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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2016,Vol.32>> Issue(4)>> 975-982     doi: 10.3866/PKU.WHXB201601281         中文摘要
Synthesis and Supercapacitance Performance of Graphene-Supported π-Conjugated Polymer Nanocomposite Electrode Materials
ZHOU Xiao1, SUN Min-Qiang1,2, WANG Geng-Chao1
1. Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science & Engineering, East China University of Science & Technology, Shanghai 200237, P. R. China;
2. Jiande Shunfa Chemical Adjuvant Co. Ltd., Hangzhou 311600, P. R. China
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Well-dispersed graphene nanosheets (GNS) were prepared by the 60Co γ-ray irradiation reduction technique. On this basis, the hierarchical graphene nanosheet-supported poly(1,5-diaminoanthraquinone) (GNS@PDAA) nanocomposites were synthesized by the chemically oxidative polymerization method using camphor sulfonic acid as both the dopant and soft template. The influence of the DAA/GNS mass ratios on the morphology, chemical structure, and supercapacitance performance for GNS@PDAA nanocomposites was investigated. The structure, morphology, and electrochemical properties of the composites were characterized by Fourier infrared spectroscopy (FTIR), Raman spectroscopy (Raman), atomic force microscope (AFM), energy dispersive spectroscopy (EDS), field emission scanning electron microscopy (FE-SEM), and electrochemical measurements. The results show that for the GNS@PDAA nanocomposite with DAA/GNS mass ratio of 6/1, the PDAA nanoparticles (20-40 nm diameter) are evenly deposited on the surface of GNS, which intercalate a large number of mesopores with 10-30 nmthrough strong π-π stacking and network confinement. As a result, the GNS@PDAA exhibits the highest specific capacitance (398.7 F·g-1 at 0.5 A·g-1), excellent rate capability (71% capacitance retention at 50 A·g-1), and superior cycling stability (only 8.3% capacitance loss after 20000 cycles). Furthermore, based on the GNS@PDAA nanocomposites as both negative and positive electrodes, the as-assembled supercapacitors showed an excellent series/parallel connection effect in aqueous system.



Keywords: Graphene   π-Conjugated polymer   Poly(1,5-diaminoanthraquinone)   Nanocomposite   Electrode materials   Supercapacitors  
Received: 2015-12-02 Accepted: 2016-01-28 Publication Date (Web): 2016-01-28
Corresponding Authors: WANG Geng-Chao Email: gengchaow@ecust.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (51173042) and Shanghai Municipality Research Project, China (15520720500).

Cite this article: ZHOU Xiao, SUN Min-Qiang, WANG Geng-Chao. Synthesis and Supercapacitance Performance of Graphene-Supported π-Conjugated Polymer Nanocomposite Electrode Materials[J]. Acta Phys. -Chim. Sin., 2016,32 (4): 975-982.    doi: 10.3866/PKU.WHXB201601281

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69. LI Le, HE Yun-Qiu, CHU Xiao-Fei, LI Yi-Ming, SUN Fang-Fang, HUANG He-Zhou.Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K2Mn4O8 Nanocomposites as Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1681-1690
70. SHI Qin, MEN Chun-Yan, LI Juan.Preparation and Electrochemical Capacitance Properties of Graphene Oxide/Polypyrrole Intercalation Composite[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1691-1697
