ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2016,Vol.32>> Issue(11)>> 2803-2810     doi: 10.3866/PKU.WHXB201607291         中文摘要
Preparation of Highly Dispersed Ni-Ce-Zr Oxides over Mesoporous γ-Alumina and Their Catalytic Properties for CO2 Methanation
NIE Wang-Xin, ZOU Xiu-Jing, WANG Xue-Guang, DING Wei-Zhong, LU Xiong-Gang
Shanghai Key Laboratory of Advanced Ferrometallurgy, State Key Laboratory of Advanced Special Steel, School of Materials Science and Engineering, Shanghai University, Shanghai 200072, P. R. China
Full text: PDF (5160KB) HTML Export: BibTeX | EndNote (RIS)

Highly dispersed Ni-Ce-Zr mixed oxides supported on mesoporous γ-alumina (Ni-Ce-Zr/γ-MA) were prepared by a citric acid (CA)-assisted impregnation method and evaluated as catalysts for the methanation of CO2 with H2. The effects of the CA content of the reaction solution on the physicochemical properties and the catalytic performance of the Ni-Ce-Zr/γ-MA catalysts were investigated in detail. The addition of CA promoted the dispersion of the Ni-Ce-Zr oxide species on the γ-alumina surface and improved the interactions between the Ni oxide species and the support, resulting in the formation of homogeneously dispersed Ni nanoparticles in the γ-MA frameworks upon reduction with H2. The resulting Ni-Ce-Zr/γ-MA catalysts were highly active and showed almost 100% selectivity for CH4 during the methanation of CO2 at temperatures in the range of 150-400℃. Notably, the catalytic activity increased as the molar ratio of CA/(Ni+Ce+Zr) increased in the range of 0-2. This effect was most likely caused by the associated decrease in the Ni particle size and the improved electronic and structural properties of the Ni-Ce-ZrOx species. The results of a stability test for the Ni-Ce-Zr/γ-MA catalyst prepared with a CA/(Ni+Ce+Zr) molar ratio of 1.0 showed that there was only a 7% decrease in the CO2 conversion following a reaction time of 300 h at 300℃ with negligible coke deposition, indicating excellent catalytic stability and good anti-coking ability of these systems for the methanation of CO2.

Keywords: Nickel catalyst   Citric acid-assistance   Mixed metal oxide   Carbon dioxide   Methanation  
Received: 2016-06-02 Accepted: 2016-07-28 Publication Date (Web): 2016-07-29
Corresponding Authors: ZOU Xiu-Jing, WANG Xue-Guang Email:;

Fund: The project was supported by the Innovation Program of Shanghai Municipal Education Commission, National Key Basic Research Program of China (973) (2014CB643403), National Science Fund for Distinguished Young Scholars, China (51225401), and Basic Major Research Program of Science and Technology Commission Foundation of Shanghai, China (14JC1491400).

Cite this article: NIE Wang-Xin, ZOU Xiu-Jing, WANG Xue-Guang, DING Wei-Zhong, LU Xiong-Gang. Preparation of Highly Dispersed Ni-Ce-Zr Oxides over Mesoporous γ-Alumina and Their Catalytic Properties for CO2 Methanation[J]. Acta Phys. -Chim. Sin., 2016,32 (11): 2803-2810.    doi: 10.3866/PKU.WHXB201607291

