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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(1)>> 9-17     doi: 10.3866/PKU.WHXB201609202         中文摘要
Core-Shell Electrocatalysts for Oxygen Reduction Reaction
CHANG Qiao-Wan, XIAO Fei, XU Yuan, SHAO Min-Hua
Department of Chemical and Biomolecular Engineering, The Hong Kong University of Science and Technology, Hong Kong, P. R. China
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The high cost of platinum in catalyst layers hinders the commercialization of proton exchange membrane fuel cells. This Account reviews recent progress on core-shell nanostructures for oxygen reduction reaction (ORR) in acidic media, which is the cathodic reaction in fuel cells. The synthesis, characterization and evaluation of different types of core-shell electrocatalysts are summarized. Various strategies to improve the performance of core-shell electrocatalysts, including dealloying, morphology control, and surface modification are presented. The issues of mass production and fuel cell performance of core-shell electrocatalysts are also discussed.



Keywords: Core-shell structure   Proton exchange membrane fuel cell   Electrocatalysis   Platinum alloy   Palladium   Shape control  
Received: 2016-08-02 Accepted: 2016-09-20 Publication Date (Web): 2016-09-20
Corresponding Authors: SHAO Min-Hua Email: kemshao@ust.hk

Fund: The project was supported by the Research Grant Council of the Hong Kong Special Administrative Region, China (26206115).

Cite this article: CHANG Qiao-Wan, XIAO Fei, XU Yuan, SHAO Min-Hua. Core-Shell Electrocatalysts for Oxygen Reduction Reaction[J]. Acta Phys. -Chim. Sin., 2017,33 (1): 9-17.    doi: 10.3866/PKU.WHXB201609202

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52. JIN Rong-Rong, LI Li-Fang, XU Xue-Feng, LIAN Ying-Hui, ZHAO Fan.Layered Double Hydroxide Supported Palladium Nanoparticles for Electrocatalytic Oxidation of Hydrazine[J]. Acta Phys. -Chim. Sin., 2012,28(08): 1929-1935
53. CONG Yan-Qing, LI Zhe, WANG Qi, ZHANG Yi, XU Qian, FU Fang-Xia.Enhanced Photoeletrocatalytic Activity of TiO2 Nanotube Arrays Modified with Simple Transition Metal Oxides (Fe2O3, CuO, NiO)[J]. Acta Phys. -Chim. Sin., 2012,28(06): 1489-1496
54. NIE Su-Lian, ZHAO Yan-Chun, FAN Jie-Wen, TIAN Jian-Niao, NING Zhen, LI Xiao-Xiao.Highly Active Pd-Co3O4/MWCNTs Catalysts for Methanol Electrocatalytic Oxidation[J]. Acta Phys. -Chim. Sin., 2012,28(04): 871-876
55. YANG Wei-Hua, YANG Wu-Tao, LIN Xiao-Yan.Preparation and Characterization of a Novel Bi-Doped PbO2 Electrode[J]. Acta Phys. -Chim. Sin., 2012,28(04): 831-836
56. SUN Ya-Ping, FAN Xin-Zhuang, LU Yong-Hong, XU Hai-Bo.Electrocatalytic Performance and Pseudo-Capacitive Characteristics of Modified Graphite Electrode with Fe3+/Fe2+ in H2SO4 Solution[J]. Acta Phys. -Chim. Sin., 2012,28(03): 603-608
57. HU Xian-Chao, CHEN Dan, SHI Bin-Bin, LI Guo-Hua.Preparation of Tungsten Carbide and Titania Nanocomposite and Its Electrocatalytic Activity for Methanol[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2863-2871
