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Acta Phys. Chim. Sin.  2015, Vol. 31 Issue (4): 693-699    DOI: 10.3866/PKU.WHXB201502021
Hydrothermal Synthesis of Al-Doped α-MnO2 Nanotubes and Their Electrochemical Performance for Supercapacitors
LI Yang, XIE Hua-Qing, LI Jing
School of Urban Development and Environmental Engineering, Shanghai Second Polytechnic University, Shanghai 201209, P. R. China
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α-MnO2 and Al-doped α-MnO2 were synthesized via a hydrothermal method. The morphologies, structures, and electrochemical performances of as-synthesized un-doped and doped α-MnO2 were studied. Scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) show that these un-doped and doped α-MnO2 are nanotube shaped. The band gaps of α-MnO2 are investigated by ultraviolet-visible absorption spectroscopy, which indicates that the band gap of α-MnO2 decreases upon Al doping. The electrochemical performances of un-doped and doped α-MnO2 as electrode materials for supercapacitors were measured by cyclic voltammetry (CV) and galvanostatical charge/discharge tests. The specific capacitances of un-doped and Al-doped α-MnO2 respectively reach 204.8 and 228.8 F·g-1under a current density of 50 mA·g-1. It was discovered that the electrochemical impedance of Al-doped α-MnO2 was decreased by Al doping analyzed using electrochemical impedance spectra (EIS), which provides a beneficial increase to its electrochemical specific capacitance. Enhanced specific capacitance and preferable cycling stability (up to 1000 cycles) for Al-doped α-MnO2 mean that these systems are favorable prospects for application in supercapacitors.

Key wordsα-MnO2      Al doping      Nanotube      Supercapacitor      Electrochemical capacitor     
Received: 09 September 2014      Published: 02 February 2015
MSC2000:  O646  

The project was supported by the Key Innovation Foundation of Shanghai Education Commission, China (13ZZ139), Key Discipline Construction (Materials Science) of Shanghai Second Polytechnic University, China (XXKPY1302), and Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning, China.

Corresponding Authors: LI Yang     E-mail:
Cite this article:

LI Yang, XIE Hua-Qing, LI Jing. Hydrothermal Synthesis of Al-Doped α-MnO2 Nanotubes and Their Electrochemical Performance for Supercapacitors. Acta Phys. Chim. Sin., 2015, 31(4): 693-699.