(1) Abe, T.; Tanizawa, M.; Watanabe, K.; Taguchi, A. Energy Environ. Sci. 2009, 2, 315. doi: 10.1039/b817740f
(2) Wang, W.; Wang, S. P.; Ma, X. B.; Gong, J. L. Chem. Soc. Rev. 2011, 40, 3703. doi: 10.1039/c1cs15008a
(3) Gao, J. J.; Liu, Q.; Gu, F. N.; Liu, B.; Zhong, Z. Y.; Su, F. B. RSC Adv. 2015, 5, 22759. doi: 10.1039/c4ra16114a
(4) Aziz, M. A. A.; Jalil, A. A.; Triwahyono, S.; Ahmad, A. Green Chem. 2015, 17, 2647. doi: 10.1039/c5gc00119f
(5) Chang, F.W.; Kuo, M. S.; Tsay, M. T.; Hsieh, M. C. Appl. Catal. A 2003, 247, 309. doi: 10.1016/S0926-860X(03)00181-9
(6) Perkas, N.; Amirian, G.; Zhong, Z. Y.; Teo, J.; Gofer, Y.; Gedanken, A. Catal. Lett. 2009, 130, 455. doi: 10.1007/s10562-009-9952-8
(7) Zhang, R. B.; Liang, L.; Zeng, X. R.; Shang, J. Y.; Wang, T.; Cai, J. X. Acta Phys. -Chim. Sin. 2012, 28, 1951. [张荣斌, 梁蕾, 曾宪荣, 商金艳, 汪涛, 蔡建信. 物理化学学报, 2012, 28, 1951.] doi: 10.3866/PKU.WHXB201206041
(8) Song, H. L.; Yang, J.; Zhao, J.; Chou, L. J. Chin. J. Catal. 2010, 31, 21. doi: 10.1016/S1872-2067(09)60036-X
(9) Lu, B.W.; Kawamoto, K. Fuel 2013, 103, 699. doi: 10.1016/j.fuel.2012.09.009
(10) Ocampo, F.; Louis, B.; Kiwi-Minsker, L.; Roger, A. C. Appl. Catal. A 2011, 392, 36. doi: 10.1016/j.apcata.2010.10.025
(11) Cai, W.; Zhong, Q.; Zhao, Y. X. Catal. Commun. 2013, 39, 30. doi: 10.1016/j.catcom.2013.04.025
(12) Fan, Z. G.; Sun, K. H.; Rui, N.; Zhao, B. R.; Liu, C. J. J. Energy Chem. 2015, 24, 655. doi: 10.1016/j.jechem.2015.09.004
(13) Guo, Z. L.; Huang, L. Q.; Chu, W.; Luo, S. Z. Acta Phys. -Chim. Sin. 2014, 30, 723. [郭章龙, 黄丽琼, 储伟, 罗仕忠. 物理化学学报, 2014, 30, 723.] doi: 10.3866/PKU.WHXB201402242
(14) Liu, H. Z.; Zou, X. J.; Wang, X. G.; Lu, X. G.; Ding, W. Z. J. Nat. Gas Chem. 2012, 21, 703. doi: 10.1016/S1003-9953(11)60422-2
(15) Luisetto, I.; Tuti, S.; Battocchio, C.; Lo Mastro, S.; Sodo, A. Appl. Catal. A 2015, 500, 12. doi: 10.1016/j.apcata.2015.05.004
(16) Boullosa-Eiras, S.; Zhao, T. J.; Vanhaecke, E.; Chen, D.; Holmen, A. Catal. Today 2011, 178, 12. doi: 10.1016/j.cattod.2011.08.029
(17) Villarreal, A.; Ramirez, J.; Caero, L. C.; Villalon, P. C.; Gutierrez-Alejandre, A. Catal. Today 2015, 250, 60. doi: 10.1016/j.cattod.2014.03.035
(18) Chen, J. J.; Labruyere, V.; Mauge, F.; Quoineaud, A. A.; Hugon, A.; Oliviero, L. J. Phys. Chem. C 2014, 118, 30039. doi: 10.1021/jp510470g
(19) Liu, X. Q.; Li, S. H.; Sun, M. T.; Yu, C. L.; Huang, B. C. Acta Phys. -Chim. Sin. 2016, 32, 1236. [刘小青, 李时卉, 孙梦婷, 喻成龙, 黄碧纯. 物理化学学报, 2016, 32, 1236.] doi: 10.3866/PKU.WHXB201602251
(20) Hu, Y.; Wang, X. G.; Tan, M.W.; Zou, X. J.; Ding, W. Z.; Lu, X. G. ChemCatChem 2016, 8, 1055. doi: 10.1002/cctc.201501384
(21) Klimova, T. E.; Valencia, D.; Mendoza-Nieto, J. A.; Hernandez-Hipolito, P. J. Catal. 2013, 304, 29. doi: 10.1016/j.jcat.2013.03.027
