Register
ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2016,Vol.32>> Issue(5)>> 1227-1235     doi: 10.3866/PKU.WHXB201602223         中文摘要
Dilational Viscoelasticity of Imidazole-Based Surface Active Ionic Liquids at the Air/Water Interface
LI Yan, CHAI Jin-Ling
Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, P. R. China
Full text: PDF (3162KB) HTML Export: BibTeX | EndNote (RIS)

Two imidazole-based surface active ionic liquids (CnmimBr) were synthesized, and their aggregation behavior at the air/water interface was studied via an oscillating bubble method. The effects of the CnmimBr concentration, inorganic salts (NaBr and CaBr2), and temperature on the aggregation behavior were investigated. The results of the adsorption dynamics showed that the adsorption-controlled process dominated, but the relaxation process was not purely mono-exponential. The addition of inorganic salt or increase in temperature improved the surface activity of the CnmimBr and lowered the dynamic surface tension. The dilational rheological results revealed that the dilational modulus, elastic modules, and viscous modules increased with increasing oscillating frequencies, and the modulus reached a maximum value with increasing CnmimBr concentration. Increasing the temperature or adding inorganic salts (NaBr or CaBr2) decreased the dilational modulus. The elastic modulus was dominant for the CnmimBr layer, and the elastic modulus of C14mimBr was larger than that of C12mimBr.



Keywords: Adsorption dynamics   Dilational modulus   Air/water interface   Imidazole-based surface active ionic liquid  
Received: 2015-12-07 Accepted: 2016-02-19 Publication Date (Web): 2016-02-22
Corresponding Authors: CHAI Jin-Ling Email: jlchai@sdnu.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (21306092, 21476133) and Science and Technology Plan Project of Shandong Provincial University, China (J12LA02).

Cite this article: LI Yan, CHAI Jin-Ling. Dilational Viscoelasticity of Imidazole-Based Surface Active Ionic Liquids at the Air/Water Interface[J]. Acta Phys. -Chim. Sin., 2016,32 (5): 1227-1235.    doi: 10.3866/PKU.WHXB201602223

(1) Zhu, S.; Wu, Y.; Chen, Q.; Yu, Z.; Wang, C.; Jin, S.; Ding, Y.; Wu, G. Green Chem. 2006, 8, 325. doi: 10.1039/B601395C
(2) Welton, T. Chem. Rev. 1999, 99, 2071. doi: 10.1021/cr980032t
(3) George, A.; Brandt, A.; Tran, K.; Zahari, S. M. S. N. S.; Klein-Marcushamer, D.; Sun, N.; Sathitsuksanoh, N.; Shi, J.; Stavila, V.; Parthasarathi, R.; Singh, S.; Holmes, B. M.; Welton, T.; Simmons, B. A.; Hallett, J. P. Green Chem. 2015, 17, 1728. doi: 10.1039/C4GC01208A
(4) Redel, E.; Krämer, J.; Thomann, R.; Janiak, C. J. Organomet. Chem. 2009, 694, 1069. doi: 10.1016/j.jorganchem.2008.09.050
(5) Vollmer, C.; Redel, E.; Abu-Shandi, K.; Thomann, R.; Manyar, H.; Hardacre, C.; Janiak, C. Chem. -Eur. J. 2010, 16, 3849. doi: 10.1002/chem.200903214
(6) Och?dzan-Siod?ak, W.; Dziubek, K.; Czaja, K. Polym. Bull. 2013, 70, 1. doi: 10.1007/s00289-012-0809-8
(7) Li, R. X. Green Solvent——Synthesis and Utilization of Ionic Liquids; Chemical Industry Press: Beijing, 2004. [李汝雄. 绿色溶剂——离子液体的合成与应用. 北京: 化学工业出版社, 2004.]