71. WU Hong-Ying, WANG Huan-Wen.Synthesis and Characterization of NiCo2O4 Nanoflower/Activated Carbon Fiber Composite and Its Supercapacitor Properties[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1501-1506
72. QIAN Jia-Sheng, LIU Ming-Xian, GAN Li-Hua, LÜ Yao-Kang, CHEN Ling-Yan, YE Rui-Jie, CHEN Long-Wu.Synthesis and Electrochemical Performance of Microporous Carbon Using a Zinc(II)-Organic Coordination Polymer[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1494-1500
73. ZHU Qi-Rong, LI Hui-Qin, LI Ning, CHAI Jing, GAO Run-Gang, LIANG Qi.Nanotribological and Wear Properties of Graphene[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1582-1587
74. PENG Jin-Ping, ZHANG Dong-Dong, GUAN Li, ZHANG Hui, ZHANG Zhong, QIU Xiao-Hui.An Electrostatic Force Microscopy Investigation of the Dynamic Properties of Microscopic Interface in Nanocomposites[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1603-1608
75. LONG Mei, CONG Ye, LI Xuan-Ke, CUI Zheng-Wei, DONG Zhi-Jun, YUAN Guan-Ming.Hydrothermal Synthesis and Photocatalytic Activity of Partially Reduced Graphene Oxide/TiO2 Composite[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1344-1350
76. LIU Li, JIANG Wei, YANG Xi-Wen, CHEN Bin-Hua, WU Shi-Xi, LI Feng-Sheng.Facile Fabrication of Novel Magnetic and Fluorescent Fe3O4-CdSe Nanocomposites[J]. Acta Phys. -Chim. Sin., 2013,29(05): 1088-1096
77. WANG Qiang, HUANG Li-Ping, YU Hong-Tao, QUAN Xie, CHEN Guo-Hua.Recent Developments of Graphene Electrodes in Bioelectrochemical Systems[J]. Acta Phys. -Chim. Sin., 2013,29(05): 889-896
78. XU Jing, ZHU Yong-Fa.Elimination of Bisphenol A from Water via Graphene Oxide Adsorption[J]. Acta Phys. -Chim. Sin., 2013,29(04): 829-836
79. TANG Peng, XIAO Jian-Jian, ZHENG Chao, WANG Shi, CHEN Run-Feng.Graphene-Like Molybdenum Disulfide and Its Application in Optoelectronic Devices[J]. Acta Phys. -Chim. Sin., 2013,29(04): 667-677
80. XU Gui-Yin, DING Bing, NIE Ping, LUO Hong-Jun, ZHANG Xiao-Gang.Preparation and Electrochemical Performance of Carbon Nanotubes/ Graphene Oxide/Sulfur Complex Cathode Material[J]. Acta Phys. -Chim. Sin., 2013,29(03): 546-552
81. PAN Hui, ZHAO Tian, ZHANG Yu-Dong, ZHANG Zhi-Jun.Preparation, Characterization and Properties of Titania/Graphite Oxide Nanocomposite[J]. Acta Phys. -Chim. Sin., 2013,29(03): 660-666
82. GAN Yong-Ping, QIN Huai-Peng, HUANG Hui, TAO Xin-Yong, FANG Jun-Wu, ZHANG Wen-Kui.Preparation and Photocatalytic Activity of Rutile TiO2-Graphene Composites[J]. Acta Phys. -Chim. Sin., 2013,29(02): 403-410
83. ZOU Hui, NI Xiang, PENG Sheng-Lin, OUYANG Jun, CHEN Yu, OUYANG Fang-Ping.First-Principles Study of Graphene-Based Biomolecular Sensor[J]. Acta Phys. -Chim. Sin., 2013,29(02): 250-254
84. HU Ying-Ying, HU Zhong-Ai, ZHANG Ya-Jun, LU Ai-Lian, XU Huan, ZHANG Zi-Yu, YANG Yu-Ying, LI Li, WU Hong-Ying.Synthesis and Electrochemical Characterization of RuO2·xH2O/Graphite Nanosheet Composite Array Electrodes for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(02): 305-310
85. LI Li-Xiang, TAO Jing, GENG Xin, AN Bai-Gang.Preparation and Supercapacitor Performance of Nitrogen-Doped Carbon Nanotubes from Polyaniline Modification[J]. Acta Phys. -Chim. Sin., 2013,29(01): 111-116
86. WANG Hong-Zhi, GAO Cui-Xia, ZHANG Peng, YAO Su-Wei, ZHANG Wei-Guo.Synthesis and Electrochemical Performance of Graphene/Polyaniline[J]. Acta Phys. -Chim. Sin., 2013,29(01): 117-122