(22) Castillo-Villalon, P.; Ramirez, J.; Vargas-Luciano, J. A. J. Catal. 2014, 320, 127. doi: 10.1016/j.jcat.2014.09.021
(23) Dik, P. P.; Klimov, O. V.; Koryakina, G. I.; Leonova, K. A.; Pereyma, V. Y.; Budukva, S. V.; Gerasimov, E. Y.; Noskov, A. S. Catal. Today 2014, 220222, 124. doi: 10.1016/j.cattod.2013.07.004
(24) Liu, G. L.; Geng, Y. X.; Pan, D. M.; Zhang, Y.; Niu, T.; Liu, Y. Fuel Process Technol. 2014, 128, 289. doi: 10.1016/j.fuproc.2014.07.010
(25) Greluk, M.; Rybak, P.; Slowik, G.; Rotko, M.; Machocki, A. Catal. Today 2015, 242, 50. doi: 10.1016/j.cattod.2014.07.032
(26) Greluk, M.; Rotko, M.; Machocki, A. Catal. Lett. 2016, 146, 163. doi: 10.1007/s10562-015-1628-y
(27) Wu, H. D.; Duan, A. J.; Zhao, Z.; Qi, D. H.; Li, J. M.; Liu, B.; Jiang, G. Y.; Liu, J.; Wei, Y. C.; Zhang, X. Fuel 2014, 130, 203. doi: 10.1016/j.fuel.2014.04.038
(28) Shang, X. F.; Wang, X. G.; Nie, W. X.; Guo, X. F.; Zou, X. J.; Ding, W. Z.; Lu, X. G. J. Mater. Chem. 2012, 22, 23806. doi: 10.1039/c2jm35508f
(29) Mendoza-Nieto, J. A.; Robles-Mendez, F.; Klimova, T. E. Catal. Today 2015, 250, 47. doi: 10.1016/j.cattod.2014.05.002
(30) Calderon-Magdaleno, M. A.; Mendoza-Nieto, J. A.; Klimova, T. E. Catal. Today 2014, 220222, 78. doi: 10.1016/j.cattod.2013.06.002
(31) Li, B. T.; Qian, X. Y.; Wang, X. J. Int. J. Hydrog. Energy 2015, 40, 8081. doi: 10.1016/j.ijhydene.2015.04.104
(32) Ye, Q.; Wang, R. P.; Xu, B. Q. Acta Phys. -Chim. Sin. 2006, 22, 33. [叶青, 王瑞璞, 徐柏庆. 物理化学学报, 2006, 22, 33.] doi: 10.3866/PKU.WHXB201206041

1. WANG Juan, LI Shi-Kun, ZHAO Zhen-Chao, ZHOU Dan-Hong, LU An-Hui, ZHANG Wei-Ping.Density Functional Theory Study of CO2 Adsorption in Amine-Functionalized Carbonaceous Materials[J]. Acta Phys. -Chim. Sin., 2016,32(7): 1666-1673
2. CHENG Xiao-Meng, LI Yu, CHEN Zong, LI Hong-Ping, ZHENG Xiao-Fang.A Comparative Study on theNMR Relaxation of Methanol in Sub-and Super-Critical Mixtures of CO2 and Methanol[J]. Acta Phys. -Chim. Sin., 2016,32(11): 2671-2677
3. ZHU Qing-Gong, SUN Xiao-Fu, KANG Xin-Chen, MA Jun, QIAN Qing-Li, HAN Bu-Xing.Cu2S on Cu Foam as Highly Efficient Electrocatalyst for Reduction of CO2 to Formic Acid[J]. Acta Phys. -Chim. Sin., 2016,32(1): 261-266
4. ZHANG Xiao-Qing, XU Yan YAN, YANG Chun-Hui, ZHANG Yan-Ping, YIN Yong-Xiang, SHANG Shu-Yong.In-situ Co-Precipitation of Ni-Mg-Al-LDH Catalytic Precursor on γ-Al2O3 for Dry Reforming of Methane: Synthesis and Evaluation[J]. Acta Phys. -Chim. Sin., 2015,31(5): 948-954
5. LI Zhe-Qi, WANG Te-Hua, LI Xiu-Yuan, ZHANG Ya-Qin, JI Min.Preparation and Catalytic Performances of a Three-Dimensionally Ordered Macroporous MgFe0.1Al1.9O4 Catalyst for Ethylbenzene Oxydehydrogenation with CO2[J]. Acta Phys. -Chim. Sin., 2015,31(4): 743-749
6. WANG Bao-Wei, LIU Si-Han, HU Zong-Yuan, LI Zhen-Hua, MA Xin-Bin.Effect of H2S Concentration on MoO3/Al2O3 and CoO-MoO3/Al2O3 Catalysts for Sulfur-Resistant Methanation[J]. Acta Phys. -Chim. Sin., 2015,31(3): 545-551