(8) Prechtl, M. H. G.; Scholten, J. D.; Dupont, J. J. Mol. Catal. AChem. 2009, 313, 74. doi: 10.1016/j.molcata.2009.08.004
(9) Wang, H. Y.; Li, H. P.; Cui, G. K.; Li, Z. Y.; Wang, J. J. Acta Phys. -Chim Sin. 2016, 32, 249. [王慧勇, 李虹培, 崔国凯, 李志勇, 王键吉. 物理化学学报, 2016, 32, 249.] doi: 10.3866/PKU.WHXB201512042
(10) dos Santos, M. R.; Diniz, J. R.; Arouca, A. M.; Gomes, A. F.; Gozzo, F. C.; Tamborim, S. M.; Parize, A. L.; Suarez, P. A. Z.; Neto, B. A. D. ChemSusChem 2012, 5, 716. doi: 10.1002/cssc.201100453
(11) Chatel, G.; Goux-Henry, C.; Mirabaud, A.; Rossi, T.; Kardos, N.; Andrioletti, B.; Draye, M. J. Catal. 2012, 291, 127. doi: 10.1016/j.jcat.2012.04.016
(12) Shi, L.; Li, N.; Zheng, L. J. Phys. Chem. C 2011, 115, 18295. doi: 10.1021/jp206325d
(13) Zhang, X. H.; Xu, H. Y.; Ge, L. L.; Guo, R. Acta Phys. -Chim. Sin. 2016, 32, 356. [张晓红, 许红岩, 葛玲玲, 郭荣. 物理化学学报, 2016, 32, 356.] doi: 10.3866/PKU.WHXB201512012
(14) Li, X.W.; Gao, Y. A.; Liu, J.; Zheng, L. Q.; Chen, B.; Wu, L. Z.; Tung, C. H. J. Colloid Interface Sci. 2010, 343, 94. doi: 10.1016/j.jcis.2009.11.010
(15) Liu, J.; Zhao, M.; Zhang, Q.; Sun, D.; Wei, X.; Zheng, L. Colloid Polym. Sci. 2011, 289, 1711. doi: 10.1007/s00396-011-2492-y
(16) Shi, L.; Li, N.; Yan, H.; Gao, Y.; Zheng, L. Langmuir 2011, 27, 1618. doi: 10.1021/la104719v
(17) Ao, M.; Huang, P.; Xu, G.; Yang, X.; Wang, Y. Colloid Polym. Sci. 2008, 287, 395. doi: 10.1007/s00396-008-1976-x
(18) Ao, M.; Xu, G.; Zhu, Y.; Bai, Y. J. Colloid Interface Sci. 2008, 326, 490. doi: 10.1016/j.jcis.2008.06.048
(19) Liu, Y.; Yu, L.; Zhang, S.; Yuan, J.; Shi, L.; Zheng, L. Colloid Surf. A 2010, 359, 66. doi: 10.1016/j.colsurfa.2010.01.065
(20) Qin, C.; Chai, J.; Chen, J.; Xia, Y.; Yu, X.; Liu, J. Colloid Polym. Sci. 2008, 286, 579. doi: 10.1007/s00396-007-1818-2
(21) Gochev, G. Curr. Opin. Colloid Interface Sci. 2015, 20, 115. doi: 10.1016/j.cocis.2015.03.003
(22) Ravera, F.; Loglio, G.; Kovalchuk, V. I. Curr. Opin. Colloid Interface Sci. 2010, 15, 217. doi: 10.1016/j.cocis.2010.04.001
(23) Ravera, F.; Ferrari, M.; Santini, E.; Liggieri, L. Adv. Colloid Interface Sci. 2005, 117, 75. doi: 10.1016/j.cis.2005.06.002
(24) Dukhin, S. S.; Kretzhmar, G.; Miller, B. Dynamics of Adsorption at Liquid Interfaces——Theory, Experiment, Application; Elsevier: Amsterdam, 1995.
