ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2016,Vol.32>> Issue(11)>> 2685-2692     doi: 10.3866/PKU.WHXB201607212         中文摘要
Anharmonic Effect of the Decomposition Reaction of Methyl Butanoate
DING Yang1, SONG Li-Guo1, YU Yi-Xuan1, YAO Li1, LIN Sheng-Hsien2
1 Marine Engineering College, Dalian Maritime University, Dalian 116026, P. R. China;
2 Department of Applied Chemistry, National Chiao-Tung University, Hsin-chu 10764, Taiwan, P. R. China
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In this paper, we have used the MP2/6-311++G(2d,2p) method to conduct a detailed investigation of the potential energy surface for the unimolecular dissociation reaction of methyl butanoate (MB). We have also used the Rice-Ramsperger-Kassel-Marcus (RRKM) theory to calculate the rate constants of the canonical and microcanonical systems at temperatures and total energies ranging from 1000 to 5000 K and 451.92 to 1519.52 kJ·mol-1, respectively. The results indicated that there was an obvious anharmonic effect for the TS2, TS4 and TS5 pathways, and that this effect was too pronounced to be neglected for the unimolecular dissociation reactions of MB.

Keywords: Anharmonic effect   Unimolecular decomposition reaction   RRKM theory   Rate constant  
Received: 2016-03-16 Accepted: 2016-07-20 Publication Date (Web): 2016-07-21
Corresponding Authors: YAO Li Email:

Fund: The project was supported by the Major Research Plan of the National Natural Science Foundation of China (91441132) and Fundamental Research Funds for the Central Universities, China (3132016127, 3132016326).

Cite this article: DING Yang, SONG Li-Guo, YU Yi-Xuan, YAO Li, LIN Sheng-Hsien. Anharmonic Effect of the Decomposition Reaction of Methyl Butanoate[J]. Acta Phys. -Chim. Sin., 2016,32 (11): 2685-2692.    doi: 10.3866/PKU.WHXB201607212

(1) Solomon, S.; Qin, D.; Manning, M.; Chen, Z.; Marquis, M.; Averyt, K. B.; Tignor M.; Miller, H. L.“IPCC, Climate Change 2007: The Physical Science Basis. Contribution ofWorking Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change”; Cambridge University Press: Cambridge and New York, 2007; p 996.
(2) Robert, L. H.; Roger, B.; Robert, W. AIChE J. 2006, 52 (1), 2. doi: 10.1002/aic.10747
(3) Gail, S.; Thomson, M. J.; Sarathy, S. M.; Syed, S. A.; Dagaut, P.; Diévart, P.; Marchese, A. J.; Dryer, F. L. Proc. Combust. Inst. 2007, 31 (1), 305. doi: 10.1016/j.proci.2006.08.051
(4) Metcalfe, W. K.; Dooley, S.; Curran, H. J.; Simmie, J. M.; El-Nahas, A. M.; Navarro, M. V. J. Phys. Chem. A 2007, 111 (19), 4001. doi: 10.1021/jp067582c
(5) Huynh, L. K.; Violi, A. J. Org Chem. 2008, 73 (1), 94. doi: 10.1021/jo701824n
(6) Huynh, L. K.; Lin, K. C.; Violi, A. J. Phys. Chem. A 2008, 112 (51), 13470. doi: 10.1021/jp804358r
(7) Westbrook, C. K.; Pitz, W. J.; Curran, H. J. J. Phys. Chem. A 2006, 110 (21), 6912. doi: 10.1021/jp056362g
(8) Herbinet, O.; Pitz, W. J.; Westbrook, C. K. Combustion and Flame 2008, 154 (4), 507. doi: 10.1016/j.combustflame.2008.03.003
(9) Hill, J.; Nelson, E.; Tilman, D.; Polasky, S.; Tiffany, D. Proc. Natl. Acad. Sci. 2006, 103 (30), 11206. doi: 10.1073/pnas.0604600103
(10) Farooqa, A.; Davidson, D. F.; Hanson, R. K.; Huynh, L. K.; Violi, A. Proc. Combust. Inst. 2009, 32, 247. doi: 10.1016/j.proci.2008.06.084
(11) Dooley, S.; Curran, H. J.; Simmie, J. M. Combustion and Flame 2008, 153 (1-2), 2. doi: 10.1016/j.combustflame.2008.01.005
(12) Fisher, E. M.; Pits, W. J.; Curran, H. J.; Westbrook, C. K. Proc. Combust. Inst. 2000, 28, 1579.
