ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(3)>> 513-519     doi: 10.3866/PKU.WHXB201610251         中文摘要
Parameters of the Activation of Viscous Flow of Aqueous[C2mim] [Ala]
College of Chemistry, Liaoning University, Shenyang 110036, P. R. China
Full text: PDF (1754KB) HTML Export: BibTeX | EndNote (RIS) Supporting Info

The density and viscosity of aqueous solutions of an ionic liquid (IL) based on alanine,[C2mim] [Ala], with various molalities were measured in the temperature range of T=288.15-328.15 K with intervals of 5 K. From the Jones-Dole equation, a viscosity B-coefficient with a large positive value and dB/dT<0 were obtained. According to Feakins, the contribution of the solute to the activation free energy for viscous flow of the solution, Δμ2≠0, was obtained. The relationship between Δμ2≠0 and temperature was linear, allowing the standard molar activation entropy, ΔS2≠0, and enthalpy, ΔH2≠0, to be obtained. On the basis of Eyring's theory, a new semi-empirical method to estimate the viscosity of aqueous[C2mim] [Ala] was proposed. The values estimated using this method agreed well with the corresponding experimental ones.

Keywords: Ionic liquid   Viscosity of solution   Viscosity B-coefficient   Activation parameter for viscous flow of solution   Transition-state theory  
Received: 2016-09-13 Accepted: 2016-10-25 Publication Date (Web): 2016-10-25
Corresponding Authors: TONG Jing Email:

Fund: The project was supported by the National Natural Science Foundation of China (21273003)

Cite this article: TONG Jing, LIU Lu, ZHANG Duo, ZHENG Xu, CHEN Xia, YANG Jia-Zhen. Parameters of the Activation of Viscous Flow of Aqueous[C2mim] [Ala][J]. Acta Phys. -Chim. Sin., 2017,33 (3): 513-519.    doi: 10.3866/PKU.WHXB201610251

(1) Zhang, S.; Wang, J.; Lu, X.; Zhou, Q. Structures and Interactions of Ionic Liquids; Springer:Heidelberg, Germany, 2014. doi: 10.1007/978-3-642-38619-0
(2) Greaves, T. L.; Drummond, C. J. Chem. Rev.2007, 108 (1), 206. doi: 10.1021/cr068040u
(3) Rantwijk, F. V.; Sheldon, R. A. Chem. Rev.2007, 38 (107), 2757. doi: 10.1021/cr050948h
(4) Tariq, M.; Freire, M. G.; Saramago, B.; Coutinho, J. A. P.; Lopes, J. N. C.; Rebelo, L. P. N. Chem. Soc. Rev. 2011, 41, 829. doi: 10.1039/c1cs15146k
(5) Sun, X.; Luo, H.; Dai, S. Chem. Rev.2012, 112, 2100. doi: 10.1021/cr200193xd
(6) Riyazuddeen; Usmani, M. A. J. Chem. Eng. Data 2011, 56, 3504. doi: 10.1021/je2000205
(7) Liu, W.; Zhao, T.; Zhang, Y.; Wang, H.; Yu, M. J. Solut. Chem.2006, 35, 1337. doi: 10.1007/s10953-006-9064-7
(8) Tao, G. H.; He, L.; Liu, W. S.; Xu, L.; Xiong, W.; Wang, T.; Kou, Y. Green Chem.2006, 8, 639. doi: 10.1039/b600813e
(9) Fukumoto, K.; Ohno, H. Chem. Commun.2006, 3081. doi: 10.1039/b606613e
(10) Fukumoto, K.; Yoshizawa, M.; Ohno, H. J. Am. Chem. Soc.2005, 127, 2398. doi: 10.1021/ja043451i
(11) Ohno, H.; Fukumoto, K. Acc. Chem. Res.2007, 40, 1122. doi: 10.1021/ar700053z
(12) Tong, J.; Hong, M.; Chen, Y.; Wang, H.; Guan, W.; Yang, J. Z. J.Chem. Thermodyn.2012, 54, 352. doi: 10.1016/j.jct.2012.05.012
(13) Hong, M.; Sun, A.; Yang, Q.; Guan, W.; Tong, J.; Yang, J. Z. J.Chem. Thermodyn.2013, 67, 91. doi: 10.1016/j.jct.2013.07.008
(14) Hong, M.; Sun, A.; Liu, C.; Guan, W.; Tong, J.; Yang, J. Z. Ind.Eng. Chem. Res. 2013, 52, 15679. doi: 10.1021/ie402890r
(15) Hong, M.; Liu, R. J.; Yang, H. X.; Guan, W.; Tong, J.; Yang, J.Z. J. Chem. Thermodyn.2014, 70, 214. doi: 10.1016/j.jct.2013.11.004
(16) Tong, J.; Liu, Q. S.; Zhang, P.; Yang, J. Z. J. Chem. Eng. Data 2007, 52, 1497. doi: 10.1021/je700102g
(17) Jenkins, H. D. B.; Marcus, Y. Chem. Rev.1995, 95, 2695. doi: 10.1021/cr00040a004
(18) Feakins, D.; Freemantle, D. J.; Lawrence, K. G. J. Chem. Soc.Faraday Trans. I 1974, 70, 795. doi: 10.1039/f19747000795
(19) Feakins, D.; Waghorne, W. E.; Lawrence, K. G. J. Chem. Soc.Faraday Trans. I 1986, 82, 563. doi: 10.1039/f19868200563
(20) Lide, D. R. Handbook of Chemistry and Physics, 82nd ed.; CRCPress:Boca Raton, 2001.
