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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2016,Vol.32>> Issue(9)>> 2171-2184     doi: 10.3866/PKU.WHXB201606131         中文摘要
Controllable Synthesis of Pd Nanocrystals for Applications in Fuel Cells
XU Han, TONG Ye-Xiang, LI Gao-Ren
School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P. R. China
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The properties of Pd nanocrystals (NCs) intended for use in electrocatalytic applications greatly depend on their surface structures and morphologies. Recent developments in the shape-controlled synthesis of polyhedral Pd NCs represent a promising means of precisely tuning their electrocatalytic properties, and thus may enable the performance enhancement of electrocatalytic Pd NCs. In this comprehensive review, we concentrate on the most important current research concerning the shape-controlled synthesis of polyhedral Pd NCs and their electrocatalytic applications in fuel cells. After a brief introduction to the general NC growth mechanisms and the relationship between their surface structures and shapes, we focus on a variety of shapecontrolled synthesis strategies that have been explored to control the fabrication of polyhedral Pd NCs. This review also examines the applications of Pd NCs to the electrocatalytic oxidation of formic acid, methanol, and ethanol as well as the reduction of O2, with an emphasis on their use in fuel cells. Finally, we outline our personal perspectives on future research directions that are underway with regard to catalytic uses of polyhedral Pd NCs.



Keywords: Pd nanocrystal   Polyhedron   Electrocatalyst   Controllable synthesis   Fuel cell  
Received: 2016-04-25 Accepted: 2016-06-13 Publication Date (Web): 2016-06-13
Corresponding Authors: LI Gao-Ren Email: ligaoren@mail.sysu.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (51173212, 21476271), National Key Basic Research Program of China (973) (2015CB932304), Natural Science Foundation of Guangdong Province, China (S2013020012833), and Project of High Level Talents in Higher School of Guangdong Province, China.

Cite this article: XU Han, TONG Ye-Xiang, LI Gao-Ren. Controllable Synthesis of Pd Nanocrystals for Applications in Fuel Cells[J]. Acta Phys. -Chim. Sin., 2016,32 (9): 2171-2184.    doi: 10.3866/PKU.WHXB201606131

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17. FU Zhao-Ming, WANG Ming-Yang, ZHANG Yan-Xing, ZHANG Na, YANG Zong-Xian.First-Principles Study on the Microstructure of Triple-Phase Boundaries in the Ni/Yttria-Stabilized Zirconia Anode[J]. Acta Phys. -Chim. Sin., 2014,30(6): 1055-1060
18. XU Li, PAN Guo-Shun, LIANG Xiao-Lu, LUO Gui-Hai, ZOU Chun-Li, LUO Hai-Mei.Electrocatalytic Activity of Fe-N/C-TsOH Catalyst for the Oxygen Reduction Reaction in Alkaline Media[J]. Acta Phys. -Chim. Sin., 2014,30(2): 318-324