(13) Ali, M. A.; Violi, A. J. Org. Chem. 2013, 78 (12), 5898. doi: 10.1021/jo400569d
(14) Huynh, L. K.; Violi, A. J. Org. Chem. 2008, 73 (1), 94. doi: 10.1021/jo701824n
(15) (a) Yao, L.; Mebel, A. M.; Lu, H. F.; Neusser, H. J.; Lin, S. H. J. Phys. Chem. A 2007, 111 (29), 6722. doi: 10.1021/jp069012i
(b) Yao, L.; Liu, Y. L.; Lin, S. H. Mod. Phys. Lett. B 2008, 22 (31), 3043. doi: 10.1142/S0217984908017552
(c) Yao, L.; Lin, S. H. Sci. China. Ser. B 2008, 51 (12), 1146. doi: 10.1007/s11426-008-0125-1
(d) Yao, L.; He, R. X.; Mebel, A. M.; Lin, S. H. Chem. Phys. Lett. 2009, 470 (4-6), 210. doi: 10.1016/j.cplett.2009.01.074
(e) Shao, Y.; Yao, L.; Lin, S. H. Chem. Phys. Lett. 2009, 478 (4-6), 277. doi: 10.1016/j.cplett.2009.07.051
(f) Yao, L.; Mebel, A. M.; Lin, S. H. J. Phys. Chem. A 2009, 113 (52), 14664. doi: 10.1021/jp9044379
(g) Shao, Y.; Yao, L.; Mao, Y. C.; Zhong, J. J. Chem. Phys. Lett. 2010, 501 (1-3), 134. doi: 10.1016/j.cplett.2010.10.041
(h) Gu, L. Z.; Yao, L.; Shao, Y.; Yung, K.; Zhong, J. J. J. Theor. Comput. Chem. 2010, 9 (1), 813. doi: 10.1142/S0219633610006006
(i) Gu, L. Z.; Yao, L.; Shao, Y.; Liu, W.; Gao, H. Mol. Phys. 2011, 109 (16), 1983. doi: 10.1080/00268976.2011.602648
(j) Li, Q.; Xia, W.W.; Yao, L.; Shao, Y. Can. J. Chem. 2012, 90 (10), 186. doi: 10.1139/v11-137
(k) Li, Q.; Yao, L.; Shao, Y. CheM 2012, 2 (12), 1. doi: 10.5618/chem.2012.v2.n1.1
(l) Li, Q.; Yao, L.; Shao, Y.; Yang, K. J. Chin. Chem. Soc. 2014, 61 (3), 309. doi: 10.1002/jccs.201300277
(16) Gonzalez, C.; Schlegel, H. B. J. Chem. Phys. 1989, 90 (4). 2154. doi: 10.1063/1.456010
(17) Frisch, M. J.; Trucks, G.W.; Schlegel, H. B.; et al. Gaussian 09, Revision C.02; Gaussian, Inc.:Wallingford, CT, 2009.
(18) Steinfeld, J. I.; Francisco, J. S.; Hase, W. L. Chemical Kinetics and Dynamic; Prentice-Hall: Englewood Cliffs, NJ, 1989.
(19) (a) Forst, W.; Prasil, Z. J. Chem. Phys. 1970, 53 (12), 3065. doi: 10.1063/1.1674450
(b) Forst, W. Chem. Rev. 1971, 71 (4), 339. doi: 10.1021/cr60272a001
(c) Forst, W. Theory of Unimolecular Reactions; Academic Press: New York, 1973.
(20) Hoare, M. R.; Ruijgrok, T.W. J. Chem. Phys. 1970, 52 (1), 113. doi: 10.1063/1.1672655
(21) Eyring, H.; Lin, S. H.; Lin, S. M. Basic Chemical Kinetics; AWiley-interscience Publication: New York, 1980.
(22) Baer, T.; Hase, W. L. Unimolecular Reaction Dynamic: Theory and Experiment; Oxford University Press: New York, 1996.
(23) Gilbert, R. G.; Smith, S. C. Theory of Unimolecular and Recombination Reactions; Blackwell: Oxford, 1990.