(21) Huang, Z. Q. An Introduction to the Theory of Electrolyte Solution, revised ed.; Science Press:Beijing, 1983.[黄子卿. 电解质溶液理论导论, 修订版. 北京:科学出版社, 1983.]
(22) Harned, H. S.; Owen, B. B. The Physical Chemistry of Electrolyte Solutions, 3rd ed.; Reinhold:New York, 1958. doi: 10.1149/1.2427250
(23) Eyring, H. J. Chem. Phys.1936, 4, 283. doi: 10.1063/1.1749836
(24) Liu, W. B.; Wang, J. J.; Wang, C. L.; Lu, J. S. Acta Phys.-Chim.Sin.1992, 8, 742.[刘文彬, 王健吉, 王彩兰, 卢俊梭. 物理化学学报, 1992, 8, 742.] doi: 10.3866/PKU.WHXB19920606
(25) Liu, W. B.; Wu, Y. P.; Wang, J. J.; Lu, J. S. Acta Phys.-Chim.Sin.1995, 11, 590.[刘文彬, 吴艳平, 王健吉, 卢俊梭. 物理化学学报, 1995, 11, 590.] doi: 10.3866/PKU.WHXB19950705
(26) Mountain, B.W.; Seward, T. M. Geochimica et Cosmochimica Acta 2003, 67, 3005. doi: 10.1016/S0016-7037(00)00303-X
(27) Hu, Y. F.; Lee, H. Electrochim Acta 2003, 48, 1789. doi: 10.1016/j.electacta.2003.03.002
(28) Hu, Y. F. Chem. Eng. Sci.2004, 59, 2457. doi: 10.1016/j.ces.2003.11.005

1. ZHENG Qi-Ge, LIU Hui, XIA Quan, LIU Qing-Shan, MOU Lin.Density, Dynamic Viscosity and Electrical Conductivity of Two Hydrophobic Phosphonium Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2017,33(4): 736-744
2. BAI Jin, CHEN Xin, XI Zhao-Yi, WANG Xiang, LI Qiang, HU Shao-Zheng.Influence of Solvothermal Post-Treatment on Photochemical Nitrogen Conversion to Ammonia with g-C3N4 Catalyst[J]. Acta Phys. -Chim. Sin., 2017,33(3): 611-619
3. YUAN Wei-Jin, DONG Zhen, ZHAO Long, YU Tian-Lin, ZHAI Mao-Lin.γ-Ray-Induced Radiolysis of CMPO/[C2mim][NTf2] and Its Effect on Eu3+ Extraction[J]. Acta Phys. -Chim. Sin., 2016,32(8): 2101-2107
4. ZHENG Xiao-Di, ZHU Yan-Li, DONG Rui, JIAO Qing-Jie.Effect of Alkyl Imidazole Ionic Liquids CnmimCl (n= 4, 6, 8) on CL-20 Recrystallization[J]. Acta Phys. -Chim. Sin., 2016,32(8): 1950-1959
5. WU Yang, YUE Li-Li, LIU Qiao-Zhen, WANG Xia.A Theoretical Study of the Thermodynamic Properties of Imidazolium Acetate Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2016,32(8): 1960-1966
6. MAI Jun-Lin, SUN De-Lin, QUAN Xue-Bo, LI Li-Bo, ZHOU Jian.Mesoscopic Structure of Nafion-Ionic Liquid Membrane Using Dissipative Particle Dynamics Simulations[J]. Acta Phys. -Chim. Sin., 2016,32(7): 1649-1657
7. ZHANG Xiao-Ning, HU Hong-Mei.Investigation of Interfaces of Ionic Liquid via Kelvin Probe Force Microscopy at Room Temperature[J]. Acta Phys. -Chim. Sin., 2016,32(7): 1722-1726
8. LI Yan, CHAI Jin-Ling.Dilational Viscoelasticity of Imidazole-Based Surface Active Ionic Liquids at the Air/Water Interface[J]. Acta Phys. -Chim. Sin., 2016,32(5): 1227-1235
9. TONG Jing, CHEN Teng-Fei, ZHANG Duo, WANG Lin-Fu, TONG Jian, YANG Jia-Zhen.Molar Surface Gibbs Free Energy of the Aqueous Solution of the Ionic Liquid [C2mim][OAc][J]. Acta Phys. -Chim. Sin., 2016,32(5): 1161-1167
10. SHI Ji-Fu, HUANG Qi-Zhang, WAN Qing-Cui, XU Xue-Qing, LI Chun-Sheng, XU Gang.Sulfide-Based Ionic Liquid Electrolyte Widening the Application Temperature Range of Quantum-Dot-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2016,32(4): 822-827
11. LIU Qing-Shan, LIU Hui, MOU Lin.Properties of 1-(Cyanopropyl)-3-methylimidazolium Bis[(trifluoromethyl)sulfonyl]imide[J]. Acta Phys. -Chim. Sin., 2016,32(3): 617-623
12. CHEN Feng-Feng, DONG Yan, SANG Xiao-Yan, ZHOU Yan, TAO Duan-Jian.Physicochemical Properties and CO2 Solubility of Tetrabutylphosphonium Carboxylate Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2016,32(3): 605-610
