Register
ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2015,Vol.31>> Issue(8)>> 1567-1574     doi: 10.3866/PKU.WHXB201506171         中文摘要
CATALYSIS AND SURFACE SCIENCE
Preparation of Nano-Manganite Loaded Titanium Electocatalytic Membrane for the Catalytic Oxidation of Benzyl Alcohol
TIAN Wen-Jie1,2, WANG Hong1,2, YIN Zhen1,3, YANG Ying1,2, LI Jian-Xin1,2
1. State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin 300387, P. R. China;
2. School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, P. R. China;
3. School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, P. R. China
Full text: PDF (9918KB) HTML Export: BibTeX | EndNote (RIS)

MnOx nanoparticles obtained by the emulsion method were loaded on a microporous tubular titanium membrane to prepare a functional MnOx/Ti electrocatalytic membrane. The effects of calcination temperature on the crystal structure of MnOx as well as the electrochemical properties and catalytic performance to oxidize benzyl alcohol of MnOx/Ti membrane were systematically investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), cyclic voltammetry (CV), chronoamperometry (CA), and other characterization methods. The results indicated that the crystal structure of MnOx was gradually transformed from Birnessite-MnO2 to K0.27MnO2, and finally to α- MnO2 from Mn3O4 with increasing calcination temperature. The α-MnO2 particles in the MnOx/Ti electrocatalytic membrane showed high crystallinity and uniform particle size (less than 30 nm). The superior electrochemical properties and catalytic performance of α-MnO2/Ti membrane obtained at a calcination temperature of 450 ℃ could be attributed to the binding effects between unsaturated coordination atoms of Mn and oxygen vacancies with the Ti substrate. The α-MnO2/Ti membrane obtained at 450 ℃ was used as the anode to assemble an electrocatalytic membrane reactor to oxidize benzyl alcohol. 64% conversion of benzyl alcohol and 79% selectivity to benzaldehyde was achieved under the operating conditions: reaction temperature 25 ℃, aqueous benzyl alcohol solution of 50 mmol·L-1, current density 2 mA·cm-2, and residence time 15 min.



Keywords: Porous titanium membrane   Electrocatalytic membrane reactor   Manganite   Benzyl alcohol   C atalytic oxidation  
Received: 2015-01-20 Accepted: 2015-06-15 Publication Date (Web): 2015-06-17
Corresponding Authors: YIN Zhen, LI Jian-Xin Email: yinzhen@tjpu.edu.cn;jxli@tjpu.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (21206119, 21303119) and Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China (IRT13084).

Cite this article: TIAN Wen-Jie, WANG Hong, YIN Zhen, YANG Ying, LI Jian-Xin. Preparation of Nano-Manganite Loaded Titanium Electocatalytic Membrane for the Catalytic Oxidation of Benzyl Alcohol[J]. Acta Phys. -Chim. Sin., 2015,31 (8): 1567-1574.    doi: 10.3866/PKU.WHXB201506171

(1) Gelalcha, F. G. Chemical Reviews 2007, 107 (7), 3338. doi: 10.1021/cr0505223
(2) Dan, I. E.; Jennifer K. E.; Philip, L.; Benjamin, S.; Albert, F. C.; Andrew, A. H.; Masashi, W.; Christopher, J. K.; David, W. K.; Graham, J. H. Science 2006, 311, 5759.
(3) Opembe, N. N.; Guild, C.; King Ondu, C.; Nelson, N. C.; Slowing, I. I.; Suib, S. L. Industrial & Engineering Chemistry Research 2014, 53 (49), 19044. doi: 10.1021/ie5024639
(4) Rezaei, S. E.; Zonoz, F. M.; Estiri, M.; Tayebee, R. Industrial & Engineering Chemistry Research 2011, 50 (4), 1837. doi: 10.1021/ie101641t
(5) Parlett, C. M. A.; Bruce, D. W.; Hondow, N. S.; Lee, A. F.; Wilson, K. ACS Catalysis 2011, 1 (6), 636. doi: 10.1021/cs200145n
(6) Mallat, T.; Baiker, A. Chemical Reviews 2004, 104 (6), 3037. doi: 10.1021/cr0200116
(7) Guo, Z.; Liu, B.; Zhang, Q.; Deng, W.; Wang, Y.; Yang, Y. Chemical Society Reviews 2014, 43 (10), 3480. doi: 10.1039/c3cs60282f
(8) Camilla, P. F. C. Green Chem. 2012, 14, 547. doi: 10.1039/c2gc16344f
(9) Choudhary, V. R.; Chaudhari, P. A.; Narkhede, V. S. Catalysis Communications 2003, 4 (4), 171.
