ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2015,Vol.31>> Issue(4)>> 783-792     doi: 10.3866/PKU.WHXB201502062         中文摘要
Syntheses of ZnO Nano-Arrays and Spike-Shaped CuO/ZnO Heterostructure
LI Xiang-Qi1, FAN Qing-Fei1, LI Guang-Li1, HUANG Yao-Han1, GAO Zhao1, FAN Xi-Mei1, ZHANG Chao-Liang2, ZHOU Zuo-Wan1
1 Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, P. R. China;
2 State Key Laboratory of Oral Diseases, West China Hospital of Stomatology, Sichuan University, Chengdu 610031, P. R. China
Full text: PDF (1352KB) Export: BibTeX | EndNote (RIS)

A low-temperature hydrothermal route was applied to fabricate ZnO nano-arrays on fluorinated tin oxide (FTO)-coated glass substrates. The effects of the molar ratios of the precursor concentrations on the ZnO nano-arrays were studied with respect to morphology, optical properties, and growth mechanism. The results show that the length reduced with the increased molar ratios of precursor concentrations, and the diameter first increased then decreased. In general, the change of optical band gap followed the same trend as that for the change in diameter. When the molar ratio of precursor concentrations is 5:5, the optical band gap is 3.2 eV, which is similar to the theoretical value at room temperature. We propose that the optimal molar ratio of zinc nitrate (Zn(NO3)2) to hexamethylenetetramine (HMT, C6H12N4) is 5:5 for the preparation of ZnO nano-arrays. Spike-shaped CuO/ZnO nano-arrays were also successfully synthesized using a two-step solution-system method. Field emission scanning electron microscope (FE-SEM) results show that there were a large number of copper oxide (CuO) nano-particles (NPs) deposited onto the ZnO nano-array surfaces to form spike-shaped structures. The covered CuO NPs exhibited improved photocatalytic properties over pure ZnO nano-arrays under UV irradiation, and the possible photocatalytic mechanism of the CuO/ZnO nano-heterojunction was discussed in detail.

Keywords: ZnO nano-array   CuO/ZnO heterostructure   Hydrothermal method   Optical property   Molar ratio  
Received: 2014-12-15 Accepted: 2015-02-04 Publication Date (Web): 2015-02-06
Corresponding Authors: FAN Xi-Mei Email:

Fund: The project was supported by the High-Tech Research and Development Program of China (2009AA03Z427).

Cite this article: LI Xiang-Qi, FAN Qing-Fei, LI Guang-Li, HUANG Yao-Han, GAO Zhao, FAN Xi-Mei, ZHANG Chao-Liang, ZHOU Zuo-Wan. Syntheses of ZnO Nano-Arrays and Spike-Shaped CuO/ZnO Heterostructure[J]. Acta Phys. -Chim. Sin., 2015,31 (4): 783-792.    doi: 10.3866/PKU.WHXB201502062

(1) Zhang, C. H.; Wang, G. F.; Liu, M.; Feng, Y. H.; Zhang, Z. D.; Fang, B. Electrochim. Acta 2010, 55 (8), 2835. doi: 10.1016/j.electacta.2009.12.068
(2) Jiang, C. Y.; Sun, X.W.; Lo, G. Q.; Kwong, D. L. Appl. Phys. Lett. 2007, 90 (26), 263501. doi: 10.1063/1.2751588
