Please wait a minute...
Acta Physico-Chimica Sinca  2016, Vol. 32 Issue (11): 2794-2802    DOI: 10.3866/PKU.WHXB201609073
ARTICLE     
Adsorption of λ-Cyhalothrin onto Macroporous Polymer Foams Derived from Pickering High Internal Phase Emulsions Stabilized by Halloysite Nanotube Nanoparticles
Xiang CHEN,Jian-Ming PAN*(),Yong-Sheng YAN
Download: HTML     PDF(2271KB) Export: BibTeX | EndNote (RIS)      

Abstract  

Macroporous polymer foams (MPFs) were prepared through oil-in-water (O/W) Pickering high internal phase emulsions (HIPEs) stabilized by the natural clay halloysite nanotube (HNT) nanoparticles with the addition of small amounts of the nonionic surfactant Tween 85. The resulting MPFs were characterized, and the results showed an open cell structure with interconnected pores and a hydrophilic surface with a suspended state in aqueous solution. These features were beneficial for the adsorption of pyrethroids. Moreover, the adsorption of λ-cyhalothrin on MPFs was examined to determine the kinetic and equilibrium data of the adsorption process. The findings of the kinetic and equilibrium studies revealed that a pseudo-second-order kinetic model and the Langmuir isotherm were the best fitted models (R2>0.99), implying that the process of adsorption is a monolayer and chemically reactive. In addition, the maximum adsorption capacity and equilibrium time for λ-cyhalothrin on MPFs were estimated to be 23.98 μmol·g-1 and 240 min at 298 K. Increasing the temperature led to an increase in adsorption capacity. Increasing the initial concentration of λ-cyhalothrin led to an increase in clear adsorption capacity. Finally, the suspended MPFs represent a promising and reliable adsorbent for the removal of hydrophobic organic pollutants from aqueous solutions.



Key wordsAdsorption      Macroporous polymer foam      Halloysite nanotube      Kinetics      Pickering high internal phase emulsion     
Received: 02 August 2016      Published: 07 September 2016
MSC2000:  O647  
Fund:  the National Natural Science Foundation of China(21574091);the National Natural Science Foundation of China(21576120);National Postdoctoral Science Foundation, China(2013M540423)
Corresponding Authors: Jian-Ming PAN     E-mail: pjm@ujs.edu.cn
Cite this article:

Xiang CHEN,Jian-Ming PAN,Yong-Sheng YAN. Adsorption of λ-Cyhalothrin onto Macroporous Polymer Foams Derived from Pickering High Internal Phase Emulsions Stabilized by Halloysite Nanotube Nanoparticles. Acta Physico-Chimica Sinca, 2016, 32(11): 2794-2802.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB201609073     OR     http://www.whxb.pku.edu.cn/Y2016/V32/I11/2794

 
 
 
 
 
 
 
 
Sample Pseudo-first-order Pseudo-second-order Intrapaticle diffusion
Qe, exp/(μmol·g-1) k1/min-1 Qe, c/(μmol·g-1) R2 k2/(g·mg-1·min-1) Qe, c/(μmol·g-1) R2 Kdif/(μmol·g-1·min-1/2) C/(μmol·g-1) R2
MPFs 1 11.96 0.027 11.56 0.968 0.0066 12.11 0.992 0.1344 9.03 0.743
MPFs 2 10.78 0.033 10.3 0.96 0.0093 10.8 0.998 0.1018 8.47 0.706
 
 
 
Sample T/K Langmuir equation Freundlich equation
R2 Qm/(μmol·g-1) KL/(L·mg-1) RL R2 KF/(L·mg-1) 1/n
MPFs 1 298 0.995 23.98 0.009 0.581 0.985 0.424 0.744
308 0.995 25.16 0.012 0.475 0.989 0.678 0.651
318 0.995 26.5 0.016 0.406 0.993 0.924 0.594
MPFs 2 298 0.996 21.26 0.01 0.511 0.982 0.465 0.699
 
