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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2016,Vol.32>> Issue(5)>> 1199-1206     doi: 10.3866/PKU.WHXB201602222         中文摘要
Fabrication of Graphene/Cotton and MnO2/Graphene/Cotton Composite Fabrics as Flexible Electrodes for Electrochemical Capacitors
BIAN Shao-Wei, XU Ling-Li, GUO Mei-Xia, SHAO Fu, LIU Si
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, P. R. China
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Graphene/cotton composite fabrics for use as flexible electrodes were prepared using a thermal reduction method. The reducing condition significantly influenced the conductivity of the graphene/cotton fabrics. The conductive graphene/cotton fabrics with hierarchical structures used as flexible electrode substrates facilitate the loading of pseudocapacitor materials, enhancing electron transport and electrolyte ion diffusion. The electrode structure was characterized in detail using scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and the standard four-point probe method. After further electrochemical deposition of MnO2 sheets on the composite fabrics, the resulting MnO2/graphene/cotton composite fabrics for use as electrode materials had excellent electrochemical performance and great flexibility. The specific capacitance reached 536 F·g-1 at a scan rate of 5 mV·s-1. The electrochemical test results indicate that it can be further used for flexible energy storage materials.



Keywords: Graphene   Cotton   Electrochemical capacitor   Flexible electrode   Textile  
Received: 2015-11-16 Accepted: 2016-02-15 Publication Date (Web): 2016-02-22
Corresponding Authors: BIAN Shao-Wei Email: swbian@dhu.edu.cn,bianshaowei@iccas.ac.cn

Fund: The project was supported by the National Natural Science Foundation of China (51402048), Fundamental Research Funds for the Central Universities, China, DHU Distinguished Young Professor Program, and Scientific Research Foundation for the Returned Overseas Chinese Scholars, Ministry of Education of China.

Cite this article: BIAN Shao-Wei, XU Ling-Li, GUO Mei-Xia, SHAO Fu, LIU Si. Fabrication of Graphene/Cotton and MnO2/Graphene/Cotton Composite Fabrics as Flexible Electrodes for Electrochemical Capacitors[J]. Acta Phys. -Chim. Sin., 2016,32 (5): 1199-1206.    doi: 10.3866/PKU.WHXB201602222