58. RAO Gui-Shi, CHENG Mei-Qin, ZHONG Yan, DENG Xiao-Cong, YI Fei, CHEN Zhi-Ren, ZHONG Qi-Ling, FAN Feng-Ru, REN Bin, TIAN Zhong-Qun.Preparation of High Catalytic Platinum Hollow Nanospheres and Their Electrocatalytic Performance for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2373-2378
59. XIA Hui-Yun, ZHANG Ying, GAO Li-Ning, YAN Lu-Ke.Ag-P(AM-co-MAA) Composite Microspheres Based on Morphology Transcription Method[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2485-2492
60. CHEN Meng-Nan, ZHANG Dong-Yun, THOMPSON Levi T., MA Zi-Feng.Hydrogen Production from Steam Reforming of Ethanol over Pd Promoted ZnO/Al2O3 Catalysts[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2185-2190
61. ZHANG Min, LI Jing-Jian, PAN Mu, XU Dong-Sheng.Catalytic Performance of Pt Nanowire Arrays for Oxygen Reduction[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1685-1688
62. YUE Jun-Pei, YANG Fang-Zu, TIAN Zhong-Qun, ZHOU Shao-Min.Electrocrystallization of Pd-Ni Alloys on Glassy Carbon Electrode[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1446-1450
63. LI Yun-Xia, WEI Zi-Dong, ZHAO Qiao-Ling, DING Wei, ZHANG Qian, CHEN Si-Guo.Preparation of Pt/Graphene Catalyst and Its Catalytic Performance for Oxygen Reduction[J]. Acta Phys. -Chim. Sin., 2011,27(04): 858-862
64. LAO Guo-Hong, SHAO Hai-Bo, FAN Yu-Qian, WANG Jian-Ming, ZHANG Jian-Qing, CAO Chu-Nan.Catalytic Oxidation of Sulfide Ion over a Spherular-Co3O4 Electrode[J]. Acta Phys. -Chim. Sin., 2011,27(03): 627-632
65. LIU Chun-Yan, XU Bin, TANG Ya-Wen, CAO Gao-Ping, YANG Yu-Sheng, LU Tian-Hong.Electrocatalytic Performance of Pd Catalyst Supported on Macropore Carbon for Oxidation of Formic Acid[J]. Acta Phys. -Chim. Sin., 2011,27(03): 604-608
66. WANG Chong-Tai, HUA Ying-Jie, SUN Zhen-Fan, WEI Ji-Chong, LI Tian-Lue, TONG Ye-Xiang, LIU Xiao-Yang.Electrochemical Properties of the Dawson-Type Heteropolytungstate Anion P2W18O626- and Its O2 Reduction Electrocatalysis[J]. Acta Phys. -Chim. Sin., 2011,27(02): 473-478
67. ZHAO Yan-Chun, ZHAN Lu, TIAN Jian-Niao, NIE Su-Lian, NING Zhen.N-Doped Amorphous Carbon Supported Pd Catalysts for Methanol Electrocatalytic Oxidation[J]. Acta Phys. -Chim. Sin., 2011,27(01): 91-96
68. LI Huan-Zhi, TANG Ya-Wen, LU Tian-Hong.Effect of NH4+ on the Electrocatalytic Performance of Carbon Supported Pd Catalyst for Formic Acid Oxidation[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3199-3202
69. ZENG Han, LIAO Ling-Wen, LI Ming-Fang, TAO Qian, KANG Jing, CHEN Yan-Xia.Poly Aryl Amide and Multiwalled Carbon Nanotube Composite Supported Laccase Electrode and Its Electrochemical Behavior[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3217-3224
70. GAO Hai-Li, LIAO Shi-Jun, ZENG Jian-Huang, LIANG Zhen-Xing, XIE Yi-Chun.Preparation and Characterization of Platinum-Decorated Ru/C Catalyst with High Performance and Superior Poison Tolerance[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3193-3198
71. LI Mei-Chao, WANG Wu-Yang, ZHU Wan-Xia, MA Chun-An.Electrocatalytic Oxidation of Ascorbic Acid on a PPy-HEImTfa/Pt Electrode and Its Mechanism[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3212-3216
72. YAN Liang-Liang, JIANG Qing-Ning, LIU De-Yu, ZHONG Yan, WEN Fei-Peng, DENG Xiao-Cong, ZHONG Qi-Ling, REN Bin, TIAN Zhong-Qun.Electrocatalytic Oxidation of Formic Acid on Pt-Se HollowNanosphere Modified Glassy Carbon Electrodes[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2337-2342
