Please wait a minute...
Acta Physico-Chimica Sinca  2016, Vol. 32 Issue (7): 1715-1721    DOI: 10.3866/PKU.WHXB201604121
ARTICLE     
Catalytic Effect of Silver Cathodes on 3,4,5,6-Tetrachloropicolinic Acid Dechlorination in Aqueous Solutions
Hong-Xing MA,Ting-Jie GE,Qian-Qian CAI,Ying-Hua XU*(),Chun-An MA*()
Download: HTML     PDF(3234KB) Export: BibTeX | EndNote (RIS)      
Received: 02 March 2016      Published: 12 April 2016
MSC2000:  O646  
Fund:  the National Natural Science Foundation of China(21106133);National Natural Science Foundation of China(21576238);Natural Science Foundation of Zhejiang Province, China(LY16B060012);National Key Basic Research Program of China (973)(2012CB722604)
Corresponding Authors: Ying-Hua XU,Chun-An MA     E-mail: xuyh@zjut.edu.cn;science@zjut.edu.cn
Cite this article:

Hong-Xing MA,Ting-Jie GE,Qian-Qian CAI,Ying-Hua XU,Chun-An MA. Catalytic Effect of Silver Cathodes on 3,4,5,6-Tetrachloropicolinic Acid Dechlorination in Aqueous Solutions. Acta Physico-Chimica Sinca, 2016, 32(7): 1715-1721.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB201604121     OR     http://www.whxb.pku.edu.cn/Y2016/V32/I7/1715

 
 
Bond TeCP free TeCP?-free TeCP-Ag4 TeCP?--Ag4
C3 —Cl 0.175 0.178 0.174 0.177
C4—Cl 0.175 0.261 0.174 0.248
C5 —Cl 0.175 0.178 0.174 0.178
C6—Cl 0.177 0.181 0.176 0.180
 
ET process Energy/(kJ?mol-1) E/V (vs Ag/AgCl)
?H ?G
TeCP free + e- → TeCP?- free 150.99 139.51 -1.64
TeCP-Ag4+ e- → TeCP?--Ag4 95.41 83.24 -1.06
 
 
Entry Operating conditions E/V t/min pH range Final product distribution/%
TeCP 3,5,6-T 3,6-D 3,5-D
1a 5 mmol·L -1 TeCP (pH = 7.0) —0.80 30 7.0—11.5 8.4 83.1 4.3 0.0
2b 5 mmol· L -1 TeCP (pH = 4.0) —0.55 30 4.0—2.0 60.0 35.0 0.0 4.3
 
