ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2016,Vol.32>> Issue(5)>> 1227-1235     doi: 10.3866/PKU.WHXB201602223         中文摘要
Dilational Viscoelasticity of Imidazole-Based Surface Active Ionic Liquids at the Air/Water Interface
LI Yan, CHAI Jin-Ling
Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, P. R. China
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Two imidazole-based surface active ionic liquids (CnmimBr) were synthesized, and their aggregation behavior at the air/water interface was studied via an oscillating bubble method. The effects of the CnmimBr concentration, inorganic salts (NaBr and CaBr2), and temperature on the aggregation behavior were investigated. The results of the adsorption dynamics showed that the adsorption-controlled process dominated, but the relaxation process was not purely mono-exponential. The addition of inorganic salt or increase in temperature improved the surface activity of the CnmimBr and lowered the dynamic surface tension. The dilational rheological results revealed that the dilational modulus, elastic modules, and viscous modules increased with increasing oscillating frequencies, and the modulus reached a maximum value with increasing CnmimBr concentration. Increasing the temperature or adding inorganic salts (NaBr or CaBr2) decreased the dilational modulus. The elastic modulus was dominant for the CnmimBr layer, and the elastic modulus of C14mimBr was larger than that of C12mimBr.

Keywords: Adsorption dynamics   Dilational modulus   Air/water interface   Imidazole-based surface active ionic liquid  
Received: 2015-12-07 Accepted: 2016-02-19 Publication Date (Web): 2016-02-22
Corresponding Authors: CHAI Jin-Ling Email:

Fund: The project was supported by the National Natural Science Foundation of China (21306092, 21476133) and Science and Technology Plan Project of Shandong Provincial University, China (J12LA02).

Cite this article: LI Yan, CHAI Jin-Ling. Dilational Viscoelasticity of Imidazole-Based Surface Active Ionic Liquids at the Air/Water Interface[J]. Acta Phys. -Chim. Sin., 2016,32 (5): 1227-1235.    doi: 10.3866/PKU.WHXB201602223

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