(24) El-Nahas, A. M.; Navarro, M.V.; Simmie, J. M.; Bosselli, J.W.; Curran, H. J.; Dooley, S.; Metcalfe, W. J. Phys. Chem. A 2007, 111 (19), 3727. doi: 10.1021/jp067413s
(25) Zhang, L.W.; Yao, L.; Li, Q.; Wang, G. Q.; Lin, S. H. Molecular Physics 2014, 112 (21), 2853. doi: 10.1080/00268976.2014.915066
(26) Miller, W. H. J. Am. Chem. Soc. 1979, 101 (23), 6810. doi: 10.1021/ja00517a004

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2. DU Niao-Feng, NING Hong-Bo, LI Ze-Rong, ZHANG Qi-Yi, LI Xiang-Yuan.Kinetic Calculation and Modeling Study of 1,3-Butadiene Pyrolysis[J]. Acta Phys. -Chim. Sin., 2016,32(2): 453-464
3. LI Shang-Jun, TAN Ning-Xin, YAO Qian, LI Ze-Rong, LI Xiang-Yuan.Calculation of Rate Constants for Intramolecular Hydrogen Migration Reactions of Alkylperoxy Radicals[J]. Acta Phys. -Chim. Sin., 2015,31(5): 859-865
4. XU Qiong, ZHANG Tian-Lei, Lü Wen-Bin, WANG Rui, WANG Zhi-Yin, WANG Wen-Liang, WANG Zhu-Qing.Theoretical Study on the effect of a Single Water Molecule on the H2O2+Cl Gas Reaction[J]. Acta Phys. -Chim. Sin., 2014,30(6): 1061-1070
5. HU Ren-Zhi, XIE Pin-Hua, ZHANG Qun, SI Fu-Qi, CHEN Yang.Temperature Dependence of C2(a3Пu) Radical Reactions with Sulfur Bearing Molecules[J]. Acta Phys. -Chim. Sin., 2014,30(5): 797-802
6. ZHANG Tian-Lei, WANG Wei-Na, LIU Chang, LU Na, CHEN Miao, GUO Sha, WANG Wen-Liang.Computational Study of the Reaction Mechanism and Kinetics of CH3CHC(CH3)COOCH3 Ozonolysis[J]. Acta Phys. -Chim. Sin., 2013,29(11): 2313-2320
7. CAO Jia, WANG Wen-Liang, GAO Lou-Jun, FU Feng.Mechanism and Thermodynamic Properties of CH3SO3 Decomposition[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1161-1167
8. HU Ren-Zhi, XIE Pin-Hua, ZHANG Qun, SI Fu-Qi, CHEN Yang.Temperature Dependence of C2(X1Σg+) in Reactions with Unsaturated Hydrocarbons[J]. Acta Phys. -Chim. Sin., 2013,29(04): 683-688
9. WANG Bi-Yao, TAN Ning-Xin, YAO Qian, LI Ze-Rong, LI Xiang-Yuan.Accurate Calculation of the Reaction Barriers and Rate Constants of the Pyrolysis of Alkyl Radicals in the β Position Using the Isodesmic Reaction Method[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2824-2830
10. FENG Li-Xia, JIN Ling-Xia, WANG Wei-Na, WANG Wen-Liang.Mechanism and Kinetics of the Hydrogen Abstraction Reaction of C2H3 with CH3F[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1623-1629
11. LI Xiao-Yan, LIU Qun, ZHENG Shi-Jun, MENG Ling-Peng.Mechanisms and Kinetics of the HOSO+NO Reaction[J]. Acta Phys. -Chim. Sin., 2011,27(03): 564-570
12. CUI Feng-Chao, YU Hong-Bo, WANG Qin, YE Wan-Li, LIU Jing-Yao.Mechanism and Kinetics of the CH3OCF2CF2OCH3+Cl Reaction[J]. Acta Phys. -Chim. Sin., 2011,27(02): 337-342
13. HU Ren-Zhi, ZHANG Qun, CHEN Yang.Temperature Dependence of Reactions of C2(a3Πu) Radical with Several Unsaturated Hydrocarbons[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2619-2624
14. DU Xuan, XU Sheng-Hua, SUN Zhi-Wei, A Yan.Effect of the Hydrodynamic Radius of Colloid Microspheres on theEstimation of the Coagulation Rate Constant[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2807-2812