(25) Zhai, X. R.; Liu, T.; Xu, G. Y.; Tan, G. R.; Lü, X.; Zhang, J. Acta Phys. -Chim. Sin. 2013, 29, 1253. [翟雪如, 刘腾, 徐桂英, 檀国荣, 吕鑫, 张健. 物理化学学报, 2013, 29, 1253.] doi: 10.3866/PKU.WHXB201303251
(26) Yuan, Z.W.; Yuan, J.; Lü, X.; Zhang, J.; Xu, G. Y. Acta Phys. -Chim. Sin. 2013, 29, 449. [苑再武, 苑敬, 吕鑫, 张健, 徐桂英. 物理化学学报, 2013, 29, 449.] doi: 10.3866/PKU.WHXB201212283
(27) Cao, C.; Lei, J.; Zhang, L.; Du, F. P. Langmuir 2014, 30, 13744. doi: 10.1021/la502890w
(28) Cao, C.; Lei, J.; Huang, T.; Du, F. P. Soft Matter 2014, 10, 8896. doi: 10.1039/C4SM01666A
(29) Huang, T.; Cao, C.; Liu, Z. L.; Li, Y.; Du, F. P. Soft Matter 2014, 10, 6810. doi: 10.1039/C4SM00950A
(30) Inoue, T.; Ebina, H.; Dong, B.; Zheng, L. J. Colloid Interface Sci. 2007, 314, 236. doi: 10.1016/j.jcis.2007.05.052
(31) Deng, Q.; Li, H.; Li, C.; Lv, W.; Li, Y. RSC Adv. 2015, 5, 61868. doi: 10.1039/C5RA09120A
(32) Dong, B.; Zhao, X.; Zheng, L.; Zhang, J.; Li, N.; Inoue, T. Colloid Surf. A 2008, 317, 666. doi: 10.1016/j.colsurfa.2007.12.001
(33) Rosen, M. J. Surfactants and Interfacial Phenomena; Wiley: New York, 2004.
(34) Jaycock, M. J.; Parfitt, G. D. Chemistry of Interfaces; John Wiley and Sons: New York, 1981.
(35) Polavarapu, P.; Krafft, M. P. J. Fluorine Chem. 2015, 171, 12. doi: 10.1016/j.jfluchem.2014.10.020
(36) Krafft, M. P.; Fainerman, V. B.; Miller, R. Colloid Polym. Sci. 2015, 293, 3091. doi: 10.1007/s00396-015-3622-8
(37) Jeribi, M.; Almir-Assad, B.; Langevin, D.; Hénaut, I.; Argillier, J. F. J. Colloid Interface Sci. 2002, 256, 268. doi: 10.1006/jcis.2002.8660
(38) Li, J. B.; Zhang, Y.; Yan, L. L. Angew. Chem. Int. Edit. 2001, 40, 891. doi: 10.1002/1521-3773(20010302)40:5<891::AIDANIE891>3.0.CO;2-K
(39) Serrien, G.; Geeraerts, G.; Ghosh, L.; Joos, P. Colloid Surface 1992, 68, 219. doi: 10.1016/0166-6622(92)80208-J
(40) Miller, R.; Aksenenko, E. V.; Liggieri, L.; Ravera, F.; Ferrari, M.; Fainerman, V. B. Langmuir 1999, 15, 1328. doi: 10.1021/la980956b
(41) Klitzing, R. V.; Müller, H. J. Curr. Opin. Colloid Interface Sci. 2002, 7, 42. doi: 10.1016/S1359-0294(02)00005-5
(42) Lv, Q.; Li, Z.; Li, B.; Li, S.; Sun, Q. Ind. Eng. Chem. Res. 2015, 54, 9468. doi: 10.1021/acs.iecr.5b02197
(43) Li, Y. M.; Xu, G. Y.; Xin, X.; Cao, X. R.; Wu, D. Carbohydr. Polym. 2008, 72, 211. doi: 10.1016/j.carbpol.2007.08.008
(44) Xin, X.; Xu, G.; Wu, D.; Gong, H.; Zhang, H.; Wang, Y. Colloid. Surf. A 2008, 322, 54. doi: 10.1016/j.colsurfa.2008.02.025
(45) Zhu, Y.; Xu, G.; Xin, X.; Zhang, H.; Shi, X. J. Chem. Eng. Data 2009, 54, 989. doi: 10.1021/je800788f
(46) Ivanov, I. B.; Danov, K. D.; Ananthapadmanabhan, K. P.; Lips, A. Adv. Colloid Interface Sci. 2005, 114115, 61. doi: 10.1016/j.cis.2004.11.001