1 Worrall F. Environ. Sci. Technol. 2001, 35, 2282.
2 Pan J. M. ; Qu Q. ; Cao J. ; Yan D. ; Liu J. X. ; Dai X. H. ; Yan Y. S. Chem. Eng. J. 2014, 253, 138.
3 Delgado-Moreno L. ; Wu L. ; Gan J. Environ. Sci. Technol. 2010, 44, 8473.
4 Hamadi N. K. ; Swaminathan S. ; Chen X. D. J. Hazard. Mater. 2004, 112, 133.
5 Al-Qodah Z. ; Shawaqfeh A. T. ; Lafi W. K. Desalination 2007, 208, 294.
6 Gupta V. K. ; Ali I. Water Res. 2001, 35, 33.
7 Zhou J. L. ; Rowland S. J. Water Res. 1997, 31, 1708.
8 Xu F. Q. ; Zhang N. N. ; Long Y. ; Si Y. M. ; Liu Y. ; Mi X. ; Wang X. D. ; Xing F. B. ; You X. D. ; Gao J. P. J. Hazard. Mater. 2011, 188, 148.
9 Chang B. B. ; Guan D. X. ; Tian Y. L. ; Yang Z. C. ; Dong X. P. J. Hazard. Mater. 2013, 262, 256.
10 Zhu Z. Q. ; Zeng H. H. ; Zhu Y. N. ; Yang F. ; Zhu H. X. ; Qin H. ; Wei W. H. Sep. Purif. Technol. 2013, 117, 124.
11 Haibach K. ; Menner A. ; Powell R. ; Bismarck A. Polymer 2006, 47, 4513.
12 Vílchez A. ; Rodríguez-Abreu C. ; Esquena J. ; Menner A. ; Bismarck A. Langmuir 2011, 27, 13342.
13 Manley S. S. ; Graeber N. ; Grof Z. ; Menner A. ; Hewitt G. F. ; Stepanek F. ; Bismarck A. Soft Matter 2009, 5, 4780.
14 Ikem V. O. ; Menner A. ; Bismarck A. Langmuir 2010, 26, 8836.
15 Hermant M. C. ; Verhuls M. ; Kyrylyuk A. V. ; Klumperman B. ; Koning C. E. Compos. Sci. Technol. 2009, 69, 656.
16 Ikem V. O. ; Menner A. ; Horozov T. S. ; Bismarck A. Adv. Mater. 2010, 22, 3588.
17 Hua Y. ; Zhang S. M. ; Zhu Y. ; Chu Y. Q. ; Chen J. D. J. Polym. Sci. Part A: Polym. Chem. 2013, 51, 2181.
18 Li Z. ; Wei X. ; Ngai T. Chem. Commun. 2011, 47, 331.
19 He Q. ; Yang D. ; Deng X. L. ; Wu Q. ; Li R. ; Zhai Y. ; Zhang L. Water Res. 2013, 47, 3976.
20 Lehle H. ; Noruzifar E. ; Oettel M. Eur. Phys. J. E. 2008, 26, 151.
21 Li H. B. ; Li Y. L. ; Cheng J. Chem. Mater. 2010, 22, 2451.
22 Koch D. A. ; Clark K. ; Tessier D. M. J. Agric. Food. Chem. 2013, 61, 2330.
23 Pan J. M. ; Yin Y. J. ; Gan M. Y. ; Meng M. J. ; Dai X. H. ; Wu R. R. ; Shi W. D. ; Yan Y. S. Chem. Eng. J. 2015, 266, 299.
24 Oh B. H. L. ; Bismarck A. ; Chan-Park M. B. Biomacromolecules 2014, 15, 1777.
25 Pan J. M. ; Zhu W. J. ; Dai X. H. ; Yan X. S. ; Gan M. Y. ; Li L. Z. ; Hang H. ; Yan Y. S. RSC Adv. 2014, 4, 4435.
26 Liang X. F. ; Wang H. J. ; Tian H. ; Luo H. ; Chang J. Acta Phys. -Chim. Sin. 2008, 24, 223.
