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Acta Physico-Chimica Sinca  2016, Vol. 32 Issue (5): 1227-1235    DOI: 10.3866/PKU.WHXB201602223
ARTICLE     
Dilational Viscoelasticity of Imidazole-Based Surface Active Ionic Liquids at the Air/Water Interface
Yan LI,Jin-Ling CHAI*()
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Abstract  

Two imidazole-based surface active ionic liquids (CnmimBr) were synthesized, and their aggregation behavior at the air/water interface was studied via an oscillating bubble method. The effects of the CnmimBr concentration, inorganic salts (NaBr and CaBr2), and temperature on the aggregation behavior were investigated. The results of the adsorption dynamics showed that the adsorption-controlled process dominated, but the relaxation process was not purely mono-exponential. The addition of inorganic salt or increase in temperature improved the surface activity of the CnmimBr and lowered the dynamic surface tension. The dilational rheological results revealed that the dilational modulus, elastic modules, and viscous modules increased with increasing oscillating frequencies, and the modulus reached a maximum value with increasing CnmimBr concentration. Increasing the temperature or adding inorganic salts (NaBr or CaBr2) decreased the dilational modulus. The elastic modulus was dominant for the CnmimBr layer, and the elastic modulus of C14mimBr was larger than that of C12mimBr.



Key wordsAdsorption dynamics      Dilational modulus      Air/water interface      Imidazole-based surface active ionic liquid     
Received: 07 December 2015      Published: 22 February 2016
MSC2000:  O647  
Fund:  the National Natural Science Foundation of China(21306092);the National Natural Science Foundation of China(21476133);Science and Technology Plan Project of Shandong Provincial University, China(J12LA02)
Corresponding Authors: Jin-Ling CHAI     E-mail: jlchai@sdnu.edu.cn
Cite this article:

Yan LI,Jin-Ling CHAI. Dilational Viscoelasticity of Imidazole-Based Surface Active Ionic Liquids at the Air/Water Interface. Acta Physico-Chimica Sinca, 2016, 32(5): 1227-1235.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB201602223     OR     http://www.whxb.pku.edu.cn/Y2016/V32/I5/1227

 
SAIL cmc/(mmol?L-1) γcmc/(mN?m-1) πcmc/(mN?m-1) pc20 Γmax/(μmol?m-2) Amin/nm2
C12mimBr 5.20 36.73 35.77 3.07 3.12 5.32
C14mimBr 1.59 36.58 36.92 3.93 3.15 5.27
 
CnmimBr Concentration of CnmimBr/(mmol?L-1)
(times of cmc)
C12mimBr 1.03 0.103 0.0103 0.00103 0.000103
(10-1cmc) (10-2cmc) (10-3cmc) (10-4cmc) (10-5cmc)
C14mimBr 0.255 0.0255 0.00255 0.000255 0.000255
(10-1cmc) (10-2cmc) (10-3cmc) (10-4cmc) (10-5cmc)
 
 
 
 
 
 
 
 
 