13. MA Qing, TONG Jin-Hui, SU Ling-Di, WANG Wen-Hui, MA Wen-Mei, BO Li-Li.Highly Selective Hydroxylation of Benzene Catalyzed by Hybrids of Polyoxometalate/Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2016,32(12): 2961-2967
14. ZHENG Ling, PAN Yi, JI Hong-Xiang, MA Xiao-Xue, XING Nan-Nan, GUAN Wei.Evaluation of the Walden Product of Ionic Liquids Using Experiments and a New Theory: An Ion Exchange Transition Model[J]. Acta Phys. -Chim. Sin., 2016,32(11): 2663-2670
15. BU Xiao-Xue, FAN Ben-Han, WEI Jie, XING Nan-Nan, MA Xiao-Xue, GUAN Wei.Thermodynamic Properties and Predicting the Surface Tension of Pyridinium-Based Ionic Liquids of [C6py][DCA] Using a New Eötvös Equation[J]. Acta Phys. -Chim. Sin., 2016,32(1): 267-273
16. ZHANG Xiao-Hong, XU Hong-Yan, GE Ling-Ling, GUO Rong.Mixed Micelle of Surface Active Ionic Liquid Lauryl Isoquinolinium Bromide and Nonionic Surfactant Triton X-100 in Aqueous Solutions[J]. Acta Phys. -Chim. Sin., 2016,32(1): 356-364
17. WANG Hui-Yong, LI Hong-Pei, CUI Guo-Kai, LI Zhi-Yong, WANG Jian-Ji.Recent Progress in Self-Assembly of Ionic Liquid Surfactants and Its Regulation and Control in Aqueous Solutions[J]. Acta Phys. -Chim. Sin., 2016,32(1): 249-260
18. SUN Tao-Xiang, SHEN Xing-Hai, CHEN Qing-De.Investigation of Selective Extraction of UO22+ from Aqueous Solution by CMPO and TBP in Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2015,31(Suppl): 32-38
19. LI Wei, ZHANG Jing, QI Chuan-Song.Quantum Chemistry Calculations of Ion Cluster Models of EMIM Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2015,31(9): 1690-1698
20. TONG La-Ga, LIU Jin-Yan, WANG Cen-Chen, RONG Hua, LI Wei.Preparation of Micro/Nano ZnO Pompons and Their Catalytic Activity for the Solar Degradation of Organic Dyes[J]. Acta Phys. -Chim. Sin., 2015,31(8): 1615-1620
21. LI Bo-Xuan, GUO Qian-Jin, XIA An-Dong.Spectroscopic Study of the Structural Heterogeneity and Microviscosity of [bmim][PF6] and [moemim][PF6] Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2015,31(8): 1452-1460
22. ZENG Yu-Qun, GUO Yong-Sheng, WU Bing-Bin, HONG Xiang, WU Kai ZHONG, Kai-Fu.Synthesis and Electrochemical Performance of Plastic Crystal Compound-Based Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1351-1358
23. MA Hao, LONG Jin-Xing, WANG Fu-Rong, WANG Le-Fu, LI Xue-Hui.Conversion of Cellulose to Butyl Levulinate in Bio-Butanol Medium Catalyzed by Acidic Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2015,31(5): 973-979
24. LIU Hai-Wang, SHEN Xing-Hai, CHEN Qing-De.Extraction Mechanism and Selectivity of UO2(NO3)2 in Tributylphosphine Oxide-Ionic Liquid System[J]. Acta Phys. -Chim. Sin., 2015,31(5): 843-851
25. ZHU Guang-Lai, WANG Yu, ZHANG Liang-Wei, LIU Yan-Cheng, WU Guo-Zhong.Photochemical Reaction Kinetics of Duroquinone in a Mixture of Ionic Liquid [BPy][BF4] and Acetonitrile[J]. Acta Phys. -Chim. Sin., 2015,31(3): 419-424
26. LONG Jin-Xing, YUAN Zheng-Qiu, MA Hao, SHU Ri-Yang, LI Xue-Hui.Catalytic Synthesis of Trimethylolpropane in the Presence of Basic Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2015,31(2): 337-343
27. ZHENG Ling, FAN Ben-Han, BU Xiao-Xue, PAN Yi, DONG Jia-Xin, GUAN Wei.Study on Thermodynamic Properties of Ionic Liquid 1-Ethyl-3-methylimidazolium Alanine[J]. Acta Phys. -Chim. Sin., 2015,31(11): 2036-2042
28. LI Chi, YANG Hong-Xu, LIU Ru-Jing, YANG Qi, TONG Jing, YANG Jia-Zhen.Volume and Surface Properties of Aqueous [C5mim][Pro] at 288.15 to 318.15 K[J]. Acta Phys. -Chim. Sin., 2015,31(1): 11-16