(10) Su, Y.; Wang, L.; Liu, Y.; Cao, Y.; He, H.; Fan, K. Catalysis Communications 2007, 8 (12), 2181.
(11) Li, J.; Wang, H.; Li, J. X.; Guan, Q. Q.; Yang, Y. Membrane Science and Technology 2013, 33 (6), 64. [李娇, 王虹, 李建新, 管崎崎, 杨阳. 膜科学与技术, 2013, 33(6), 64.]
(12) Li, J.; Li, J.; Wang, H.; Cheng, B.; He, B.; Yan, F.; Yang, Y.; Guo, W.; Ngo, H. H. Chemical Communications 2013, 49 (40), 4501. doi: 10.1039/c3cc41181h
(13) Wang, H.; Wang, H.; Li, J.; Bin, D.; Yin, Z.; Kang, J.; He, B. Electrochimica Acta 2014, 123, 33. doi: 10.1016/j.electacta. 2014.01. 016
(14) Bin, D.; Wang, H.; Li, J.; Wang, H.; Yin, Z.; Kang, J.; He, B.; Li, Z. Electrochimica Acta 2014, 130, 170. doi: 10.1016/j. electacta.2014.02. 128
(15) Fang, X.; Yin, Z.; Wang, H.; Li, J.; Liang, X.; Kang, J.; He, B. Journal of Catalysis 2015, 329, 187. doi: 10.1016/j.jcat. 2015.05.004
(16) Xiao, W.; Wang, D.; Lou, X. W. The Journal of Physical Chemistry C 2010, 114 (3), 1694. doi: 10.1021/jp909386d
(17) Chen, H.; He, J.; Zhang, C.; He, H. The Journal of Physical Chemistry C 2007, 111 (49), 18033.
(18) Lee, J. W.; Hall, A. S.; Kim, J.; Mallouk, T. E. Chemistry of Materials 2012, 24 (6), 1158. doi: 10.1021/cm203697w
(19) Devaraj, S.; Munichandraiah, N. The Journal of Physical Chemistry C 2008, 112 (11), 4406. doi: 10.1016/j.orgel. 2008.12.008
(20) Nesbitt, H. W. B. The American Mineralogist 1998, 83 (3-4), 305.
(21) Beyreuther, E.; Grafstr, M. S.; Eng, L. M. Physical Review B 2006, 73 (15), 155425. doi: 10.1103/PhysRevB.73.155425
(22) Kang, J.; Hirata, A.; Qiu, H. J.; Chen, L.; Ge, X.; Fujita, T.; Chen, M. Advanced Materials 2014, 26 (2), 269. doi: 10.1002/adma.201302975
(23) Dai, Y.; Li, J. H.; Peng, Y.; Tang, X. F. Acta Phys.-Chim. Sin. 2012, 7, 1771. [戴韵, 李俊华, 彭悦, 唐幸福. 物理化学学报, 2012, 7, 1771.]. doi: 10.3866/PKU.WHXB201204175
(24) Crist, B. V. Handbook of Monochromatic XPS Spectra, Volume 1: The Elements of Native Oxides; Wiley & Sons; Chichester, 2000; pp 515-519.
(25) Chen, Q. Y.; Tong, H. X.; Yin, Z. L.; Hu, H. P.; Li, J.; Liu, L. L. Acta Phys. -Chim. Sin. 2007, 12, 1917. [陈启元, 童海霞, 尹周澜, 胡慧萍, 李洁, 刘亮亮. 物理化学学报, 2007, 12, 1917.] doi: 10.3866/PKU.WHXB20071216
(26) Huang, Y.; Li, H.; Balogun, M.; Liu, W.; Tong, Y.; Lu, X.; Ji, H. ACS Applied Materials & Interfaces 2014, 6 (24), 22920. doi: 10.1021/am507641k
(27) Zhang, X. J.; Liu, Q. J.; Deng, S. G.; Chen, J.; Gao, P. Acta Phys. Sin. 2011, 08, 567. [张学军, 柳清菊, 邓曙光, 陈娟, 高攀. 物理学报, 2011, 08, 567.]
