Register
ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(2)>> 370-376     doi: 10.3866/PKU.WHXB201610311         中文摘要
Phosphomolybdic Acid as a Mediator for Indirect Carbon Electrooxidation in LowTemperature Carbon Fuel Cell
YIN Jin-Ling, LIU Jia, WEN Qing, WANG Gui-Ling, CAO Dian-Xue
Key Laboratory of Superlight Material and Surface Technology of Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, P. R. China
Full text: PDF (970KB) HTML Export: BibTeX | EndNote (RIS)

Phosphomolybdic acid was investigated as a mediator for indirect carbon electrooxidation at low temperatures. Linear sweeping voltammetry and chronoamperometry experiments showed that the carbon electrooxidation process was influenced by the type of carbonaceous material, reaction conditions, reaction time, and phosphomolybdic acid concentration. The mechanism underlying indirect carbon electrooxidation was explored using cyclic voltammetry. The results showed that the reactivity of coconut-derived activated carbon was higher than that of coal-derived activated carbon or coal in the chemical reaction between phosphomolybdic acid and carbon materials. Sunlight and heating to 80℃ similarly improved the efficiency of the indirect carbon electrooxidation. The electrooxidation mechanism is as follows:MoVI in phosphomolybdic oxidizes carbon to form MoV, and is then electrooxidized back to MoVI in an anodic reaction, releasing the electron obtained from the carbon material. This process facilitated the indirect electrooxidation of carbon at low temperatures. Sunlight was found to enhance the rate of the chemical reaction between phosphomolybdic acid and carbon materials in two ways:1) thermally by increasing the reaction temperature and thus improving the reaction rate; 2) photocatalytically, as sunlight absorbed by phosphomolybdic acid is converted into chemical energy, which is the main effect. A full cell test with phosphomolybdic acid demonstrated a power density of 0.087 mW·cm-2 at room temperature, indicating that the concept of low-temperature carbon fuel cells is feasible.



Keywords: Low-temperature carbon fuel cell   Indirect electrooxidation   Phosphomolybdic acid   Activated carbon   Sunlight irradiation  
Received: 2016-09-07 Accepted: 2016-10-31 Publication Date (Web): 2016-10-31
Corresponding Authors: CAO Dian-Xue Email: caodianxue@hrbeu.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (21306033, 21476053).

Cite this article: YIN Jin-Ling, LIU Jia, WEN Qing, WANG Gui-Ling, CAO Dian-Xue. Phosphomolybdic Acid as a Mediator for Indirect Carbon Electrooxidation in LowTemperature Carbon Fuel Cell[J]. Acta Phys. -Chim. Sin., 2017,33 (2): 370-376.    doi: 10.3866/PKU.WHXB201610311

(1) Cao, D. X.; Sun, Y.; Wang, G. L. J. Power Sources 2007, 167, 250. doi: 10.1016/j.jpowsour.2007.02.034
(2) Kacprzak, A.; Kobylecki, R.; Bis, Z. J. Power Sources 2013, 239, 409. doi: 10.1016/j.jpowsour.2013.03.159
(3) Kacprzak, A.; Koby?ecki, R.; W?odarczyk, R.; Bis, Z. J. Power Sources 2014, 255, 179. doi: 10.1016/j.jpowsour.2014.01.012
(4) Wang, C. Q.; Liu, J.; Zeng, J.; Yin, J. L.; Wang, G. L.; Cao, D.X. J. Power Sources 2013, 233, 244. doi: 10.1016/j.jpowsour.2013.01.016
(5) Liu, J.; Ye, K.; Zeng, J.; Wang, G. L.; Yin, J. L.; Cao, D. X. Electrochem. Commun. 2014, 38, 12. doi: 10.1016/j.elecom.2013.10.031