29. WANG Shuo-Jue, AO Yin-Yong, ZHOU Han-Yang, YUAN Li-Yong, PENG Jing, ZHAI Mao-Lin.Research Progress in Radiation Effects on Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2014,30(9): 1597-1604
30. SONG Da-Yong, CHEN Jing.Hydrogen-Bonding Interactions between Ionic Liquid 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate and Water[J]. Acta Phys. -Chim. Sin., 2014,30(9): 1605-1610
31. YUAN Shu-Wei, LÜ Rong, YU An-Chi.Photoisomerization Kinetics of IR125 and HDITCP in Ionic Liquids with Different Cation Alkyl Chain Lengths[J]. Acta Phys. -Chim. Sin., 2014,30(5): 987-993
32. MEI Qing-Qing, HOU Min-Qiang, NING Hui, MA Jun, YANG De-Zhong, HAN Bu-Xing.Microstructure and Intermolecular Interactions of [Bmim][PF6]+Water+ Alcohol Systems: A Molecular Dynamics Simulation Study[J]. Acta Phys. -Chim. Sin., 2014,30(12): 2210-2215
33. YUE Ling, HE Zi-Meng, WANG Yu-Qin, SHANG Ya-Zhuo, LIU Hong-Lai.Effect of the Surfactant C12mimBr on the Aggregation Behavior of Gemini12-2-12 at an Air/Water Interface, Investigated Using an Interfacial Dilational Rheology Method[J]. Acta Phys. -Chim. Sin., 2014,30(12): 2291-2299
34. LI Chang-Ping, LI Zhuo, ZOU Ben-Xue, LIU Qing-Shan, LIU Xiao-Xia.Density, Viscosity and Conductivity of Protic Ionic Liquid N,N-DimethylethanolammoniumPropionate[J]. Acta Phys. -Chim. Sin., 2013,29(10): 2157-2161
35. NING Hui, HOU Min-Qiang, YANG De-Zhong, KANG Xin-Chen, HAN Bu-Xing.Ionic Association in Binary Ionic Liquids by Conductivity[J]. Acta Phys. -Chim. Sin., 2013,29(10): 2107-2113
36. MA Jing-Yuan, ZOU Yang, JIANG Zheng, HUANG Yu-Ying.Effect of the Ratio between Ionic Liquids [BMIM]Br and [BMIM][BF4] on the Charge Transfer of Br-[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1618-1622
37. WU Jing-Ke, SHEN Xing-Hai, CHEN Qing-De.Electrochemical Behavior of the System of Uranium(VI) Extraction with CMPO-Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1705-1711
38. PEI Qi-Fei, HUA Yi-Xin, XU Cun-Ying, ZHANG Qi-Bo, LI Yan, RU Juan-Jian, GONG Kai.Dissolution Process of an Aluminum Anode in Acidic AlCl3-BMIC Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2013,29(05): 946-952
39. NING Hui, HOU Min-Qiang, MEI Qing-Qing, YANG De-Zhong, HAN Bu-Xing.Phase Behaviors of 1-Butyl-3-methylimidazolium Hexafluorophosphate+Water+Alcohol Systems[J]. Acta Phys. -Chim. Sin., 2013,29(04): 678-682
40. CUI Zhen-Peng, WANG Shuo-Jue, AO Yin-Yong, PENG Jing, LI Jiu-Qiang, ZHAI Mao-Lin.Study of γ Radiation-Induced Colored Products on [Cnmim][NTf2] Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2013,29(03): 619-624
41. WANG Hai, XU Xue-Qing, SHI Ji-Fu, XU Gang.Application of Ionic Liquids with Carboxyl and Aromatic Ring Conjugated Anions in Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2013,29(03): 525-532
42. ZhONG Hao-Xiang, ZHAO Chun-Bao, LUO Hao, ZHANG Ling-Zhi.Novel Organosilicon Ionic Liquid Based Electrolytes for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2641-2647
43. WANG Ding, TIAN Guo-Cai.Simulation Study of the Effect ofMethanol on the Structure and Properties of 1-Butyl-3-methylimidazolium Tetrafluoroborate Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2558-2566
44. ZHAO Xue-Yan, CAO Yu-Rong, CAO Gui-Rong, XIAO Rui-Jie.Lamellar Liquid Crystalline Phase Formed by Triblock Copolymer L64 in 1-Butyl-3-methylimidazolium Tetrafluoroborate Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2012,28(06): 1411-1417
45. GONG Yan-Yan, LIU Min, JIA Song-Yan, FENG Jian-Ping, SONG Chun-Shan, GUO Xin-Wen.Production of 5-Hydroxymethylfurfural from Inulin Catalyzed by Sulfonated Amorphous Carbon in an Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2012,28(03): 686-692