(3) Zhang, Y. Z.; Liu, Y. P.; Wu, L. H.; Li, H.; Han, L. Z.; Wang, B. C.; Xie, E. Q. Appl. Surf. Sci. 2009, 255 (9), 4801. doi: 10.1016/j.apsusc.2008.11.091
(4) Yang, P. D.; Yan, H. Q.; Mao, S.; Russo, R.; Johnson, J.; Saykally, R.; Morris, N.; Pham, J.; He, R. H.; Choi, H. J. Adv. Funct. Mater. 2002, 12 (5), 323. doi: 10.1002/1616-3028 (20020517)12:5<323::AID-ADFM323>3.0.CO;2-G
(5) Liu, C. H.; Zapien, J. A.; Yao, Y.; Meng, X. M.; Lee, C. S.; Fan, S. S.; Lifshitz, Y.; Lee, S. T. Adv. Mater. 2003, 15 (10), 838. doi: 10.1002/adma.200304430
(6) Lee, C. J.; Lee, T. J.; Lyu, S. C.; Zhang, Y.; Ruh, H.; Lee, H. J. Appl. Phys. Lett. 2002, 81 (19), 3648. doi: 10.1063/1.1518810
(7) Zhu, S. B.; Chen, X. N.; Zuo, F. B.; Jiang, M.; Zhou, Z.W. J. Solid State Chem. 2013, 197, 69. doi: 10.1016/j.jssc.2012.09.001
(8) Kuo, T. J.; Lin, C. N.; Kuo, C. L.; Huang, M. H. Chem. Mater. 2007, 19 (21), 5143. doi: 10.1021/cm071568a
(9) Zhai, X. H.; Long, H. J.; Dong, J. Z.; Cao, Y. A. Acta Phys. -Chim. Sin. 2010, 26 (3), 663. [翟晓辉, 龙绘锦, 董江舟, 曹亚安. 物理化学学报, 2010, 26 (3), 663.] doi: 10.3866/PKU.WHXB20100317
(10) Elias, J.; Lévy-Clément, C.; Bechelany, M.; Michler, J.; Wang, G.; Wang, Z.; Philippe, L. Adv. Mater. 2010, 22 (14), 1607. doi: 10.1002/adma.200903098
(11) Lyu, S. C.; Zhang, Y.; Lee, C. J.; Ruh, H.; Lee, H. J. Chemistry of Materials 2003, 15 (17), 3294. doi: 10.1021/cm020465j
(12) Kang, S.W.; Mohanta, S. K.; Kim, Y. Y.; Cho, H. K. Crystal Growth and Design 2008, 8 (5), 1458. doi: 10.1021/cg701216f
(13) Sun, Y.; Fuge, G. M.; Ashfold, M. N. R. Chemical Physics Letters 2004, 396 (1), 21.
(14) Gao, Y. F.; Nagai, M.; Chang, T. C.; Shyue, J. J. Crystal Growth and Design 2007, 7 (12), 2467. doi: 10.1021/cg060934k
(15) Liu, B.; Zeng, H C. Journal of the American Chemical Society 2003, 125 (15), 4430. doi: 10.1021/ja0299452
(16) Kumar, P. S.; Raj, A. D.; Mangalaraj, D.; Nataraj, D. Applied Surface Science 2008, 255 (5), 2382. doi: 10.1016/j.apsusc.2008.07.136
(17) Liu, Z. Y.; Bai, H.W.; Sun, D. D. Int. J. Photoenergy 2011, 2012.
(18) Yan, W. P.; Wang, D. J.; Chen, L. P.; Lu, Y. C.; Xie, T. F.; Lin, Y. H. Acta Phys. -Chim. Sin. 2013, 29 (5), 1021. [闫伟平, 王德军, 陈礼平, 卢永春, 谢腾峰, 林艳红. 物理化学学报, 2013, 29 (5), 1021.] doi: 10.3866/PKU.WHXB201303043
(19) Zhang, Q. B.; Feng, Z. F.; Han, N. N.; Lin, L. L.; Zhou, J. Z.; Lin, Z. H. Acta Phys. -Chim. Sin. 2010, 26 (11), 2927. [张桥保, 冯增芳, 韩楠楠, 林玲玲, 周剑章, 林仲华. 物理化学学报, 2010, 26 (11), 2927.] doi: 10.3866/PKU.WHXB20101113
(20) Wang, J.; Fan, X. M.; Wu, D. Z.; Dai, J.; Liu, H. R.; Zhou, Z.W. Appl. Surf. Sci. 2011, 258 (5), 1797. doi: 10.1016/j.apsusc.2011.10.048
(21) Koffyberg, F. P.; Benko, F. A. J. Appl. Phys. 1982, 53 (2), 1173. doi: 10.1063/1.330567
(22) Wang, L.; Han, K.; Song, G.; Yang, X.; Tao, M. Characterization of Electro-Deposited CuO as a Low-Cost Material for High-Efficiency Solar Cells. In Photovoltaic Energy Conversion; the 2006 IEEE 4thWorld Conference, Singapore, 2006; IEEE, 2006, 1, 130-133.