87. WANG Wan-Li, MA Zi-Feng.Synthesis and Characteristics of Pt/graphene by Co-Reduction Method for Oxygen Reduction Reactions[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2879-2884
88. ZhONG Hao-Xiang, ZHAO Chun-Bao, LUO Hao, ZHANG Ling-Zhi.Novel Organosilicon Ionic Liquid Based Electrolytes for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2641-2647
89. SU Peng, GUO Hui-Lin, PENG San, NING Sheng-Ke.Preparation of Nitrogen-Doped Graphene and Its Supercapacitive Properties[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2745-2753
90. LI Song-Mei, WANG Bo, LIU Jian-Hua, YU Mei, AN Jun-Wei.Synthesis and Microwave Absorption Properties of Nickel Nanoparticles-Graphene Composites with Different Morphologies[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2754-2760
91. HUANG Wen, ZHAO Jin, KANG Qi, XU Kaichen, YU Zhen, WANG Jian, MA Yan-Wen, HUANG Wei.Preparation of Three-Dimensional Carbon Microtube/Carbon Nanotube Composites and Their Application in Supercapacitor[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2269-2275
92. ZHANG Yan-Feng, GAO Teng, ZHANG-Yu, LIU Zhong-Fan.Controlled Growth of Graphene on Metal Substrates and STM Characterizations for Microscopic Morphologies[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2456-2464
93. FAN Cheng-Wei, ZHANG Xin, CHEN Sheng, WANG Hai-Fang, CAO Ao-Neng.Solution-Processable, Highly Conductive, Permanently Rippled Graphene Sheets[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2465-2470
94. LING Xi, ZHANG Jin.Investigation of the Adsorption Behavior of PbPc on Graphene by Raman Spectroscopy[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2355-2362
95. LI Guo-Hua, CHEN Dan, ZHENG Xiang, XIE Wei-Miao, CHENG Yuan.Preparation and Electrocatalytic Activity of WC/W2C Nanocomposite with Core-Shell Structure[J]. Acta Phys. -Chim. Sin., 2012,28(09): 2077-2083
96. ZHANG Jun-Jun, ZHANG Zhen-Hua, GUO Chao, LI Jie, DENG Xiao-Qing.Electronic Transport Properties for a Zigzag-Edged Triangular Graphene[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1701-1706
97. SHEN Bao-Shou, FENG Wang-Jun, LANG Jun-Wei, WANG Ru-Tao, TAI Zhi-Xin, YAN Xing-Bin.Nitric Acid Modification of Graphene Nanosheets Prepared by Arc- Discharge Method and Their Enhanced Electrochemical Properties[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1726-1732
98. RAN Ke, CHEN Qing, ZUO Jian-Min.Fabrication and Structure Characterization of Quasi-2-Dimensional Amorphous Carbon Structures[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1551-1555
99. ZHANG Xiao, YANG Rong, WANG Chen, HENG Cheng-Lin.Cell Biocompatibility of Functionalized Graphene Oxide[J]. Acta Phys. -Chim. Sin., 2012,28(06): 1520-1524
100. LIU Bo, SUN Hong-Juan, PENG Tong-Jiang.Factor Group Analysis of Molecular Vibrational Modes of Graphene and Density Functional Calculations[J]. Acta Phys. -Chim. Sin., 2012,28(04): 799-804
101. CHE Qian, ZHANG Fang, ZHANG Xiao-Gang, LU Xiang-Jun, DING Bing, ZHU Jia-Jia.Preparation of Ordered Mesoporous Carbon/NiCo2O4 Electrode and Its Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2012,28(04): 837-842
102. LIU Dong, SHEN Jun, LI Ya-Jie, LIU Nian-Ping, LIU Bin.Pore Structures of Carbon Aerogels and Their Effects on Electrochemical Supercapacitor Performance[J]. Acta Phys. -Chim. Sin., 2012,28(04): 843-849
103. LIU Kong-Hua, LIU Lan, GAO Hong, LUO Yuan-Fang, JIA De-Min.In situ Preparation of Epoxy-Based Conductive Nanocomposites Containing Nanosilver-Decorated Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2012,28(03): 711-719