(28) Lu, X.; Wang, G.; Zhai, T.; Yu, M.; Gan, J.; Tong, Y.; Li, Y. Nano Letters 2012, 12 (3), 1690.
(29) Zhang, Y.; Sun, C.; Lu, P.; Li, K.; Song, S.; Xue, D. CrystEngComm 2012, 14 (18), 5892. doi: 10.1039/c2ce25610j
(30) Cheng, F.; Su, Y.; Liang, J.; Tao, Z.; Chen, J. Chemistry of Materials 2010, 22 (3), 898. doi: 10.1021/cm901698s
(31) Dupont, M.; Hollenkamp, A. F.; Donne, S. W. Electrochimica Acta 2013, 104, 140. doi: 10.1016/j.electacta.2013.04.007

1. LI Yue, ZHANG Ting-Ting, WANG Juan, ZHU Zhen, JIA Bing, YU Jiang.Catalytic Combustion of n-Hexanal Using Cu-Mn Composite Oxide Supported on TiO2[J]. Acta Phys. -Chim. Sin., 2016,32(8): 2084-2092
2. LIU Zhao-Xin, LI Wei-Bin.Catalytic Activity and Deactivation of Toluene Combustion on Rod-Like Copper-Manganese Mixed Oxides[J]. Acta Phys. -Chim. Sin., 2016,32(7): 1795-1800
3. LIU Xiao-Qing, LI Shi-Hui, SUN Meng-Ting, YU Cheng-Long, HUANG Bi-Chun.Preparation, Characterization and Low-Temperature NH3-SCR Activity of MnOx/SAPO-11 Catalysts[J]. Acta Phys. -Chim. Sin., 2016,32(5): 1236-1246
4. ZHANG Xiao-Dong, WANG Yin, YANG Yi-Qiong, CHEN Dan.Recent Progress in the Removal of Volatile Organic Compounds by Mesoporous Silica Materials and Supported Catalysts[J]. Acta Phys. -Chim. Sin., 2015,31(9): 1633-1646
5. LI Yan, ZHANG Ting-Ting, LI Yue, JIA Bing, TAN Hua-Hua, YU Jiang.Influence of Calcination Temperature on Dechlorination Performance of V2O5/CNTs-TiO2 Catalysts[J]. Acta Phys. -Chim. Sin., 2015,31(8): 1541-1548
6. JIAO Jin-Zhen, LI Shi-Hui, HUANG Bi-Chun.Preparation of Manganese Oxides Supported on Graphene Catalysts and Their Activity in Low-Temperature NH3-SCR[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1383-1390
7. XIE Xing-Xing, FEI Zhao-Yang, ZOU Chong, LI Zheng-Zhou, CHEN Xian, TANG Ji-Hai, CUI Mi-Fen, QIAO Xu.Effects of Rare-Earth Additives on Structures and Performances of CuO-CeO2-SiO2 Catalysts for Recycling Cl2 from HCl Oxidation[J]. Acta Phys. -Chim. Sin., 2015,31(6): 1153-1161
8. CHEN Hong, WANG Shi-Xian, ZHAO Wan-Long, ZHANG Neng-Neng, ZHENG Ying-Ping, SUN Yue-Ming.Preparation of Pt/TiO2 Nanofibers and Their Electrocatalytic Activity towards Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2015,31(2): 302-308
9. ZHANG Jie, ZHANG Jiang-Hao, ZHANG Chang-Bin, HE Hong.Complete Catalytic Oxidation of Ethanol over MnO2 with Different Crystal Phase Structures[J]. Acta Phys. -Chim. Sin., 2015,31(2): 353-359
10. REN Cheng-Jun, ZHOU Li-Na, SHANG Hong-Yan, CHEN Yao-Qiang.Pd-MnOx/γ-Al2O3 Monolithic Catalysts Prepared by Impregnation Method and Effect of Different Supports on Ground-Level Ozone Decomposition[J]. Acta Phys. -Chim. Sin., 2014,30(5): 957-964
11. TAN Hai-Yan, WU Jin-Ping.Performance of a Metal-Organic Framework MIL-53(Al)-Supported Cobalt Catalyst in the CO Catalytic Oxidation Reaction[J]. Acta Phys. -Chim. Sin., 2014,30(4): 715-722
12. YANG Chao, LIU Xiao-Qing, HUANG Bi-Chun, WU You-Ming.Structural Properties and Low-Temperature SCR Activity of Zirconium-Modified MnOx/MWCNTs Catalysts[J]. Acta Phys. -Chim. Sin., 2014,30(10): 1895-1902