(23) Rai, A. K.; Anh, L. T.; Gim, J.; Mathew, V.; Kang, J.; Paul, B. J.; Singh, N. K.; Song, J.; Kim, J. J. Power Sources 2013, 244, 435. doi: 10.1016/j.jpowsour.2012.11.112
(24) Nezamzadeh-Ejhieh, A.; Karimi-Shamsabadi, M. Chem. Eng. J. 2013, 228, 631. doi: 10.1016/j.cej.2013.05.035
(25) Steinhauer, S.; Brunet, E.; Maier, T.; Mutinati, G. C.; Kock, A.; Freudenberg, O.; Gspan, C.; Grogger, W.; Neuhold, A.; Resel, R. Sensor Actuat. B-Chem. 2013, 187, 50. doi: 10.1016/j.snb.2012.09.034
(26) Anandan, S.; Wen, X. G.; Yang, S. H. Mater. Chem. Phys. 2005, 93 (1), 35. doi: 10.1016/j.matchemphys.2005.02.002
(27) Kim, J.; Kim, W.; Yong, K. J. Phys. Chem. C 2012, 116 (29), 15682. doi: 10.1021/jp302129j
(28) Kargar, A.; Jing, Y.; Kim, S. J.; Riley, C. T.; Pan, X. Q.; Wang, D. L. ACS Nano 2013, 7 (12), 11112. doi: 10.1021/nn404838n
(29) Jung, S.; Yong, K. Chem. Commun. 2011, 47 (9), 2643. doi: 10.1039/c0cc04985a
(30) Law, M.; Greene, L. E.; Johnson, J. C.; Saykally, R.; Yang, P. D. Nat. Mater. 2005, 4 (6), 455. doi: 10.1038/nmat1387
(31) Goldie, W. Plating 1964, 51 (11), 1069.
(32) Jung, J.; Myoung, J.; Lim, S. Thin Solid Films 2012, 520 (17), 5779. doi: 10.1016/j.tsf.2012.04.052
(33) Zhu, K. X.; Wang, W. J.; Chen, X. L.; Liu, J.; Song, B.; Jiang, L. B.; Guo, J. G.; Cheng, J. Y. J. Alloy. Compd. 2011, 509 (24), 6942. doi: 10.1016/j.jallcom.2011.04.007
(34) Chen, Z. T.; Gao, L. J. Cryst. Growth 2006, 293 (2), 522. doi: 10.1016/j.jcrysgro.2006.05.082
(35) Lee, Y. L.; Zhang, Y.; Ng, S. L. G.; Kartawidja, F. C.; Wang, J. J. Am. Ceram. Soc. 2009, 92 (9), 1940. doi: 10.1111/jace.2009.92.issue-9
(36) Wang, Z. L. Mater. Today 2004, 7 (6), 26. doi: 10.1016/S1369-7021(04)00286-X
(37) Vayssieres, L.; Keis, K.; Lindquist, S. E.; Hagfeldt, A. J. Phys. Chem. B 2001, 105 (17), 3350. doi: 10.1021/jp010026s
(38) Pankove, J. I. Optical Process in Semiconductor; Dover Publications: New York, 2012.
(39) Wang, B. L.; Zhao, J. J.; Jia, J. M.; Shi, D. N.; Wan, J. G.; Wang, G. H. Appl. Phys. Lett. 2008, 93 (2), 021918. doi: 10.1063/1.2951617
(40) Schmidt, T. M.; Miwa, R. H. Nanotechnology 2009, 20 (21), 215202. doi: 10.1088/0957-4484/20/21/215202
(41) Zheng, J.; Jiang, Z. Y.; Kuang, Q.; Xie, Z. X.; Huang, R. B.; Zheng, L. S. J. Solid State Chem. 2009, 182 (1), 115. doi: 10.1016/j.jssc.2008.10.009
(42) Ai, Z. H.; Zhang, L. Z.; Lee, S. C.; Ho, W. K. J. Phys. Chem. C 2009, 113 (49), 20896. doi: 10.1021/jp9083647
(43) Borgohain, K.; Murase, N.; Mahamuni, S. J. Appl. Phys. 2002, 92 (3), 1292. doi: 10.1063/1.1491020
(44) Li, B. X.; Wang, Y. F. Superlattice Microst. 2010, 47 (5), 615. doi: 10.1016/j.spmi.2010.02.005
(45) Sakai, Y.; Ninomiya, S.; Hiraoka, K. Surf. Int. Anal. 2012, 44 (8), 938. doi: 10.1002/sia.4843
(46) Capece, F. M.; Castro, V. D.; Furlani, C.; Mattogno, G. J. Electron. Spectrosc. 1982, 27 (2), 119. doi: 10.1016/0368-2048(82)85058-5
(47) Wan, Y.; Zhang, Y. D.; Wang, X. L.; Wang, Q. Electrochem. Commun. 2013, 36, 99. doi: 10.1016/j.elecom.2013.09.026
(48) Xiang, F. M.; Wu, J.; Liu, L.; Huang, T.; Wang, Y.; Chen, C.; Peng, Y.; Jiang, C. X.; Zhou, Z.W. Polym. Adv. Technol. 2011, 22 (12), 2533. doi: 10.1002/pat.v22.12
(49) Saravanan, R.; Karthikeyan, S.; Gupta, V. K.; Sekaran, G.; Narayanan, V.; Stephen, A. Mater. Sci. Eng. C 2013, 33 (1), 91. doi: 10.1016/j.msec.2012.08.011
(50) Serpone, N.; Maruthamuthu, P.; Pichat, P.; Pelizzetti, E.; Hidaka, H. J. Photochem. Photobiol. A 1995, 85 (3), 247. doi: 10.1016/1010-6030(94)03906-B
(51) Wei, S. Q.; Chen, Y. Y.; Ma, Y. Y.; Shao, Z. C. J. Mol. Catal. AChem. 2010, 331 (1), 112.