(47) Stubenrauch, C.; Fainerman, V. B.; Aksenenko, E. V.; Miller, R. J. Phys. Chem. B 2005, 109, 1505. doi: 10.1021/jp046525l
(48) Wu, D.; Xu, G.; Feng, Y.; Li, Y. Int. J. Biol. Macromol. 2007, 40, 345. doi: 10.1016/j.ijbiomac.2006.09.004
(49) He, F.; Xu, G.; Pang, J.; Ao, M.; Han, T.; Gong, H. Langmuir 2011, 27, 538. doi: 10.1021/la103478c
(50) Stubenrauch, C.; Miller, R. J. Phys. Chem. B 2004, 108, 6412. doi: 10.1021/jp049694e

1. LIU Zhi-Hong, FAN Cheng-Cheng, ZHANG Tian-Tian, JI Xian-Jing, CHEN Sheng-Hui, SUN Shuang-Qing, HU Song-Qing.Density Functional Theory Study of the Interaction between Sodium Dodecylbenzenesulfonate and Mineral Cations[J]. Acta Phys. -Chim. Sin., 2016,32(2): 445-452
2. NIE Long-Hui, TAN Qiao, ZHU Wei, WEI Qi, LIN Zhi-Kui.Fast Adsorption Removal of Congo Red on Hierarchically Porous γ-Al2O3 Hollow Microspheres Prepared by Microwave-Assisted Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2015,31(9): 1815-1822
3. LI Ming, CAO Chong, XIONG Ke-Jie, DU Feng-Pei.Effect of Hydrophobic Chain Length on the Interfacial Dilational Rheological Properties of Polyoxyethylene Sorbitan Fatty Acid Ester[J]. Acta Phys. -Chim. Sin., 2015,31(2): 322-328
4. HU Song-Qing, JI Xian-Jing, FAN Zhong-Yu, ZHANG Tian-Tian, SUN Shuang-Qing.Counterion Effects on the Properties of Sulfate Surfactants at the Air/Liquid Interface by Molecular Dynamics Simulation[J]. Acta Phys. -Chim. Sin., 2015,31(1): 83-89
5. SHEN Qi, FAN Ying-Ju, YIN Long, SUN Zhong-Xi.Two-Dimensional Continuous Online In situ ATR-FTIR Spectroscopic Investigation of Adsorption of Butyl Xanthate on CuO Surfaces[J]. Acta Phys. -Chim. Sin., 2014,30(2): 359-364
6. DONG Zhi-Long, DING Wei, LIU Kun, ZHANG Zhi-Wei, QU Guang-Miao, YU Tao.Adsorption Performance of Tetradecyl Aryl Sulfonates on Oil Sand from the Daqing Oilfield[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2767-2772
7. DENG Lin, QI Zhi-Mei.Effect of Glass Silylation on the Adsorption Behavior of Rhodamine 6G and Methylene Blue[J]. Acta Phys. -Chim. Sin., 2010,26(07): 1923-1928
8. SONG Bing-Lei, ZHAO Jian-Xi.Adsorption of Photosensitive Quaternary Ammonium Gemini Surfactant a4-6-m at the Air/Water Interface[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2020-2025
9. SUN Xiao-Li, ZENG Qing-Xuan, FENG Chang-Gen.Adsorption Kinetics of Chromium (VI) onto an Anion Exchange Fiber Containing Polyamine[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1951-1957
10. LI Zhen-Quan, ZHANG Lei, YAN Feng, ZHANG Lu, ZHAO Sui, YU Jia-Yong.Surface Dilational Properties of N-Acyltaurate Amphiphiles with Aromatic Side Chains[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1939-1944
