon precursors via a two-step method that combined hydrothermal treatment and post-KOH activation. The morphology, pore texture, and surface chemical properties of the activated carbon materials were investigated by scanning electron microscopy, transmission electron microscopy, N2 adsorption/desorption, X-ray photoelectron spectroscopy, energy dispersive spectroscopy, and Fourier transform infrared spectroscopy. The electrochemical capacitive behavior of the prepared carbons was systematically studied in 6 mol·L-1 KOH electrolyte. The maximum specific surface area of the prepared carbons was found to be 1849.4 m2·g-1 with a porosity that mainly consisted of micropores. Nitrogen and sulfur contents varied from 1.6% to 2.5% and from 0.2% to 0.5% (atomic fraction (x)), respectively. The synergistic-positive effect of N, O, and S-containing groups caused the prepared carbons to exhibit a large pseudo-capacitance. High specific capacitances of up to 200 F·g-1 at 0.2 A·g-1 were observed, response to an energy density of 6.9 Wh·kg-1. At a power density of 10000 W·kg-1, the energy density was found to be 4.1 Wh·kg-1. The present work highlights the significance of this new strategy to prepare N, S co-doped carbon materials from renewable biomass.



Keywords: Carbon materials   Supercapacitor   Human hair   Electrochemical property   Hydrothermal treatment  
Received: 2014-11-13 Accepted: 2015-01-23 Publication Date (Web): 2015-01-28
Corresponding Authors: ZHOU Jin, ZHUO Shu-Ping Email: zhoujsdut@gmail;zhuosp_cademic@yahoo.com

Fund: The project was supported by the National Natural Science Foundation of China (51302156).

Cite this article: LI Zhao-Hui, LI Shi-Jiao, ZHOU Jin, ZHU Ting-Ting, SHEN Hong-Long, ZHUO Shu-Ping. Preparation and Supercapacitive Performance of N, S Co-Doped Activated Carbon Materials[J]. Acta Phys. -Chim. Sin., 2015,31 (4): 676-684.    doi: 10.3866/PKU.WHXB201501281

(1) Horst, J. R.; Karl, F. K. Am. Chem. Soc. 1983, 7, 71.
(2) Ishida, M.; Jin, H. Ind. Eng. Chem. Res. 1996, 35, 2469. doi: 10.1021/ie950680s
(3) Fan, L. S.; Zeng, L.; Wang, W.; Luo, S.W. Energy Environ. Sci. 2012, 5, 7254. doi: 10.1039/c2ee03198a
(4) Adanez, J.; Abad, A.; Garcia-Labiano, F.; Gayan, P.; de Diego, L. F. Prog. Energy Combust. Sci. 2012, 38, 215. doi: 10.1016/j.pecs.2011.09.001
(5) Zhang, Y.; Doroodchi, E.; Moghtaderi, B. Energy Fuels 2012, 26, 287.
(6) Fang, H.; Haibin, L.; Zengli, Z. Int. J. Chem. Eng. 2009, 710515
(7) Lyngfelt, A.; Leckner, B.; Mattisson, T. Chem. Eng. Sci. 2001, 56, 3101. doi: 10.1016/S0009-2509(01)00007-0
(8) Johansson, M.; Mattisson, T.; Lyngfelt, A. J. Therm. Sci. 2006, 10, 93. doi: 10.2298/TSCI0603093J
(9) Saha, C.; Bhattacharya, S. Int. J. Chem. Eng. 2011, 36, 12048.
(10) Cho, P.; Mattisson, T.; Lyngfelt, A. Fuels 2004, 83, 1215. doi: 10.1016/j.fuel.2003.11.013
(11) Zhao, H. B.; Liu, L. M.; Wang, B.W.; Xu, D.; Jiang, L. L.; Zheng, C. G. Energy Fuels 2008, 22, 898. doi: 10.1021/ef7003859
(12) Dennis, J. S.; Scott, S. A. Fuels 2010, 89, 1623. doi: 10.1016/j.fuel.2009.08.019
(13) Lee, J. B.; Park, C. S.; Choi, S. I.; Song, Y.W.; Kim, Y. H.; Yang, H. S. J. Ind. Engin. Chem. 2005, 11, 96.
(14) Yang, J. B.; Cai, N. S.; Li, Z. S. Energy Fuels 2007, 21, 360.