(52) Li, J.; Wang, J.; Huang, L.; Lu, G. D. Photochem. Photobiol. Sci. 2010, 9 (1), 39. doi: 10.1039/b9pp00084d
(53) Chandrinou, C.; Boukos, N.; Stogios, C.; Travlos, A. Microelectron. J. 2009, 40 (2), 296. doi: 10.1016/j.mejo.2008.07.024
(54) Greene, L. E.; Law, M.; Goldberger, J.; Kim, F.; Johnson, J. C.; Zhang, Y. F.; Saykally, R. J.; Yang, P. D. Angew. Chem. Int. Edit. 2003, 42 (26), 3031. doi: 10.1002/anie.200351461

1. CAI Li-Li, WEN Yue-Hua, CHENG Jie, CAO Gao-Ping, YANG Yu-Sheng.Synthesis and Electrochemical Performance of a Benzoquinone-Based Polymer Anode for Aqueous Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2016,32(4): 969-974
2. HU Hai-Feng, HE Tao.Controllable Modulation of Morphology and Photocatalytic Performance of ZnO Nanomaterials via pH Adjustment[J]. Acta Phys. -Chim. Sin., 2016,32(2): 543-550
3. ZHUANG Jian-Dong, TIAN Qin-Fen, LIU Ping.Bi2Sn2O7 Visible-Light Photocatalysts: Different Hydrothermal Preparation Methods and Their Photocatalytic Performance for As(Ⅲ) Removal[J]. Acta Phys. -Chim. Sin., 2016,32(2): 551-557
4. HU Wei, WANG Yun, SHANG Hong-Yan, XU Hai-Di, ZHONG Lin, CHEN Jian-Jun, GONG Mao-Chu, CHEN Yao-Qiang.Effects of Zr Addition on the Performance of the Pd-Pt/Al2O3 Catalyst for Lean-Burn Natural Gas Vehicle Exhaust Purification[J]. Acta Phys. -Chim. Sin., 2015,31(9): 1771-1779
5. HU Hai-Feng, HE Tao.Controlled Aspect Ratio Modulation of ZnO Nanorods via Indium Doping[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1421-1429
6. SHI Chen-Yang, HE Hui-Bin, HONG Zan-Fa, ZHAN Hong-Bing, FENG Miao.Effect of HCl Post-Treatment on Morphology of Hydrothermally Prepared Titanate Nanomaterials with Optical Limiting Properties[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1430-1436
7. JIANG Xiao-Jia, JIA Jian-Ming, LU Han-Feng, ZHU Qiu-Lian, HUANG Hai-Feng.Preparation and Characterization of Sr/TiO2 Catalysts with Different Structures and High Photocatalytic Activity under Visible Light[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1399-1405
8. QIU Kun-Zan, GUO Wen-Wen, WANG Hai-Xia, ZHU Ling-Jun, WANG Shu-Rong.Influence of Catalyst Structure on Performance of Cu/SiO2 in Hydrogenation of Methyl Acetate[J]. Acta Phys. -Chim. Sin., 2015,31(6): 1129-1136
9. CHEN Yang, ZHANG Zi-Lan, SUI Zhi-Jun, LIU Zhi-Ting, ZHOU Jing-Hong, ZHOU Xing-Gui.Preparation and Electrochemical Performance of Ni(OH)2 Nanowires/ Three-Dimensional Graphene Composite Materials[J]. Acta Phys. -Chim. Sin., 2015,31(6): 1105-1112
10. YU Jian-Hua, FAN Min-Guang, LI Bin, DONG Li-Hui, ZHANG Fei-Yue.Preparation and Photocatalytic Activity of Mixed Phase TiO2-Graphene Composites[J]. Acta Phys. -Chim. Sin., 2015,31(3): 519-526
11. ZHANG Yuan-Hang, WANG Zhi-Yuan, SHI Chun-Sheng, LIU En-Zuo, HE Chun-Nian, ZHAO Nai-Qin.Synthesis of Uniform Nickel Oxide Nanoparticles Embedded in Porous Hard Carbon Spheres and Their Application in High Performance Li-Ion Battery Anode Materials[J]. Acta Phys. -Chim. Sin., 2015,31(2): 268-276
12. QI Qi, WANG Yu-Qiao, WANG Sha-Sha, QI Hao-Nan, WEI Tao, SUN Yue-Ming.Preparation of Reduced Graphene Oxide/TiO2 Nanocomposites and Their Photocatalytic Properties[J]. Acta Phys. -Chim. Sin., 2015,31(12): 2332-2340