73. CHEN Zhao-Yang, ZHAO Feng-Ming, MA Chun-An, QIAO Yun.Ultrasonic-Assisted Preparation of Bimodal Mesoporous HollowGlobal Tungsten Carbide and Its Electrocatalytic Performance[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2569-2574
74. XU Jia-Xin, JIANG Yan-Xia, LIAO Hong-Gang, CHEN Sheng-Pei, SUN Shi-Gang.Room Temperature Synthesis of Thorn-Like Pd Nanoparticles and Their Enhanced Electrocatalytic Property for Ethanol Oxidation[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2139-2143
75. ZHAO Yan-Chun, LAN Huang-Xian, DENG Bin-Bin, TIAN Jian-Niao, YANG Xiu-Lin, WANG Feng-Yang.Electrocatalytic Oxidation of Methanol with Poly Functionalized Multiwalled Carbon Nanotubes Supported Pt Catalysts[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2255-2260
76. SHEN Bin, WANG Yong-An, WANG Zhi-Fei, ZHANG Ling.Catalytic Activity of an Oxime Carbapalladacycle Complex Grafted onto Superparamagnetically Mesoporous Nanoparticles for the Heck Reaction[J]. Acta Phys. -Chim. Sin., 2010,26(07): 1860-1866
77. WEN Zhu-Liang, YANG Su-Dong, SONG Qi-Jun, HAO Liang, ZHANG Xiao-Gang.High Activity of Pd/Graphene Catalysts for Ethanol Electrocatalytic Oxidation[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1570-1574
78. YAO Guo-Xin, SHI Bin-Bin, LI Guo-Hua, ZHENG Yi-Fan.Preparation and Electrocatalytic Activity of Tungsten Carbide and Zeolite Nanocomposite[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1317-1322
79. SUN Dun, HE Jian-Ping, ZHOU Jian-Hua, WANG Tao, DI Zhi-Yong, DING Xiao-Chun.Galvanic Replacement Strategy for a Core-Shell Like Ni-Pt Electrocatalyst with High Pt Utilization[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1219-1224
80. WU Yan-Ni, LIAO Shi-Jun.Shortened Carbon Nanotubes as Supports to Prepare High-Performance Pt/SCNT and PtRu/SCNT Catalysts for Fuel Cells[J]. Acta Phys. -Chim. Sin., 2010,26(03): 669-674
81. LIANG Peng, XU Hong-Feng, LIU Ming, LU Lu, FU Jie.Electrochemical Performance Testing and Characterization of Silver-Plated and Graphite-Coated 316L Stainless Steel Bipolar Plates[J]. Acta Phys. -Chim. Sin., 2010,26(03): 595-600
82. GUO Yong-Fu, XUE Cheng-Shan, SHI Feng, ZHUANG Hui-Zhao, LIU Wen-Jun, SUN Hai-Bo, CAO Yu-Ping.Optical Properties of Single-Crystal GaN Nanowires Synthesized by Pd Catalysis[J]. Acta Phys. -Chim. Sin., 2010,26(02): 507-510
83. TANG Dian-Yong, HUANG Xue-Na, ZOU Ting, JIN Cheng, HU Jian-Ping, FU Qin-Chao.Geometric Structures and Electronic Properties of Small Gold-Palladium Binary Clusters[J]. Acta Phys. -Chim. Sin., 2010,26(02): 453-460
84. YANG Gai-Xiu, CHEN Ting-Ting, TANG Ya-Wen, LU Tian-Hong.Electrocatalytic Performance of Silicotungstic Acid Modified Carbon Supported Pd Catalyst for Oxidation of Fomic Acid[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2450-2454
85. LI Peng, HE Chi, CHENG Jie, HAO Zheng-Ping.Catalytic Oxidation of Chlorobenzene on Composite Oxide Pd/M3AlO (M=Mg, Co, Ni, Cu, Zn) Catalysts Derived fromPd-Contained Hydrotalcite Precursors[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2279-2284
