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Acta Phys. Chim. Sin.  2015, Vol. 31 Issue (6): 1105-1112    DOI: 10.3866/PKU.WHXB201504081
Preparation and Electrochemical Performance of Ni(OH)2 Nanowires/ Three-Dimensional Graphene Composite Materials
CHEN Yang, ZHANG Zi-Lan, SUI Zhi-Jun, LIU Zhi-Ting, ZHOU Jing-Hong, ZHOU Xing-Gui
State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China
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We synthesized Ni(OH)2 nanowires/three-dimensional graphene composites using a hydrothermal method, and compared their properties with those of three-dimensional graphene, Ni(OH)2 nanowires, reduced graphene oxide, and Ni(OH)2 nanowires/reduced graphene oxide. The samples were characterized using Xray diffraction, scanning electron microscopy, thermogravimetric analysis, and N2 physisorption measurements. The electrochemical performances were investigated using cyclic voltammetry and galvanostatic chargedischarge methods. The results showed that Ni(OH)2 nanowires of width 20-30 nm were closely combined with graphene and crosslinked to one another to form a three-dimensional structure with a high specific surface area (136 m2·g-1) and mesoporosity (pore diameter 20-50 nm). The mass fraction of Ni(OH)2 nanowires in the Ni(OH)2 nanowires/three-dimensional graphene composite was 88%. The maximum specific capacitance of the Ni(OH)2 nanowires/three-dimensional graphene composite was 1664 F·g-1 in 6 mol·L-1 KOH electrolyte at 1 A·g-1. The specific capacitance decreased by only 7% after 3000 cycles at 1 A·g-1. A comparative study of the specific capacitances and cycling performances of Ni(OH)2 nanowires, Ni(OH)2 nanowires/reduced graphene oxide, three-dimensional graphene, reduced graphene oxide, and Ni(OH)2 nanowires/three-dimensional graphene indicated that three-dimensional graphene with three-dimensional porosity and a larger specific surface area than conventional reduced graphene oxide enabled improved use of the active material and significantly enhanced the electrochemical performance of Ni(OH)2 nanowires.

Key wordsGraphene gel      Three-dimensional porosity      Specific capacitance      Hydrothermal method      Capacitance retention     
Received: 09 February 2015      Published: 08 April 2015
MSC2000:  O646  

The project was supported by the National Key Basic Research Program of China (973) (2014CB239702) and Fundamental Research Funds for the Central Universities, China (WA1514011).

Corresponding Authors: ZHOU Jing-Hong     E-mail:
Cite this article:

CHEN Yang, ZHANG Zi-Lan, SUI Zhi-Jun, LIU Zhi-Ting, ZHOU Jing-Hong, ZHOU Xing-Gui. Preparation and Electrochemical Performance of Ni(OH)2 Nanowires/ Three-Dimensional Graphene Composite Materials. Acta Phys. Chim. Sin., 2015, 31(6): 1105-1112.