1 Zhu S. ; Wu Y. ; Chen Q. ; Yu Z. ; Wang C. ; Jin S. ; Ding Y. ; Wu G. Green Chem. 2006, 8, 325.
2 Welton T. Chem. Rev. 1999, 99, 2071.
3 George A. ; Brandt A. ; Tran K. ; Zahari S. M. S. N. S. ; Klein-Marcushamer D. ; Sun N. ; Sathitsuksanoh N. ; Shi J. ; Stavila V. ; Parthasarathi R. ; Singh S. ; Holmes B. M. ; Welton T. ; Simmons B. A. ; Hallett J. P. Green Chem. 2015, 17, 1728.
4 Redel E. ; Kr?mer J. ; Thomann R. ; Janiak C. J. Organomet. Chem. 2009, 694, 1069.
5 Vollmer C. ; Redel E. ; Abu-Shandi K. ; Thomann R. ; Manyar H. ; Hardacre C. ; Janiak C. Chem. -Eur. J. 2010, 16, 3849.
6 Och?dzan-Siod?ak W. ; Dziubek K. ; Czaja K. Polym. Bull. 2013, 70, 1.
7 Li R. X. Green Solvent——Synthesis and Utilization of Ionic Liquids Beijing: Chemical Industry Press, 2004.
7 李汝雄. 绿色溶剂——离子液体的合成与应用, 北京: 化学工业出版社, 2004.
8 Prechtl M. H. G. ; Scholten J. D. ; Dupont J. J. Mol. Catal. AChem. 2009, 313, 74.
9 Wang H. Y. ; Li H. P. ; Cui G. K. ; Li Z. Y. ; Wang J. J. Acta Phys. -Chim Sin. 2016, 32, 249.
9 王慧勇; 李虹培; 崔国凯; 李志勇; 王键吉. 物理化学学报, 2016, 32, 249.
10 dos Santos M. R. ; Diniz J. R. ; Arouca A. M. ; Gomes A. F. ; Gozzo F. C. ; Tamborim S. M. ; Parize A. L. ; Suarez P. A. Z. ; Neto B. A. D. ChemSusChem 2012, 5, 716.
11 Chatel G. ; Goux-Henry C. ; Mirabaud A. ; Rossi T. ; Kardos N. ; Andrioletti B. ; Draye M. J. Catal. 2012, 291, 127.
12 Shi L. ; Li N. ; Zheng L. J. Phys. Chem. C 2011, 115, 18295.
13 Zhang X. H. ; Xu H. Y. ; Ge L. L. ; Guo R. Acta Phys. -Chim. Sin. 2016, 32, 356.
13 张晓红; 许红岩; 葛玲玲; 郭荣. 物理化学学报, 2016, 32, 356.
14 Li X.W. ; Gao Y. A. ; Liu J. ; Zheng L. Q. ; Chen B. ; Wu L. Z. ; Tung C. H. J. Colloid Interface Sci. 2010, 343, 94.
15 Liu J. ; Zhao M. ; Zhang Q. ; Sun D. ; Wei X. ; Zheng L. Colloid Polym. Sci. 2011, 289, 1711.
16 Shi L. ; Li N. ; Yan H. ; Gao Y. ; Zheng L. Langmuir 2011, 27, 1618.
17 Ao M. ; Huang P. ; Xu G. ; Yang X. ; Wang Y. Colloid Polym. Sci. 2008, 287, 395.
18 Ao M. ; Xu G. ; Zhu Y. ; Bai Y. J. Colloid Interface Sci. 2008, 326, 490.
19 Liu Y. ; Yu L. ; Zhang S. ; Yuan J. ; Shi L. ; Zheng L. Colloid Surf. A 2010, 359, 66.
20 Qin C. ; Chai J. ; Chen J. ; Xia Y. ; Yu X. ; Liu J. Colloid Polym. Sci. 2008, 286, 579.
21 Gochev G. Curr. Opin. Colloid Interface Sci. 2015, 20, 115.
22 Ravera F. ; Loglio G. ; Kovalchuk V. I. Curr. Opin. Colloid Interface Sci. 2010, 15, 217.
23 Ravera F. ; Ferrari M. ; Santini E. ; Liggieri L. Adv. Colloid Interface Sci. 2005, 117, 75.
24 Dukhin S. S. ; Kretzhmar G. ; Miller B. Dynamics of Adsorption at Liquid Interfaces——Theory, Experiment, Application Elsevier: Amsterdam, 1995.
25 Zhai X. R. ; Liu T. ; Xu G. Y. ; Tan G. R. ; Lü X. ; Zhang J. Acta Phys. -Chim. Sin. 2013, 29, 1253.
25 翟雪如; 刘腾; 徐桂英; 檀国荣; 吕鑫; 张健. 物理化学学报, 2013, 29, 1253.
26 Yuan Z.W. ; Yuan J. ; Lü X. ; Zhang J. ; Xu G. Y. Acta Phys. -Chim. Sin. 2013, 29, 449.
26 苑再武; 苑敬; 吕鑫; 张健; 徐桂英. 物理化学学报, 2013, 29, 449.
27 Cao C. ; Lei J. ; Zhang L. ; Du F. P. Langmuir 2014, 30, 13744.
28 Cao C. ; Lei J. ; Huang T. ; Du F. P. Soft Matter 2014, 10, 8896.
29 Huang T. ; Cao C. ; Liu Z. L. ; Li Y. ; Du F. P. Soft Matter 2014, 10, 6810.
30 Inoue T. ; Ebina H. ; Dong B. ; Zheng L. J. Colloid Interface Sci. 2007, 314, 236.
31 Deng Q. ; Li H. ; Li C. ; Lv W. ; Li Y. RSC Adv. 2015, 5, 61868.
32 Dong B. ; Zhao X. ; Zheng L. ; Zhang J. ; Li N. ; Inoue T. Colloid Surf. A 2008, 317, 666.
33 Rosen M. J. Surfactants and Interfacial Phenomena Wiley: New York, 2004.
34 Jaycock M. J. ; Parfitt G. D. Chemistry of Interfaces John Wiley and Sons: New York, 1981.
35 Polavarapu P. ; Krafft M. P. J. Fluorine Chem. 2015, 171, 12.
36 Krafft M. P. ; Fainerman V. B. ; Miller R. Colloid Polym. Sci. 2015, 293, 3091.
37 Jeribi M. ; Almir-Assad B. ; Langevin D. ; Hénaut I. ; Argillier J. F. J. Colloid Interface Sci. 2002, 256, 268.
38 Li J. B. ; Zhang Y. ; Yan L. L. Angew. Chem. Int. Edit. 2001, 40, 891.
39 Serrien G. ; Geeraerts G. ; Ghosh L. ; Joos P. Colloid Surface 1992, 68, 219.
40 Miller R. ; Aksenenko E. V. ; Liggieri L. ; Ravera F. ; Ferrari M. ; Fainerman V. B. Langmuir 1999, 15, 1328.
41 Klitzing R. V. ; Müller H. J. Curr. Opin. Colloid Interface Sci. 2002, 7, 42.
42 Lv Q. ; Li Z. ; Li B. ; Li S. ; Sun Q. Ind. Eng. Chem. Res. 2015, 54, 9468.
43 Li Y. M. ; Xu G. Y. ; Xin X. ; Cao X. R. ; Wu D. Carbohydr. Polym. 2008, 72, 211.
44 Xin X. ; Xu G. ; Wu D. ; Gong H. ; Zhang H. ; Wang Y. Colloid. Surf. A 2008, 322, 54.
45 Zhu Y. ; Xu G. ; Xin X. ; Zhang H. ; Shi X. J. Chem. Eng. Data 2009, 54, 989.
46 Ivanov I. B. ; Danov K. D. ; Ananthapadmanabhan K. P. ; Lips A. Adv. Colloid Interface Sci. 2005, 114- 11, 61.
47 Stubenrauch C. ; Fainerman V. B. ; Aksenenko E. V. ; Miller R. J. Phys. Chem. B 2005, 109, 1505.
48 Wu D. ; Xu G. ; Feng Y. ; Li Y. Int. J. Biol. Macromol. 2007, 40, 345.
49 He F. ; Xu G. ; Pang J. ; Ao M. ; Han T. ; Gong H. Langmuir 2011, 27, 538.
50 Stubenrauch C. ; Miller R. J. Phys. Chem. B 2004, 108, 6412.
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