86. ZHAO Yan-Chun, LAN Huang-Xian, TIAN Jian-Niao, YANG Xiu-Lin, WANG Feng-Yang.Electrocatalytic Oxidation of Methanol on Pt Nanoparticles Supported on Porous Poly(N-acetylaniline) Nanofibrils[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2050-2054
87. WANG Run-Han, JIANG Ji-Sen, HU Ming.Controlled Syntheses of FeNi3 Alloy Nanostructures via Reverse Microemulsion-Directed Hydrothermal Motheds[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2167-2172
88. FANG Xiang, SHEN Pei-Kang.Mechanism of Ethanol Electrooxidation on Pd Electrode[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1933-1938
89. HUANG Si-Ping, YUAN Zhong-Zhi.Electrocatalytic Performance of Binuclear Co-Mn Phthalocyanine for the Reduction of Thionyl Chloride[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1599-1604
90. CHU Dao-Bao, HE Jian-Guo, HOU Yuan-Yuan, XU Mai, WANG Shu-Xi, WANG Jian, ZHA Long-Wu, ZHANG Xue-Jiao.Electrocatalytic Oxidation of Glyoxal on Ti/NanoTiO2-Pt Modified Electrode[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1434-1438
91. XU Hai-Qing, LIU Xiu-Ning, WANG Yu-Qiao, WANG Hua-Lin, SUN Yue-Ming.Electro-Catalytic Performance of Composite Oxide Sn-Sb-Mn/Ceramic Particle Electrode System[J]. Acta Phys. -Chim. Sin., 2009,25(05): 840-846
92. ZHENG Gen-Wen, GONG Chun-Li, WEN Sheng, ZHOU Huan-Bo, XIE Xiao-Lin.Preparation and Properties of Sulfonated Poly(ether sulfone)/Boron Phosphate Composite Proton Exchange Membranes[J]. Acta Phys. -Chim. Sin., 2009,25(03): 575-582
93. KE Xi; CUI Guo-Feng; SHEN Pei-Kang.Stability of Pd-Fe Alloy Catalysts[J]. Acta Phys. -Chim. Sin., 2009,25(02): 213-217
94. ZHANG Hong-Wei, ZHANG Zheng-Fu, LI Yang, YANG Xi-Hun, LIU Shuo.Structural Effects and Electrooxidation Activity of a Two-Dimensional Multilayer PtRu/PtNd Alloy Nanostructure Thin Film[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2268-2274
95. ZHAO Feng-Ming; SHEN Hai-Ping; CHEN Zhao-Yang; MA Chun-An.Electrocatalytic Reduction of Maleic Acid at Bundles of TiO2 Anodization Film[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2139-2142
96. HUANG Yong-Li; LIU Zhi-Ping.DFT Study on Hydrogen and Sulfur Adsorption on (111) Surface of Pd, Cu, Au, and PdAu, PdCu Alloys[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1662-1668
97. ZHENG Yi-Xiong; YAO Shi-Bing; ZHOU Shao-Min.Electrooxidation of Ethanol at Ni-B Amorphous Alloy Electrode and Measurements of Kinetic Parameters[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1643-1649
98. LUO Ming-Hong; LIN Shen; ZHANG Xiao-Feng; LIN Yue-Xu; LIU Jiao-Hua.Preparation and Electrocatalytic Property of Multilayer Films Constructed from Vanadium Substituted Polyoxometalate and
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99. SHI Yan-Hua; MENG Hui-Min; SUN Dong-Bai; YU Hong-Ying; FU Hua-Rong.Manganese Oxide Coating Electrodes Prepared by Pulse Anodic Electrodeposition[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1199-1206
100. ZHOU Jian-Hua; HE Jian-Ping; JI Ya-Jun; ZHAO Gui-Wang; ZHANG Chuan-Xiang; CHEN Xiu; WANG Tao.Influence of Hierarchical Porosity in Carbon Material on Electrocatalytic Property of Supported Pt Nanoparticles[J]. Acta Phys. -Chim. Sin., 2008,24(05): 839-843