46. ZHU Ying-Hong, ZENG Hong-Yan, LI Shan-Shan, LU Zai-Xiang, MA Chun-An.Electrochemical Oxidation of p-Methoxy Toluene in BMIMBF4 Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2012,28(02): 421-426
47. CHEN Xiao-Yun, LU Dong-Fang, HUANG Jin-Feng, LU Yan-Feng, ZHENG Jian-Qiang.Preparation and Properties of N-F Co-Doped TiO2 Photocatalyst with Wide Range Light Response and Multipore Structure from Ionic Liquid-Water Mixture Solvent[J]. Acta Phys. -Chim. Sin., 2012,28(01): 161-169
48. GAO Li-Xia, WANG Li-Na, QI Tao, YU Jiang.Preparation of Ni and Ni-Al Alloys from 2AlCl3/Et3NHCl Ionic Liquid by Electrodeposition[J]. Acta Phys. -Chim. Sin., 2012,28(01): 111-120
49. LIU Qing-Shan, YAN Pei-Fang, YANG Miao, TAN Zhi-Cheng, LI Chang-Ping, WELZ-BIERMANN Urs.Dynamic Viscosity and Conductivity of Ionic Liquids [Cnpy][NTf2] (n=2, 4, 5)[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2762-2766
50. LI Wei, QI Chuan-Song, WU Xin-Min, RONG Hua, GONG Liang-Fa.Relationship between Melting Point and the Interaction Energy of Alkyl Imidazolium Tetrafluoroborate Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2059-2064
51. FU Su-Zhen, CHEN Qing-De, SHEN Xing-Hai.Aggregation Behavior of 1-Alkyl-3-methylimidazolium Tetrafluoroborate Ionic Liquids in Aqueous Solutions[J]. Acta Phys. -Chim. Sin., 2011,27(08): 1913-1918
52. LIU Yu-Sheng, FU Hai-Ying, TANG Zhong-Feng, HUANG Wei, WU Guo-Zhong.Melting Point and Structure of Ionic Liquid [EMIM][PF6] on the Surface of Nano-SiOx Particles[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1725-1729
53. LONG Jin-Xing, GUO Bin, LI Xue-Hui, WANG Fu-Rong, WANG Le-Fu.Catalytic Decomposition of Cellulose in Cooperative Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2011,27(05): 995-999
54. ZHU Guang-Lai, WU Guo-Zhong, CUI Zhi-Feng, XU Xin-Sheng.Transient Absorption Spectroscopy of the Effects of the Ionic Liquid [bmim][BF4] on the Photochemical Reactions of Benzil[J]. Acta Phys. -Chim. Sin., 2011,27(04): 971-976
55. ZHANG Qi-Bo, HUA Yi-Xin.Effect of Alkylimidazolium Ionic Liquids on the Corrosion Inhibition of Copper in Sulfuric Acid Solution[J]. Acta Phys. -Chim. Sin., 2011,27(03): 655-663
56. CUI Feng-Chao, YU Hong-Bo, WANG Qin, YE Wan-Li, LIU Jing-Yao.Mechanism and Kinetics of the CH3OCF2CF2OCH3+Cl Reaction[J]. Acta Phys. -Chim. Sin., 2011,27(02): 337-342
57. CUI Wen-Yu, AN Mao-Zhong, YANG Pei-Xia, ZHANG Jin-Qiu.Cathodic and Thermal Stabilities of the P(VdF-HFP)-Based Ionic Liquid Composite Polymer Electrolyte[J]. Acta Phys. -Chim. Sin., 2011,27(01): 78-84
58. ZHANG Qi-Bo, HUA Yi-Xin.Effect of the Ionic Liquid Additive-[BMIM]HSO4 on the Kinetics of Oxygen Evolution during Zinc Electrowinning[J]. Acta Phys. -Chim. Sin., 2011,27(01): 149-155
59. ZHANG Li-Qun, LI Hao-Ran.Progress of Investigations on Structures and Interactions of Ionic Liquids by Infrared Spectroscopy and Raman Spectroscopy[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2877-2889
60. PAN Shan-Fei, HU Gui-Xiang, LV Yang, ZOU Jian-Wei, YU Qing-Sen.QSPRModel Analysis on the Solubility of Organic Compounds in Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2494-2502
61. CAO Hai, JIANG Jian, ZHU Xue-Feng, DUAN Peng-Fei, LIU Ming-Hua.Interfacial Assembly of Diethyl Ester Glutamic Acid Terminated Bolaamphiphile at the Air/Water Interface: Chiral Interaction and Morphology[J]. Acta Phys. -Chim. Sin., 2010,26(07): 1842-1846
