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Acta Physico-Chimica Sinca  2016, Vol. 32 Issue (11): 2724-2730    DOI: 10.3866/PKU.WHXB201607272
ARTICLE     
Organic-Inorganic Hybrid Perovskite Solar Cells Processed with Br or Cl Doping via a Two-Step Deposition
Yan-Qing WANG1,*(),Long LI1,Lin-Hui NIE1,Nan-Nan LI2,Cheng-Wu SHI1,2
1 Department of Chemical Engineering and Food Processing, Xuancheng Campus, Hefei University of Technology, Xuancheng 242000, Anhui Province, P. R. China
2 School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, P. R. China
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Abstract  

Mixed halide perovskites of MAPbI3-xBrx and MAPbI3-xClx (MA=CH3NH3) with film thickness of about 300 nm were synthesized through the Br or Cl doping, thanks to the two steps deposition of controlled concentration of the precursor solution and the intramolecular exchange of DMSO molecules intercalated in PbI2 (PbI2(DMSO) complex) with MAX (X=I, Br) or MAX (X=I, Cl), respectively. The doping of Br or Cl in the perovskite film can improve the photovoltaic performance of PSCs with the precursor of MAX contains 5% (in mole fraction, same below) MABr or 15% MACl, respectively, while further increase in the content of MABr or MACl in the precursor did not lead to significant changes in doping amounts, but small white particles or pin-holes were formed in mixed perovskite materials, therefore resulted in adverse effects on the performance of solar cells. The MAPbI3-xBrx perovskite solar cells with 5% MABr in precursor solution showed a power conversion efficiency (PCE) of 13.2%, and the MAPbI3-xClx perovskite solar cells with 15% MACl in precursor solution showed the highest PCE of 13.5%.



Key wordsPerovskite solar cell      PbI2(DMSO) complex      Doping      Two-step deposition     
Received: 25 May 2016      Published: 27 July 2016
MSC2000:  O644  
Fund:  the National Natural Science Foundation of China(51472071);the National Natural Science Foundation of China(51272016);the National Natural Science Foundation of China(51072043);Startup Foundation of Hefei University of Technology, China(JZ2014HGBZ0371);Startup Foundation of Hefei University of Technology, China(JZ2014HGBZ0358)
Corresponding Authors: Yan-Qing WANG     E-mail: yqwang@hfut.edu.cn
Cite this article:

Yan-Qing WANG,Long LI,Lin-Hui NIE,Nan-Nan LI,Cheng-Wu SHI. Organic-Inorganic Hybrid Perovskite Solar Cells Processed with Br or Cl Doping via a Two-Step Deposition. Acta Physico-Chimica Sinca, 2016, 32(11): 2724-2730.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB201607272     OR     http://www.whxb.pku.edu.cn/Y2016/V32/I11/2724

 
 
 
 
 
 
 
 
 
 
Device Voc/V Jsc/(mA·cm-2) FF/% PCE/%
best best
0.35 mol·L-1 MAX 0% MABr 0.96 17.5 62.9 11.1 10.6
5% MABr 1 18 71.2 13.2 12.9
10% MABr 0.98 17.3 67.6 11.9 11.4
0.465 mol·L-1 MAX 10% MACl 0.97 16.5 64.4 11.2 10.3
15% MACl 1.03 17.6 74.2 13.5 13.4
20% MACl 0.95 17 68.3 11.5 11.1
 
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