(6) Rady, A. C.; Gibbdey, S.; Kulkarni, A.; Badwal, S. P. S.; Bhattacharya, S.; Ladewig, B. P. Appl. Energy 2014, 120, 56. doi: 10.1016/j.apenergy.2014.01.046
(7) Kularni, A.; Giddey, S.; Badwal, S. P. S.; Paul, G. Electrochim. Acta 2014, 121, 34. doi: 10.1016/j.electacta.2013.12.110
(8) Xu, X. Y.; Zhou, W.; Liang, F. L.; Zhu, Z. H. Appl. Energy 2013, 108, 402. doi: 10.1016/j.apenergy.2013.03.053
(9) Elleuch, A.; Yu, J. S.; Boussetta, A.; Halouani, K.; Li, Y. D. Int. J. Hydrog. Energy 2013, 38, 8514. doi: 10.1016/j.ijhydene.2012.11.070
(10) Weibel, D. B.; Boulatov, R.; Lee, A.; Ferrigno, R.; Whitesides, G. M. Angew. Chem. Int. Ed. 2005, 44, 5682. doi: 10.1002/anie.200501192
(11) Paraknowitsch, J. P.; Thomas, A.; Antonietti, M. Chem. Mater. 2009, 21, 1170. doi: 10.1021/cm801586c
(12) Kozhevnikov, I. V. Chem. Rev. 1998, 98, 171. doi: 10.1021/cr960400y
(13) Subba Reddy, B. V.; Narasimhulu, G.; Subba Lakshumma, P.; Vikram Reddy, Y.; Yadav, J. S. Tetrahedron Lett. 2012, 53 (14), 1776. doi: 10.1016/j.tetlet.2012.01.115
(14) Yadav, J. S.; Satyanarayana, M.; Balanarsaiah, E.; Raghavendra, S. Tetrahedron Lett. 2006, 47 (34), 6095. doi: 10.1016/j.tetlet.2006.06.084
(15) Wang, B.; Zhang, J.; Zou, X.; Dong, H. G.; Yao, P. P. Chem. Eng. J. 2015, 260, 172. doi: 10.1016/j.cej.2014.08.076
(16) Song, X. J.; Zhu, W. C.; Yan, Y.; Gao, H. C.; Gao, W. X.; Zhang, W. X.; Jia, M. J. J. Mol. Catal. A: Chem. 2016, 413, 32. doi: 10.1016/j.molcata.2015.12.012
(17) Kendell, S. M.; Brown, T. C.; Burns, R. C. Catal. Today 2008, 131 (1-4), 526. doi: 10.1016/j.cattod.2007.10.027
(18) Gao, Y. Z.; Syed, J. A.; Lu, H. B.; Meng, X. K. Appl. Surf. Sci. A 2016, 360, 389. doi: 0.1016/j.apsusc.2015.11.029
(19) Martínez-Morlanes, M. J.; Martos, A. M.; Várez, A.; Levenfeld, B. J. Membr. Sci. 2015, 492, 371. doi: 10.1016/j.memsci.2015.05.031
(20) Gómez-Romero, P.; Asensio, J. A.; Borrós, S. Electrochim. Acta 2005, 50 (24), 4715. doi: 10.1016/j.electacta.2005.02.029
(21) Sauk, J.; Byun, J.; Kim, H. J. Power Sources 2005, 143 (1-2), 136. doi: 10.1016/j.jpowsour.2004.11.030
(22) Guo, X.; Guo, D. J.; Wang, J. S.; Qiu, X. P.; Chen, L. Q.; Zhu, W. T. J. Electroanal. Chem. 2010, 638 (1), 167. doi: 10.1016/j.jelechem.2009.09.001
(23) Zhu, M. Y.; Gao, X. L.; Luo, G. Q.; Dai, B. J. Power Sources 2013, 225, 27. doi: 10.1016/j.jpowsour.2012.10.023
(24) Jin, X. L.; He, B.; Miao, J. G.; Yuan, J. H.; Zhang, Q. X.; Niu, L. Carbon 2012, 50 (8), 3083. doi: 10.1016/j.carbon.2012.03.004
(25) Dong, Q.; Wang, X. Y.; Lu, Y. M.; Sun, H. Y.; Meng, Q. L.; Liu, S. L.; Feng, W.; Han, X. K. J. Mol. Struct. 2014, 1075, 154. doi: 10.1016/j.molstruc.2014.07.003
(26) He, T.; Yao, J. Progress in Materials Science 2006, 51, 810. doi: 10.1016/j.pmatsci.2005.12.001
(27) Liu, W.; Mu, W.; Liu, M.; Zhang, X.; Cai, H.; Deng, Y. Nat. Commun. 2014, 5, 3208. doi: 10.1038/ncomms4208
(28) Yamase, T. Chem. Rev. 1998, 98, 307. doi: 10.1021/cr9604043
(29) Pham, M. C.; Bouallala, S.; Lé, L. A.; Dang, V. M.; Lacaze, P.C. Electrochim. Acta 1997, 42 (3), 439. doi: 10.1016/S0013-4686(96)00239-3
(30) Sun, C. Q.; Zhang, J. D. Electrochim. Acta 1998, 43 (8), 943. doi: 10.1016/S0013-4686(97)00215-6
(31) Wang, Y. Q. Study of Methanol Oxidation on Pt-Au Electrode Enhanced by Phosphomolybdic Acid. M. S. Dissertation, Chongqing University, Chongqing, 2007. [王耀琼. Pt-Au电极上磷钼酸增强甲醇电化学氧化的研究[D]. 重庆: 重庆大学, 2007.]