7. HE Zhi-Qiao, TONG Li-Li, ZHANG Zhi-Peng, CHEN Jian-Meng, SONG Shuang.Ag/Ag2WO4 Plasmonic Catalyst for Photocatalytic Reduction of CO2 under Visible Light[J]. Acta Phys. -Chim. Sin., 2015,31(12): 2341-2348
8. GAO Peng, LI Feng, ZHAO Ning, WANG Hui, WEI Wei, SUN Yu-Han .Preparation of Cu/Zn/Al/(Zr)/(Y) Catalysts from Hydrotalcite-Like Precursors and Their Catalytic Performance for the Hydrogenation of CO2 to Methanol[J]. Acta Phys. -Chim. Sin., 2014,30(6): 1155-1162
9. WANG Guan-Nan, CHEN Li-Min, GUO Yuan-Yuan, FU Ming-Li, WU Jun-Liang, HUANG Bi-Chun, YE Dai-Qi.Effect of Chromium Doping on the Catalytic Behavior of Cu/ZrO2/CNTs-NH2 for the Synthesis of Methanol from Carbon Dioxide Hydrogenation[J]. Acta Phys. -Chim. Sin., 2014,30(5): 923-931
10. GUO Zhang-Long, HUANG Li-Qiong, CHU Wei, LUO Shi-Zhong.Effects of Promoter on NiMgAl Catalyst Structure and Performance for Carbon Dioxide Reforming of Methane[J]. Acta Phys. -Chim. Sin., 2014,30(4): 723-728
11. ZHANG Hai-Xin, CHEN Shu-Wei, CUI Xing-Yu, PAN Da-Hai, QIN Zhang-Feng, WANG Jian-Guo.Effect of Ce Promoter on Catalytic Performance of V/SiO2 in Oxidative Dehydrogenation of Ethylbenzene with Carbon Dioxide[J]. Acta Phys. -Chim. Sin., 2014,30(2): 351-358
12. LAN Ben-Yue, SHI Hai-Feng.Review of Systems for Photocatalytic Conversion of CO2 to Hydrocarbon Fuels[J]. Acta Phys. -Chim. Sin., 2014,30(12): 2177-2196
13. ZHAO Wei-Rong, XI Hai-Ping, LIAO Qiu-Wen.Cu-Doped Titania Nanotubes for Visible-Light Photocatalytic Mineralization of Toluene[J]. Acta Phys. -Chim. Sin., 2013,29(10): 2232-2238
14. CHEN Li, ZHU Rong-Jiao, YUAN Ping-Fang, CAO Li-Qian, TIAN Yi-Ling.Vapor-Liquid Equilibrium Data for Carbon Dioxide+Dimethyl Carbonate Binary System[J]. Acta Phys. -Chim. Sin., 2013,29(01): 11-16
15. ZHANG Rong-Bin, LIANG Lei, ZENG Xian-Rong, SHANG Jin-Yan, WANG Tao, CAI Jian-Xin.Catalytic Properties of Ni /MWCNT and La-Promoted Ni /MWCNT for Methanation of Carbon Dioxide Reaction[J]. Acta Phys. -Chim. Sin., 2012,28(08): 1951-1956
16. ZHENG Bin, ZHANG An-Feng, LIU Min, DING Fan-Shu, DAI Cheng-Yi, SONG Chun-Shan, GUO Xin-Wen.Properties of the Nano-Particle Fe-based Catalyst for the Hydrogenation of Carbon Dioxide to Hydrocarbons[J]. Acta Phys. -Chim. Sin., 2012,28(08): 1943-1950
17. ZHAO Jing-Mao, LI Jun.Corrosion Inhibition Performance of Carbon Steel in Brine Solution Containing H2S and CO2by Novel Gemini Surfactants[J]. Acta Phys. -Chim. Sin., 2012,28(03): 623-629
18. GUO Xiao-Ming, MAO Dong-Sen, LU Guan-Zhong, WANG Song.Preparation of CuO-ZnO-ZrO2 by Citric Acid Combustion Method and Its Catalytic Property for Methanol Synthesis from CO2 Hydrogenation[J]. Acta Phys. -Chim. Sin., 2012,28(01): 170-176