13. YU Hua-Feng, ZHANG Guo-Pei, HAN Li-Na, CHANG Li-Ping, BAO Wei-Ren, WANG Jian-Cheng.Cu-SSZ-13 Catalyst Synthesized under Microwave Irradiation and Its Performance in Catalytic Removal of NOx from Vehicle Exhaust[J]. Acta Phys. -Chim. Sin., 2015,31(11): 2165-2173
14. LIU Chun-Mei, ZHANG Guo-Ying, ZHANG Xin, XU Yan-Yan, GAO Dong-Zhao.Hydrothermal Synthesis of Ag3PO4 Polyhedrons with Oriented {110} Facets and Visible-Light-Driven Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2015,31(10): 1939-1948
15. LIN Cai-Fang, CHEN Xiao-Ping, CHEN Shu, SHANGGUAN Wen-Feng.Preparation of NiS-Modified Cd1-xZnxS by a Hydrothermal Method and Its Use for the Efficient Photocatalytic H2 Evolution[J]. Acta Phys. -Chim. Sin., 2015,31(1): 153-158
16. WANG Jian-De, PENG Tong-Jiang, XIAN Hai-Yang, SUN Hong-Juan.Preparation and Supercapacitive Performance of Three-Dimensional Reduced Graphene Oxide/Polyaniline Composite[J]. Acta Phys. -Chim. Sin., 2015,31(1): 90-98
17. LI Qing-Zhou, LI Yu-Hui, LI Ya-Juan, LIU You-Nian.One-Step Hydrothermal Preparation and Electrochemical Performance of Graphene/Sulfur Cathode Composites[J]. Acta Phys. -Chim. Sin., 2014,30(8): 1474-1480
18. WANG Jian-De, PENG Tong-Jiang, SUN Hong-Juan, HOU Yun-Dan.Effect of the Hydrothermal Reaction Temperature on Three-Dimensional Reduced Graphene Oxide's Appearance, Structure and Super Capacitor Performance[J]. Acta Phys. -Chim. Sin., 2014,30(11): 2077-2084
19. TANG Jia-Yong, CAO Pei-Qi, FU Yan-Bao, LI Peng-Hui, MA Xiao-Hua.Synthesis of a Mesoporous Manganese Dioxide-Graphene Composite by a Simple Template-Free Strategy for High-Performance Supercapacitors[J]. Acta Phys. -Chim. Sin., 2014,30(10): 1876-1882
20. ZHAO Ning-Ning, HE Cui-Cui, LIU Jian-Bing, MA Hai-Xia, AN Ting, ZHAO Feng-Qi, HU Rong-Zu.Preparation and Characterization of Superthermite Al/Fe2O3 and Its Effect on Thermal Decomposition of Cyclotrimethylene Trinitramine[J]. Acta Phys. -Chim. Sin., 2013,29(12): 2498-2504
21. ZHAO Wei-Rong, XI Hai-Ping, LIAO Qiu-Wen.Cu-Doped Titania Nanotubes for Visible-Light Photocatalytic Mineralization of Toluene[J]. Acta Phys. -Chim. Sin., 2013,29(10): 2232-2238
22. WU Hong-Ying, WANG Huan-Wen.Synthesis and Characterization of NiCo2O4 Nanoflower/Activated Carbon Fiber Composite and Its Supercapacitor Properties[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1501-1506
23. LIN Pei-Bin, YANG Yu, CHEN Wei, GAO Han-Yang, CHEN Xiao-Ping, YUAN Jian, SHANGGUAN Wen-Feng.Hydrothermal Synthesis and Activity of NiS-PdS/CdS Catalysts for Photocatalytic Hydrogen Evolution under Visible Light Irradiation[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1313-1318
24. HUANG Hai-Feng, JIA Jian-Ming, LU Han-Feng, ZHANG Hong-Hua, PAN Lie-Qun.Effect of Designed Zr/Ti Molar Ratio on the Photocatalytic Activity of Sr-Zr-Ti Mixed Oxide Catalysts under Visible Light[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1319-1326
25. GAN Yong-Ping, QIN Huai-Peng, HUANG Hui, TAO Xin-Yong, FANG Jun-Wu, ZHANG Wen-Kui.Preparation and Photocatalytic Activity of Rutile TiO2-Graphene Composites[J]. Acta Phys. -Chim. Sin., 2013,29(02): 403-410