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(1) Miller, J. R.; Simon, P. Science 2008, 321 (5889), 651. doi: 10.1126/science.1158736
(2) Wang, J. D.; Peng, T. J.; Sun, H. J.; Hou, Y. D. Acta Phys. -Chim. Sin. 2014, 30 (11), 2077. [汪建德, 彭同江, 孙红娟, 侯云丹. 物理化学学报, 2014, 30 (11), 2077.] doi: 10.3866/PKU.WHXB201409152
(3) Zhu, Y.W.; Murali, S.; Stoller, M. D.; Ganesh, K.; Cai, W.W.; Ferreira, P. J.; Pirkle, A.; Wallace, R. M.; Cychosz, K. A.; Thommes, M.; Su, D.; Stach, E. A.; Ruoff, R. S. Science 2011, 332 (6037), 1537. doi: 10.1126/science.1200770
(4) El-Kady, M. F.; Strong, V.; Dubin, S.; Kaner, R. B. Science 2012, 335 (6074), 1326. doi: 10.1126/science.1216744
(5) Zhang, Y. D.; Lee, S. H.; Yoonessi, M.; Liang, K.W.; Pittman, C. U. Polymer 2006, 47 (9), 2984. doi: 10.1016/j. polymer.2006.03.005
(6) Zhao, Y. Q.; Schiraldi, D. A. Polymer 2005, 46 (25), 11640. doi: 10.1016/j.polymer.2005.09.070
(7) Dong, X. C.; Xu, H.; Wang, X.W.; Huang, Y. X.; Chan-Park, M. B.; Zhang, H.; Wang, L. H.; Huang, W.; Chen, P. ACS Nano 2012, 6 (4), 3206. doi: 10.1021/nn300097q
(8) Wang, H. L.; Cui, L. F.; Yang, Y.; Casalongue, H. S.; Robinson, J. T.; Liang, Y. Y.; Cui, Y.; Dai, H. J. J. Am. Chem. Soc. 2010, 132 (40), 13978. doi: 10.1021/ja105296a
(9) Zhang, X. J.; Shi, W. H.; Zhu, J. X.; Zhao, W. Y.; Ma, J.; Mhaisalkar, S.; Maria, T.; Yang, Y. H.; Zhang, H.; Hng, H. H.; Yan, Q. Y. Nano Res. 2010, 3 (9), 643. doi: 10.1007/s12274-010-0024-6
(10) Feng, L. D.; Zhu, Y. F.; Ding, H. Y.; Ni, C. Y. J. Power Sources 2014, 267 430. doi: 10.1016/j.jpowsour.2014.05.092
(11) Meher, S. K.; Justin, P.; Rao, G. R. Nanoscale 2011, 3 (2), 683. doi: 10.1039/C0NR00555J
(12) Xia, X. H.; Tu, J. P.; Mai, Y. J.; Wang, X. L.; Gu, C. D.; Zhao, X. B. J. Mater. Chem. 2011, 21 (25), 9319. doi: 10.1039/c1jm10946d
(13) Chen, Z.; Augustyn, V.; Wen, J.; Zhang, Y.W.; Shen, M. Q.; Dunn, B.; Lu, Y. F. Adv. Mater. 2011, 23 (6), 791. doi: 10.1002/adma.201003658
(14) Xia, X. H.; Tu, J. P.; Zhang, Y. Q.; Mai, Y. J.; Wang, X. L.; Gu, C. D.; Zhao, X. B. RSC Adv. 2012, 2 (5), 1835. doi: 10.1039/c1ra00771h
(15) Ji, J. Y.; Zhang, L. L.; Ji, H. Y.; Li, Y.; Zhao, X.; Bai, X.; Fan, X. B.; Zhang, F. B.; Ruoff, R. S. ACS Nano 2013, 7 (7), 6237. doi: 10.1021/nn4021955
(16) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Katsnelson, M. I.; Grigorieva, I. V.; Dubonos, S. V.; Firsov, A. A. Nature 2005, 438 (7065), 197. doi: 10.1038/nature04233
(17) Yan, J.; Fan, Z. J.; Sun, W.; Ning, G. Q.; Wei, T.; Zhang, Q.; Zhang, R. F.; Zhi, L. J.; Wei, F. Adv. Funct. Mater. 2012, 22 (12), 2632. doi: 10.1002/adfm.201102839
(18) Wang, Y. G.; Zhou, D. D.; Zhao, D.; Hou, M. Y.; Wang, C. X.; Xia, Y. Y. J. Electrochem. Soc. 2013, 160 (1), A98.
(19) Li, C.; Shi, G. Q. Nanoscale 2012, 4 (18), 5549. doi: 10.1039/c2nr31467c
(20) Xu, Y. X.; Lin, Z. Y.; Huang, X. Q.; Wang, Y.; Huang, Y.; Duan, X. F. Adv. Mater. 2013, 25 (40), 5779. doi: 10.1002/adma.v25.40
(21) Zhang, J. T.; Zhao, X. S. J. Phys. Chem. C 2012, 116 (9), 5420. doi: 10.1021/jp211474e
(22) Chen, H. Q.; Müller, M. B.; Gilmore, K. J.; Wallace, G. G.; Li, D. Adv. Mater. 2008, 20 (18), 3557. doi: 10.1002/adma.200800757
(23) Lu, Y. J.; Wang, H. R.; Gu, Y.; Xu, L.; Sun, X. J.; Deng, Y. D. Acta Chim. Sin. 2012, 70, 1731. [卢亚骏, 王浩然, 顾煜, 徐岚, 孙晓骏, 邓意达. 化学学报, 2012, 70, 1731.] doi: 10.6023/A12070376
(24) Wang, H. L.; Robinson, J. T.; Li, X. L.; Dai, H. J. J. Am. Chem. Soc. 2009, 131 (29), 9910. doi: 10.1021/ja904251p
(25) Hall, D. S.; Lockwood, D. J.; Poirier, S.; Bock, C.; MacDougall, B. R. J. Phys. Chem. A 2012, 116 (25), 6771. doi: 10.1021/jp303546r
(26) Gao, T.; Jelle, B. P. J. Phys. Chem. C 2013, 117 (33), 17294. doi: 10.1021/jp405149d
(27) Zhang, L.; Yang, X.; Zhang, F.; Long, G. K.; Zhang, T. F.; Leng, K.; Zhang, Y.W.; Huang, Y.; Ma, Y. F.; Zhang, M. T.; Chen, Y. S. J. Am. Chem. Soc. 2013, 135 (15), 5921. doi: 10.1021/ja402552h
(28) Pandolfo, A. G.; Hollenkamp, A. F. J. Power Sources 2006, 157 (1), 11. doi: 10.1016/j.jpowsour.2006.02.065
(29) Lu, Q.; Chen, J. G.; Xiao, J. Q. Angew. Chem. Int. Edit. 2013, 52 (7), 1882. doi: 10.1002/anie.v52.7
(30) Zhu, J.W.; Chen, S.; Zhou, H.; Wang, X. Nano Res. 2012, 5 (1), 11. doi: 10.1007/s12274-011-0179-9
(31) Liu, H. Y.; Zhang, W.; Song, H. H.; Chen, X. H.; Zhou, J. S.; Ma, Z. K. Electrochim. Acta 2014, 146, 511. doi: 10.1016/j.electacta.2014.09.083
(32) Simon, P.; Gogotsi, Y. Nat. Mater. 2008, 7 (11), 845. doi: 10.1038/nmat2297

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