104. JIN Yu, CHEN Hong-Yuan, CHEN Ming-Hai, LIU Ning, LI Qing-Wen.Carbon Nanotube/Polyaniline/Graphene Composite Paper and Its Electrochemical Capacitance Behaviors[J]. Acta Phys. -Chim. Sin., 2012,28(03): 609-614
105. XIE Peng-Yang, ZHUANG Gui-Lin, LÜ Yong-An, WANG Jian-Guo, LI Xiao-Nian.Enhanced Bonding between Noble Metal Adatoms and Graphene with Point Defects[J]. Acta Phys. -Chim. Sin., 2012,28(02): 331-337
106. ZHU Jian-Bo, XU You-Long, WANG Jie, WANG Jing-Ping.Electropolymerization and Characterization of Fast Charge-Discharge PPy/F-SWNTs Composite Materials[J]. Acta Phys. -Chim. Sin., 2012,28(02): 373-380
107. SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei.Activated Carbon-Based Supercapacitors Using Li2SO4 Aqueous Electrolyte[J]. Acta Phys. -Chim. Sin., 2012,28(02): 367-372
108. XU Ke, SHEN Lai-Fa, MI Chang-Huan, ZHANG Xiao-Gang.Synthesis and Electrochemical Performance of Graphene Modified LiFePO4 Cathode Materials[J]. Acta Phys. -Chim. Sin., 2012,28(01): 105-110
109. ZHANG Xiao-Yan, SUN Ming-Xuan, SUN Yu-Jun, LI Jing, SONG Peng, SUN Tong, CUI Xiao-Li.Photoelectrochemical Properties of Graphene Oxide Thin Film Electrodes[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2831-2835
110. GUO Pei-Zhi, JI Qian-Qian, ZHANG Li-Li, ZHAO Shan-Yu, ZHAO Xiu-Song.Preparation and Characterization of Peanut Shell-Based Microporous Carbons as Electrode Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2836-2840
111. TANG Jun, KANG Chao-Yang, LI Li-Min, XU Peng-Shou.Direct Graphene Growth by Depositing Carbon Atoms on Si Substrate Covered by SiC Buffer Layers[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2953-2959
112. HU Xian-Chao, CHEN Dan, SHI Bin-Bin, LI Guo-Hua.Preparation of Tungsten Carbide and Titania Nanocomposite and Its Electrocatalytic Activity for Methanol[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2863-2871
113. YANG Xiao-Wei, HE Yu-Shi, LIAO Xiao-Zhen, MA Zi-Feng.Improved Graphene Film by Reducing Restacking for Lithium Ion Battery Applications[J]. Acta Phys. -Chim. Sin., 2011,27(11): 2583-2586
114. XUE Rong, YAN Jing-Wang, TIAN Ying, YI Bao-Lian.Lanthanum Doped Manganese Dioxide/Carbon Nanotube Composite Electrodes for Electrochemical Supercapacitors[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2340-2346
115. LU Xiang-Jun, DOU Hui, YANG Su-Dong, HAO Liang, ZHANG Fang, ZHANG Xiao-Gang.Fabrication and Electrochemical Capacitive Behavior of Freestanding Graphene/Polyaniline Nanofibre Film[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2333-2339
116. YUAN Wen-Hui, LI Bao-Qing, LI Li.Superior Graphene for Hydrogen Adsorption Prepared by the Improved Liquid Oxidation-Reduction Method[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2244-2250
117. MIN Shi-Xiong, Lü Gong-Xuan.Preparation of CdS/Graphene Composites and Photocatalytic Hydrogen Generation from Water under Visible Light Irradiation[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2178-2184
118. LI Zhao, XU Ju-Liang, LI Xu-Yan, GUO Li-Fang, LI Jin, JIANG Yi-Ming.Preparation of Manganese Dioxide for Electrodes of Supercapacitors Based on Duplex Stainless Steel[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1424-1430
119. YING Hong, WANG Zhi-Yong, GUO Zheng-Duo, SHI Zu-Jin, YANG Shang-Feng.Reduced Graphene Oxide-Modified Bi2WO6 as an Improved Photocatalyst under Visible Light[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1482-1486