19. LIU Dan-Dan, XIE Yong-Min, LIU Jiang, WANG Jin-Xia.Preparation of NiO-YSZ-Graphite Aqueous Slurry and Its Application in Fabricating Solid Oxide Fuel Cells by Slip-Casting[J]. Acta Phys. -Chim. Sin., 2014,30(2): 331-337
20. ZHOU Yang, HU Xian-Chao, LI Li-Qing, CHEN Xi-Rong.Palladium Nanoparticles Supported on Hollow Mesoporous Tungsten Trioxide Microsphere as Electrocatalyst for Formic Acid Oxidation[J]. Acta Phys. -Chim. Sin., 2014,30(1): 83-87
21. HAN Shuai-Yuan, YUE Bao-Hua, YAN Liu-Ming.Research Progress in the Development of High-Temperature Proton Exchange Membranes Based on Phosphonic Acid Group[J]. Acta Phys. -Chim. Sin., 2014,30(1): 8-21
22. HU Zhi, HUANG Xiao-Wei, CHEN Yang-Hui.Synthesis and Properties of SmBaCo2O5+δ Cathode Material via EDTA-Glycine Process[J]. Acta Phys. -Chim. Sin., 2013,29(12): 2585-2591
23. LIU De-Zhi, HOU Xi-Xin, ZHU Xiu-Ling, WANG Rui, JING Jian, CUI Yue.Preparation and Physicochemical Property of Self-Crosslinked Poly(phthalazinone ether ketone) Anion-Exchange Membranes[J]. Acta Phys. -Chim. Sin., 2013,29(12): 2573-2578
24. TANG Fa-Wei, GUO Wei-Min, TANG Nan-Nan, PEI Jun-Yan, XU Xuan.Quantum Chemical Study on the Adsorption of Formic on a Pt-Sn(111)/CAlloy Surface[J]. Acta Phys. -Chim. Sin., 2013,29(10): 2198-2206
25. ZHAO Tian-Tian, LIN Rui, ZHANG Lu, CAO Chui-Hui, MA Jian-Xin.Effects of Pt Content on the Catalytic Performance of Co@Pt/C Core-Shell Structured Electrocatalysts[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1745-1752
26. LIN Xue, YU Li-Li, Yan Li-Na, GUAN Qing-Feng, Yan Yong-Sheng, ZHAO Han.Controllable Synthesis and Photocatalytic Activity of Spherical, Flowerlike and Threadlike Bismuth Vanadates[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1771-1777
27. MENG Xiu-Xia, GONG Xun, YANG Nai-Tao, TAN Xiao-Yao, MA Zi-Feng.Preparation and Properties of Direct-Methane Solid Oxide Fuel Cell Based on a Graded Cu-CeO2-Ni-YSZ Composite Anode[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1719-1726
28. ZHOU Yang, LIU Wei-Ming, HU Xian-Chao, CHU You-Qun, MA Chun-An.Nano-WO3 Composite Materials as Electro-Catalyst for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1487-1493
29. DENG Xu-Li, ZHAO Dong-Mei, DING Zuo-Long, MA Gui-Lin.Dense 5%Al3+-Doped SnP2O7-SnO2 Composite Ceramic for Application in Intermediate Temperature Fuel Cell[J]. Acta Phys. -Chim. Sin., 2013,29(05): 953-958
30. SUN Hong-Yan, ZHAO Lian-Hua, Yu Feng-Chun.Preparation and Characterization of Pt-Ir-SnO2/C Anode Catalyst for Direct Ethanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2013,29(05): 959-965
31. WANG Qiang, HUANG Li-Ping, YU Hong-Tao, QUAN Xie, CHEN Guo-Hua.Recent Developments of Graphene Electrodes in Bioelectrochemical Systems[J]. Acta Phys. -Chim. Sin., 2013,29(05): 889-896
32. LI Shang, WANG Jia-Tang, CHEN Rui-Xin, ZHAO Wei, QIAN Liu, PAN Mu.Catalytic Performance of Heat-Treated Fe-Melamine/C and Fe-g-C3N4/C Electrocatalysts for Oxygen Reduction Reaction[J]. Acta Phys. -Chim. Sin., 2013,29(04): 792-798