26 梁晓飞; 王汉杰; 田惠; 罗浩; 常津. 物理化学学报, 2008, 24, 223.
27 Menner A. ; Biamarck A. Macromol. Symp. 2006, 242, 19.
28 Pan J. M. ; Zeng J. ; Cao Q. ; Gao H. P. ; Gen Y. C. ; Peng Y. X. ; Dai X. H. ; Yan Y. S. Chem. Eng. J. 2016, 284, 1361.
29 Zhang Y. ; Liu R. J. ; Hu Y. L. ; Li G. K. Anal. Chem. 2009, 81, 967.
30 Chen H. Q. ; Wang W. ; Li G. L. ; Li C. ; Zhang Y. Synth. Met. 2011, 161, 1921.
31 Khorramabadi G. S. ; Soltani R. D. C. ; Rezaee A. ; Khataee A.R. ; Jafari A. J. Can. J. Chem. Eng. 2012, 90, 1539.
32 Soltani R. D. C. ; Khorramabadi G. S. ; Khataee A. R. ; Jorfi S. J. Taiwan. Inst. Chem. Eng. 2014, 45, 973.
33 Sun Y. B. ; Yang S. B. ; Zhao G. X. ; Wang Q. ; Wang X. K. Chem. Asian J. 2013, 8, 2755.
34 Weber W. ; Morris J. J. Sanit. Eng. Div. Am. Soc. Civ. Eng. 1963, 89, 31.
35 Wu F. C. ; Tseng R. L. ; Juang R. S. Chem. Eng. J. 2009, 153, 1.
36 Hameed B. H. ; Tan I. A.W. ; Ahmad A. L. Chem. Eng. J. 2008, 144, 235.
37 Juang R. S. ; Wu F. C. ; Tseng R. L. J. Colloid Interface Sci. 2000, 227, 437.
38 Zhou J. B. ; Wang L. ; Zhang Z. ; Yu J. G. J. Colloid Interface Sci. 2013, 394, 509.
39 Xue G. H. ; Gao M. L. ; Gu Z. ; Luo Z. X. ; Hu Z. C. Chem. Eng. J. 2013, 218, 223.
40 Allen S. J. ; Mckay G. ; Porter J. F. J. Colloid Interface Sci. 2004, 280, 322.
41 Wang Y. ; Qi Y. X. ; Li Y. F. ; Wu J. J. ; Ma X. J. ; Yu C. ; Ji L. J. Hazard. Mater. 2013, 260, 9.
42 Garbassi F. ; Balducci L. ; Chiurlo P. ; Deiana L. Appl. Surf. Sci. 1995, 84, 145.
43 Heidari A. ; Younesi H. ; Mehraban Z. Chem. Eng. J. 2009, 153, 70.
44 Rahmani A. ; Mousav H. Z. ; Fazli M. Desalination 2010, 253, 94.
[1] Jyotirmoy DEB,Debolina PAUL,David PEGU,Utpal SARKAR. Adsorption of Hydrazoic Acid on Pristine Graphyne Sheet: A Computational Study[J]. Acta Physico-Chimica Sinca, 2018, 34(5): 537-542.
[2] Xuanjun WU,Lei LI,Liang PENG,Yetong WANG,Weiquan CAI. Effect of Coordinatively Unsaturated Metal Sites in Porous Aromatic Frameworks on Hydrogen Storage Capacity[J]. Acta Physico-Chimica Sinca, 2018, 34(3): 286-295.
[3] Chen-Hui ZHANG,Xin ZHAO,Jin-Mei LEI,Yue MA,Feng-Pei DU. Wettability of Triton X-100 on Wheat (Triticum aestivum) Leaf Surfaces with Respect to Developmental Changes[J]. Acta Physico-Chimica Sinca, 2017, 33(9): 1846-1854.
[4] Chan YAO,Guo-Yan LI,Yan-Hong XU. Carboxyl-Enriched Conjugated Microporous Polymers: Impact of Building Blocks on Porosity and Gas Adsorption[J]. Acta Physico-Chimica Sinca, 2017, 33(9): 1898-1904.