11. ZHANG Lei; GONG Qing-Tao; ZHOU Zhao-Hui; WANG Wu-Ning; ZHANG Lu; ZHAO Sui; YU Jia-Yong.Study of Interfacial Dilational Properties by the Spinning Drop Technique[J]. Acta Phys. -Chim. Sin., 2009,25(01): 41-46
12. ZHANG Lei; WANG Xiao-Chun; GONG Qing-Tao; LUO Lan; ZHANG Lu; ZHAO Sui; YU Jia-Yong.Dilational Properties of Tri-substituent Sodium Alkyl Benzene Sulfonates with Different Structures at the Air/Water and Decane/Water Interfaces[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1881-1885
13. ZHANG Lei; WANG Xiao-Chun; GONG Qing-Tao; LUO Lan; ZHANG Lu; ZHAO Sui; YU Jia-Yong.Dynamic Dilational Properties of 2,5-dipropyl-4-undecylbenzene Sulfonate at the Air/Water Interface[J]. Acta Phys. -Chim. Sin., 2007,23(10): 1652-1656
14. ZHOU Tian-Hua; ZHAO Jian-Xi.Adsorption Kinetics of Asymmetric Gemini Surfactants at Air/Water Interface[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1047-1052
15. ZHANG Chun-Rong;LI Zhen-Quan;LUO Lan;ZHANG Lu;SONG Xin-Wang;CAO Xu-Long;ZHAO Sui;YU Jia-Yong .Effect of Oxyethylene Numbers on Surface Dilational Properties of Octylphenol polyoxyethylene ethers[J]. Acta Phys. -Chim. Sin., 2007,23(02): 247-252
16. HUANG Yu-Ping;ZHANG Lei;LUO Lan;ZHANG Lu;ZHAO Sui;YU Jia-Yong.Dilational Properties of Hydroxy-substituted Sodium Alkyl Benzene Sulfonate at Surface and Water-decane Interface[J]. Acta Phys. -Chim. Sin., 2007,23(01): 12-15
17. SONG Xin-Wang;WANG Yi-Yang;CAO Xu-Long;LUO Lan;WANG Lin;ZHANG Lu;YUE Xiang-An;ZHAO Sui;YU Jia-Yong.Dilational Viscoelastic Properties of Sodium Alkyl Benzene Sulfonates with Different Structures at Octane/Water Interface[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1441-1444
18. WANG Dong-xian; LUO Lan; ZHANG Lu; WANG Yi-yang; ZHAO Sui; YU Jia-yong.Study on Interfacial Interaction between Hydrophobically Modified Polyacrylamide and Surfactants[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1205-1210
19. Wang Yi-Yang;Zhang Lu;Sun Tao-Lei;Fang Hong-Bo;Zhao Sui;Yu Jia-Yong.Influences of Demulsifiers with Different Structures on Dilational Properties of Decane-Water Interface by Interfacial Tension Relaxation Methods[J]. Acta Phys. -Chim. Sin., 2003,19(05): 455-459
20. Wang Yi-Yang;Zhang Lu;Sun Tao-Lei;Fang Hong-Bo;Zhao Sui;Yu Jia-Yong.Influences of Demulsifiers with Different Structures on Dilational Properties of Decane/Water Interface[J]. Acta Phys. -Chim. Sin., 2003,19(04): 297-301
21. LIU Shan-Shan, JI Shan, CHEN Qi-Bin, PENG Chang-Jun, LIU Hong-Lai.Surface Patterning and Force-induced Reversible Structure Transformation of Supramolecular Polymer Brush PVP-Chol[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388 Email:whxb@pku.edu.cn
^ Top