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73. JIN Yu, CHEN Hong-Yuan, CHEN Ming-Hai, LIU Ning, LI Qing-Wen.Carbon Nanotube/Polyaniline/Graphene Composite Paper and Its Electrochemical Capacitance Behaviors[J]. Acta Phys. -Chim. Sin., 2012,28(03): 609-614
74. XIE Peng-Yang, ZHUANG Gui-Lin, LÜ Yong-An, WANG Jian-Guo, LI Xiao-Nian.Enhanced Bonding between Noble Metal Adatoms and Graphene with Point Defects[J]. Acta Phys. -Chim. Sin., 2012,28(02): 331-337
75. XU Ke, SHEN Lai-Fa, MI Chang-Huan, ZHANG Xiao-Gang.Synthesis and Electrochemical Performance of Graphene Modified LiFePO4 Cathode Materials[J]. Acta Phys. -Chim. Sin., 2012,28(01): 105-110
76. ZHANG Xiao-Yan, SUN Ming-Xuan, SUN Yu-Jun, LI Jing, SONG Peng, SUN Tong, CUI Xiao-Li.Photoelectrochemical Properties of Graphene Oxide Thin Film Electrodes[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2831-2835
77. TANG Jun, KANG Chao-Yang, LI Li-Min, XU Peng-Shou.Direct Graphene Growth by Depositing Carbon Atoms on Si Substrate Covered by SiC Buffer Layers[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2953-2959
78. YANG Xiao-Wei, HE Yu-Shi, LIAO Xiao-Zhen, MA Zi-Feng.Improved Graphene Film by Reducing Restacking for Lithium Ion Battery Applications[J]. Acta Phys. -Chim. Sin., 2011,27(11): 2583-2586
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80. YUAN Wen-Hui, LI Bao-Qing, LI Li.Superior Graphene for Hydrogen Adsorption Prepared by the Improved Liquid Oxidation-Reduction Method[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2244-2250
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82. YING Hong, WANG Zhi-Yong, GUO Zheng-Duo, SHI Zu-Jin, YANG Shang-Feng.Reduced Graphene Oxide-Modified Bi2WO6 as an Improved Photocatalyst under Visible Light[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1482-1486
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84. SUN Da-Li, PENG Sheng-Lin, OUYANG Jun, OUYANG Fang-Ping.Electronic Transport Properties of Graphene Nanoribbons with Nanoholes[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1103-1107
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87. YANG Yong-Hui, SUN Hong-Juan, PENG Tong-Jiang, HUANG Qiao.Synthesis and Structural Characterization of Graphene-Based Membranes[J]. Acta Phys. -Chim. Sin., 2011,27(03): 736-742
88. SUN Gang-Wei, SONG Wen-Hua, LIU Xiao-Jun, QIAO Wen-Ming, LING Li-Cheng.Asymmetric Capacitance Behavior Based on the Relationship between Ion Dimension and Pore Size[J]. Acta Phys. -Chim. Sin., 2011,27(02): 449-454
89. DAI Xian-Qi, LI Yan-Hui, ZHAO Jian-Hua, TANG Ya-Nan.Effects of Vacancy and Boron Doping on Si Adsorption on Graphene[J]. Acta Phys. -Chim. Sin., 2011,27(02): 369-373
90. WU Xiao-Qin, ZONG Rui-Long, MU Hao-Jie, ZHU Yong-Fa.Cataluminescence Performance on Catalysts of Graphene Supported Platinum[J]. Acta Phys. -Chim. Sin., 2010,26(11): 3002-3008
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92. HU Yao-Juan, JIN Juan, ZHANG Hui, WU Ping, CAI Chen-Xin.Graphene: Synthesis, Functionalization and Applications in Chemistry[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2073-2086
93. WEN Zhu-Liang, YANG Su-Dong, SONG Qi-Jun, HAO Liang, ZHANG Xiao-Gang.High Activity of Pd/Graphene Catalysts for Ethanol Electrocatalytic Oxidation[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1570-1574
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97. YE Xiang-Guo; ZHANG Xiao-Gang; MI Hong-Yu; YANG Su-Dong.Hydrothermal Microemulsion Synthesis of Co3O4 with Different Morphologies and Their Electrochemical Capacitance[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1105-1110
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100. LI Qiang;LI Kai-Xi;SUN Guo-Hua;FAN Hui;GU Jian-Yu.A New Kind of Redox Electrolyte Electrochemical Capacitor System[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1445-1450
101. YANG Hong-Sheng; ZHOU Xiao; ZHANG Qing-Wu.Electrochemical Performances of Supercapacitor with Polyaniline Particles with Hierarchy as Active Electrode Material[J]. Acta Phys. -Chim. Sin., 2005,21(04): 414-418
102. WANG Xiao-Feng; WANG Da-Zhi; LIANG Ji.Pseudo-capacitance of Ultrafine Nickel Hydroxide Prepared by Sol-gel Method[J]. Acta Phys. -Chim. Sin., 2005,21(02): 117-122
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104. Wang Xiao-Feng;Wang Da-Zhi;Liang Ji.Carbon Nanotube Capacitor Materials Loaded with Different Amounts of Ruthenium Oxide[J]. Acta Phys. -Chim. Sin., 2003,19(06): 509-513
105. LI Guang-Yong, WU Xiao-Han, HE Wei-Na, FANG Jian-Hui, ZHANG Xue-Tong.Controlled Assembly of the Graphene-based Aerogel[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
106. WANG Cheng-Xian, YU Fei, MA Jie.Applications of Graphene-based Hybrid Material as Electrodes in Microbial Fuel Cells[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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109. LIANG Jia-Xu, XIAO Zhi-Chang, ZHI Lin-Jie.Graphenal Polymers: 3D Carbon-rich Polymers as Energy Materials with both Electronic and Ionic Transport Path[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
110. XIA Kai-Lun, JIAN Mu-Qiang, ZHANG Ying-Ying.Advances in Flexible Conductors Based on Nanocarbon Materials[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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