19. PENG Xuan, ZHANG Qin-Xue, CHENG Xuan, CAO Da-Peng.Adsorption and Separation of CO2/CH4/N2 Binary Mixtures in an Ordered Mesoporous Carbon Material CMK-3[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2065-2071
20. ZHOU Dan, YU Wen, XU Qin-Qin, YIN Jian-Zhong.Solubilization of Polyalcohol in Supercritical CO2 Microemulsion[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1300-1304
21. AN Xiao-Hui, LIU Da-Huan, ZHONG Chong-Li.Stepped Behavior of Carbon Dioxide Adsorption in Metal-Organic Frameworks[J]. Acta Phys. -Chim. Sin., 2011,27(03): 553-558
22. MA Yan-Hui, ZHAO Hui-Ling, TANG Sheng-Jie, HU Jun, LIU Hong-Lai.Synthesis of Micro/Mesoporous Composites and Their Application as CO2 Adsorbents[J]. Acta Phys. -Chim. Sin., 2011,27(03): 689-696
23. WU Wei-Kang, WANG Jia-Li, LIU Su-Qin, HUANG Ke-Long, LIU Yan-Fei.Thermal Decomposition Kinetics of Poly(propylene carbonate maleate)[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2915-2919
24. BAI Mei-Gui, TAO Xu-Mei, WU Qing-You, HUANG Zhi-Jun, LI Yu-Liang, YIN Yong-Xiang, DAI Xiao-Yan.Effect of Different Feeding Modes on CO2 Reforming of CH4 by Thermal Plasma[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2455-2460
25. WANG Wei-Bin, YIN Jian-Zhong, SUN Li-Hua, FENG En-Min.Molecular Dynamics Simulation of Thermodynamic Properties for CO2/Ionic Liquid Systems[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2291-2295
26. AI Xin-Peng, YUE Bao-Hua, WANG Xue-Guang, YANG Jun, LU Xiong-Gang, DING Wei-Zhong.Catalytic Conversion of Tar Components in Hot Coke Oven Gas over Ni/MgO-Al2O3 Catalysts[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1517-1522
27. LI Xue-Ling, YUE Bao-Hua, WANG Xue-Guang, YU Fei, KONG Ling-Hua, LU Xiong-Gang, DING Wei-Zhong.Preparation of NiO/MgxSi1-xOy Catalysts and Their Application in Catalytic Cracking of Tar Components in Hot Coke Oven Gas[J]. Acta Phys. -Chim. Sin., 2009,25(04): 762-766
28. DENG Wen-Ping, XU Gang, WAN Lei, LIU An-Wen, GAO Bo, DU Jun-He, HU Shui-Ming, CHEN Yang.Apparatus for High-Resolution Solid Hydrogen Matrix Isolation Spectroscopy and Its Application[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1329-1334
29. LU Zhao-Ling; QIU Yu-Bing; GUO Xing-Peng.Effect of pH Value on the Adsorption Behavior and Inhibition Mechanism of Dodecylamine on Carbon Steel[J]. Acta Phys. -Chim. Sin., 2008,24(02): 243-249
30. YUE Qiao-Hong; SHAO Xiao-Hong; CAO Da-Peng.Separation of Hydrogen and Carbon Dioxide in Activated Mesocarbon Microbeads with High Specific Surface[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1080-1084
31. LIU Shi-jun; CHEN Qi-yuan; FUNAHASHI Shigenobu.Kinetic Study of the Reactions of Porphyrin with Co(II), Ni(II) and Zn(II) Compounds in Supercritical Carbon Dioxide[J]. Acta Phys. -Chim. Sin., 2005,21(08): 893-897
32. Liu Ying-Xin;Wei Zuo-Jun;Chen Ji-Xiang;Zhang Ji-Yan;Li Xin-Xue;Wei Xiong-Hui.Sol-gel Preparation,Characterization and Hydrogenation Property of Silica Supported Ni Catalyst[J]. Acta Phys. -Chim. Sin., 2004,20(07): 780-784