13. LI Le, HE Yun-Qiu, CHU Xiao-Fei, LI Yi-Ming, SUN Fang-Fang, HUANG He-Zhou.Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K2Mn4O8 Nanocomposites as Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1681-1690
14. CHEN Yong-Dong, WANG Lei, GUAN Xiao-Xu, LIU Yong-Bing, GONG Mao-Chu, CHEN Yao-Qiang.Catalytic Oxidation of Soluble Organic Fraction in Diesel Exhausts Using Composite Oxides (CeO2)x(La-Al2O3)1-x[J]. Acta Phys. -Chim. Sin., 2013,29(05): 1048-1054
15. CUI Ying, KUANG Yin-Jie, ZHANG Xiao-Hua, LIU Bo, CHEN Jin-Hua.Spontaneous Deposition of Pt Nanoparticles on Poly(diallyldimethylammonium chloride)/Carbon Nanotube Hybrids and Their Electrocatalytic Oxidation of Methanol[J]. Acta Phys. -Chim. Sin., 2013,29(05): 989-995
16. XU Wen-Qing, ZHAO Jun, WANG Hai-Rui, ZHU Ting-Yu, LI Peng, JING Peng-Fei.Catalytic Oxidation Activity of NO on TiO2-Supported Mn-Co Composite Oxide Catalysts[J]. Acta Phys. -Chim. Sin., 2013,29(02): 385-390
17. MENG Zhong-Hua, YANG Peng, ZHOU Ren-Xian.Influence of Ce/Cr Ratio on 2-CrOx Mixed Oxide Catalysts for the Catalytic Oxidation of 1,2-Dichloroethane[J]. Acta Phys. -Chim. Sin., 2013,29(02): 391-396
18. NIE Su-Lian, ZHAO Yan-Chun, FAN Jie-Wen, TIAN Jian-Niao, NING Zhen, LI Xiao-Xiao.Highly Active Pd-Co3O4/MWCNTs Catalysts for Methanol Electrocatalytic Oxidation[J]. Acta Phys. -Chim. Sin., 2012,28(04): 871-876
19. XUE Wen-Juan, ZHANG Xin-Yan, LI Peng, LIU Zhao-Tie, HAO Zheng-Ping, MA Chun-Yan.Catalytic Activities for the Complete Oxidation of Ethylene over Au-Cu/Co3O4 Catalysts[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1730-1736
20. ZHAN Wang-Cheng, ZHOU Guo-Jun, CHU Guo-Hai, SHEN Kai, YU Jun, WANG Ai-Yong, SU Na, LU Guan-Zhong, GUO Yang-Long.Effect of Supports on the Catalytic Performance of Pd-Cu/Activated Carbon Catalyst for Eliminating CO in Cigarette Smoke[J]. Acta Phys. -Chim. Sin., 2011,27(03): 705-710
21. YE Qing, ZHAO Jian-Sheng, LI Dong-Hui, ZHAO Jun, CHENG Shui-Yuan, KANG Tian-Fang.Au/SnO2 and M-Au (M=Pt, Pd)/SnO2 Bimetallic Catalysts for the Low-Temperature Catalytic Oxidation of CO[J]. Acta Phys. -Chim. Sin., 2011,27(01): 169-176
22. LI Mei-Chao, WANG Wu-Yang, ZHU Wan-Xia, MA Chun-An.Electrocatalytic Oxidation of Ascorbic Acid on a PPy-HEImTfa/Pt Electrode and Its Mechanism[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3212-3216
23. WU Xiao-Qin, ZONG Rui-Long, MU Hao-Jie, ZHU Yong-Fa.Cataluminescence Performance on Catalysts of Graphene Supported Platinum[J]. Acta Phys. -Chim. Sin., 2010,26(11): 3002-3008
24. LI Qiao-Xia, ZHOU Xiao-Jin, LI Jin-Guang, XU Qun-Jie.Electrodeposition Preparation of a Pt-Ru Alloy Filmand Its Electrochemical Surface-Enhanced IR Absorption Spectroscopy[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1488-1492
25. WEN Zhu-Liang, YANG Su-Dong, SONG Qi-Jun, HAO Liang, ZHANG Xiao-Gang.High Activity of Pd/Graphene Catalysts for Ethanol Electrocatalytic Oxidation[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1570-1574