15. LIU Xiong-Min, QIN Rong-Xiu, HUANG Pin-Xian, LIU Jia-Ling, MA Li, LI Wei-Guang.Oxidation Reaction Kinetics of Abietic Acid and Rosin under Ultraviolet Light Irradiation[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2115-2120
16. GAI Yan-Bo, GE Mao-Fa, WANG Wei-Gang.Rate Constants for the Gas Phase Reactions of Ozone with Diethylamine and Triethylamine[J]. Acta Phys. -Chim. Sin., 2010,26(07): 1768-1772
17. WANG Yong-Xia, DUAN Xue-Mei, Wang Qin, LIU Jing-Yao.Direct Ab initio Dynamics on the Reaction o fMethanethiol and Hydrogen Atom[J]. Acta Phys. -Chim. Sin., 2010,26(01): 183-187
18. SUN Xiao-Li, ZENG Qing-Xuan, FENG Chang-Gen.Adsorption Kinetics of Chromium (VI) onto an Anion Exchange Fiber Containing Polyamine[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1951-1957
19. WEI Qing, XU Bao-En, SUN Cui-Hong, LI Xiao-Yan, MENG Ling-Peng, REN Lei.Reaction Mechanism and Topological Analysis of Electronic Density for the Reaction of HNCS with Cl[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1623-1628
20. WANG Hai-Tao; ZHANG Yu-Jie; MU Yu-Jin.Rate Constants for Reactions of·OH with Several Reduced Sulfur Compounds Determined by Relative Rate Constant Method[J]. Acta Phys. -Chim. Sin., 2008,24(06): 945-950
21. LI Hong-Mei; CHEN Ya-Dong; YAN Zheng-Yu; HU Yu-Zhu.Fluorescence Self-quenching and the Quenching Mechanism of Magnolol[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1454-1458
22. LIU Rui-Li; ZHAO Hong-Wei; ZHANG Zhao-Xia; YAO Si-De; LI Qing-Nuan; LI Wen-Xin.Laser Flash Photolysis of C60-dexamethasone[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1127-1130
23. JIA Long;XU Yong-Fu;GE Mao-Fa;DU Lin;WANG Geng-Chen;ZHUANG Guo-Shun.Kinetic Study of the Gas-phase Ozonolysis of Propylene[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1260-1265
24. JIANG Hui;WU Tao;LI Hao-Ran.Theoretical Study on the Decomposition of DMP and DEP in Condensed Phase∶Solvent Effect and Tunneling Effect[J]. Acta Phys. -Chim. Sin., 2006,22(09): 1047-1051
25. WEI Wen-mei; ZHENG Ren-hui; TIAN Yan; HE Tian-jing; CHEN Dong-ming; LIU Fan-chen.Theoretical Studies of the Rate Constants for Peroxyacetyl Nitrate Decomposing to CH3C(O)O+NO3[J]. Acta Phys. -Chim. Sin., 2006,22(01): 53-58
26. LIU Peng-Jun;DU Qi-Shi;CHANG Ying-Fei;WANG Rong-Shun.Theoretical Study on the Mechanism and Dynamics for the Reaction of HNCS with C2H(X2Π) Radica[J]. Acta Phys. -Chim. Sin., 2005,21(12): 1347-1351
27. ZHAO Peng; FANG Hui-jue; XUE Teng; QI Xi-min; LU Jia-xing.Diffusion Coefficients and Rate Constants of NiCl2(bpy)3 in DMF Determined by Chronocoulometry[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1235-1239
28. WANG Hong-mei; TANG Xiao-shuan; CHU Yan-nan; ZHOU Shi-kang.Studies on the Quenching of SO (c1Σ,v=0)[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1195-1197