1 Isse A. A. ; Durante C. ; Gennaro A. Electrochem. Commun. 2011, 13, 810.
2 Yong B. ; Yu G. ; Huang J. Acta Phys. -Chim. Sin. 2006, 22, 306.
2 杨波; 余刚; 黄俊. 物理化学学报, 2006, 22, 306.
3 Rondinini, S.; Vertova, A. Electroreduction of Halogenated Organic Compounds. In Electrochemistry for the Environment; Comninellis, C., Chen G. Eds.; Springer: New York, 2010; pp 279-284. doi: 10.1007/978-0-387-68318-8
4 Sun Z. R. ; Li B. H. ; Hu X. ; Shi M. ; Ge H. ; Peng Y. Z. J. Chem. Ind. Eng. 2008, 59, 1271.
4 孙治荣; 李保华; 胡翔; 石敏; 葛慧; 彭永臻. 化工学报, 2008, 59, 1271.
5 Scialdone O. ; Guarisco C. ; Galia A. ; Herbois R. J. Electroanal. Chem. 2010, 641, 14.
6 Isse A. A. ; Mussini P. R. ; Gennaro A. J. Phys. Chem. C 2009, 113, 14983.
7 Xu Y. H. ; Ma H. X. ; Cai Q. Q. ; Zhu Y. H. ; Ma C. A. Acta Phys. -Chim. Sin. 2013, 29, 973.
7 徐颖华; 马红星; 蔡倩倩; 朱英红; 马淳安. 物理化学学报, 2013, 29, 973.
8 Isse A. A. ; Giusti A. D. ; Gennaro A. ; Falciola L. ; Mussini P. R. Electrochim. Acta 2006, 51, 4956.
9 Andrieux C. P. ; Gorande A. L. ; Savéant J. M. J.Am. Chem. Soc. 1992, 114, 6892.
10 Isse A. A. ; Falciola L. ; Mussini P. R. ; Gennaro A. Chem. Commun. 2006, No. 3, 344.
11 Isse A. A. ; Berzi G. ; Falciola L. ; Rossi M. ; Mussini P. R. ; Gennaro A. J.Appl. Electrochem. 2009, 39, 2217.
12 Isse A. A. ; Gottardello S. ; Durante C. ; Gennaro A. Phys. Chem. Chem. Phys. 2008, 10, 2409.
13 Rondinini S. ; Aricci G. ; Krpetic Z. ; Locatelli C. ; Minguzzi A. ; Porta F. ; Vertova A. Fuel Cells 2009, 9, 253.
14 Ardizzone S. ; Cappelletti G. ; Doubova L. M. ; Mussini P. R. ; Passeri S. M. ; Rondinini S. Electrochim. Acta 2003, 48, 3789.
15 Isse A. A. ; Gottardello S. ; Maccato C. ; Gennaro A. Electrochem. Commun. 2006, 8, 1707.
16 Saez V. ; Esclapez M. D. ; Bonete P. ; Gonzalez-Garcia J. ; Perez J. M. Electrochim. Acta 2008, 53, 3210.
17 Esclapez M. D. ; Diez-Garcia M. I. ; Saez V. ; Tudela I. ; Perez J. M. ; Gonzalez-Garcia J. ; Bonete P. Electrochim. Acta 2011, 56, 8138.
18 Wang A. ; Huang Y. F. ; Sur U. K. ; Wu D. Y. ; Ren B. ; Rondinini S. ; Amatore C. ; Tian Z. Q. J.Am. Chem. Soc. 2010, 132, 9534.
19 Huang Y. F. ; Wu D. Y. ; Wang A. ; Ren B. ; Rondinini S. ; Tian Z. Q. ; Amatore C. J. Am. Chem. Soc. 2010, 132, 17199.
20 Sun S. C. ; Bernard I. ; Birke R. L. ; Lombardi J. R. J.Electroanal. Chem. 1985, 196, 359.
21 Wen R. ; Fang Y. Vib. Spectrosc. 2005, 39, 106.
22 Dressler D. H. ; Mastai Y. ; Rosenbluh M. ; Fleger Y. J.Mol. Struct. 2009, 935, 92.
23 Xu Y. H. ; Zhang H. ; Chu C. P. ; Ma C. A. J.Electroanal. Chem. 2012, 664, 39.
24 Xu Y. H. ; Zhu Y. H. ; Zhao F. M. ; Ma C. A. Appl. Catal. A: Gen. 2007, 324, 83.
25 Xu Y. H. ; Ding X. F. ; Ma H. X. ; Chu Y. Q. ; Ma C. A. Electrochim. Acta 2015, 151, 284.
26 Yanai T. ; Tew D. P. ; Handy N. C. Chem. Phys. Lett. 2004, 393, 51.
27 Krishnan R. ; Binkley J. S. ; Seeger R. ; Pople J. A. J.Chem. Phys. 1980, 72, 650.
28 McLean A. D. ; Chandler G. S. J.Chem. Phys. 1980, 72, 5639.
29 Frisch, M. J.; Trucks, G.W.; Schlegel, H. B.; et al. Gaussian 03, Revision C.01; Gaussian Inc.: Pittsburgh, PA, 2003.
30 Lopez-Salido I. ; Lim D. C. ; Kim Y. D. Surf. Sci. 2005, 588, 6.
31 Minguzzi A. ; Lugaresi O. ; Aricci G. ; Rondinini S. ; Vertova A. Electrochem. Commun. 2012, 22, 25.
32 Lugaresi O. ; Perales-Rondón J. V. ; Minguzzi A. ; Solla-Gullón J. ; Rondinini S. ; Feliu J. M. ; Sánchez-Sánchez C. M. Appl. Catal. B: Environ. 2015, 163, 554.
33 Cardinale A. ; Isse A. A. ; Gennaro A. ; Robert M. ; Savéant J. M. J.Am. Chem. Soc. 2002, 124, 13533.
34 Isse A. A. ; Gennaro A. J.Phys. Chem. A 2004, 108, 4180.
35 Savéant J. M. Chem. Rev. 2008, 108, 2348.
36 Costentin C. ; Louault C. ; Robert M. ; Teillout A. L. J.Phys. Chem. A 2005, 109, 2984.