26. LIU Bo-Jie, LI Xue-Yi, CHEN Wei, LIU Ren-Xiao, GE Guang-Lu.Surface Ligand Exchange and Phase Transfer of Iron Oxide Magnetic Nanoparticles[J]. Acta Phys. -Chim. Sin., 2010,26(03): 784-788
27. WANG Fan, WANG Yan-Min, WEN Yan-Xuan, SU Hai-Feng, LI Bin.Structural and Morphological Transformation of MnO2 Nanostructures from Mn3O4 Precursor[J]. Acta Phys. -Chim. Sin., 2010,26(02): 521-526
28. HU Long-Xing, DANG Song-Tao, YANG Xia-Ping.Incorporation of CuO into Mesoporous Carbon CMK-3 and Its Adsorption and Catalytic Oxidation of Phenol[J]. Acta Phys. -Chim. Sin., 2010,26(02): 373-377
29. LI Peng, HE Chi, CHENG Jie, HAO Zheng-Ping.Catalytic Oxidation of Chlorobenzene on Composite Oxide Pd/M3AlO (M=Mg, Co, Ni, Cu, Zn) Catalysts Derived fromPd-Contained Hydrotalcite Precursors[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2279-2284
30. ZHAO Yan-Chun, LAN Huang-Xian, TIAN Jian-Niao, YANG Xiu-Lin, WANG Feng-Yang.Electrocatalytic Oxidation of Methanol on Pt Nanoparticles Supported on Porous Poly(N-acetylaniline) Nanofibrils[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2050-2054
31. WANG Rui-Xin, JIAO Wei-Zhou, GAO Bao-Jiao.Catalytic Performance of P(4VP-co-St)/SiO2-Supported Co Tetraphenylporphyrins for the Aerobic Oxidation of Phenylethane[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1791-1798
32. ZHANG Hong-Wei, ZHANG Zheng-Fu, LI Yang, YANG Xi-Hun, LIU Shuo.Structural Effects and Electrooxidation Activity of a Two-Dimensional Multilayer PtRu/PtNd Alloy Nanostructure Thin Film[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2268-2274
33. GAO Cheng-Yao; CHANG Ming.Ta/BDD Film Electrode for Electrochemical Oxidation Nitrophenol[J]. Acta Phys. -Chim. Sin., 2008,24(11): 1988-1994
34. YU Jun, WU Gui-Sheng, MAO Dong-Sen, LU Guan-Zhong.Effect of La2O3 on Catalytic Performance of Au/TiO2 for CO Oxidation[J]. Acta Phys. -Chim. Sin., 2008,24(10): 1751-1755
35. YANG Shun-Yi; WANG Xian-You; WEI Jian-Liang; LI Xiu-Qin; TANG An-Ping.Preparation and Electrochemical Performance of Na-Mn-O Cathode Materials[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1669-1674
36. ZHENG Yi-Xiong; YAO Shi-Bing; ZHOU Shao-Min.Electrooxidation of Ethanol at Ni-B Amorphous Alloy Electrode and Measurements of Kinetic Parameters[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1643-1649
37. SUN Yi; XU Juan; CAI Wen-Bin; JIANG Zhi-Yu.Mechanism of Photokilling LoVo Cells by Nano TiO2 Photocatalytic Oxidation Combined with Immunity and Electroporation Method[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1359-1365
38. MA Ying; CHEN Min; SONG Cui; ZHENG Xiao-Ming.Catalytic Oxidation of Toluene, Acetone and Ethyl Acetate on a New Pt-Pd/Stainless Steel Wire Mesh Catalyst[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1132-1136
39. BULGAN G.; LIANG Shu-Hui; TENG Fei; YAO Wen-Qing; ZHU Yong-Fa.Effect of Ce Doping on the Structure and Catalytic Activity of La1-xCexCoO3 Catalysts[J]. Acta Phys. -Chim. Sin., 2008,24(02): 205-210