62. LIU Qing-Shan, YANG Miao, TAN Zhi-Cheng, WELZ-BIERMANN Urs.Estimation and Prediction of the Physicochemical Properties of Imidazolium-Based Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1463-1467
63. LIANG Rui, YANG Mei-Rong, ZHOU Qing-Xiang.Thermal Stability, Equilibrium Vapor Pressure and Standard Enthalpy of Vaporization of 1-Butyl-3-methylimidazolium Tetrafluoroborate[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1468-1472
64. ZHAO Di, HUANG Qing, JIN Xian-Bo, WEI Xian-Jun, CHEN George Z..Capacitance at the Electrode/Ionic Liquid Interface[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1239-1248
65. LI Xue-Liang, CHEN Jie-Jie, LUO Mei, CHEN Xiang-Ying, LI Pei-Pei.Quantum Chemical Calculation of Hydroxyalkyl Ammonium Functionalized Ionic Liquids for Absorbing SO2[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1364-1372
66. CUI Wen-Yu, AN Mao-Zhong, YANG Pei-Xia.Preparation of an Ionic Liquid Gel Polymer Electrolyte and Its Compatibility with a LiFePO4 Cathode[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1233-1238
67. WANG Wei, LV Rong, YU An-Chi.Low Frequency Spectrumof Ionic Liquid [bmim][PF6] Studied by Femtosecond Optically Heterodyne-Detected Optical Kerr Effect Spectroscopy and Low Frequency Raman Spectroscopy[J]. Acta Phys. -Chim. Sin., 2010,26(04): 964-970
68. YUAN Li-Yong, PENG Jing, LI Jiu-Qiang, ZHAI Mao-Lin.Radiation-Induced Changes of Phase Behavior and Fluorescence Properties of the Ionic Liquids [C4mim][PF6] and [C4mim][NTf2][J]. Acta Phys. -Chim. Sin., 2010,26(04): 981-987
69. YUAN Xiao, LOU Shu-Jie, KOU Yuan.Ionic Liquid and Water: Making Nanoparticle Catalysis More Efficient and Greener[J]. Acta Phys. -Chim. Sin., 2010,26(04): 908-914
70. WANG Yong-Xia, DUAN Xue-Mei, Wang Qin, LIU Jing-Yao.Direct Ab initio Dynamics on the Reaction o fMethanethiol and Hydrogen Atom[J]. Acta Phys. -Chim. Sin., 2010,26(01): 183-187
71. WANG Wei-Bin, YIN Jian-Zhong, SUN Li-Hua, FENG En-Min.Molecular Dynamics Simulation of Thermodynamic Properties for CO2/Ionic Liquid Systems[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2291-2295
72. WU Yang, ZHANG Tian-Tian, YU Ning.Interaction between 1-Ethyl-3-Methyl-Imidazolium Cation and Asparagine Anion[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1689-1696
73. ZHAI Cui-Ping, LIU Xue-Jun, ZHAO Yang, WANG Jian-Ji.NMR Study on the Aggregation of [C4mim][BF4] in D2O and CDCl3[J]. Acta Phys. -Chim. Sin., 2009,25(06): 1185-1189
74. YAN Chao-Qun, WAN Hui, GUAN Guo-Feng.Prediction of Melting Points for 1,3-Disubstituent Imidazolium Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2198-2202
75. WANG Xiao-Lu; WAN Hui; GUAN Guo-Feng.Structure and Interaction of Ion-Pairs of [EPy]Cl and [EPy]Br in Gas and Liquid Phases[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2077-2082
76. YANG Pei-Xia; AN Mao-Zhong; SU Cai-Na; WANG Fu-Ping.Electrodeposition Behaviors of Pure Cobalt in Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2032-2036
77. ZHENG Yong-Jun; ELI Wumanjiang.Phase Behavior of Tween80/BmimPF6/Alcohol/Toluene Systems[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2143-2148
78. ZHANG Xu-Zhi; JIAO Kui.Single-Walled Carbon Nanotubes and RoomTemperature Ionic Liquid Composite Film Modified Electrode[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1439-1444
79. GAO Li-Xia; WANG Li-Na; QI Tao; LI Yu-Ping; CHU Jing-Long; QU Jing-Kui.Electrodeposition of Aluminium from AlCl3/Et3NHCl Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2008,24(06): 939-944