26. YANG Xiao-Hong, TONG Qin, LIU Chang, LIU Jin-Ku, HE Wen-Zhi, LI Guang-Ming.Photocatalytic Properties of Aluminum Doped Zinc Oxide Nanocrystals Controlled Prepared via a Synergistic Ultrasonic/Hydrothermal Technique[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2713-2720
27. SU Peng, GUO Hui-Lin, PENG San, NING Sheng-Ke.Preparation of Nitrogen-Doped Graphene and Its Supercapacitive Properties[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2745-2753
28. AN Ting, CAO Hui-Qun, ZHAO Feng-Qi, REN Xiao-Ning, TIAN De-Yu, XU Si-Yu, GAO Hong-Xu, TAN Yi, XIAO Li-Bai.Preparation and Characterization of Ag/CNTs Nanocomposite and Its Effect on Thermal Decomposition of Cyclotrimethylene Trinitramine[J]. Acta Phys. -Chim. Sin., 2012,28(09): 2202-2208
29. ZHAO Peng-Jun, WU Rong, HOU Juan, CHANG Ai-min, GUAN Fang, ZHANG Bo.One-Step Hydrothermal Synthesis and Visible-Light Photocatalytic Activity of Ultrafine Cu-Nanodot-Modified TiO2 Nanotubes[J]. Acta Phys. -Chim. Sin., 2012,28(08): 1971-1977
30. HU Wen-Liang, XU Gang, MA Jian-Wei, XIONG Bin, SHI Ji-Fu.Optical and Phase Transition Properties of TixV1-xO2 Thin Films[J]. Acta Phys. -Chim. Sin., 2012,28(06): 1533-1538
31. LIU Qiu-Ping, HUANG Hui-Juan, ZHOU Yang, DUAN Yan-Dong, SUN Qing-Wen, LIN Yuan.Photovoltaic Performance of Dye-Sensitized Solar Cells Based on Al-Doped TiO2 Thin Films[J]. Acta Phys. -Chim. Sin., 2012,28(03): 591-595
32. LIU Yan-Fang, MA Xin-Guo, YI Xin, ZHU Yong-Fa.Controllable Synthesis and Photocatalytic Performance of Bismuth Phosphate Nanorods[J]. Acta Phys. -Chim. Sin., 2012,28(03): 654-660
33. XIAO Yao-Ming, WU Ji-Huai, YUE Gen-Tian, LIN Jian-Ming, HUANG Miao-Liang, FAN Le-Qing, LAN Zhang.Preparation of Single-Crystalline TiO2 Nanowires and Their Application in Flexible Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2012,28(03): 578-584
34. XU Ke, SHEN Lai-Fa, MI Chang-Huan, ZHANG Xiao-Gang.Synthesis and Electrochemical Performance of Graphene Modified LiFePO4 Cathode Materials[J]. Acta Phys. -Chim. Sin., 2012,28(01): 105-110
35. ZHAN Hong-Quan, JIANG Xiang-Ping, LI Xiao-Hong, LUO Zhi-Yun, CHEN Chao, LI Yue-Ming.Formation Mechanism of Barium Titanate Nanoparticle Aggregations[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2927-2932
36. ZHAO Hao-Chuan, SONG Yang, GUO Xiao-Dong, ZHONG Ben-He, DONG Jing, LIU Heng.Effect of Precursor Ingredient Temperature on the Performance of LiFePO4 by Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2347-2352
37. YAN Hui, ZHANG Huan, ZHANG Ding, ZHU Zhi, QI Lu.Hydrothermal Synthesis of Spherical Li4Ti5O12 as Anode Material for High Power Lithium-Ion Secondary Battery[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2118-2122
38. LI Xue-Fei, ZHAO Yun, JIAO Qing-Ze, LI Han-Sheng, WU Hong-Yu, LIU Hong-Bo, CUI Wen-Jia.Preparation of One-Dimensional Titanate Nanomaterials Using Different Titania Sources[J]. Acta Phys. -Chim. Sin., 2011,27(08): 1996-2000
39. SHEN Shan-Shan, LU Wen-Cong, ZHANG Liang-Miao, YUE Bao-Hua, HAN Ling, ZHANG Hao.Fabrication of Mesoporous NiAl2O4 Nanorods and Their Catalytic Properties for Toluene Hydrocracking[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1743-1750
40. YING Hong, WANG Zhi-Yong, GUO Zheng-Duo, SHI Zu-Jin, YANG Shang-Feng.Reduced Graphene Oxide-Modified Bi2WO6 as an Improved Photocatalyst under Visible Light[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1482-1486