101. GAN Ning; WANG Lu-Yan; LI Tian-Hua; WANG Feng; JIANG Qian-Li.Preparaton and Electrocatalytic Activities of Nano Pt/Dimercaptosuccinic Amide Copper Modified Electrode[J]. Acta Phys. -Chim. Sin., 2008,24(05): 915-920
102. ZHOU Yong-Hua; YE Hong-Qi.Deposition of Pd Nano-Particles in W/O Microemulsion by Chemical Demulsifying[J]. Acta Phys. -Chim. Sin., 2008,24(03): 487-491
103. SUN Li-Mei; CAO Dian-Xue; WANG Gui-Ling; LU Yan-Zhuo; ZHANG Mi-Lin.Electrocatalytic Reduction of Hydrogen Peroxide on Pd Nanoparticles[J]. Acta Phys. -Chim. Sin., 2008,24(02): 323-327
104. RAO Gui-Shi; FAN Feng-Ru; WANG Guo-Fu; WU Zhi-Xiang; YI Fei; ZHONG Qi-Ling; REN Bin; TIAN Zhong-Qun.In-situ SERS of Formic Acid Electro-catalytic Oxidation on Aucore@Ptshell/Pt Electrode[J]. Acta Phys. -Chim. Sin., 2008,24(02): 345-349
105. LI Guo-Hua; TIAN Wei; TANG Jun-Yan; MA Chun-An.Preparation and Electrocatalytic Property for Methanol Oxidation of WC/CNT Nanocomposite[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1370-1374
106. ZHENG Hai-Tao; LI Yong-Liang; LIANG Jian-Ying; SHEN Pei-Kang.Methanol Oxidation on Pd-based Electrocatalysts[J]. Acta Phys. -Chim. Sin., 2007,23(07): 993-996
107. HUANG Ke-Long; LIU Ren-Sheng; YANG You-Ping; LIU Su-Qin; WANG Li-Ping.Shape-controlled Synthesis and Formation Mechanism of Co3O4 by Solvothermal Method[J]. Acta Phys. -Chim. Sin., 2007,23(05): 655-658
108. LIU Yong; WEI Zi-Dong; CHEN Si-Guo; FENG Yong-Chao; YIN Guang-Zhi; SUN Cai-Xin.PEMFC Electrodes Platinized by Modulated Pulse Current Electrodeposition[J]. Acta Phys. -Chim. Sin., 2007,23(04): 521-525
109. MA Wei;SUN Deng-Ming.Electrocatalytical Oxidation of Dopamine and Epinephrine at Poly(L-threonine) Modified Electrode[J]. Acta Phys. -Chim. Sin., 2007,23(03): 332-336
110. SHENG Jiang-Feng;MA Chun-An;ZHANG Cheng;LI Guo-Hua .Preparation of Tungsten Carbide-Supported Nano Platinum Catalyst and Its Electrocatalytic Activity for Hydrogen Evolution[J]. Acta Phys. -Chim. Sin., 2007,23(02): 181-186
111. LÜ Ya-Fen;YIN Ya-Jing;WU Ping;CAI Chen-Xin.Direct Electrochemistry and Bioelectrocatalysis of Myoglobin at a Carbon Nanotube-Modified Electrode[J]. Acta Phys. -Chim. Sin., 2007,23(01): 5-11
112. TIAN Juan;ZHENG Dan;ZHANG Xi-Gui;ZHANG Bao-Hong;XIA Bao-Jia;YANG Hui.Preparation of Pt Nanoparticle Modified Porous Silicon Electrode and Its Electrocatalytic Performance[J]. Acta Phys. -Chim. Sin., 2007,23(01): 68-72
113. ZONG Ye;WANG Yu;LIN Chang-Jian .Preparation and Characterization of a High Loading Nano PtRu/C Catalysts in DMFC[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1305-1309
114. LIN Qi;FU Hai-Yan;YUAN Mao-Lin;CHEN Hua;LI Xian-Jun.Carbonylation of Aryl Halide Catalyzed by Active-carbon Supported Ionic Liquid-phase Palladium Catalyst[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1272-1276
115. SHI Yan-Mao;WU Ping;DU Pan;CAI Chen-Xin.Solid-state Electrochemistry of Gadolinium Hexacyanoferrate Modified Electrode and Its Electrocatalytic Property[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1227-1232
116. HU Ji-Ming;HOU Yan-Yuan;WANG Xiao-Mei;ZHANG Jian-Qing;CAO Chun-Nan .Effect of Calcination Procedure on the Electrocatalytic Activities of Ti/IrO2 Electrodes in Acidic Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2006,22(08): 1010-1014
