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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2015,Vol.31>> Issue(11)>> 2220-2228     doi: 10.3866/PKU.WHXB201510131         中文摘要
PHYSICAL CHEMISTRY OF MATERIALS
Preparation and Supercapacitor Properties of Carbon-Coated SnO2 Hollow Fibers
HAN Xiao-Mei1, WU Yan-Bo2, ZHAO Heng-Yan2, BI Jun2, WEI Bin-Bin2
1 College of Materials Science and Engineering, Dalian Jiaotong University, Dalian 116028, Liaoning Province, P. R. China;
2 College of Environmental and Chemical Engineering, Dalian Jiaotong University, Dalian 116028, Liaoning Province, P. R. China
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A new carbon-coated SnO2 hollow fiber was successfully prepared by coaxial electrospinning, and its supercapacitor properties were well studied. The surface morphology and structure were examined using X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and the Brunauer-Emmett-Teller (BET) method. The results showed hollow fibers of average diameter 1 μm and carbon-coated SnO2 particles of average size 3-15 nm uniformly distributed on the fiber shell. The surface area was 565 m2·g-1. In a three-electrode system, the electrode achieved a respectable specific capacitance of 397.5 F·g-1 at 0.25 A·g-1, and the capacitance retained ratio was still 88% of the initial value after 3000 cycles at 1.0 A·g-1. In the case of a symmetrical two-electrode system, the electrode achieved a specific capacitance of 162.0 F·g-1 at 0.25 A·g-1 current density, and the capacitance retained ratio was 84% of the initial value after 3000 cycles at 1.0 A·g-1.



Keywords: Coaxial electrospinning   Carbon-coated nano-SnO2   Hollow structure   Supercapacitor  
Received: 2015-04-27 Accepted: 2015-10-12 Publication Date (Web): 2015-10-13
Corresponding Authors: WU Yan-Bo Email: wuyanbo_djd@126.com

Fund: The project was supported by the National Natural Science Foundation of China (21076028) and National Training Programs of lnnovation and Entreprenurship for Undergraduates, China (201410150016).

Cite this article: HAN Xiao-Mei, WU Yan-Bo, ZHAO Heng-Yan, BI Jun, WEI Bin-Bin. Preparation and Supercapacitor Properties of Carbon-Coated SnO2 Hollow Fibers[J]. Acta Phys. -Chim. Sin., 2015,31 (11): 2220-2228.    doi: 10.3866/PKU.WHXB201510131

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