(15) Guo, L.; Zhao, H. B.; Ma, J. C.; Mei, D. F.; Zheng, C. G. Chem. Eng. Technol. 2014, 37, 1211. doi: 10.1002/ceat.v37.7
(16) Zhu, X.; Li, K. Z.; Wei, Y. G.; Wang, H.; Sun, L. Y. Fuels 2014, 28, 754. doi: 10.1021/ef402203a
(17) Wang, C. P.; Cui, H. R.; Di, H. S.; Guo, Q. J.; Huang, F. Fuels 2014, 28, 4162. doi: 10.1021/ef500354w
(18) Azimi, G.; Leion, H.; Mattisson, T.; Rydén, M.; Snijkers, F.; Lyngfelt, A. Ind. Eng. Chem. Res. 2014, 53, 10358. doi: 10.1021/ie500994m
(19) Qin, W.; Wang, Y.; Dong, C.; Zhang, J.; Chen, Q.; Yang, Y. Energ. Appl. Surf. Sci. 2013, 282, 718. doi: 10.1016/j.apsusc.2013.06.041
(20) Wang, B.W.; Yan, R.; Zhao, H. B.; Zheng, Y.; Liu, Z. H.; Zheng, C. G. Energy Fuels 2011, 25, 3344. doi: 10.1021/ef2004078
(21) Qin, W.; Chen, Q.; Wang, Y.; Dong, C.; Zhang, J.; Li, W.; Yang, Y. Energ. Appl. Surf. Sci. 2013, 266, 350. doi: 10.1016/j.apsusc.2012.12.023
(22) Wang, S. Z.; Wang, G. X.; Jiang, F.; Luo, M.; Li, H. Y. Energy Environ. Sci. 2010, 3, 1353. doi: 10.1039/b926193a
(23) Liu, L.; Zachariah, M. R. Energy Fuels 2013, 27, 4977. doi: 10.1021/ef400748x
(24) Bao, J.; Li, Z.; Cai, N. Ind. Eng. Chem. Res. 2013, 52, 6119. doi: 10.1021/ie400237p
(25) Ksepko, E.; Siriwardane, R. V.; Tian, H. J.; Simonyi, T.; Sciazko, M. Energy Fuels 2012, 26, 2461. doi: 10.1021/ef201441k
(26) Moghtaderi, B.; Song, H. Energy Fuels 2010, 24, 5359.
(27) Yang, H. G.; Sun, C. H.; Qiao, S. Z.; Zou, J.; Liu, G.; Smith, S. C.; Cheng, H. M.; Lu, G. Q. Nature 2008, 453, 638. doi: 10.1038/nature06964
(28) Xie, X.W.; Li, Y.; Liu, Z. Q.; Haruta, M.; Shen, W. J. Nature 2009, 458, 746. doi: 10.1038/nature07877
(29) Zhou, X.; Xu, Q.; Lei, W.; Zhang, T.; Qi, X.; Liu, G.; Deng, K.; Yu, J. Small 2014, 10, 674. doi: 10.1002/smll.201301870
(30) Zhu, J.; Ng, K. Y. S.; Deng, D. Cryst. Growth Des. 2014, 14, 2811. doi: 10.1021/cg5000777
(31) Liu, X. H.; Zhang, J.; Wu, S. H.; Yang, D. J.; Liu, P.; Zhang, H. M.; Wang, S. R.; Yao, X. D.; Zhu, G. S.; Zhao, H. J. RSC Adv. 2012, 2, 6178. doi: 10.1039/c2ra20797d
(32) Guo, H.; Barnard, A. S. J. Colloid Interface Sci. 2012, 386, 315. doi: 10.1016/j.jcis.2012.07.011
(33) Cornell, R. M.; Schwertmann, U. The Iron Oxides: Structure, Properties, Reactions, Occurrence and Uses;Wiley-VCH: New York, USA, 2003.
