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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2016,Vol.32>> Issue(2)>> 481-492     doi: 10.3866/PKU.WHXB201511041         中文摘要
Electrochemical Properties of Phosphorus-Containing Activated Carbon Electrodes on Electrical Double-Layer Capacitors
WANG Yong-Fang, ZUO Song-Lin
Jiangsu Key Laboratory of Biomass-based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, P. R. China
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Different kinds of phosphorus-containing activated carbons were prepared by phosphoric acid activation of lignocellulosic precursor and modification with H3PO4. Elemental analysis, X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption were employed to analyze the elemental content, surface chemistry, and pore structures of the activated carbons. The electrochemical properties of the carbon materials were characterized for their application as supercapacitors in KOH and H2SO4 electrolytes using galvanostatic charge/discharge, cyclic voltammetry, and electrochemical impedance spectroscopic analyses. A statistical analysis by an intercept-free multiple linear regression method was employed to investigate the factors that influence the specific capacitance of activated carbon electrodes. In addition, a three-electrode cell setup was used to analyze the cause of the phosphorus contribution on capacitance. The results show that phosphorus increases the specific capacitance of activated carbons by the introduction of pseudo-capacitance; the activated carbon with phosphorus content of 5.88% (w) exhibits a specific capacitance of 185 F·g-1 at 0.1 A·g-1. The statistical analysis showed that mesopores facilitate an access of electrolyte ions to the surface of micropores. The pores in the width ranges of 1.10-1.61 nm, 2.12-2.43 nm and 3.94 -4.37 nm benefit the formation of the electric double layer in 6 mol·L-1 KOH electrolyte; the pores with sizes of 0.67-0.72 nm have a positive effect in 1 mol·L-1 H2SO4 electrolyte.



Keywords: Activated carbon   Phosphorus functional group   Pore structure   Pseudo-capacitance   Supercapacitor  
Received: 2015-06-30 Accepted: 2015-11-03 Publication Date (Web): 2015-11-04
Corresponding Authors: ZUO Song-Lin Email: zslnl@hotmail.com

Fund: The project was supported by the National Natural Science Foundation of China (31270621) and State Forestry Administration 948 Importation Project, China (2012-4-08).

Cite this article: WANG Yong-Fang, ZUO Song-Lin. Electrochemical Properties of Phosphorus-Containing Activated Carbon Electrodes on Electrical Double-Layer Capacitors[J]. Acta Phys. -Chim. Sin., 2016,32 (2): 481-492.    doi: 10.3866/PKU.WHXB201511041

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