117. YANG Ying;GONG Chu-Qing;XIAO Si;GONG Hong-Mei;WANG Qu-Quan;ZHONG Jia-Cheng.Influences of Titania Concentration on the Structure and the Three-order Nonlinear Optical Properties of Core-shell Ag/TiO2 Nanocomposites[J]. Acta Phys. -Chim. Sin., 2006,22(07): 791-796
118. GU Hong;XU Bo-Lian;ZHOU Jing;LI Yuan-Zhi;FAN Yi-Ning.Catalytic Properties of Supported Pd/TiO2 and Pd-Ag/TiO2 Catalysts for Selective Hydrogenation of Acetylene[J]. Acta Phys. -Chim. Sin., 2006,22(06): 712-715
119. LI Li;WU Gang;YE Qing;DENG Wei;XU Bo-Qing.Electrochemical Modification of Pt/C Catalyst by Silicomolybdic Acid[J]. Acta Phys. -Chim. Sin., 2006,22(04): 419-423
120. CHU Dao-Bao; ZHANG Li-Yan; ZHANG Jin-Hua; ZHANG Xiu-Mei; YIN Xiao-Juan.Heterogeneous Electrocatalytic Reduction of Furfural on Nanocrystalline TiO2-CNT Complex Film Electrode in DMF Solution[J]. Acta Phys. -Chim. Sin., 2006,22(03): 373-377
121. YANG Bo; YU Gang; HUANG Jun.Electrocatalytic Reductive Dechlorination of 2,4,5-PCB in Aqueous Solution by Palladium-modified Titanium Mesh as Cathode[J]. Acta Phys. -Chim. Sin., 2006,22(03): 306-311
122. DENG Xiang-Hui;KAN Xian-Wen;YU Yan;ZHANG Wen-Zhi;LIU Hong-Ying;FANG Bin.Electrochemical and Catalytic Properties of Ferrocene/L-cysteine Modified Electrode[J]. Acta Phys. -Chim. Sin., 2005,21(12): 1399-1402
123. GAO En-jun; DING Li-na; LIU Qi-tao; SUN Ya-guang.Studies on Stability of Pd(Ⅱ)Ternary Complexes and Interaction with DNA[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1091-1095
124. WANG Zhen-bo; YIN Ge-ping; SHI Peng-fei.The Influence of Three Groups of Pt-Ru/C Catalyst’s Precursors on Its Performance for Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1156-1160
125. LI Li; XU Bo-qing.Electrooxidation of CO Adsorbed on PtMo/C Catalyst:Effect of Catalyst Preparation[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1132-1137
126. ZHANG Li-juan; XIA Ding-guo.Electrocatalytic Activity of Ordered Intermetallic PtSb for Ethanol Electrooxidation[J]. Acta Phys. -Chim. Sin., 2005,21(09): 1006-1010
127. MA Chun-an; HUANG Ye; TONG Shao-ping; ZHANG Wei-min.The Catalytic Behavior of Tungsten Carbide for the Electroreduction of p-nitrophenol[J]. Acta Phys. -Chim. Sin., 2005,21(07): 721-724
128. ZHANG Li-Juan; XIA Ding-Guo; WANG Zhen-Yao; YUAN Rong; WU Zi-Yu.Intermetallic PtBi as Methanol-tolerant Catalysts for Oxygen Reduction[J]. Acta Phys. -Chim. Sin., 2005,21(03): 287-290
129. TIAN Na;CHEN Wei;SUN Shi-Gang.Spectroscopic Characterization and Electrocatalytic Properties of Core-Shell Au-Pt Nanoparticles[J]. Acta Phys. -Chim. Sin., 2005,21(01): 74-78
130. Sun Shi-Gang.Enhanced IR Absorption and Abnormal IR Effects of Low-dimensional Nanomaterials[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 1017-1023
131. Zhou Ming-Hua;Dai Qi-Zhou;Lei Le-Cheng;Wu Zu-Cheng;Ma Chun-An;Wang Da-Hui.Electrochemical Oxidation for the Degradation of Organic Pollutants on a Novel PbO2 Anode[J]. Acta Phys. -Chim. Sin., 2004,20(08): 871-876
132. Wan Li-Juan;Gao Ying;Wu Bing;Liu Chang-Peng;Xing Wei;Lu Tian-Hong.Cocatalysis of Adsorbed Eu3+ and Ho3+ at Pt-TiO2/C Electrode for Electrooxidaton of Ethanol[J]. Acta Phys. -Chim. Sin., 2004,20(06): 616-620