33. ZHU Yan-Yan, LIU Yan-Fang, LÜ Yan-Hui, WANG Hua, LING Qiang, ZHU Yong-Fa.Reflux Preparation and Photocatalytic Performance of Bismuth Phosphate Nanorods[J]. Acta Phys. -Chim. Sin., 2013,29(03): 576-584
34. CHEN Qiu-Xiang, ZHANG Jie-Jing, WANG Yu-Xin.Micro-Modelling of PEMFC Taking Account of Gaseous and Liquid Water inside the Catalyst Layer[J]. Acta Phys. -Chim. Sin., 2013,29(03): 559-568
35. LIN Xue, GUAN Qing-Feng, LIU Ting-Ting, ZHANG Yao, ZOU Chun-Jie.Controllable Synthesis and Photocatalytic Activity of Bi4Ti3O12 Particles with Different Morphologies[J]. Acta Phys. -Chim. Sin., 2013,29(02): 411-417
36. ZHOU Yang, CHU You-Qun, LIU Wei-Ming, MA Chun-An.Nano-WO3 Modified Carbon Nanotube Supported Pt and Their Electrocatalytic Activity for Methanol Electro-Oxidation[J]. Acta Phys. -Chim. Sin., 2013,29(02): 287-292
37. QIN Guo-Heng, HUANG Xiao-Wei, HU Zhi.Chemical Compatibility and Electrochemical Performance between LaAlO3-Based Electrolyte and Selected Anode Materials[J]. Acta Phys. -Chim. Sin., 2013,29(02): 311-318
38. CAO Chun-Hui, LIN Rui, ZHAO Tian-Tian, HUANG Zhen, MA Jian-Xin.Preparation and Characterization of Core-Shell Co@Pt/C Catalysts for Fuel Cell[J]. Acta Phys. -Chim. Sin., 2013,29(01): 95-101
39. WANG Hong-Tao, SUN Lin, CHEN Ji-Tang, LUO Chun-Hua.Ionic Conduction in Sn0.9Mg0.1P2O7 at Intermediate Temperatures[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2893-2897
40. WANG Wan-Li, MA Zi-Feng.Synthesis and Characteristics of Pt/graphene by Co-Reduction Method for Oxygen Reduction Reactions[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2879-2884
41. ZHENG Ning, ZHU Chun-Mei, SUN Bin, SHI Zu-Jin, LIU Yan, WANG Yuan.Nanocomposite Cathode Catalyst with High Methanol Tolerance and Durability[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2263-2268
42. LI Zhen-Hu, MA Yu-Rong, QI Li-Min.Controlled Synthesis of Cobalt-Doped Magnetic Iron Oxide Nanoparticles[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2493-2499
43. ZHOU Xin-Wen, GAN Ya-Li, SUN Shi-Gang.Studies of Oxidation Processes of Methanol on Hollow CoPt Nanospheres and In situ Electrochemical Fourier Transform Infrared Spectroscopy[J]. Acta Phys. -Chim. Sin., 2012,28(09): 2071-2076
44. LI Qiang, ZHAO Hui, JIANG Rui, GUO Li-Fan.Synthesis and Electrochemical Properties of La1.6Sr0.4Ni1-xCuxO4 as Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells[J]. Acta Phys. -Chim. Sin., 2012,28(09): 2065-2070
45. SUN De-Lin, ZHOU Jian.Dissipative Particle Dynamics Simulations on Mesoscopic Structures of Nafion and PVA/Nafion Blend Membranes[J]. Acta Phys. -Chim. Sin., 2012,28(04): 909-916
46. NIE Su-Lian, ZHAO Yan-Chun, FAN Jie-Wen, TIAN Jian-Niao, NING Zhen, LI Xiao-Xiao.Highly Active Pd-Co3O4/MWCNTs Catalysts for Methanol Electrocatalytic Oxidation[J]. Acta Phys. -Chim. Sin., 2012,28(04): 871-876