120. ZHOU Jin, LI Wen, XING Wei, ZHUO Shu-Ping.Capacitive Performance of Tunable Ordered Mesoporous Carbons in Organic and H2SO4 Electrolytes[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1431-1438
121. ZHANG Yi, CHEN Biao, YANG Zu-Pei, ZHANG Zhi-Jun.Controlled Synthesis and Characterization of the Structure and Property of Fe3O4 Nanoparticle-Graphene Oxide Composites[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1261-1266
122. SUN Da-Li, PENG Sheng-Lin, OUYANG Jun, OUYANG Fang-Ping.Electronic Transport Properties of Graphene Nanoribbons with Nanoholes[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1103-1107
123. LI Yun-Xia, WEI Zi-Dong, ZHAO Qiao-Ling, DING Wei, ZHANG Qian, CHEN Si-Guo.Preparation of Pt/Graphene Catalyst and Its Catalytic Performance for Oxygen Reduction[J]. Acta Phys. -Chim. Sin., 2011,27(04): 858-862
124. MI Juan, WANG Yu-Ting, GAO Peng-Cheng, LI Wen-Cui.Effects of Thermal Treatment on the Electrochemical Behavior of Manganese Dioxide[J]. Acta Phys. -Chim. Sin., 2011,27(04): 893-899
125. CHEN Jin-Yi, LI Nian, LI Jing, ZHU Liang, PENG Chang-Jun.Synthesis and Visible Light Photocatalytic Activity of Cross-Linked Sodium Rectorite/Cu2O Nanocomposites[J]. Acta Phys. -Chim. Sin., 2011,27(04): 932-938
126. LI Wen, ZHOU Jin, XING Wei, ZHUO Shu-Ping, Lü Yi-Min.Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance[J]. Acta Phys. -Chim. Sin., 2011,27(03): 620-626
127. YU Li-Qiu, CHEN Shu-Li, CHANG Sha, LI Yun-Hu, GAO Yin-Yi, WANG Gui-Ling CAO Dian-Xue.Supercapacitance of NiCo2O4 Nanowire Arrays Grown on Nickel Foam[J]. Acta Phys. -Chim. Sin., 2011,27(03): 615-619
128. YANG Yong-Hui, SUN Hong-Juan, PENG Tong-Jiang, HUANG Qiao.Synthesis and Structural Characterization of Graphene-Based Membranes[J]. Acta Phys. -Chim. Sin., 2011,27(03): 736-742
129. TIAN Ying, YAN Jing-Wang, XUE Rong, YI Bao-Lian.Influence of Electrolyte Concentration and Temperature on the Capacitance of Activated Carbon[J]. Acta Phys. -Chim. Sin., 2011,27(02): 479-485
130. DAI Xian-Qi, LI Yan-Hui, ZHAO Jian-Hua, TANG Ya-Nan.Effects of Vacancy and Boron Doping on Si Adsorption on Graphene[J]. Acta Phys. -Chim. Sin., 2011,27(02): 369-373
131. ZHANG Hai-Jun, ZHANG Xiao-Gang, YUAN Chang-Zhou, GAO Bo, SUN Kang, FU Qing-Bin, LU Xiang-Jun, JIANG Jian-Chun.Preparation of Water Soluble Chitosan-Based Porous Carbon/NiO Composites and Their Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2011,27(02): 455-460
132. LI Guo-Xian, WANG Tao, HE Jian-Ping, ZHOU Jian-Hua, XUE Hai-Rong, MAYi-Ou, HU Yuan-Yuan.Synthesis and Infrared Emissivity of Ordered Mesoporous C-Al2O3-TiO2 Nanocomposites with a Dual Pore System[J]. Acta Phys. -Chim. Sin., 2011,27(01): 248-254
133. ZHANG Fang, YUAN Chang-Zhou, ZHANG Xiao-Gang, ZHANG Luo-Jiang, XU Ke.5-Sulfosalicylic Acid-Assisted Hydrothermal Synthesis and Supercapacitive Properties of Co-Ni Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3175-3180
134. ZHANG Xiao-Bo, CHEN Ming-Hai, ZHANG Xiao-Gang, LI Qing-Wen.Preparation of Porous Carbon Nanofibers by Electrospinning and Their Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3169-3174
135. WU Xiao-Qin, ZONG Rui-Long, MU Hao-Jie, ZHU Yong-Fa.Cataluminescence Performance on Catalysts of Graphene Supported Platinum[J]. Acta Phys. -Chim. Sin., 2010,26(11): 3002-3008