133. Yang Fang-Zu;Huang Ling;Xu Shu-Kai;Zhou Shao-Min.Studies on the Electrodeposition Behaviors of Palladium by the Actions of Additive[J]. Acta Phys. -Chim. Sin., 2004,20(05): 463-467
134. Peng Cheng;Cheng Xuan;Zhang Ying;Chen Ling;Fan Qing-Bai.Comparison of Methanol Electrooxidation on Carbon Supported Pt and PtRu Catalysts[J]. Acta Phys. -Chim. Sin., 2004,20(04): 436-439
135. Chu You-Qun;Ma Chun-An;Zhu Ying-Hong.Electrocatalytic Reduction of Oxygen on Carbon Nanotubes Electrode[J]. Acta Phys. -Chim. Sin., 2004,20(03): 331-335
136. Chu Dao-Bao;Wang Feng-Wu;Wei Yi-Jun;Yao Wen-Li;Li Xiao-Hua.Electrocatalytic Activities and Preparation of Nanocrystalline TiO2 -Pt Modified Electrode[J]. Acta Phys. -Chim. Sin., 2004,20(02): 182-185
137. He Chong-Heng;Wang Ren.The Properties of Pd Catalysts Prepared by Sol-gel Method[J]. Acta Phys. -Chim. Sin., 2003,19(10): 952-956
138. Mu Shao-Lin;Yang Yi-Fei;Tan Zhi-An.The Electrocatalytic Oxidation of Hydrogen Peroxide on Polyaniline Doped with Ferrocenesulfonic Acid[J]. Acta Phys. -Chim. Sin., 2003,19(07): 588-592
139. Chen Wei;Sun Shi-Gang;Si Di;Chen Sheng-Pei.Electrocatalytic Properties of Agglomerates of Pt Nanoparticles in Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2003,19(05): 441-444
140. Li Xu-Guang;Han Fei;Xing Wei;Tang Ya-Wen;Lu Tian-Hong.Influence of Methanol on the Kinetics of Oxygen Reduction on Pt/C and CoPcTc/C[J]. Acta Phys. -Chim. Sin., 2003,19(04): 380-384
141. Li Li;Wang Heng-Xiu;Xu Bo-Qing;Li Jin-Lu;Xing Wei;Mao Zong-Qiang.Studies on PEMFC Electrocatalysts: Physicochemical Characterization of Homemade Pt/C Electrocatalyst[J]. Acta Phys. -Chim. Sin., 2003,19(04): 342-346
142. Guo Xiang-Yun.Formation and Growth Mechanism of Pdn Clusters Studied by the Monte Carlo Method[J]. Acta Phys. -Chim. Sin., 2003,19(02): 174-176
143. Zhang Yu-Zhong;Zhao Hong;Yuan Zhuo-Bin.Electrochemical Characteristics and Catalytic Properties of Poly (ferulic acid) Glassy Carbon Modified Electrode[J]. Acta Phys. -Chim. Sin., 2002,18(09): 841-845
144. Wang Feng-Bin;Jiang Hui-Jun;Xing Wei;Lu Tian-Hong;Chen Hui-Lan.Electrochemical and Electrocatalytic Properties of Microperoxidase-11 Adsorbed on the Poly-L-Lysine Modified Ag Electrode[J]. Acta Phys. -Chim. Sin., 2002,18(05): 404-408
145. Xu Li-Na;Xu Hong-Fei;Zhou Kai-Chang;Xu Ai-Qun;Yue Zeng-Quan;Gu Ning;Zhang Hai-Qian;Liu Ju-Zheng;Chen Kun-Ji.Study on a New Activation Method for Initiating Electroless Plating on Alumina Powders Based on SAMs Bonded Palladium[J]. Acta Phys. -Chim. Sin., 2002,18(03): 284-288
146. Kong Jing-Lin;Xue Kuan-Hong;Shao Ying;He Chun-Jian;Chen Qiao-Ling.Measurements for the Kinetic Parameters of Electrocatalytic Oxidation of Ethanol at the Nickel Nanowire Electrode[J]. Acta Phys. -Chim. Sin., 2002,18(03): 268-271
147. Wang Yu-Ling;Cai Nai-Cai;Huo Yao-Dong;Chen Hao.Electrochemical Oxidation for the Degradation of Aniline on the SnO2/Ti Anode[J]. Acta Phys. -Chim. Sin., 2001,17(07): 609-613
148. Xia Sheng-Qing;Chen Sheng-Pei;Sun Shi-Gang.Electrocatalytic Reduction of Oxalic Acid on Platinum Based PbSb Surface Alloy Electrode[J]. Acta Phys. -Chim. Sin., 2001,17(02): 140-143
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