80. LI Wei; RONG Hua; WU Xin-Min; CHEN Zhong-Yuan.Microwave Synthesis, Characterization and Theoretical Study of para-Toluenesulfonic Acid Threonine Salt and Its Ester Derivatives[J]. Acta Phys. -Chim. Sin., 2008,24(05): 868-872
81. SUN Guo-Hua; LI Kai-Xi; FAN Hui; GU Jian-Yu; LI Qiang; LIU Yue.Eelectrochemical Performance of Capacitors Using [BMIm]BF4/Fc as Electrolyte[J]. Acta Phys. -Chim. Sin., 2008,24(01): 103-108
82. MA Chun-An; WANG Xiao-Juan; LI Guo-Hua; LI Mei-Chao; CHEN Song.Electroreduction Characteristics of Nitromethane in Ionic Liquid BMImBF4[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1719-1722
83. LEI Sheng; ZHANG Jing; HUANG Jian-Bin.Promotion of the Surface Activity and Aggregation Ability of Sodium Dodecylsulfate in Aqueous Solution by Ionic Liquid 1-butyl-3-methyl-imidazolium Tetrafluoroborate[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1657-1661
84. WANG Jin-Bo; MING Fang-Yong; JIANG Wei-Dong; FAN Guang-Yin; LIU De-Rong; CHEN Hua; LI Xian-Jun.Asymmetric Hydrogenation of Acetophenone and Its Derivatives Catalyzed by Ruthenium Nanoparticles in Ionic Liquid Media[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1381-1386
85. SUN Wei; GAO Rui-Fang; WANG Dan-Dan; JIAO Kui.Direct Electrochemistry of Hemoglobin at Room Temperature Ionic Liquid [BMIM]PF6 Modified Carbon Paste Electrode[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1247-1251
86. YAN Zhi-Ying; WU Li-Yan; SUN Gui-Xiang; ZHANG Ning; ZHENG Wen-Jun.Structural Characterization of Nanocrystalline TiO2 fromIonic Liquid-Water Solvent Mixture and Its Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1032-1036
87. LI Shu; LIU Lei; CAO Zhen; WANG Ji-Qiang; YAN Tian-Ying.Molecular Dynamics Simulation on a Eutectic Systemof LiTFSI/Urea[J]. Acta Phys. -Chim. Sin., 2007,23(07): 983-986
88. MA Chun-An; CHEN Song; CHU You-Qun; MAO Xin-Biao.Electrochemical Reduction of Nitrobenzene in Ionic Liquid BMimBF4-H2O[J]. Acta Phys. -Chim. Sin., 2007,23(04): 575-580
89. LIU Le-Yan;GENG Zhi-Yuan;ZHAO Cun-Yuan;WANG Yong-Cheng;LI Zhao-Hui .Gas-phase Reaction Mechanism of Allyl anion with N2O[J]. Acta Phys. -Chim. Sin., 2007,23(02): 217-222
90. LIN Qi;FU Hai-Yan;YUAN Mao-Lin;CHEN Hua;LI Xian-Jun.Carbonylation of Aryl Halide Catalyzed by Active-carbon Supported Ionic Liquid-phase Palladium Catalyst[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1272-1276
91. LI Xue-Hui;JIANG Yan-Bin;ZHANG Lei;LI Rong.Synthesis and Characterization of N-ester Appended Pyridine Task-specific Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2006,22(06): 747-751
92. Ding Yun-Sheng;Wang Seng-Shan;Zha Min;Wang Zhi-Gang.Adsorption and Aggregative Structures of an Organic Cation [C18mim] of the Ionic Liquid in the Interlayer of Montmorillonite[J]. Acta Phys. -Chim. Sin., 2006,22(05): 548-551
93. LIN Qi;FU Hai-Yan;XUE Fang;YUAN Mao-Lin;CHEN Hua;LI Xian-Jun.Hydroformylation of Long-chain Olefins Catalyzed by Rhodium-Phosphine Complexes in New Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2006,22(04): 465-469
94. ZHAI Cui-Ping;WANG Jian-Ji;XUAN Xiao-Peng;WANG Han-Qing.NMR Study on the Interactions of Ionic Liquid with Acetone[J]. Acta Phys. -Chim. Sin., 2006,22(04): 456-459
95. LI Xue-Hui;ZHANG Lei;WANG Le-Fu;TANG Ying-Biao.Characterization of N-carboxyl Appended Pyridine Task-Specific Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2006,22(04): 430-435
96. GENG Wei-guo; LI Xue-hui; WANG Le-fu; DUAN Hong-li; PAN Wei-ping.Acidic Characterization of Polycarboxyl Imidazolium Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2006,22(02): 230-233