40. RAO Gui-Shi; FAN Feng-Ru; WANG Guo-Fu; WU Zhi-Xiang; YI Fei; ZHONG Qi-Ling; REN Bin; TIAN Zhong-Qun.In-situ SERS of Formic Acid Electro-catalytic Oxidation on Aucore@Ptshell/Pt Electrode[J]. Acta Phys. -Chim. Sin., 2008,24(02): 345-349
41. BULGAN G.; TENG Fei; LIANG Shu-Hui; YAO Wen-Qing; ZHU Yong-Fa.Effect of Cu Doping on the Structure and Catalytic Activity of LaMnO3 Catalyst[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1387-1392
42. ZHUANG Quan-chao; FAN Xiao-yong; XU Jin-mei; CHEN Zuo-feng; DONG Quan-feng; JIANG Yan-xia; HUANG Ling; SUN Shi-gang.Electrochemical Impedance Spectroscopic Study of the First Delithiation of Spinel Lithium Manganese Oxide[J]. Acta Phys. -Chim. Sin., 2006,22(02): 234-238
43. ZHU Ling; WANG Xue-zhong; YU Jun-jie; HAO Zheng-ping.Catalytic Performance of K-Ce0.5Zr0.5O2 Catalysts for Soot Combustion[J]. Acta Phys. -Chim. Sin., 2005,21(08): 840-845
44. JI Hong-bing; WANG Le-fu; CHEN Qing-lin.Development of Catalysts with Tunable Catalytic Oxidative Performance for Alcohols Conversion[J]. Acta Phys. -Chim. Sin., 2005,21(07): 746-751
45. SHAO Guang-Xin; LUO Lai-Tao; DUAN Zhan-Hui.Preparation, Catalytic Oxidation Properties and Characterization of LaSrCo0.9B’0.1O4 (B’=Mn, Fe, Ni, Cu) Mixed Oxides[J]. Acta Phys. -Chim. Sin., 2005,21(03): 328-332
46. LIU Jian;ZHAO Zhen;XU Chun-Ming.The Structures of VOx/ZrO2 and K-VOx/ZrO2 Catalysts and Their Catalytic Performances for Diesel Soot Oxidation[J]. Acta Phys. -Chim. Sin., 2005,21(02): 156-160
47. Zhou Ming-Hua;Dai Qi-Zhou;Lei Le-Cheng;Wu Zu-Cheng;Ma Chun-An;Wang Da-Hui.Electrochemical Oxidation for the Degradation of Organic Pollutants on a Novel PbO2 Anode[J]. Acta Phys. -Chim. Sin., 2004,20(08): 871-876
48. Lü Ai-Xia;Fu Zai-Hui;Yin Du-Lin;Xu You-Zhi;Ming Du-Juan;Yang Qing;Yin Dong-Hong.Studies on Titanium Tartrate Complex Assembled HMS and NaY[J]. Acta Phys. -Chim. Sin., 2004,20(07): 749-754
49. Wan Li-Juan;Gao Ying;Wu Bing;Liu Chang-Peng;Xing Wei;Lu Tian-Hong.Cocatalysis of Adsorbed Eu3+ and Ho3+ at Pt-TiO2/C Electrode for Electrooxidaton of Ethanol[J]. Acta Phys. -Chim. Sin., 2004,20(06): 616-620
50. Wu Shu-Xin;Ma Zhi;Qin Yong-Ning;He Fei;Jia Li-Shan;Zhang Yan-Jun.XPS Study of Copper Doping TiO2 Photocatalyst[J]. Acta Phys. -Chim. Sin., 2003,19(10): 967-969
51. Zhao Li-Li;Wang Rong-Shu.Preparation of MnO2(Li) and Its Ion Exchange Kinetics[J]. Acta Phys. -Chim. Sin., 2003,19(10): 933-937
52. Chen Wei;Sun Shi-Gang;Si Di;Chen Sheng-Pei.Electrocatalytic Properties of Agglomerates of Pt Nanoparticles in Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2003,19(05): 441-444
53. Guo Xia;Xu Hui;Guo Rong.The Fluorescence Quenching of Anthracene by Phenothiazine in Sodium Dodecyl Sulfate / Benzyl Alcohol / Water Microemulsion[J]. Acta Phys. -Chim. Sin., 2002,18(06): 500-503
54. Li Dan-Zhen;Zheng Yi;Fu Xian-Zhi.Study on the Effect and Mechanism of the Coupling between Microwave and Photocatalysis[J]. Acta Phys. -Chim. Sin., 2002,18(04): 332-335