33. Chen Ji-Xiang;Qiu Ye-Jun;Zhang Ji-Yan;Su Wan-Hua.Influence of La2O3 and CeO2 Promoters on Physico-chemical Properties and Catalytic Performance of Ni/MgO Catalyst in Methane Reforming with Carbon Dioxide[J]. Acta Phys. -Chim. Sin., 2004,20(01): 76-80
34. Chen Song-Zhe;Zhong Shun-He.The Photo Stimulated Surface Reaction of Synthesis of Methanol from Carbon Dioxide and Water on Cu/TiO2-NiO[J]. Acta Phys. -Chim. Sin., 2002,18(12): 1099-1103
35. Liu Yue;Liu Jia-Wen;Yang Xiao-Zhen.Cationic Reaction Mechanism for Ethylene Polymerization of New Nickel Catalysts[J]. Acta Phys. -Chim. Sin., 2002,18(12): 1068-1070
36. Zou Ji-Jun;Li Yang;Zhang Yue-Ping;Liu Chang-Jun.Product Distribution of Conversions of Methane and Carbon Dioxide Using Dielectric Barrier Discharge[J]. Acta Phys. -Chim. Sin., 2002,18(08): 759-763
37. Yang Yong-Lai;Xu Heng-Yong;Li Wen-Zhao.Study on Carbon Deposition of CH4,C2H6 and C2H4 Cracking over Ni-based Catalysts[J]. Acta Phys. -Chim. Sin., 2001,17(09): 773-775
38. Li Han-Sheng;Zhong Shun-He;Wang Jian-Wei;Xiao Xiu-Fen.Effect of K2O on Properties of Cu-Ni/V2O5-SiO2 Catalyst for the Synthesis of Dimethyl Carbonate[J]. Acta Phys. -Chim. Sin., 2001,17(06): 552-554
39. Zhong Shun-He, Li Han-Sehng, Wang Jian-Wei, Xiao Xiu-Fen.Cu-Ni/V2O5-SiO2 Catalyst for the Direct Synthesis of Dimethyl Carbonate from Carbon Dioxide and Methanol[J]. Acta Phys. -Chim. Sin., 2000,16(03): 226-231
40. Li Chun-Yi, Yu Chang-Chun, Shen Shi-Kong.The Main Origin of CO2 in Partial Oxidation of Methane to syngas over a Ni/Al2O3 Catalyst[J]. Acta Phys. -Chim. Sin., 2000,16(02): 97-100
41. Jin Rong-Chao, Chen Yan-Xin, Cui Wei, Li Wen-Zhao, Yu Chun-Ying, Jiang Yi.Mechanism of Catalytic Partial Oxidation of Methane to Synthesis Gas on Nickel Catalyst[J]. Acta Phys. -Chim. Sin., 1999,15(04): 313-318
42. Li Yu-Guang, Porter John F, Chan Chak K.Microstructure Characteristies and Photoreactivity of Calcined P-25 TiO2[J]. Acta Phys. -Chim. Sin., 1999,15(01): 82-86
43. Ke Jie,Jin Shun-Zi,Han Bu-Xing,Yan Hai-Ke,Shen De-Yan.FTIR Study on the Interactions between Benzoic Acid and Ethanol,Benzoic Acid and Dimethyl Sulfoxide in Supercritical CO2[J]. Acta Phys. -Chim. Sin., 1996,12(11): 986-989
44. Liu Xin-Hua,Miao-Yin,Li Xiao-Li,Sheng Shi-Shan.Promoting Effect of La2O3 on Ni/γ-Al2O3 Methanstion Catalyst[J]. Acta Phys. -Chim. Sin., 1995,11(08): 746-750
45. Xu Bin, Zhu Chong-Ye, Li Quan-Zhi.Surface Species of Molybdenum-Nickel Loaded Catalysts and Their Catalytic Activity[J]. Acta Phys. -Chim. Sin., 1994,10(06): 543-548
46. Le Qing-Hua; Xu Jin-Lin; Shi Ya-Jun.Catalytic Activity of Vanadium Pentoxide for the Absorption of Carbon Dioxide by Potassium Carbonate Solution[J]. Acta Phys. -Chim. Sin., 1992,8(06): 753-759
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388
^ Top