29. ZUO Guo-ping; TANG Bi-yu; HAN Ke-li.Time-dependent Quantum Scattering Calculation of the O(3P)+HBr(DBr) Reaction[J]. Acta Phys. -Chim. Sin., 2005,21(09): 1022-1027
30. XUE Yong-qiang; DU Jian-ping; WANG Pei-dong; WANG Zhi-zhong.Effect of Particle Size on Kinetic Parameters of the Heterogeneous Reactions[J]. Acta Phys. -Chim. Sin., 2005,21(07): 758-762
31. Zhang Zhi-Qiang;Hu Chang-Jin;Pei Lin-Sen;Chen Cong-Xiang;Chen Yang.The Rate Constants of the Reactions of NCO with SO2 or CS2[J]. Acta Phys. -Chim. Sin., 2004,20(05): 535-539
32. Liu Xin-Guo;Zhang Qing-Gang.Time-dependent Wave Packet Theoretical Study for D+CH4 Reaction with SVRT Model[J]. Acta Phys. -Chim. Sin., 2004,20(05): 468-471
33. Liu Yun-Zhen;Hu Chang-Jin;Pei Lin-Sen;Chen Cong-Xiang;Ma Xing-Xiao.Experimental and Theoretical Study on the Reaction of CCl2+H2O[J]. Acta Phys. -Chim. Sin., 2003,19(06): 481-486
34. Huang Cun-Shun;Zhu Zhi-Qiang;Ran Qin;Chen Cong-Xiang;Chen Yang.Study on the Rate Constant of the Reaction of C2H3 Radical with Nitric Dioxide[J]. Acta Phys. -Chim. Sin., 2003,19(01): 51-54
35. Wang Ning;Ding Ke-Qiang;Tong Ru-Ting;Shao Hui-Bo.The Electrochemical Behavior of Self-assembled Monolayers of Schiff Base[J]. Acta Phys. -Chim. Sin., 2002,18(09): 846-849
36. Ji Yong-Qiang;Feng Wen-Lin;Hao Mao-Rong;Li Hui-Ying.The Reaction Path and Varitional Rate Constant of the Reaction CH3+CH3NO2→CH4+CH2NO2[J]. Acta Phys. -Chim. Sin., 2002,18(08): 721-726
37. Li Hui-Ying;Feng Wen-Lin;Ji Yong-Qiang;Xu Zhen-Feng;Lei Ming.The Reaction Path and Variational Rate Constant of the Hydrogen Abstraction Reaction CH2O+O[3P]→CHO+OH[J]. Acta Phys. -Chim. Sin., 2002,18(05): 446-450
38. Wang Yong-Cheng;Geng Zhi-Yuan;Chen Hong-Shan.A Density Functional Method(DFT) Study on the Cyclic Reaction Kinetics[J]. Acta Phys. -Chim. Sin., 2002,18(01): 45-49
39. Gao Yi-De;Liu Yun-Zhen;Ran Qin;Chen Cong-Xiang.Measurements of Quenching Rate Constants of CCl2(A 1B1 and a 3B 1) by Some Inorganic Molecules[J]. Acta Phys. -Chim. Sin., 2001,17(10): 944-947
40. Gao Yi-De;Hu Chang-Jin;Jin Jin;Chen Yang;Chen Cong-Xiang.Kinetic Studies on Quenching of CCl2(A 1B 1,a3B1) by Alkanes[J]. Acta Phys. -Chim. Sin., 2001,17(06): 516-520
41. Xiang Juan, Wu Bing-Liang, Chen Sheng-Li.An EQCM Investigation of the Mechanism of Surface Electro-oxidation of Formic Acid on Pt-electrode[J]. Acta Phys. -Chim. Sin., 2000,16(10): 906-911
42. Hou Hua, Wang Bao-Shan, Gu Yue-Shu.Mechanism and Kinetics of the F+NCO Reaction[J]. Acta Phys. -Chim. Sin., 2000,16(06): 517-521
43. Chen Jie-Hao, Wang Yan, Feng Wen-Lin.Mechanism of Pyrolysis of Pyruvic Acid and Benzoylformic Acid and Calculations of Thermal Rate Constants[J]. Acta Phys. -Chim. Sin., 1999,15(05): 431-435
44. Shi Tu-Jin, Li Zong-He, Liu Ruo-Zhuang.Mechanism of Reaction HNCO+OH->H2O+NCO[J]. Acta Phys. -Chim. Sin., 1999,15(03): 247-252
45. Hou Shi-Feng, Yang Ke-Sheng, Fang Hui-Qun, Chen Hong-Yuan.Electron Transfer Mechanism Characteristics of 2,3,5,6-tetrachloride-quinone Anchored on the Self-assembled Monolayers of Dithiol[J]. Acta Phys. -Chim. Sin., 1998,14(07): 640-644