47. LIU Yan-Fang, MA Xin-Guo, YI Xin, ZHU Yong-Fa.Controllable Synthesis and Photocatalytic Performance of Bismuth Phosphate Nanorods[J]. Acta Phys. -Chim. Sin., 2012,28(03): 654-660
48. ZHUANG Shu-Xin, LIU Su-Qin, ZHANG Jin-Bao, TU Fei-Yue, HUANG Hong-Xia, HUANG Ke-Long, LI Yan-Hua.Application of Nanoporous Perovskite La1-xCaxCoO3 in an Al-H2O2 Semi Fuel Cell[J]. Acta Phys. -Chim. Sin., 2012,28(02): 355-360
49. FAN Yu-Qian, SHAO Hai-Bo, WANG Jian-Ming, LIU Liang, ZHANG Jian-Qing, CAO Chu-Nan.Discharge Performance of Alkaline Sulfide Fuel Cells Using Non-Precious Anode Catalysts[J]. Acta Phys. -Chim. Sin., 2012,28(01): 90-94
50. YANG Jun-Fang, CHENG Ji-Gui, FAN Yu-Meng, WANG Rui, GAO Jian-Feng.Preparation, Structure and Properties of Pr1.2Sr0.8NiO4 Cathode Materials for Intermediate-Temperature Solid Oxide Fuel Cells[J]. Acta Phys. -Chim. Sin., 2012,28(01): 95-99
51. LI Qing-Wu, WEI Zi-Dong, CHEN Si-Guo, QI Xue-Qiang, LIU Xiao, DING Wei, MAYu.PtSnCo/C Anode Catalyst for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2857-2862
52. DANG Dai, GAO Hai-Li, PENG Liang-Jin, SU Yun-Lan, LIAO Shi-Jun, WANG Ye.Preparation of High Performance Core-Shell PdRu@Pt/CNT Electrocatalyst[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2379-2384
53. XU Li, QIAO Jin-Li, DING Lei, HU Long-Yu, LIU Ling-Ling, WANG Hai-Jiang.Electrocatalytic Activity of CoPy/C Catalyst for the Oxygen Reduction Reaction in Alkaline Electrolyte[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2251-2254
54. FU Rong, ZHENG Jun-Sheng, WANG Xi-Zhao, MA Jian-Xin.Effect of the Reduction Heat-Treatment Condition on the Performance of Pt-Fe/C Alloy Catalyst[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2141-2147
55. WANG Xi-Zhao, FU Rong, ZHENG Jun-Sheng, Ma Jian-Xin.Platinum Nanoparticles Supported on Carbon Nanofibers as Anode Electrocatalysts for Proton Exchange Membrane Fuel Cells[J]. Acta Phys. -Chim. Sin., 2011,27(08): 1875-1880
56. WEN Sheng, GONG Chun-Li, TSAI Fang-Chang, YEH Jen-Taut.Properties of SPES/AlOOH Composite Proton Exchange Membranes[J]. Acta Phys. -Chim. Sin., 2011,27(08): 1886-1892
57. ZHANG Min, LI Jing-Jian, PAN Mu, XU Dong-Sheng.Catalytic Performance of Pt Nanowire Arrays for Oxygen Reduction[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1685-1688
58. LI Yun-Xia, WEI Zi-Dong, ZHAO Qiao-Ling, DING Wei, ZHANG Qian, CHEN Si-Guo.Preparation of Pt/Graphene Catalyst and Its Catalytic Performance for Oxygen Reduction[J]. Acta Phys. -Chim. Sin., 2011,27(04): 858-862
59. LIU Chun-Yan, XU Bin, TANG Ya-Wen, CAO Gao-Ping, YANG Yu-Sheng, LU Tian-Hong.Electrocatalytic Performance of Pd Catalyst Supported on Macropore Carbon for Oxidation of Formic Acid[J]. Acta Phys. -Chim. Sin., 2011,27(03): 604-608
60. WANG Yu, YU Gang, CAI Bin, ZHU Yue-Xiang, XIE You-Chang.Delicately Controlled Synthesis of Mesoporous Carbon Materials with Thin Pore Walls[J]. Acta Phys. -Chim. Sin., 2011,27(03): 729-735