(32) Zhang, H. B.; Wu, T. H.; Yan, X. B.; Leng, Y. C.; Li, S. J. Chem. J. Chin. Univ. 1990, 11 (10), 1096. [张恒彬, 吴通好, 阎晓斌, 冷玉春, 李树家. 高等学校化学学报, 1990, 11 (10), 1096.]
(33) Jing, S. B.; Zhang, H. B.; Zhu, W. C.; Wang, Z. L.; Wang, G. J. J. Jilin Univ.(Science Edition) 2003, 41 (4), 534. [井淑波, 张恒彬, 朱万春, 王振旅, 王国甲. 吉林大学学报(理学版), 2003, 41(4), 534.] doi: 10.13413/j.cnki.jdxblxb.2003.04.026
(34) Unoura, K.; Tanaka, N. Inorg. Chem. 1983, 22, 2963. doi: 10.1021/ic00162a042

1. Lü Qian-Rui, LI Jing, LIAN Zhi-Peng, ZHAO Hao-Yan, DONG Gui-Fang, LI Qiang, WANG Li-Duo, YAN Qing-Feng.CH3NH3PbI3 Single Crystal-Based Ambipolar Field-Effect Transistor with Ta2O5 as the Top Gate Dielectric[J]. Acta Phys. -Chim. Sin., 2017,33(1): 249-254
2. CAO Hong-Yu, GAO Ling-Xing, TANG Qian, SU Jin-Hong, ZHENG Xue-Fang.Mechanism of Oxymyoglobin Oxidation Reaction Induced by Ultraviolet Light[J]. Acta Phys. -Chim. Sin., 2016,32(4): 872-878
3. WANG Yong-Fang, ZUO Song-Lin.Electrochemical Properties of Phosphorus-Containing Activated Carbon Electrodes on Electrical Double-Layer Capacitors[J]. Acta Phys. -Chim. Sin., 2016,32(2): 481-492
4. TONG Li, XU Wen-Qing, QI Hao, ZHOU Xuan, LIU Rui-Hui, ZHU Ting-Yu.Enhanced Effect of O/N Groups on the Hg0 Removal Efficiency over the HNO3-Modified Activated Carbon[J]. Acta Phys. -Chim. Sin., 2015,31(3): 512-518
5. YANG Jie-Yang, HUANG Zhang-Gen, HAN Xiao-Jin, JING Wen, ZENG Ze-Quan.Effect of Activated Carbon Pore Structure on the Adsorption of Pb(II) from Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2015,31(10): 1956-1962
6. XIAO Bo, LIU Shou-Qing.Photocatalytic Oxidation of Ammonia via an Activated Carbon-Nickel Ferrite Hybrid Catalyst under Visible Light Irradiation[J]. Acta Phys. -Chim. Sin., 2014,30(9): 1697-1705
7. SUN Xian-Zhong, HUANG Bo, ZHANG Xiong, ZHANG Da-Cheng, ZHANG Hai-Tao, MA Yan-Wei.Experimental Investigation of Electrochemical Impedance Spectroscopy of Electrical Double Layer Capacitor[J]. Acta Phys. -Chim. Sin., 2014,30(11): 2071-2076
8. HUANG Bo, SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei.Organic Electrolytes for Activated Carbon-Based Supercapacitors with Flexible Package[J]. Acta Phys. -Chim. Sin., 2013,29(09): 1998-2004
9. TANG Zi-Long, LI Dong-Mei, CHENG Jing-Wei, JIANG Jie-Ru.Preparation and Fluorescence Properties of Aqueous Soluble Thiourea Modified ZnSe:Cu Quantum Dots[J]. Acta Phys. -Chim. Sin., 2013,29(03): 653-659
10. JIN Wei-Yang, CHENG Dang-Guo, CHEN Feng-Qiu, ZHAN Xiao-Li.Synthesis of MFI-Type Zeolite Membrane Encapsulated Activated Carbon Particles Using a Modified Seeded Method[J]. Acta Phys. -Chim. Sin., 2013,29(01): 139-143
11. ZhONG Hao-Xiang, ZHAO Chun-Bao, LUO Hao, ZHANG Ling-Zhi.Novel Organosilicon Ionic Liquid Based Electrolytes for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2641-2647