37 Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications, 2nd ed.; Wiley: New York, 2001; pp 595-601.
38 Ma C. A. ; Ma H. ; Xu Y. H. ; Chu Y. Q. ; Zhao F. M. Electrochem. Commun. 2009, 11, 2133.
39 Bode D. D. ; Andersen J. T. N. ; Eyring H. J.Phys. Chem. 1967, 71, 792.
40 Durante C. ; Isse A. A. ; Sandonà G. ; Gennaro A. Appl. Catal. B: Environ. 2009, 88, 479.
[1] SHEN Xiangyan, HE Jianjiang, WANG Ning, HUANG Changshui. Graphdiyne for Electrochemical Energy Storage Devices[J]. Acta Physico-Chimica Sinca, 0, (): 0-0.
[2] CHEN Yanhuan, LI Jiaofu, LIU Huibiao. Preparation of Graphdiyne-Organic Conjugated Molecular Composite Materials for Lithium Ion Batteries[J]. Acta Physico-Chimica Sinca, 0, (): 0-0.
[3] Shichao ZHOU,Guitao FENG,Dongdong XIA,Cheng LI,Yonggang WU,Weiwei LI. Star-Shaped Electron Acceptor based on Naphthalenediimide-Porphyrin for Non-Fullerene Organic Solar Cells[J]. Acta Physico-Chimica Sinca, 2018, 34(4): 344-347.
[4] Ke CHEN,Zhenhua SUN,Ruopian FANG,Feng LI,Huiming CHENG. Development of Graphene-based Materials for Lithium-Sulfur Batteries[J]. Acta Physico-Chimica Sinca, 2018, 34(4): 377-390.
[5] Mingchuan LUO,Yingjun SUN,Yingnan Yingjun,Yong YANG,Dong WU,Shaojun GUO. Boosting Oxygen Reduction Catalysis by Tuning the Dimensionality of Pt-based Nanostructures[J]. Acta Physico-Chimica Sinca, 2018, 34(4): 361-376.
[6] YANG Huachao, BO Zheng, SHUAI Xiaorui, YAN Jianhua, CEN Kefa. Influence of Wettability on the Charging Dynamics of Electric Double-Layer Capacitors[J]. Acta Physico-Chimica Sinca, 0, (): 0-0.
[7] YANG Ruilong, ZHANG Diyu, ZHU Kangwei, ZHOU Huanlin, YE Xiaoqiu, KLEYN Aart W., HU Yin, HUANG Qiang. In Situ Study of the Conversion Reaction of CO2 and CO2-H2 Mixtures in Radio Frequency Discharge Plasma[J]. Acta Physico-Chimica Sinca, 0, (): 0-0.
[8] Xiyue ZHANG,Yalan HUANG,Shuwei WU,Yinxiang ZENG,Minghao YU,Faliang CHENG,Xihong LU,Yexiang TONG. Engineering Oxygen-Deficient Na2Ti3O7 Nanobelt Arrays on Carbon Cloth as Advanced Flexible Anodes for Sodium-Ion Batteries[J]. Acta Physico-Chimica Sinca, 2018, 34(2): 219-226.
[9] Qiang MA,Yongsheng HU,Hong LI,Liquan CHEN,Xuejie HUANG,Zhibin ZHOU. An Sodium Bis (trifluoromethanesulfonyl) imide-based Polymer Electrolyte for Solid-State Sodium Batteries[J]. Acta Physico-Chimica Sinca, 2018, 34(2): 213-218.
[10] GU Yuxing, YANG Juan, WANG Dihua. Electrochemical Features of Carbon Prepared by Molten Salt Electro-reduction of CO2[J]. Acta Physico-Chimica Sinca, 0, (): 0-0.
[11] NING Hui, WANG Wenhang, MAO Qinhu, ZHENG Shirui, YANG Zhongxue, ZHAO Qingshan, WU Mingbo. Catalytic Electroreduction of CO2 to C2H4 Using Cu2O Supported on 1-Octyl-3-methylimidazole Functionalized Graphite Sheets[J]. Acta Physico-Chimica Sinca, 0, (): 0-0.
[12] ZHAO Mingyu, ZHU Lin, FU Bowen, JIANG Suhua, ZHOU Yongning, SONG Yun. Sodium Ion Storage Performance of NiCo2S4 Hexagonal Nanosheets[J]. Acta Physico-Chimica Sinca, 0, (): 0-0.
[13] TIAN Xiaochun, WU Xuee, ZHAN Dongping, ZHAO Feng, JIANG Yanxia, SUN Shigang. Research on Electron Transfer in the Microenvironment of the Biofilm by Scanning Electrochemical Microscopy[J]. Acta Physico-Chimica Sinca, 0, (): 0-0.
[14] Shao-Qing ZHANG,Jian-Hui HOU. Rational Design Strategies for Polymer Donors for Applications in Non-Fullerene Organic Photovoltaic Cells[J]. Acta Physico-Chimica Sinca, 2017, 33(12): 2327-2338.
[15] Xiao-Ye NIU,Xiao-Qin DU,Qin-Chao WANG,Xiao-Jing WU,Xin ZHANG,Yong-Ning ZHOU. AlN-Fe Nanocomposite Thin Film:A New Anode Material for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinca, 2017, 33(12): 2517-2522.