61. WANG Xi-Zhao, ZHENG Jun-Sheng, FU Rong, MA Jian-Xin.Pulse-Microwave Assisted Chemical Reduction Synthesis of Pt/C Catalyst and Its Electrocatalytic Oxygen Reduction Activity[J]. Acta Phys. -Chim. Sin., 2011,27(01): 85-90
62. ZHAO Yan-Chun, ZHAN Lu, TIAN Jian-Niao, NIE Su-Lian, NING Zhen.N-Doped Amorphous Carbon Supported Pd Catalysts for Methanol Electrocatalytic Oxidation[J]. Acta Phys. -Chim. Sin., 2011,27(01): 91-96
63. LI Huan-Zhi, TANG Ya-Wen, LU Tian-Hong.Effect of NH4+ on the Electrocatalytic Performance of Carbon Supported Pd Catalyst for Formic Acid Oxidation[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3199-3202
64. GAO Hai-Li, LIAO Shi-Jun, ZENG Jian-Huang, LIANG Zhen-Xing, XIE Yi-Chun.Preparation and Characterization of Platinum-Decorated Ru/C Catalyst with High Performance and Superior Poison Tolerance[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3193-3198
65. GONG Chun-Li, ZHOU Yi, YAN Li-Cheng, WEN Sheng, ZHENG Gen-Wen.Properties of SPES/PWA/SiO2 Composite Proton Exchange Membranes[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2967-2974
66. ZHAO Yan-Chun, LAN Huang-Xian, DENG Bin-Bin, TIAN Jian-Niao, YANG Xiu-Lin, WANG Feng-Yang.Electrocatalytic Oxidation of Methanol with Poly Functionalized Multiwalled Carbon Nanotubes Supported Pt Catalysts[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2255-2260
67. TANG Yu-Bao, LIU Jiang.Fueling Solid Oxide Fuel Cells with Activated Carbon[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1191-1194
68. SUN Dun, HE Jian-Ping, ZHOU Jian-Hua, WANG Tao, DI Zhi-Yong, DING Xiao-Chun.Galvanic Replacement Strategy for a Core-Shell Like Ni-Pt Electrocatalyst with High Pt Utilization[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1219-1224
69. AN Xiao-Sha, CHEN De-Jun, ZHOU Zhi-You, WANG Qiang, FAN You-Jun, SUN Shi-Gang.Rare Earth Eu Doped PtRu/C Catalysts and Their Properties for Methanol Electrooxidation[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1207-1213
70. DONG Bo, CHEN Fei-Wu, WEI Mei-Ju.Comparative Study of Two Integration Methods for Solvation Effect Calculation[J]. Acta Phys. -Chim. Sin., 2010,26(04): 1043-1050
71. ZONG Wei-Zheng, ZHU Yong-Fa.Preparation of Single-Chamber Solid Oxide Fuel Cell by Co-Pressing and Direct Forming Process[J]. Acta Phys. -Chim. Sin., 2010,26(04): 827-832
72. WU Yan-Ni, LIAO Shi-Jun.Shortened Carbon Nanotubes as Supports to Prepare High-Performance Pt/SCNT and PtRu/SCNT Catalysts for Fuel Cells[J]. Acta Phys. -Chim. Sin., 2010,26(03): 669-674
73. LEI Ze, ZHU Qing-Shan, HAN Min-Fang.Fabrication and Performance of Direct Methane SOFC with a Cu-CeO2-Based Anode[J]. Acta Phys. -Chim. Sin., 2010,26(03): 583-588
74. LIANG Peng, XU Hong-Feng, LIU Ming, LU Lu, FU Jie.Electrochemical Performance Testing and Characterization of Silver-Plated and Graphite-Coated 316L Stainless Steel Bipolar Plates[J]. Acta Phys. -Chim. Sin., 2010,26(03): 595-600