136. ZHANG Dong-Feng, NIU Li-Ya, GUO Lin.Solution Synthesis Strategies for Hierarchical Nanostructures[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2865-2876
137. TIAN Ying, YAN Jing-Wang, LIU Xiao-Xue, XUE Rong, YI Bao-Lian.Electrochemical Capacitance of Composites with MnOx Loaded on the Surface of Activated Carbon Electrodes[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2151-2157
138. HU Yao-Juan, JIN Juan, ZHANG Hui, WU Ping, CAI Chen-Xin.Graphene: Synthesis, Functionalization and Applications in Chemistry[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2073-2086
139. WEN Zhu-Liang, YANG Su-Dong, SONG Qi-Jun, HAO Liang, ZHANG Xiao-Gang.High Activity of Pd/Graphene Catalysts for Ethanol Electrocatalytic Oxidation[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1570-1574
140. LI Li-Min, LIU En-Hui, LI Jian, YANG Yan-Jing, SHEN Hai-Jie, HUANG Zheng-Zheng, XIANG Xiao-Xia.Polyaniline-Based Carbon for a Supercapacitor Electrode[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1521-1526
141. JI Qian-Qian, GUO Pei-Zhi, ZHAO Xiu-Song.Preparation of Chitosan-Based Porous Carbons and Their Application as Electrode Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1254-1258
142. YAO Guo-Xin, SHI Bin-Bin, LI Guo-Hua, ZHENG Yi-Fan.Preparation and Electrocatalytic Activity of Tungsten Carbide and Zeolite Nanocomposite[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1317-1322
143. GAN Lin, LIU Song, LI Dan-Na, GU Hang, CAO Yang, SHEN Qian, WANG Zhen-Xing, WANG Qing, GUO Xue-Feng.Facile Fabrication of the Crossed Nanotube-Graphene Junctions[J]. Acta Phys. -Chim. Sin., 2010,26(04): 1151-1156
144. ZANG Yang, HAO Xiao-Gang, WANG Zhong-De, ZHANG Zhong-Lin, LIU Shi-Bin.Copolymerization and Capacitive Performance of Composite Carbon Nanotubes/Polyaniline/Nickel Hexacyanoferrate Films[J]. Acta Phys. -Chim. Sin., 2010,26(02): 291-298
145. TANG Jun, LIU Zhong-Liang, KANG Chao-Yang, YAN Wen-Sheng, XU Peng-Shou, PAN Hai-Bin, WEI Shi-Qiang, GAO Yu-Qiang, XU Xian-Gang.Annealing Time Dependence of Morphology and Structure of Epitaxial Graphene on 6H-SiC(0001) Surface[J]. Acta Phys. -Chim. Sin., 2010,26(01): 253-258
146. PANG Xu, MA Zheng-Qing, ZUO Lie.Sn Doped MnO2 Electrode Material for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2433-2437
147. SUN Jian-Ping, WENG Jia-Bao, LIN Ting, MA Lin-Pu.Synthesis and Optical Effects of Poly(2-methoxy-5-butoxy)-p-phenylene Vinylene/Eu2O3 Nanocomposites[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2385-2390
148. FU Qing-Bin, GAO Bo, SU Ling-Hao, YUAN Chang-Zhou, LU Xiang-Jun, ZHANG Xiao-Gang.Preparation of Polypyrrole/Benzenesulfonic Functionalized Multi-Walled Carbon Nanotubes Induced by Hydrogen Bonding and Their Electrochemical Behavior[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2199-2204
149. SUN Zhe, LIU Kai-Yu, ZHANG Hai-Feng, LI Ao-Sheng, XU Xiao-Cun.Study on Meso-C/MnO2 Asymmetric Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1991-1997
150. WANG Tao, ZHOU Jian-Hua, WANG Dao-Jun, SUN Dun, DI Zhi-Yong, HE Jian-Ping.Syntheses and Infrared Emissivities of Ordered Mesoporous C-Al2O3 Nanocomposites[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2155-2160
151. JIANG Qi, ZHAO Xiao-Feng, HUANG Bin, DU Bing, ZHAO Yong.Effect of the Activated Carbon Reactivation on Its Electrochemical Capacitance[J]. Acta Phys. -Chim. Sin., 2009,25(04): 757-761
152. MA Ruo-Biao, FU Yan-Bao, MA Xiao-Hua.Preparation and Electrochemical Performance of Tin-Dioxide Filled Multi-Walled Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2009,25(03): 441-445
