ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2016,Vol.32>> Issue(8)>> 2108-2112     doi: 10.3866/PKU.WHXB201605091         中文摘要
Effects of F- Concentration on the Morphologies and Fluorescent Lifetimes of Ln3+-Doped Up-Conversion Nanocrystals
LIU Shan-Shan1,2, XU Zheng1,2, ZHAO Su-Ling1,2, LIANG Zhi-Qin1,2, ZHU Wei1,2
1 Key Laboratory of Luminescence and Optical Information (Beijing Jiaotong University), Ministry of Education, Beijing 100044, P. R. China;
2 Institute of Optoelectronics Technology, Beijing Jiaotong University, Beijing 100044, P. R. China
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Up-conversion luminescent NaYF4:Yb3+/Er3+ nanomaterials were synthesized using a solvo-thermal method. It was determined that the size, morphology, and luminescence intensity of these nanoparticles can be controlled by varying the concentration of fluoride ions. Low reactant concentrations were found to always result in monodisperse, hexagonal nanocrystals, and to gradually and uniformly decrease the size of the NaYF4 nanocrystals. In contrast, at higher concentrations, the nanocrystals grow to form a mixed phase. Fluoride ion concentrations over a specific range tend to promote the fluorescence emission of the material and may also significantly affect the fluorescent lifetime.

Keywords: Up-conversion luminescent   Nanomaterial   NaYF4   Morphology control   Fluorescent llifetime  
Received: 2016-03-07 Accepted: 2016-05-06 Publication Date (Web): 2016-05-09
Corresponding Authors: XU Zheng Email:

Fund: The projiect was supported by the National High Technology Research and Development Program of China (863 )(2013AA032205), Natioal Natural Science Foundation of China (51272022, 11474018), and Research Fund for the Doctoral Program of Higher Education, China (20120009130005), and State Key Laboratory of New Technology of Float Glass Project in 2014 Open Topic, China.

Cite this article: LIU Shan-Shan, XU Zheng, ZHAO Su-Ling, LIANG Zhi-Qin, ZHU Wei. Effects of F- Concentration on the Morphologies and Fluorescent Lifetimes of Ln3+-Doped Up-Conversion Nanocrystals[J]. Acta Phys. -Chim. Sin., 2016,32 (8): 2108-2112.    doi: 10.3866/PKU.WHXB201605091

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