(34) Dong, C. Q.; Liu, X. L.; Qin, W.; Lu, Q.; Wang, X. Q.; Shi, S. M.; Yang, Y. P. Appl. Surf. Sci. 2012, 258, 2562. doi: 10.1016/j.apsusc.2011.10.092
(35) Payne, M. C.; Teter, M. P.; Allan, D. C.; Arias, T. A.; Joannopoulos, J. D. Rev. Mod. Phys. 1992, 64, 1045. doi: 10.1103/RevModPhys.64.1045
(36) Perdew, J. P.; Chevary, J. A.; Vosko, S. H.; Jackson, K. A.; Pederson, M. R.; Singh, D. J.; Fiolhais, C. Phys. Rev. B: Condens. Matter Mater. Phys. 1992, 46, 6671. doi: 10.1103/PhysRevB.46.6671
(37) Leung, T. C.; Chan, C. T.; Harmon, B. N. Phys. Rev. B 1991, 44, 2923. doi: 10.1103/PhysRevB.44.2923
(38) Guo, H. B.; Barnard, A. S. Phys. Rev. B 2011, 83, 094112. doi: 10.1103/PhysRevB.83.094112
(39) Song, J. J.; Niu, X. Q.; Ling, L. X.; Wang, B. J. Fuel Process. Technol. 2013, 115, 26. doi: 10.1016/j.fuproc.2013.04.003
(40) Wong, K.; Zeng, Q. H.; Yu, A. B. J. Phys. Chem. C 2011, 115, 4656. doi: 10.1021/jp1108043
(41) Martin, G. J.; Cutting, R. S.; VauGhan, D. J.; Warren, M. C. Am. Mineral. 2009, 94, 1341. doi: 10.2138/am.2009.3029
(42) Sandratskii, L. M.; Uhl, M.; Kübler, J. J. Phys.: Condes. Matter 1996, 8, 983. doi: 10.1088/0953-8984/8/8/009
(43) White, J. A.; Bird, D. M. Phys. Rev. B: Condes. Matter Mater. Phys. 1994, 50, 4954. doi: 10.1103/PhysRevB.50.4954
(44) Govind, N.; Petersen, M.; Fitzgerald, G.; King-Smith, D.; Andzelm, J. Comput. Mater. Sci. 2003, 28, 250. doi: 10.1016/S0927-0256(03)00111-3
(45) Rohmann, C.; Metson, J. B.; Idriss, H. Phys. Chem. Chem. Phys. 2014, 16, 14287. doi: 10.1039/c4cp01373e
(46) Gilbert, B.; Frandsen, C.; Maxey, E. R.; Sherman, D. M. Phys. Rev. B 2009, 79, 035108. doi: 10.1103/PhysRevB.79.035108
(47) Al-Kuhaili, M. F.; Saleem, M.; Durrani, S. M. A. J. Alloy. Compd. 2012, 521, 178. doi: 10.1016/j.jallcom.2012.01.115
(48) Turkdogan, E. T.; Vinters, J. V. Metall. Trans. 1974, 5, 11.
(49) Dong, C. Q.; Sheng, S. H.; Qin, W.; Lu, Q.; Zhao, Y.; Wang, X. Q.; Zhang, J. J. Appl. Surf. Sci. 2011, 257, 8647. doi: 10.1016/j.apsusc.2011.05.042
(50) Wang, B.W.; Yan, R.; Lee, D. H.; Liang, D. T.; Zheng, Y.; Zhao, H. B.; Zheng, C. G. Energy Fuels 2008, 22, 1012. doi: 10.1021/ef7005673

1. LIU Zhao-Xin, LI Wei-Bin.Catalytic Activity and Deactivation of Toluene Combustion on Rod-Like Copper-Manganese Mixed Oxides[J]. Acta Phys. -Chim. Sin., 2016,32(7): 1795-1800
2. ZHOU Xiao, SUN Min-Qiang, WANG Geng-Chao.Synthesis and Supercapacitance Performance of Graphene-Supported π-Conjugated Polymer Nanocomposite Electrode Materials[J]. Acta Phys. -Chim. Sin., 2016,32(4): 975-982
3. WANG Yong-Fang, ZUO Song-Lin.Electrochemical Properties of Phosphorus-Containing Activated Carbon Electrodes on Electrical Double-Layer Capacitors[J]. Acta Phys. -Chim. Sin., 2016,32(2): 481-492
4. LIN You-Cheng, ZHONG Xin-Xian, HUANG Han-Xing, WANG Hong-Qiang, FENG Qi-Peng, LI Qing-Yu.Preparation and Application of Polyaniline Doped with Different Sulfonic Acids for Supercapacitor[J]. Acta Phys. -Chim. Sin., 2016,32(2): 474-480
5. LI Ya-Jie, NI Xing-Yuan, SHEN Jun, LIU Dong, LIU Nian-Ping, ZHOU Xiao-Wei .Preparation and Performance of Polypyrrole/Nitric Acid Activated Carbon Aerogel Nanocomposite Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2016,32(2): 493-502
6. HAYIERBIEK Kulisong, ZHAO Shu-Xian, YANG Yang, ZENG Han.Performance of Nitrogen-Doped Carbon Nanocomposite with Entrapped Enzyme-Based Fuel Cell[J]. Acta Phys. -Chim. Sin., 2015,31(9): 1715-1726
