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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2016,Vol.32>> Issue(1)>> 48-60     doi: 10.3866/PKU.WHXB201511092         中文摘要
Structure-Sensitivity of Au Catalysis
HUANG Wei-Xin, QIAN Kun, WU Zong-Fang, CHEN Shi-Long
CAS Key Laboratory of Materials for Energy Conversion, Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, P. R. China
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Au catalysis is representative of nanocatalysis. Au catalysis has been demonstrated to be very complex and structure-sensitive. In this short review we summarize the literature reports on Au catalysis and our recent progress on the fundamental understanding of Au catalysis using model catalysts from single crystals to nanocrystals. We demonstrate the structure-sensitivity of Au catalysis used for NO decomposition, CO oxidation, and propylene epoxidation with H2 and O2 and the corresponding active Au structures. We discuss the effects of the geometric and electronic structures and the Au-oxide support interactions on Au catalysis, and the origin of high catalytic activity of the Au surface at low temperatures. Finally, we provide an outlook for future research directions of structure-sensitive Au catalysis.



Keywords: Surface chemistry   Heterogeneous catalysis   Model catalyst   CO oxidation reaction   NO decomposition reaction   Propylene epoxidation reaction  
Received: 2015-10-12 Accepted: 2015-11-09 Publication Date (Web): 2015-11-09
Corresponding Authors: HUANG Wei-Xin Email: huangwx@ustc.edu.cn

Fund: The project was supported by the National Key Basic Research Program of China (973) (2013CB933104), National Natural Science Foundation of China (21525313, 20973161, 21373192), MOE Fundamental Research Funds for the Central Universities, China (WK2060030017), MPG-CAS Partner Group Program and Collaborative Innovation Center of Suzhou Nano Science and Technology.

Cite this article: HUANG Wei-Xin, QIAN Kun, WU Zong-Fang, CHEN Shi-Long. Structure-Sensitivity of Au Catalysis[J]. Acta Phys. -Chim. Sin., 2016,32 (1): 48-60.    doi: 10.3866/PKU.WHXB201511092

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