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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2016,Vol.32>> Issue(10)>> 2574-2580     doi: 10.3866/PKU.WHXB201606294         中文摘要
Synthesis and Catalytic Oxidation Performance of B-TS-1
WANG Lei, YIN Han-Mei, WANG Jian-Hao, WU Li-Zhi, LIU Yue-Ming
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, College of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, P. R. China
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In this paper, boron-modified titanium silicalite-1 (B-TS-1) was synthesized, and its catalytic performance was studied. B-TS-1 improved the stability of cyclohexanone ammoximation. Combined with the root of deactivation of the catalyst and H2O2 reaction behavior in the liquid-phase ammoximation process, analysis showed that H2O2 is the key to control the side reactions of the cyclohexanone ammoximation system to form organic byproducts, and these byproducts result in the deactivation of catalyst because they block pores. It is concluded that B-TS-1 could effectively decrease the residual H2O2 to suppress the side reactions and prolong the catalyst lifetime in cyclohexanone ammoximation. Simultaneous introduction of appropriate amounts of B and Al to form B/Al-TS-1 resulted in a material that further improved the stability of cyclohexanone ammoximation.



Keywords: B/Al-TS-1   Catalytic oxidation   H2O2   Cyclohexanone ammoximation   Deactivation  
Received: 2016-05-03 Accepted: 2016-06-27 Publication Date (Web): 2016-06-29
Corresponding Authors: LIU Yue-Ming Email: ymliu@chem.ecnu.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (U1462106) and Shanghai Leading Academic Discipline Project, China (B409).

Cite this article: WANG Lei, YIN Han-Mei, WANG Jian-Hao, WU Li-Zhi, LIU Yue-Ming. Synthesis and Catalytic Oxidation Performance of B-TS-1[J]. Acta Phys. -Chim. Sin., 2016,32 (10): 2574-2580.    doi: 10.3866/PKU.WHXB201606294

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