7. LI Yang, XIE Hua-Qing, LI Jing.Hydrothermal Synthesis of Al-Doped α-MnO2 Nanotubes and Their Electrochemical Performance for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2015,31(4): 693-699
8. YANG Shuo, XU Gui-Yin, HAN Jin-Peng, BING Huan, DOU Hui, ZHANG Xiao-Gang.Nitrogen-Doped Porous Carbon Derived from Dopamine-Modified Polypyrrole and Its Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2015,31(4): 685-692
9. WU Yan-Bo, BI Jun, WEI Bin-Bin.Preparation and Supercapacitor Properties of Double-Perovskite La2CoNiO6 Inorganic Nanofibers[J]. Acta Phys. -Chim. Sin., 2015,31(2): 315-321
10. LU Jian-Jian, YING Zong-Rong, LIU Xin-Dong, ZHAO Shuang-Sheng.Preparation of Cross-Linked Porous Carbon Nanofiber Networks by Electrospinning Method and Their Electrochemical Capacitive Behaviors[J]. Acta Phys. -Chim. Sin., 2015,31(11): 2099-2108
11. HAN Xiao-Mei, WU Yan-Bo, ZHAO Heng-Yan, BI Jun, WEI Bin-Bin.Preparation and Supercapacitor Properties of Carbon-Coated SnO2 Hollow Fibers[J]. Acta Phys. -Chim. Sin., 2015,31(11): 2220-2228
12. YI Chao, XIONG Xin-Bo, ZOU Zhi-Biao, LI Jun-Jie, HUANG Tuo, LI Bin, MA Jun, ZENG Xie-Rong.Fabrication of Nickel-Based Composite Film Electrode for Supercapacitors by a New Method of Anodization/GCD[J]. Acta Phys. -Chim. Sin., 2015,31(1): 99-104
13. WANG Li-Li, XING Rui-Guang, ZHANG Bang-Wen, HOU Yuan.Preparation and Electrochemical Properties of Functionalized Graphene/Polyaniline Composite Electrode Materials[J]. Acta Phys. -Chim. Sin., 2014,30(9): 1659-1666
14. HU Yu-Xiang, JIANG Chun-Xiang, FANG Liang, ZHENG Fen-Gang, DONG Wen, SU Xiao-Dong, SHEN Ming-Rong.Effect of HF Treatment on the Photoelectrochemical Properties of a Hematite Thin Film Photoanode for Water Splitting[J]. Acta Phys. -Chim. Sin., 2014,30(6): 1099-1106
15. ZHANG Xuan-Xuan, RAN Fen, FAN Hui-Li, KONG Ling-Bin, KANG Long.Hydrothermal Synthesis and Electrochemical Measurements of Interconnected Porous Carbon/MnO2 Composites[J]. Acta Phys. -Chim. Sin., 2014,30(5): 881-890
16. SUN Xian-Zhong, ZHANG Xiong, HUANG Bo, MA Yan-Wei.Effects of Separator on the Electrochemical Performance of Electrical Double-Layer Capacitor and Hybrid Battery-Supercapacitor[J]. Acta Phys. -Chim. Sin., 2014,30(3): 485-491
17. CHEN Chan-Juan, HU Zhong-Ai, HU Ying-Ying, LI Li, YANG Yu-Ying, AN Ning, LI Zhi-Min, WU Hong-Ying.SnO2/Graphite Nanosheet Composite Electrodes and Their Application in Supercapacitors[J]. Acta Phys. -Chim. Sin., 2014,30(12): 2256-2262
18. WANG Jian-De, PENG Tong-Jiang, SUN Hong-Juan, HOU Yun-Dan.Effect of the Hydrothermal Reaction Temperature on Three-Dimensional Reduced Graphene Oxide's Appearance, Structure and Super Capacitor Performance[J]. Acta Phys. -Chim. Sin., 2014,30(11): 2077-2084
19. TANG Jia-Yong, CAO Pei-Qi, FU Yan-Bao, LI Peng-Hui, MA Xiao-Hua.Synthesis of a Mesoporous Manganese Dioxide-Graphene Composite by a Simple Template-Free Strategy for High-Performance Supercapacitors[J]. Acta Phys. -Chim. Sin., 2014,30(10): 1876-1882
20. JIANG Chun-Xiang, HU Yu-Xiang, DONG Wen, ZHENG Fen-Gang, SU Xiao-Dong, FANG Liang, SHEN Ming-Rong.Bias-Determined Cu2O and Cu Growth on TiO2 Surface and Their Photoelectrochemical Properties[J]. Acta Phys. -Chim. Sin., 2014,30(10): 1867-1875
21. MA Guo-Fu, MU Jing-Jing, ZHANG Zhi-Guo, SUN Kan-Jun, PENG Hui, LEI Zi-Qiang.Preparation of Polypyrrole/Sodium Alginate Nanospheres and Their Application for High-Performance Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(11): 2385-2391