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(1) Yao, W.; Wang, J.; Li, H.; Lu, Y. J. Power Sources 2014, 247, 824. doi: 10.1016/j.jpowsour.2013.09.039
(2) Ghimbeu, C. M.; Malak-Polaczyk, A.; Frackowiak, E.; Vix- Guterl, C. J. Appl. Electrochem. 2014, 44, 123. doi: 10.1007/s10800-013-0614-6
(3) Zhu, G.; Deng, L.; Wang, J.; Kang, L.; Liu, Z. H. Colloids Surfaces A 2013, 434, 42. doi: 10.1016/j.colsurfa.2013.05.008
(4) Jiang, H.; Dai, Y.; Hu, Y.; Chen, W.; Li, C. ACS Sustain. Chem. Eng. 2014, 2, 70. doi: 10.1021/sc400313y
(5) Azhagan, M. V. K.; Vaishampayan, M. V.; Shelke, M. V. J. Mater. Chem. A 2014, 2, 2152. doi: 10.1039/C3TA14076H
(6) Zolfaghari, A.; Naderi, H. R.; Mortaheb, H. R. J. Electroanal. Chem. 2013, 697, 60. doi: 10.1016/j.jelechem.2013.03.012
(7) Yu, M.; Sun, H.; Sun, X.; Lu, F.; Wang, G.; Hu, T.; Qiu, H.; Lian, J. Int. J. Electrochem. Sci. 2013, 8, 2313.
(8) Li, L.; He, Y. Q.; Chu, X. F.; Li, Y. M.; Sun, F. F.; Huang, H. Z. Acta Phys. -Chim. Sin. 2013, 29, 1681. [李乐, 贺蕴秋, 储晓菲, 李一鸣, 孙芳芳, 黄河洲. 物理化学学报, 2013, 29, 1681.] doi: 10.3866/PKU.WHXB201305223
(9) Hashem, A. M.; Abuzeid, H. M.; Mikhailova, D.; Ehrenberg, H.; Mauger, A.; Julien, C. M. J. Mater. Sci. 2012, 47, 2479. doi: 10.1007/s10853-011-6071-x
(10) Wang, G.; Shao, G.; Du, J.; Zhang, Y.; Ma, Z. Mater. Chem. Phys. 2013, 138, 108. doi: 10.1016/j.matchemphys.2012.11.024
(11) Dubal, D. P.; Lokhande, C. D. Ceram. Int. 2013, 39, 415. doi: 10.1016/j.ceramint.2012.06.042
(12) Hashem, A. M.; Abuzeid, H. M.; Narayanan, N.; Ehrenberg, H.; Julien, C. M. Mater. Chem. Phys. 2011, 130, 33. doi: 10.1016/j.matchemphys.2011.04.074
(13) Ryu, W. H.; Han, D.W.; Kim, W. K.; Kwon, H. S. J. Nanopart. Res. 2011, 13, 4777. doi: 10.1007/s11051-011-0448-2
(14) Shanthi, S.; Ravi, S. Int. J. Chem. Tech. Res. 2014, 6, 2066.
(15) Wang, S.; Liu, Q.; Yu, J.; Zeng, J. Int. J. Electrochem. Sci. 2012, 7, 1242.
(16) Kunkalekar, R. K.; Salker, A. V. React. Kinet. Mech. Catal. 2012, 106, 395. doi: 10.1007/s11144-012-0443-3
(17) Hashem, A. M.; Abdel-Latif, A. M.; Abuzeid, H. M.; Abbas, H. M.; Ehrenberg, H.; Farag, R. S.; Mauger, A.; Julien, C. M. J. Alloy. Compd. 2011, 509, 9669. doi: 10.1016/j.jallcom.2011.07.075
(18) Malankar, H.; Umare, S. S.; Singh, K. Mater. Lett. 2009, 63, 2016. doi: 10.1016/j.matlet.2009.06.044
(19) Jung, K. N.; Riaz, A.; Lee, S. B.; Lim, T. H.; Park, S. J.; Song, R. H.; Yoon, S.; Shin, K. H.; Lee, J.W. J. Power Sources 2013, 244, 328. doi: 10.1016/j.jpowsour.2013.01.028
(20) Zhang, Y.; Liu, H.; Zhu, Z.; Wong, K.W.; Mi, R.; Mei, J.; Lau, W. M. Electrochim. Acta 2013, 108, 465. doi: 10.1016/j.electacta.2013.07.002
(21) Song, Z.; Liu, W.; Zhao, M.; Zhang, Y.; Liu, G.; Yu, C.; Qiu, J. J. Alloy. Compd. 2013, 560, 151. doi: 10.1016/j.jallcom.2013.01.117
(22) Wang, G. S.; He, S.; Luo, X.; Wen, B.; Lu, M. M.; Guo, L.; Cao, M. S. RSC Adv. 2013, 3, 18009. doi: 10.1039/c3ra42412j
(23) Zhou, M.; Zhang, X.; Wang, L.; Wei, J.; Zhu, K.; Feng, B. J. Nanosci. Nanotechnol. 2013, 13, 904. doi: 10.1166/jnn.2013.5958
(24) Shan, J.; Zhu, Y.; Zhang, S.; Zhu, T.; Rouvimov, S.; Tao, F. J. Phys. Chem. C 2013, 117, 8329. doi: 10.1021/jp4018103
(25) Wu, Y.; Lu, Y.; Song, C.; Ma, Z.; Xing, S.; Gao, Y. Catal. Today 2013, 201, 32. doi: 10.1016/j.cattod.2012.04.032
(26) Umek, P.; Gloter, A.; Pregelj, M.; Dominko, R.; Jagodic, M.; Jaglicic, Z.; Zimina, A.; Brzhezinskaya, M.; Potocnik, A.; Filipic, C.; Levstik, A.; Arcon, D. J. Phys. Chem. C 2009, 113, 14798. doi: 10.1021/jp9050319
(27) Sakai, N.; Ebina, Y.; Takada, K.; Sasaki, T. J. Phys. Chem. B 2005, 109, 9651. doi: 10.1021/jp0500485
(28) Kang, J. L.; Hirata, A. H.; Kang, L. J.; Zhang, X. M.; Hou, Y.; Chen, L. Y.; Li, C.; Fujita, T.; Atagi, K.; Chen, M.W. Angew. Chem. Int. Edit. 2013, 52, 1664. doi: 10.1002/anie.v52.6

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