46. Qian Ying,Wang Yan,Feng Wen-Lin,Liu Ruo-Zhuang.Theoretical Calculation on the Canonical Rate Constants for the Addition Reaction of 1,3-cyclohexa-diene with Propylene[J]. Acta Phys. -Chim. Sin., 1997,13(12): 1084-1089
47. Luo Ren-Sheng,Yan Jiang-Li,Mao Xi-An.Study of Ligand Exchange Kinetics for Sn(IV) Complex Using 2D NMR[J]. Acta Phys. -Chim. Sin., 1997,13(10): 925-928
48. Xu Xian-Zhong,Li Zong-He,Liu Ruo-Zhuang.Theoretical Study of Reaction HCN + OH→CN + H2O[J]. Acta Phys. -Chim. Sin., 1997,13(09): 769-772
49. Zhao Jian-Wei,Yu Hua-Zhong,Wang Yong-Qiang,Zhang Hao-Li,Liu Z.Structure-Dependent Electron Transfer Kinetics of Azobenzene Self-Assembled Monolayers on Gold[J]. Acta Phys. -Chim. Sin., 1997,13(01): 42-47
50. Wu Li-Ming,Li Zong-He,Liu Ruo-Zhuang.Theoretical Studies of Reaction F+H-C≡C-H→HF+C≡C-H[J]. Acta Phys. -Chim. Sin., 1996,12(11): 1018-1021
51. Kou Fu-Ping,Lin Hua-Kuan,Zhu Shou-Rong,Chen Rong-Ti.A Zinc(II) Complex of Tripyridylamine(TPA) as a Model for Carbonic Anhydrase[J]. Acta Phys. -Chim. Sin., 1996,12(09): 804-808
52. Cai Ji-Ye,Liu Yi,Li Ya-Dong,Cheng Guo-Sheng,Zhang Wei,Zhang Bing,Zhou Shi-Kang,G.Diode Laser Probing of NH3ν2 Vibrational Mode Excited by Relaxation of Highly Vibrational Exited NO2[J]. Acta Phys. -Chim. Sin., 1996,12(09): 786-795
53. Cao Xiao-Yan,Li Zong-He,Liu Ruo-Zhuang.State-selected Reaction Studies on H2 + CN(n=0,1)→H + HCN[J]. Acta Phys. -Chim. Sin., 1996,12(03): 239-244
54. Feng Wen-Lin,Wang Yan,Zhang Shao-Wen,Li Zong-He.Calculation on the Microcanonical Unimolecular Rate Constants for the Vibrational-state-selected Reactions[J]. Acta Phys. -Chim. Sin., 1995,11(08): 716-718
55. Zhang Lin-Yang,Zhang Jia-Mu,W.Fuss.The Effect of Light Intensity on the Photoinduced BrC2F4Br+C2F4 Telomerization Reaction[J]. Acta Phys. -Chim. Sin., 1995,11(04): 308-314
56. Li Zong-He, Wu Jun-Nan, Liu Ruo-Zhuang, Ma Si-Yu, Feng Wen-Lin, Wang Mei-Tian.Dynamics and Product Vibrational State Distributions of the Reaction of the F-N=C→F-C≡N[J]. Acta Phys. -Chim. Sin., 1994,10(12): 1075-1080
57. Li Quan-Xin, Chen Cong-Xiang, Ma Xing-Xiao, Li Xue-Chu, Shen Guan-Lin.The Study of Energy Transfer Reaction form He(23S) to CH3Cl and CH3I in a Beam-gas Condition[J]. Acta Phys. -Chim. Sin., 1994,10(12): 1081-1086
58. Zhang Hong-Lin, Li Ji-Sheng, Nan Zhao-Dong, Sun Hai-Tao, Liu Yong-Jun, Xie Chang-Li, Qu Song-Sheng.Investigation of Optimum Growth Temperature of Bacteria by Microcalorimetric Method[J]. Acta Phys. -Chim. Sin., 1994,10(10): 928-930
59. Peng Yue-Xiang; Chen Xin-Guo; Song Fen-Hong; Qiu Lian-Xiong.The Establishment of the SET-UP ion-Neutral Reaction and Application[J]. Acta Phys. -Chim. Sin., 1993,9(02): 145-147
60. Liu Ruo-Zhuang; Ma Si-Yu; Li Zong-He.Theoretical Study on the Dynamic Properties and State-Selected rate Constants of the Reaction CH(4Σ-)+H2→CH2(3B1)+H[J]. Acta Phys. -Chim. Sin., 1993,9(02): 155-160
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