22. HUANG Bo, SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei.Organic Electrolytes for Activated Carbon-Based Supercapacitors with Flexible Package[J]. Acta Phys. -Chim. Sin., 2013,29(09): 1998-2004
23. LI Le, HE Yun-Qiu, CHU Xiao-Fei, LI Yi-Ming, SUN Fang-Fang, HUANG He-Zhou.Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K2Mn4O8 Nanocomposites as Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1681-1690
24. WU Hong-Ying, WANG Huan-Wen.Synthesis and Characterization of NiCo2O4 Nanoflower/Activated Carbon Fiber Composite and Its Supercapacitor Properties[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1501-1506
25. NA Yin-Na, LIU Min, SONG Chun-Shan, GUO Xin-Wen.Effect of Water on Biphenyl Methylation over Modified HZSM-5[J]. Acta Phys. -Chim. Sin., 2013,29(05): 1073-1079
26. HU Ying-Ying, HU Zhong-Ai, ZHANG Ya-Jun, LU Ai-Lian, XU Huan, ZHANG Zi-Yu, YANG Yu-Ying, LI Li, WU Hong-Ying.Synthesis and Electrochemical Characterization of RuO2·xH2O/Graphite Nanosheet Composite Array Electrodes for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(02): 305-310
27. LI Li-Xiang, TAO Jing, GENG Xin, AN Bai-Gang.Preparation and Supercapacitor Performance of Nitrogen-Doped Carbon Nanotubes from Polyaniline Modification[J]. Acta Phys. -Chim. Sin., 2013,29(01): 111-116
28. ZhONG Hao-Xiang, ZHAO Chun-Bao, LUO Hao, ZHANG Ling-Zhi.Novel Organosilicon Ionic Liquid Based Electrolytes for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2641-2647
29. SU Peng, GUO Hui-Lin, PENG San, NING Sheng-Ke.Preparation of Nitrogen-Doped Graphene and Its Supercapacitive Properties[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2745-2753
30. HUANG Wen, ZHAO Jin, KANG Qi, XU Kaichen, YU Zhen, WANG Jian, MA Yan-Wen, HUANG Wei.Preparation of Three-Dimensional Carbon Microtube/Carbon Nanotube Composites and Their Application in Supercapacitor[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2269-2275
31. WANG Yu, JIANG Jun-Cong, ZHU Yue-Xiang, XIE You-Chang.Applications of Monolayer-Dispersed Organic Compounds in the Preparation of Related Materials[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2327-2335
32. SHEN Bao-Shou, FENG Wang-Jun, LANG Jun-Wei, WANG Ru-Tao, TAI Zhi-Xin, YAN Xing-Bin.Nitric Acid Modification of Graphene Nanosheets Prepared by Arc- Discharge Method and Their Enhanced Electrochemical Properties[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1726-1732
33. WANG Yu, DONG Hui, GENG Liang, YU Gang, ZHU Yue-Xiang, XIE You-Chang.Facile Synthesis of Bimodal Mesoporous Carbon with Thin Pore Walls[J]. Acta Phys. -Chim. Sin., 2012,28(06): 1525-1532
34. CHE Qian, ZHANG Fang, ZHANG Xiao-Gang, LU Xiang-Jun, DING Bing, ZHU Jia-Jia.Preparation of Ordered Mesoporous Carbon/NiCo2O4 Electrode and Its Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2012,28(04): 837-842
35. HUANG Ye, LIU Yu-Yang, LI Wen-Zhang, CHEN Qi-Yuan.Effects of Calcination Temperature on Morphologies and Photoelectrochemical Properties of Anodized WO3 Nanoporous Films[J]. Acta Phys. -Chim. Sin., 2012,28(04): 865-870
36. LIU Dong, SHEN Jun, LI Ya-Jie, LIU Nian-Ping, LIU Bin.Pore Structures of Carbon Aerogels and Their Effects on Electrochemical Supercapacitor Performance[J]. Acta Phys. -Chim. Sin., 2012,28(04): 843-849
37. LIU Jia, GUO Li-Qin, ZHANG Xiao-Hong, RUAN Wen-Juan, ZHU Zhi-Ang.Synthesis, Characterization and Properties of Salen-Type Complexes[J]. Acta Phys. -Chim. Sin., 2012,28(02): 265-272