[5] . Influencing Mechanism of Cyclohexene on Thiophene Adsorption over CuY Zeolites[J]. Acta Physico-Chimica Sinca, 2017, 33(6): 1236-1241.
[6] Wei-Guo DAI,Dan-Nong HE. Selective Photoelectrochemical Oxidation of Chiral Ibuprofen Enantiomers[J]. Acta Physico-Chimica Sinca, 2017, 33(5): 960-967.
[7] Lei HE,Xiang-Qian ZHANG,An-Hui LU. Two-Dimensional Carbon-Based Porous Materials: Synthesis and Applications[J]. Acta Physico-Chimica Sinca, 2017, 33(4): 709-728.
[8] Fang CHENG,Han-Qi WANG,Kuang XU,Wei HE. Preparation and Characterization of Dithiocarbamate Based Carbohydrate Chips[J]. Acta Physico-Chimica Sinca, 2017, 33(2): 426-434.
[9] Tao-Na ZHANG,Xue-Wen XU,Liang DONG,Zhao-Yi TAN,Chun-Li LIU. Molecular Dynamics Simulations of Uranyl Species Adsorption and Diffusion Behavior on Pyrophyllite at Different Temperatures[J]. Acta Physico-Chimica Sinca, 2017, 33(10): 2013-2021.
[10] Jun-Jun CHEN,Cheng-Wu SHI,Zheng-Guo ZHANG,Guan-Nan XIAO,Zhang-Peng SHAO,Nan-Nan LI. 4.81%-Efficiency Solid-State Quantum-Dot Sensitized Solar Cells Based on Compact PbS Quantum-Dot Thin Films and TiO2 Nanorod Arrays[J]. Acta Physico-Chimica Sinca, 2017, 33(10): 2029-2034.
[11] Shao-Zheng ZHANG,Jia LIU,Yan XIE,Yin-Ji LU,Lin LI,Liang LÜ,Jian-Hui YANG,Shi-Hao WEI. First-Principle Study of Hydrogen Evolution Activity for Two-dimensional M2XO2-2x(OH)2x (M=Ti, V; X=C, N)[J]. Acta Physico-Chimica Sinca, 2017, 33(10): 2022-2028.
[12] Yan-Ting LI,Xin-Min LIU,Rui TIAN,Wu-Quan DING,Wei-Ning XIU,Ling-Ling TANG,Jing ZHANG,Hang LI. An Approach to Estimate the Activation Energy of Cation Exchange Adsorption[J]. Acta Physico-Chimica Sinca, 2017, 33(10): 1998-2003.
[13] LI Kui, ZHAO Yao-Lin, DENG Jia, HE Chao-Hui, DING Shu-Jiang, SHI Wei-Qun. Adsorption of Radioiodine on Cu2O Surfaces: a First-Principles Density Functional Study[J]. Acta Physico-Chimica Sinca, 2016, 32(9): 2264-2270.
[14] XING Lei, JIAO Li-Ying. Recent Advances in the Chemical Doping of Two-Dimensional Molybdenum Disulfide[J]. Acta Physico-Chimica Sinca, 2016, 32(9): 2133-2145.
[15] NIU Hui-Chang, JI Dan, LIU Nai-An. Method for Optimizing the Kinetic Parameters for the Thermal Degradation of Forest Fuels Based on a Hybrid Genetic Algorithm[J]. Acta Physico-Chimica Sinca, 2016, 32(9): 2223-2231.