41. HAN Ling, NI Ji-Peng, ZHANG Liang-Miao, YUE Bao-Hua, SHEN Shan-Shan, ZHANG Hao, LU Wen-Cong.Controlled Synthesis of Mesoporous MnO2 Nanospindles[J]. Acta Phys. -Chim. Sin., 2011,27(03): 743-748
42. HU Xiao-Yan, LI Chun-Yi, YANG Chao-He.Catalytic Cracking Behavior of n-Heptane over HZSM-5 Catalyst[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3291-3298
43. ZHANG Fang, YUAN Chang-Zhou, ZHANG Xiao-Gang, ZHANG Luo-Jiang, XU Ke.5-Sulfosalicylic Acid-Assisted Hydrothermal Synthesis and Supercapacitive Properties of Co-Ni Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3175-3180
44. WU Tao, TAO Jie, DENG Jie, TANG Yu-Xin, ZHU Hong, GAO Peng.Preparation and Characterization of One-Dimensional TiO2 Nanowire Films on a Flexible Stainless Steel Substrate[J]. Acta Phys. -Chim. Sin., 2010,26(11): 3087-3094
45. ZHU Yan-Feng, DU Rong-Gui, LI Jing, QI Hai-Qing, LIN Chang-Jian.Photogenerated Cathodic Protection Properties of a TiO2 Nanowire FilmPrepared by a Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2349-2353
46. HE Yue, DONG Mei, LI Jun-Fen, WANG Jian-Guo, FAN Wei-Bin.Synthesis and Catalytic Properties of MeAPO-5 Molecular Sieves for Selective Oxidation of Cinnamyl Alcohol[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1305-1310
47. ZHANG Ai-Ping, ZHANG Jin-Zhi.Syntheses and Activities of Visible-Light-Driven Cu/BiVO4 Composite Photocatalysts[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1337-1342
48. YAN Dong-Xia, WANG Hua, LI Kong-Zhai, WEI Yong-Gang, ZHU Xing, CHENG Xian-Ming.Structure and Catalytic Property of Ce1-xFexO2 Mixed Oxide Catalysts for Low Temperature Soot Combustion[J]. Acta Phys. -Chim. Sin., 2010,26(02): 331-337
49. XU Xin, WANG Xiao-Jing, HU Zhong-Hua, LIU Ya-Fei, WANG Chen-Chen, ZHAO Guo-Hua.Influence of Sol-Gel and Dip-Hydrothermal Preparation Methods on Structure and Performance of TiO2/AC Photocatalysts[J]. Acta Phys. -Chim. Sin., 2010,26(01): 79-86
50. WANG Run-Han, JIANG Ji-Sen, HU Ming.Controlled Syntheses of FeNi3 Alloy Nanostructures via Reverse Microemulsion-Directed Hydrothermal Motheds[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2167-2172
51. DONG Xiang, TAO Jie, LI Ying-Ying, WANG Tao, ZHU Hong.Photoelectrochemical Properties of Three-Dimensional Network TiO2 Nanowire Film Prepared by Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1874-1882
52. LV Yong, LU Wen-Cong, ZHANG Liang-Miao, YUE Bao-Hua, SHANG Xing-Fu, NI Ji-Peng.Synthesis, Characterization and Growth Mechanism of Core/Shell AlOOH Microspheres[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1391-1396
53. CHEN Qi-Feng, JIANG Dong, XU Yao, WU Dong, SUN Yu-Han.Visible Region Photocatalysis of Ce-Si/TiO2 Synthesized Using Sol-Gel-Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2009,25(04): 617-623
54. YANG Xiao-Hong; LUO Chong-Xiao; LIU Jin-Ku; WANG Jian-Dong; CHEN Lei.Induced Synthesis and Optical Properties of Nanoparticle HgS Chains[J]. Acta Phys. -Chim. Sin., 2009,25(01): 173-177
55. ZHAO Rui-Hua, DONG Mei, QIN Zhang-Feng, DING Jian-Fei, GUO Xing-Cui, WANG Jian-Guo.Synthesis and Characterization of CoAPO-5 with different Cobalt Contents and Their Catalytic Performance for Cyclohexane Oxidation[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2304-2308