12. LIN Xue, Lü Peng, GUAN Qing-Feng, LI Hai-Bo, LI Hong-Ji, CAI Jie, ZOU Yang.Visible Light Photocatalytic Properties of Bi3.25La0.75Ti3O12 Nanowires[J]. Acta Phys. -Chim. Sin., 2012,28(08): 1978-1984
13. PING Li-Na, ZHENG Jia-Ming, SHI Zhi-Qiang, WANG Cheng-Yang.Electrochemical Performance of Lithium Ion Capacitors Using Li+-Intercalated Mesocarbon Microbeads as the Negative Electrode[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1733-1738
14. LIN Xue, GUAN Qing-Feng, LI Hai-Bo, LI Hong-Ji, BA Chun-Hua, DENG Hai-De.Bi3.25Nd0.75Ti3O12 Nanostructures: Controllable Synthesis and Visible-Light Photocatalytic Activities[J]. Acta Phys. -Chim. Sin., 2012,28(06): 1481-1488
15. TANG Jing, ZENG Qiao, CHEN Zhen-Dong, HUANG Xiang-Qian.Electrochemical Indirect Measurement for the Study of Glutathione Adsorption on Multiwalled Carbon Nanotubes and Activated Carbon[J]. Acta Phys. -Chim. Sin., 2012,28(05): 1269-1274
16. ZHAO Lei, XU Xiang-Sheng, ZHANG Kai-Chao, YAN Xin-Huan.Selective Hydrogenation of Cinnamaldehyde with Efficient Assembled Pt-Fe/C Catalysts[J]. Acta Phys. -Chim. Sin., 2012,28(04): 923-927
17. SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei.Activated Carbon-Based Supercapacitors Using Li2SO4 Aqueous Electrolyte[J]. Acta Phys. -Chim. Sin., 2012,28(02): 367-372
18. XU San-Kui, LI Li-Min, GUO Nan-Nan, SU Yun-Lai, ZHANGPeng.Hydrogenation of Glucose Using Ru/Activated Carbon Catalysts: Effects of Modification Methods on Surface Properties of Activated Carbon[J]. Acta Phys. -Chim. Sin., 2012,28(01): 177-183
19. ZHANG Xiao-Yan, SUN Ming-Xuan, SUN Yu-Jun, LI Jing, SONG Peng, SUN Tong, CUI Xiao-Li.Photoelectrochemical Properties of Graphene Oxide Thin Film Electrodes[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2831-2835
20. LU Sheng-Yong, HUANG Yi-Long, WANG Qiu-Lin, LI Xiao-Dong, YAN Jian-Hua.Photocatalytic Degradation of Gaseous 1,2-Dichlorobenzene over TiO2/AC Photocatalysts[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2191-2199
21. CAO Guo-Fei, LIAO Yi, ZHANG Xiao-Hua, CHEN Jin-Hua.Preparation and Characterization of Peasecod-Based Activated Carbons as Electrode Materials for Electrochemical Double-Layer Capacitors[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1679-1684
22. ZHAN Wang-Cheng, ZHOU Guo-Jun, CHU Guo-Hai, SHEN Kai, YU Jun, WANG Ai-Yong, SU Na, LU Guan-Zhong, GUO Yang-Long.Effect of Supports on the Catalytic Performance of Pd-Cu/Activated Carbon Catalyst for Eliminating CO in Cigarette Smoke[J]. Acta Phys. -Chim. Sin., 2011,27(03): 705-710
23. TIAN Ying, YAN Jing-Wang, XUE Rong, YI Bao-Lian.Influence of Electrolyte Concentration and Temperature on the Capacitance of Activated Carbon[J]. Acta Phys. -Chim. Sin., 2011,27(02): 479-485