75. GAO Yin-Yi, CAO Dian-Xue, WANG Gui-Ling, YIN Cui-Lei.Catalytic Behavior of NiCo2O4 for H2O2 Electroreduction in Alkaline Medium[J]. Acta Phys. -Chim. Sin., 2010,26(01): 29-33
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77. FANG Xiang, SHEN Pei-Kang.Mechanism of Ethanol Electrooxidation on Pd Electrode[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1933-1938
78. WANG Jian-She, GUO Xun, SONG Cheng-Ying, WANG Liu-Cheng, ZHAO Jian-Hong, QIU Xin-Ping.Promoting Methanol Electro-Oxidation through Fabricating Pore Structure in Pt/CNTs Catalyst Layer by Dissolving Away Premixed La2O3 Particles[J]. Acta Phys. -Chim. Sin., 2009,25(04): 767-772
79. ZHENG Gen-Wen, GONG Chun-Li, WEN Sheng, ZHOU Huan-Bo, XIE Xiao-Lin.Preparation and Properties of Sulfonated Poly(ether sulfone)/Boron Phosphate Composite Proton Exchange Membranes[J]. Acta Phys. -Chim. Sin., 2009,25(03): 575-582
80. KE Xi; CUI Guo-Feng; SHEN Pei-Kang.Stability of Pd-Fe Alloy Catalysts[J]. Acta Phys. -Chim. Sin., 2009,25(02): 213-217
81. WEN Qing; LIU Zhi-Min; CHEN Ye; LI Kai-Feng; ZHU Ning-Zheng.Electrochemical Performance of Microbial Fuel Cell with Air-Cathode[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1063-1067
82. WANG Lin; CHEN Shun-Quan; LIU Yuan.NiO/LaMnO3 Catalysts for Steam Reforming of Ethanol[J]. Acta Phys. -Chim. Sin., 2008,24(05): 849-854
83. ZHENG Gen-Wen; GONG Chun-Li; WEN Sheng; XIE Xiao-Lin.Preparation and Performances of Sulfonated Poly(ether imide) and Poly (ether sulfone) Blends for Proton Exchange Membrane[J]. Acta Phys. -Chim. Sin., 2008,24(05): 855-860
84. DENG Hui-Ning; WANG Yu-Xin.Preparation and Properties of Proton Conducting Composite Membranes from Sulfonated Poly(phthalazinone ether keton) and Phosphotungstic Acid[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1235-1240
85. ZHENG Hai-Tao; LI Yong-Liang; LIANG Jian-Ying; SHEN Pei-Kang.Methanol Oxidation on Pd-based Electrocatalysts[J]. Acta Phys. -Chim. Sin., 2007,23(07): 993-996
86. MA Guo-Xian; ZHONG Hui; LU Tian-Hong; XIA Yong-Yao.Direct Electrochemistry and Immobilization of Glucose Oxidase on Carbon Black[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1053-1058
87. FENG Rui-Xiang; CAO Yu-Liang; AI Xin-Ping; YANG Han-Xi.AgNi Alloy Used as Anodic Catalyst for Direct Borohydride Fuel Cells[J]. Acta Phys. -Chim. Sin., 2007,23(06): 932-934
88. WU Wei; CAO Jie-Ming; CHEN Yu; LU Tian-Hong.Preparation of High-alloying Pt-Ru/CMK-3 Catalysts in THF-H2O-EtOH Ternary Solution System[J]. Acta Phys. -Chim. Sin., 2007,23(04): 559-564
89. HE Qiong; WANG Shi-Zhong.Effects of the Concentration of LSGMC5 on the Performance of Ni-Fe Composite Anodes for Dimethyl Ether Fuel Cells[J]. Acta Phys. -Chim. Sin., 2007,23(04): 473-478
90. DENG Hui-Ning;WANG Yu-Xin .Sulfonated Poly(phthalazinones) Membranes For Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2007,23(02): 187-191