55. Li Hua-Ming;Ye Xing-Kai;Wu Yue.Effect of FePc Structure on the Activity in the Oxidation of Cyclohexene Catalyzed by Pd(OAc)2/HQ/FePc[J]. Acta Phys. -Chim. Sin., 2001,17(05): 432-437
56. Yang Jian-Jun;Li Dong-Xu;Li Qing-Lin;Zhang Zhi-Jun;Wang Han-Qing.Mechnism of Photocatalytic Oxidation of Formaldehyde[J]. Acta Phys. -Chim. Sin., 2001,17(03): 278-281
57. Li Dan-Zhen;Zheng Yi;Fu Xian-Zhi;Liu Ping.SO2-4/TiO2 Catalyst Prepared by Microwave Method and the Research of its Photocatalytic Oxidation Activity[J]. Acta Phys. -Chim. Sin., 2001,17(03): 270-272
58. Li Zhen;Xia Chun-Gu.Rapid-Mixing Stopped-Flow Spectra Studies on Water-soluble Manganese Porphyrin Enzyme-Mimic Systems[J]. Acta Phys. -Chim. Sin., 2001,17(02): 101-106
59. Fu Zai-Hui, Chen Jun-Hua, Chen Yuan-Dao, Xiang Yan-Hai, Zhang Lu-Xi, Yin Du-Lin.Synthesis,Characterization and Catalytic Properties of Transition Metals Substituted HMS[J]. Acta Phys. -Chim. Sin., 2000,16(05): 410-415
60. She Pei-Liang, Yao Shi-Bing, Zhou Shao-Min.Electrocatalytic Oxidation of Ethanol on Palladium and Platinum Electrodes Prepared by Electrodeposition[J]. Acta Phys. -Chim. Sin., 2000,16(01): 22-26
61. Li Yu-Guang, Porter John F, Chan Chak K.Microstructure Characteristies and Photoreactivity of Calcined P-25 TiO2[J]. Acta Phys. -Chim. Sin., 1999,15(01): 82-86
62. Meng Xiao-Ping, Luo Ning, Wang Ying-Xia, Li Neng, Lin Bing-Xiong, Zhao Tong-Fu.Studies on the Synthesis,Structural Imperfection and catalytic Properties of Cu-Cr-O Composite Oxides[J]. Acta Phys. -Chim. Sin., 1998,14(02): 185-187
63. Yang Hui,Li Chang-Zhi,Lu Tian-Hong,Xue Kuan-Hong,Sun Shi-Gang,Lu Guo-Qiang,Chen.Electrocatalytic Oxidation of Methanol on Polythionine Film Modified with Pt Microparticles[J]. Acta Phys. -Chim. Sin., 1997,13(06): 542-547
64. Yang Hui,Lu Tian-Hong,Xue Kuan-Hong,Zhou Yi-Ming,Sun Shi-Gang,Chen Sheng-Pei.Cyclic Voltammetry and in-situ FTIR Spectroscopic Studies on Electro-oxidation of Formaldehyde at a Gold Electrode[J]. Acta Phys. -Chim. Sin., 1996,12(06): 527-531
65. Cai Lin-Tao, Yao Shi-Bing, Zhou Shao-Min.Electrocatalytic Oxidation of Ascorbic Acid at Polyaniline Modified Electrode and the Effects of the Magnetic Field[J]. Acta Phys. -Chim. Sin., 1995,11(02): 185-188
66. Deng Jing-Fa; Peng Ying; Jiang An-Ren; Wang Zhi-Hong.The Catalytic Oxidation of Co Over Ba2-xSrxYCu3O7-a[J]. Acta Phys. -Chim. Sin., 1993,9(02): 206-210
67. Dong Shao-Jun; Song Fa-Yi.Electrocatalytic Oxidation of Ascorbic Acid at Polyaniline Film Modified Glassy Carbon Electrodes[J]. Acta Phys. -Chim. Sin., 1992,8(01): 82-86
68. WANG Lei, YIN Han-Mei, WANG Jian-Hao, WU Li-Zhi, LIU Yue-Ming.Study on Synthesis of B-TS-1 and Its Catalytic Oxidation Performance[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
69. DU Jun, WU Xiang-Ying, PAN Xing-Peng, YU Jiang.Oxygenation and Oxidation Desulfurization Property of CeO2/NaY Catalysts[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388 Email:whxb@pku.edu.cn
^ Top