38. ZHU Jian-Bo, XU You-Long, WANG Jie, WANG Jing-Ping.Electropolymerization and Characterization of Fast Charge-Discharge PPy/F-SWNTs Composite Materials[J]. Acta Phys. -Chim. Sin., 2012,28(02): 373-380
39. SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei.Activated Carbon-Based Supercapacitors Using Li2SO4 Aqueous Electrolyte[J]. Acta Phys. -Chim. Sin., 2012,28(02): 367-372
40. GUO Pei-Zhi, JI Qian-Qian, ZHANG Li-Li, ZHAO Shan-Yu, ZHAO Xiu-Song.Preparation and Characterization of Peanut Shell-Based Microporous Carbons as Electrode Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2836-2840
41. XUE Rong, YAN Jing-Wang, TIAN Ying, YI Bao-Lian.Lanthanum Doped Manganese Dioxide/Carbon Nanotube Composite Electrodes for Electrochemical Supercapacitors[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2340-2346
42. LU Xiang-Jun, DOU Hui, YANG Su-Dong, HAO Liang, ZHANG Fang, ZHANG Xiao-Gang.Fabrication and Electrochemical Capacitive Behavior of Freestanding Graphene/Polyaniline Nanofibre Film[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2333-2339
43. LI Zhao, XU Ju-Liang, LI Xu-Yan, GUO Li-Fang, LI Jin, JIANG Yi-Ming.Preparation of Manganese Dioxide for Electrodes of Supercapacitors Based on Duplex Stainless Steel[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1424-1430
44. ZHOU Jin, LI Wen, XING Wei, ZHUO Shu-Ping.Capacitive Performance of Tunable Ordered Mesoporous Carbons in Organic and H2SO4 Electrolytes[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1431-1438
45. MI Juan, WANG Yu-Ting, GAO Peng-Cheng, LI Wen-Cui.Effects of Thermal Treatment on the Electrochemical Behavior of Manganese Dioxide[J]. Acta Phys. -Chim. Sin., 2011,27(04): 893-899
46. WANG Zhi-Ping, LUO Hong, GAO Li-Hua, WANG Ke-Zhi.Electrostatically Self-Assembled Films Prepared Using Bipolar Thiophene Hemicyanine and Prussian Blue[J]. Acta Phys. -Chim. Sin., 2011,27(03): 754-758
47. YU Li-Qiu, CHEN Shu-Li, CHANG Sha, LI Yun-Hu, GAO Yin-Yi, WANG Gui-Ling CAO Dian-Xue.Supercapacitance of NiCo2O4 Nanowire Arrays Grown on Nickel Foam[J]. Acta Phys. -Chim. Sin., 2011,27(03): 615-619
48. LI Wen, ZHOU Jin, XING Wei, ZHUO Shu-Ping, Lü Yi-Min.Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance[J]. Acta Phys. -Chim. Sin., 2011,27(03): 620-626
49. TIAN Ying, YAN Jing-Wang, XUE Rong, YI Bao-Lian.Influence of Electrolyte Concentration and Temperature on the Capacitance of Activated Carbon[J]. Acta Phys. -Chim. Sin., 2011,27(02): 479-485
50. ZHANG Hai-Jun, ZHANG Xiao-Gang, YUAN Chang-Zhou, GAO Bo, SUN Kang, FU Qing-Bin, LU Xiang-Jun, JIANG Jian-Chun.Preparation of Water Soluble Chitosan-Based Porous Carbon/NiO Composites and Their Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2011,27(02): 455-460
51. LUO Ying, CUI Xiao-Li, XIE Jing-Ying.Preparation and Visible Light Photoelectrochemical Response of TiO2-MoO3 Composite Nanotube Thin Films[J]. Acta Phys. -Chim. Sin., 2011,27(01): 135-142
52. ZHANG Fang, YUAN Chang-Zhou, ZHANG Xiao-Gang, ZHANG Luo-Jiang, XU Ke.5-Sulfosalicylic Acid-Assisted Hydrothermal Synthesis and Supercapacitive Properties of Co-Ni Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3175-3180
53. ZHANG Xiao-Bo, CHEN Ming-Hai, ZHANG Xiao-Gang, LI Qing-Wen.Preparation of Porous Carbon Nanofibers by Electrospinning and Their Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3169-3174
54. GAN Li-Hua, LIU Ming-Xian, CHEN Long-Wu, HU Jun, LIU Hong-Lai.Effect of Catalysts on the Morphologies of Carbon Materials Synthesized by an Emulsion Templating Method[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2666-2671