153. DU Bing, JIANG Qi, ZHAO Xiao-Feng, LIN Sun-Zhong, MU Pei-Shan, ZHAO Yong.Preparation of PPy/CNTs Composite Based on the Electrostatic Absorption Effect[J]. Acta Phys. -Chim. Sin., 2009,25(03): 513-518
154. GAO Qiang; LIU Ya-Fei; HU Zhong-Hua; ZHENG Xiang-Wei; WEN Zu-Biao.Electrochemical Properties of Manganese Oxide Surface-Modified Activated Carbon Electrode Materials[J]. Acta Phys. -Chim. Sin., 2009,25(02): 229-236
155. CHEN Li; ZHANG Xiao-Gang; YUAN Chang-Zhou; CHEN Sheng-Yao.Electrochemical Properties of Poly(3,4-ethylenedioxythiophene)/Manganese Oxide Synthesized by Interfacial Polymerization[J]. Acta Phys. -Chim. Sin., 2009,25(02): 304-308
156. JIANG Qi; ZHANG Qian; DU Bing; ZHAO Xiao-Feng; ZHAO Yong.Preparation and Electrochemical Properties of CNTs-PANI Composite Material via Finite Field Polymerization[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1719-1723
157. LIU Ya-Fei; HU Zhong-Hua; XU Kun; ZHENG Xiang-Wei; GAO Qiang.Surface Modification and Performance of Activated Carbon Electrode Material[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1143-1148
158. ZENG Wen-Wen; HUANG Ke-Long; YANG You-Ping; LIU Su-Qin; LIU Ren-Sheng.Solvothermal Synthesis and Capacitance Performance of Co3O4 with Different Morphologies[J]. Acta Phys. -Chim. Sin., 2008,24(02): 263-268
159. YANG Jing; LIU Ya-Fei; CHEN Xiao-Mei; HU Zhong-Hua; ZHAO Guo-Hua.Carbon Electrode Material with High Densities of Energy and Power[J]. Acta Phys. -Chim. Sin., 2008,24(01): 13-19
160. WANG Yi; JIANG Wei; CHENG Zhi-Peng; ZHANG Xian-Feng; AN Chong-Wei; SONG Xiao-Lan; LI Feng-Sheng.Thermal Performance Investigation of Core-Shell Cu/Al Micron-Nano Composites with WO3[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1753-1759
161. YU Jun-Sheng; SUO Fan; LI Wei-Zhi; LIN Hui; LI Lu; JIANG Ya-Dong.Influence of Electrode Materials on the Performance of NPB/Alq3 Organic Electroluminescent Devices[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1821-1826
162. YANG Jian-Jun; HUANG Jun-Jie; JIANG Zhi-Yu.Supercapacitance of MnO2 Thin Film Electrodes Prepared Using Jet Printing Method[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1365-1369
163. LI Guo-Hua; TIAN Wei; TANG Jun-Yan; MA Chun-An.Preparation and Electrocatalytic Property for Methanol Oxidation of WC/CNT Nanocomposite[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1370-1374
164. WANG Jie; XU You-Long; SUN Xiao-Fei; XIAO Fang; MAO Sheng-Chun.Capacitance Properties of Porous Polypyrrole Thick Films Prepared Electrochemically by Multi-step Polymerization[J]. Acta Phys. -Chim. Sin., 2007,23(06): 877-882
165. WANG Jie;XU You-Long;CHEN Xi;DU Xian-Feng;LI Xi-Fei.Effect of Doping Ions on Electrochemical Capacitance Properties of Polypyrrole Films[J]. Acta Phys. -Chim. Sin., 2007,23(03): 299-304
166. ZHU Lu-Ping;HUANG Wen-Ya;MA Li-Li;FU Shao-Yun;YU Ying;JIA Zhi-Jie.Synthesis and Characteristics of ZnO-CNTs Nanocomposites[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1175-1180
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168. XIAO Xue-Zhang; CHEN Chang-Pin; WANG Xin-Hua; CHEN Li-Xin; WANG Li; GAO Lin-Hui.Microstructure and Electrochemical Properties of Amorphous Mg-Fe-Ni Hydrogen Storage Electrode Material[J]. Acta Phys. -Chim. Sin., 2005,21(05): 565-568
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