56. LI Hai-Long; LUO Wu-Lin; CHEN Tao; TIAN Wen-Yu; SUN Mao; LI Chun; ZHU Di; LIU Ran-Ran; ZHAO Yu-Liang; LIU Chun-Li.Preparation and Photocatalytic Performance of Titania Nanotubes Loaded with Ag Nanoparticles[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1383-1386
57. WANG Bai-Qi; XIA Chun-Hui; FU Qiang; WANG Peng-Wei; SHAN Xu-Dong; YU Da-Peng.Hydrothermal Preparation and Photoluminescence Property of Co-Doped ZnO Nanorods[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1165-1168
58. CAO Ji-Lin; XING Dong-Qiang; LIU Xiu-Wu; TAN Zhao-Yang.Synthesis of Magnetic 4A Zeolite at Ultrasonic Condition[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1893-1898
59. SONG Xu-Chun;ZHENG Yi-Fan;LIN Shen;WANG Yun.A Simple Method to Synthesize α-MnO2 and β-MnO2 Single-crystalline Nanorods[J]. Acta Phys. -Chim. Sin., 2007,23(02): 258-261
60. FANG Li-Mei;LI Zhi-Jie;LIU Chun-Ming;ZU Xiao-Tao.Synthesis of Fe3+-modified SnO2 Nanoparticles by Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1212-1216
61. HAO Yan-Zhong; HAN Wen-Tao.Preparation and Photoelectrochemical Properties of Titanate Nanotubes[J]. Acta Phys. -Chim. Sin., 2006,22(02): 221-225
62. SONG Xu-chun; ZHENG Yi-fan; YIN Hao-yong; CAO Guang-sheng.Synthesis and Characterization of Transition Element Substituted Titanate Nanotubes[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1076-1080
63. ZHANG Zhen-jiang; LU Jian-mei; ZHOU Wei-qun; QI Xiu-xiu.Theoretical Studies on the Third-order Nonlinear Optical Property of Polyamic Acid and It′s Grafted Ramification[J]. Acta Phys. -Chim. Sin., 2005,21(07): 711-715
64. Cai Wei-Quan;Li Hui-Quan;Zhang Yi.Hydrothrmal Crystal Growth of Very Light Boehmite products[J]. Acta Phys. -Chim. Sin., 2004,20(07): 717-721
65. Zhang Xin;Wan Hui-Lin;Weng Wei-Zheng;Yang Le-Fu;Yi Xiao-Dong.Role of Ce on Selective Oxidation of Propane to Acrolein over Ce-Ag-Mo-P-O Catalysts[J]. Acta Phys. -Chim. Sin., 2003,19(06): 492-497
66. Guo Min;Diao Peng;Ren Yan-Jie;Wang Bin;Cai Sheng-Min.Preparation and Characterization of Highly Oriented ZnO Single Crystal Submicrorod Arrays[J]. Acta Phys. -Chim. Sin., 2003,19(05): 478-480
67. Cheng Hu-Min;Ma Yu-Rong;Liao Fu-Hui;Ma Ji-Ming;Qi Li-Min.Synthesis of Mesoporous Zirconia with Hydrothermal Homogeneous Precipitation Method[J]. Acta Phys. -Chim. Sin., 2003,19(04): 326-328
68. Zhai Shang-Ru;Pu Min;Gong Yan-Jun;Zhang Ye;Wu Dong;Sun Yu-Han.The Synthesis of Mesoporous Molecular Sieve MCM-48 Using Two Surfactants as Co-template[J]. Acta Phys. -Chim. Sin., 2002,18(10): 911-915
69. Yu Hai-Hu;Wu Hong-Biao;Li Xiao-Fu;Zhu Yun-Zhou;Jiang De-Sheng.Self-assembly and Optical Properties of Silica Nanoparticulate Thin Films[J]. Acta Phys. -Chim. Sin., 2001,17(12): 1057-1061
70. Gao En-Qin;Zhang Li;Yang Mai-Zhi;Cai Sheng-Min.Preparation of TiO2 Nanoparticles by Hydrothermal Method and its Application for Photoelectrochemical Cell[J]. Acta Phys. -Chim. Sin., 2001,17(02): 177-180
71. Gan Li-Hua,Yue Tian-Yi,Chen Long-Wu,Li Guang-Ming,Zhou Bin.Preparation and Characterization of β-FeOOH Aerogels[J]. Acta Phys. -Chim. Sin., 1997,13(01): 48-51
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388
^ Top