55. ZHOU Yan-Li, ZHI Jin-Fang, ZHANG Xiang-Fei, XU Mao-Tian.Comparative Study of Electrochemical Performances of Three Carbon-Based ElectrodeMaterials[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2405-2409
56. TIAN Ying, YAN Jing-Wang, LIU Xiao-Xue, XUE Rong, YI Bao-Lian.Electrochemical Capacitance of Composites with MnOx Loaded on the Surface of Activated Carbon Electrodes[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2151-2157
57. HU Yao-Juan, JIN Juan, ZHANG Hui, WU Ping, CAI Chen-Xin.Graphene: Synthesis, Functionalization and Applications in Chemistry[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2073-2086
58. LI Li-Min, LIU En-Hui, LI Jian, YANG Yan-Jing, SHEN Hai-Jie, HUANG Zheng-Zheng, XIANG Xiao-Xia.Polyaniline-Based Carbon for a Supercapacitor Electrode[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1521-1526
59. JI Qian-Qian, GUO Pei-Zhi, ZHAO Xiu-Song.Preparation of Chitosan-Based Porous Carbons and Their Application as Electrode Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1254-1258
60. MAO Dong-Sen, GUO Qiang-Sheng, MENG Tao, LU Guan-Zhong.Effect of Hydrothermal Treatment on the Acidity and Catalytic Performance of Nanosized HZSM-5 Zeolites for the Conversion of Methanol to Propene[J]. Acta Phys. -Chim. Sin., 2010,26(02): 338-344
61. ZANG Yang, HAO Xiao-Gang, WANG Zhong-De, ZHANG Zhong-Lin, LIU Shi-Bin.Copolymerization and Capacitive Performance of Composite Carbon Nanotubes/Polyaniline/Nickel Hexacyanoferrate Films[J]. Acta Phys. -Chim. Sin., 2010,26(02): 291-298
62. PANG Xu, MA Zheng-Qing, ZUO Lie.Sn Doped MnO2 Electrode Material for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2433-2437
63. FU Qing-Bin, GAO Bo, SU Ling-Hao, YUAN Chang-Zhou, LU Xiang-Jun, ZHANG Xiao-Gang.Preparation of Polypyrrole/Benzenesulfonic Functionalized Multi-Walled Carbon Nanotubes Induced by Hydrogen Bonding and Their Electrochemical Behavior[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2199-2204
64. SUN Zhe, LIU Kai-Yu, ZHANG Hai-Feng, LI Ao-Sheng, XU Xiao-Cun.Study on Meso-C/MnO2 Asymmetric Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1991-1997
65. JIANG Qi, ZHAO Xiao-Feng, HUANG Bin, DU Bing, ZHAO Yong.Effect of the Activated Carbon Reactivation on Its Electrochemical Capacitance[J]. Acta Phys. -Chim. Sin., 2009,25(04): 757-761
66. DU Bing, JIANG Qi, ZHAO Xiao-Feng, LIN Sun-Zhong, MU Pei-Shan, ZHAO Yong.Preparation of PPy/CNTs Composite Based on the Electrostatic Absorption Effect[J]. Acta Phys. -Chim. Sin., 2009,25(03): 513-518
67. CHEN Li; ZHANG Xiao-Gang; YUAN Chang-Zhou; CHEN Sheng-Yao.Electrochemical Properties of Poly(3,4-ethylenedioxythiophene)/Manganese Oxide Synthesized by Interfacial Polymerization[J]. Acta Phys. -Chim. Sin., 2009,25(02): 304-308
68. JIANG Qi; ZHANG Qian; DU Bing; ZHAO Xiao-Feng; ZHAO Yong.Preparation and Electrochemical Properties of CNTs-PANI Composite Material via Finite Field Polymerization[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1719-1723
69. CHEN Qiao-Lin; ZHOU Jian-Zhang; LIANG Jin-Ling; LIN Ling-Ling; LIN Zhong-Hua.Spectroscopic and Photoelectrochemical Properties of DNA/CdS Nanoparticle Composites[J]. Acta Phys. -Chim. Sin., 2008,24(05): 749-754
70. ZENG Wen-Wen; HUANG Ke-Long; YANG You-Ping; LIU Su-Qin; LIU Ren-Sheng.Solvothermal Synthesis and Capacitance Performance of Co3O4 with Different Morphologies[J]. Acta Phys. -Chim. Sin., 2008,24(02): 263-268