97. TONG Jing; ZHANG Qing-guo; HONG Mei; YANG Jia-zhen.Thermodynamic Properties of Ionic Liquid BMIAlCl4[J]. Acta Phys. -Chim. Sin., 2006,22(01): 71-75
98. WU Xiao-ping; LIU Zhi-ping; WANG Wen-chuan.Molecular Dynamics Simulation of Gas Solubility in Room Temperature Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1138-1142
99. WU Xiao-ping; LIU Zhi-ping.Computer Simulation Study of the Mixtures of Room Temperature Ionic Liquid [bmim][BF4] and Water[J]. Acta Phys. -Chim. Sin., 2005,21(09): 1036-1041
100. CAO Jie-ming; WANG Jun; FANG Bao-qing; ZHENG Ming-bo; LU Hong-xia; CHANG Xin; WANG Hai-yan.Synthesis and Characterization of ZnO Nanomaterials with Different Morphologies in Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2005,21(06): 668-672
101. PAN Xu; DAI Song-yuan; WANG Kong-jia; SHI Cheng-wu; GUO Li.Development and Application of Electrolyte based on Ionic Liquid in Dye-sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2005,21(06): 697-702
102. WANG Yong; LI Hao-Ran; WU Tao; WANG Cong-Min; HAN Shi-Jun.Reaction Mechanism Study for the Synthesis of Alkylimidazolium-based Halide Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2005,21(05): 517-522
103. WANG Xiao-Hua; TAO Guo-Hong; WU Xiao-Mu; KOU Yuan.Investigation of the Acidity of Ionic Liquids by IR Spectroscopy[J]. Acta Phys. -Chim. Sin., 2005,21(05): 528-533
104. PU Min; CHEN Biao-Hua; LI Hui-Ying; LIU Kun-Hui.DFT Studies on Reaction Mechanism of the Double Bond Isomerization of Butene Catalyzed by 1-ethyl-3-methyl-imidazolium of the Ionic Liquid (II)[J]. Acta Phys. -Chim. Sin., 2005,21(04): 383-387
105. Zhang Zhi-Heng; Guan Wei; Yang Jia-Zhen; Tan Zhi-Cheng; Sun Li-Xian.The Standard Molar Enthalpy of Formation of Room Temperature Ionic Liquid EMIES[J]. Acta Phys. -Chim. Sin., 2004,20(12): 1469-1471
106. Li Xue-Hui; Zhang Lei; Li Qiong; Geng Wei-Guo; Ye Yu-Jia; Wang Le-Fu.TGA-FTIR Study of 1-n-butyl-3-methylimidazolium Bromide Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2004,20(12): 1465-1468
107. Piao Ling-Yu;Han Yang;Kou Yuan.The Reuse of Acidic Ionic Liquids as Catalysts in Diphenyl Oxide Alkylation with Dodecene[J]. Acta Phys. -Chim. Sin., 2004,20(09): 1083-1088
108. Pu Min;Liu Kun-Hui;Li Hui-Ying;Chen Biao-Hua.DFT Studies on Reaction Mechanism of the Double Bond Isomerization of Butene Catalyzed by 1-ethyl-3-methyl-lmidazolium of the Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2004,20(08): 826-830
109. Zhang Sheng-Mao;Zhang Chun-Li;Zhang Jing-Wei;Zhang Zhi-Jun;Dang Hong-Xin;Wu Zhi-Shen;Liu Wei-Min.Preparation of Silver Nanoparticles in Room Temperature Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2004,20(05): 554-556
110. Ji Yong-Qiang;Feng Wen-Lin;Hao Mao-Rong;Li Hui-Ying.The Reaction Path and Varitional Rate Constant of the Reaction CH3+CH3NO2→CH4+CH2NO2[J]. Acta Phys. -Chim. Sin., 2002,18(08): 721-726
111. Li Hui-Ying;Feng Wen-Lin;Ji Yong-Qiang;Xu Zhen-Feng;Lei Ming.The Reaction Path and Variational Rate Constant of the Hydrogen Abstraction Reaction CH2O+O[3P]→CHO+OH[J]. Acta Phys. -Chim. Sin., 2002,18(05): 446-450
112. Liu Wen-Bin,Wu Yan-Ping,Wang Jian-Ji,Lu Jin-Suo.Viscosity of NaCl and KCl in Aqueous Sucrose Solutions[J]. Acta Phys. -Chim. Sin., 1995,11(07): 590-595
113. Feng Ke; Zeng Zhao-Hua; Li Zhuo-Mei.Study on Sulfonated EPDM Ionomers Containing Various Ions[J]. Acta Phys. -Chim. Sin., 1992,8(03): 370-375
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388
^ Top