91. LEI Ze;ZHU Qing-Shan .Solution Combustion Synthesis and Characterization of Nanocrystalline La0.6Sr0.4Co0.2Fe0.8O3-δ Cathode Powders[J]. Acta Phys. -Chim. Sin., 2007,23(02): 232-236
92. HUANG Mian-Yan;CHEN Hua-Yan;GUO Jian-Zhao;WANG Zhi-Tao;XU Li;WANG Yu-Xin.Methanol Resistant Poly(Ether Sulfone)/Sulfonated Poly(Ether Ether Ketone) Blend Proton Exchange Membrane for DMFC[J]. Acta Phys. -Chim. Sin., 2007,23(01): 44-49
93. CAI Yu-Fen;LIU Jun-Min;LIAO Shi-Jun.Preparation, Characterization and Electrocatalytic Properties of Promoted PtMoSi/C Catalysts[J]. Acta Phys. -Chim. Sin., 2007,23(01): 92-97
94. SHEN Pei-Kang;WANG Sheng-Long;HU Zhi-Yi;LI Yong-Liang;ZENG Rong;HUANG Yue-Qiang.Hydrogen Production by Alcohol Electrolysis[J]. Acta Phys. -Chim. Sin., 2007,23(01): 107-110
95. TIAN Juan;ZHENG Dan;ZHANG Xi-Gui;ZHANG Bao-Hong;XIA Bao-Jia;YANG Hui.Preparation of Pt Nanoparticle Modified Porous Silicon Electrode and Its Electrocatalytic Performance[J]. Acta Phys. -Chim. Sin., 2007,23(01): 68-72
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97. LI Chang-Yu;LÜ Zhe;LIU Li-Li;LIU Zhi-Ming;SU Wen-Hui.Preparation and Performance Test of Ni-Fe/SDC Cell Anode[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1181-1184
98. ZOU Yu-Man;WANG Shi-Zhong .Preparation of Sm0.5Sr0.5CoO3-La0.8Sr0.2Ga0.8Mg0.15Co0.05O3 composite cathodes using wet-chemistry method and characterization of their properties[J]. Acta Phys. -Chim. Sin., 2006,22(08): 958-961
99. GAO Jie;WANG Shi-Zhong.Study of Ni Composite Anodes for Dimethyl Ether Fuel Cell[J]. Acta Phys. -Chim. Sin., 2006,22(07): 851-855
100. LI Li;WU Gang;YE Qing;DENG Wei;XU Bo-Qing.Electrochemical Modification of Pt/C Catalyst by Silicomolybdic Acid[J]. Acta Phys. -Chim. Sin., 2006,22(04): 419-423
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102. CHEN Yong-Hong;WEI Yi-Jun;ZHONG Hong-Hai;GAO Jian-Feng;LIU Xing-Qin;MENG Guang-Yao.Synthesis and Properties of La0.5RE0.3Sr0.2FeO3-δ (RE = Nd, Ce, Sm) System with Two Rare Earths for Cathodes[J]. Acta Phys. -Chim. Sin., 2005,21(12): 1357-1362
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106. HU Sheng-zhi; CHEN Ming-dan; ROBERTSON B. E..Study on the Scondary Bonding and Coordination Polyhedra in Crystal of Antimony(III) Complexonate Family[J]. Acta Phys. -Chim. Sin., 2005,21(06): 646-652
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109. Wan Li-Juan;Gao Ying;Wu Bing;Liu Chang-Peng;Xing Wei;Lu Tian-Hong.Cocatalysis of Adsorbed Eu3+ and Ho3+ at Pt-TiO2/C Electrode for Electrooxidaton of Ethanol[J]. Acta Phys. -Chim. Sin., 2004,20(06): 616-620
110. Wang Shi-Zhong;Liu Xuan.Preparation and Characterization of High Performance Sm0.5Sr0.5CoO3 Cathodes[J]. Acta Phys. -Chim. Sin., 2004,20(04): 391-395
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115. Wang Shi-Zhong;Ishihara Tatsumi.Improvement of the Performance of Fuel Cells Anodes with Sm3+ Doped CeO2 Interlayer[J]. Acta Phys. -Chim. Sin., 2003,19(09): 849-853
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