71. YANG Jing; LIU Ya-Fei; CHEN Xiao-Mei; HU Zhong-Hua; ZHAO Guo-Hua.Carbon Electrode Material with High Densities of Energy and Power[J]. Acta Phys. -Chim. Sin., 2008,24(01): 13-19
72. YANG Jian-Jun; HUANG Jun-Jie; JIANG Zhi-Yu.Supercapacitance of MnO2 Thin Film Electrodes Prepared Using Jet Printing Method[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1365-1369
73. ZHANG Ji-Fu; SANG Shang-Bin; WU Qiu-Mei; LIAO Yu-Gen.Preparation and Characterization of the Composite Alkaline Polymer Electrolyte Based on PVA-Bentonite-KOH-H2O[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1136-1140
74. WANG Jie; XU You-Long; SUN Xiao-Fei; XIAO Fang; MAO Sheng-Chun.Capacitance Properties of Porous Polypyrrole Thick Films Prepared Electrochemically by Multi-step Polymerization[J]. Acta Phys. -Chim. Sin., 2007,23(06): 877-882
75. WANG Jie;XU You-Long;CHEN Xi;DU Xian-Feng;LI Xi-Fei.Effect of Doping Ions on Electrochemical Capacitance Properties of Polypyrrole Films[J]. Acta Phys. -Chim. Sin., 2007,23(03): 299-304
76. WANG Guo-guang WANG Jian-ming MAO Wen-qu LIU Li-qing ZHANG Jian-qing CAO Chu-nan.Structure and Electrochemical Performance of LiNiyCo0.1-yMn1.9O4 Cathode Materials Prepared by a Precipitation Method[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1285-1290
77. WANG Wen; LIN Mei-juan; LING Qi-dan; ZHANG Wen-gong.Properties of Multi-functional Polymers Containing Terbium Complex[J]. Acta Phys. -Chim. Sin., 2005,21(08): 857-861
78. YANG Hong-Sheng; ZHOU Xiao; ZHANG Qing-Wu.Electrochemical Performances of Supercapacitor with Polyaniline Particles with Hierarchy as Active Electrode Material[J]. Acta Phys. -Chim. Sin., 2005,21(04): 414-418
79. Jiang Qi;Lu Xiao-Ying;Zhao Yong;Yu Zuo-Long.Effect of Microstructure’s Change on Electrochemical Capacitance of Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2004,20(05): 546-549
80. Liu Xian-Ming;Zhang Yi-He;Zhang Xiao-Gang;Fu Shao-Yun.The Supercapacitive Properties of Ni-Ru Oxide Composites[J]. Acta Phys. -Chim. Sin., 2004,20(04): 417-420
81. Deng Mei-Gen;Zhang Zhi-An;Hu Yong-Da;Wang Bin-Hua;Yang Bang-Chao.Effect of Activation and Surface Modification on the Properties of Carbon Nanotubes Supercapacitors[J]. Acta Phys. -Chim. Sin., 2004,20(04): 432-435
82. Ning Bin;Fan Lou-Zhen;Zheng Li-Ping;Cao Yong;Guo Zhi-Xin.Electrochemical Properties of Methanofullerenes[J]. Acta Phys. -Chim. Sin., 2003,19(10): 917-921
83. Zhuang Xin-Guo;Yang Yu-Sheng;Ji You-Ju;Yang Dong-Ping;Tang Zhi-Yuan.The Influence of Porous Structure of Activated Carbons Used as Supercapacitor Electrode Materials on Its Properties[J]. Acta Phys. -Chim. Sin., 2003,19(08): 689-694
84. Wang Xiao-Feng;Wang Da-Zhi;Liang Ji.Carbon Nanotube Capacitor Materials Loaded with Different Amounts of Ruthenium Oxide[J]. Acta Phys. -Chim. Sin., 2003,19(06): 509-513
85. Zhang Bao-Hong;Zhang Na.Research on Nanophase MnO2 for Electrochemical Supercapacitor[J]. Acta Phys. -Chim. Sin., 2003,19(03): 286-288
86. Dong Song-Tao;Li Xuan-Wen;Li Da-Dong;Shi Ya-Hua;Nie Hong;Kang Xiao-Hong.Study on the Formation of Mesopore during Hydrothermal Dealumination of Y Zeolite[J]. Acta Phys. -Chim. Sin., 2002,18(03): 201-206
87. Kong Yong;Mu Shao-Lin.Electrochemical Polymerization of Thionine and Properties of Polythionine[J]. Acta Phys. -Chim. Sin., 2001,17(04): 295-299
88. XIA Kai-Lun, JIAN Mu-Qiang, ZHANG Ying-Ying.Advances in Flexible Conductors Based on Nanocarbon Materials[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388 Email:whxb@pku.edu.cn
^ Top