24. TIAN Ying, YAN Jing-Wang, LIU Xiao-Xue, XUE Rong, YI Bao-Lian.Electrochemical Capacitance of Composites with MnOx Loaded on the Surface of Activated Carbon Electrodes[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2151-2157
25. DING Liang-Xin, WANG Shi-Rui, ZHENG Xiao-Long, CHEN Yu, LU Tian-Hong, CAO Dian-Xue, TANG Ya-Wen.Effect of Carbon Modification on Electrocatalytic Performance of Carbon Supported Pd Catalysts[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1311-1316
26. ZHANG Tian-Yong, YANG Qiu-Sheng, SHI Hui-Xian, HAN Cong, LIU Xu.Adsorption of Naphthalene on a Viscose-Based Activated Carbon Fiber[J]. Acta Phys. -Chim. Sin., 2010,26(02): 367-372
27. XU Xin, WANG Xiao-Jing, HU Zhong-Hua, LIU Ya-Fei, WANG Chen-Chen, ZHAO Guo-Hua.Influence of Sol-Gel and Dip-Hydrothermal Preparation Methods on Structure and Performance of TiO2/AC Photocatalysts[J]. Acta Phys. -Chim. Sin., 2010,26(01): 79-86
28. JIANG Qi, ZHAO Xiao-Feng, HUANG Bin, DU Bing, ZHAO Yong.Effect of the Activated Carbon Reactivation on Its Electrochemical Capacitance[J]. Acta Phys. -Chim. Sin., 2009,25(04): 757-761
29. GAO Qiang; LIU Ya-Fei; HU Zhong-Hua; ZHENG Xiang-Wei; WEN Zu-Biao.Electrochemical Properties of Manganese Oxide Surface-Modified Activated Carbon Electrode Materials[J]. Acta Phys. -Chim. Sin., 2009,25(02): 229-236
30. CHEN Yu-Juan; HU Zhong-Hua; WANG Xiao-Jing; ZHAO Guo-Hua; LIU Ya-Fei; LIU Wei.Influence of Pore Size and Surface Area of Activated Carbon on the Performance of TiO2/AC Photocatalyst[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1589-1596
31. LIU Ya-Fei; HU Zhong-Hua; XU Kun; ZHENG Xiang-Wei; GAO Qiang.Surface Modification and Performance of Activated Carbon Electrode Material[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1143-1148
32. GUO Liang; WU Zhan-Song.Mechanism of Methane’s Adsorption on Nanometer Active Carbon at Supercritical State[J]. Acta Phys. -Chim. Sin., 2008,24(05): 737-742
33. LIU Shou-Xin; CHEN Xiao-Yun.Effect of Pore Structure of Activated Carbon on the Photocatalytic Activity of TiO2/AC Composite Photocatalyst[J]. Acta Phys. -Chim. Sin., 2008,24(03): 533-538
34. YANG Jing; LIU Ya-Fei; CHEN Xiao-Mei; HU Zhong-Hua; ZHAO Guo-Hua.Carbon Electrode Material with High Densities of Energy and Power[J]. Acta Phys. -Chim. Sin., 2008,24(01): 13-19
35. LI Jing-Yi; MA Jun-Hua; BAI Tu-Ya; SUYOU Le-Ma.Effect of Fluoride Ion on the Photocatalytic Degradation of Sulforhodamine B on TiO2/Bentonite[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1213-1218
36. QIU Kai-Dong;LI Wei-Bin.Adsorption of Hexavalent Chromium Ions on Multi-wall Carbon Nanotubes in Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1542-1546
37. CHEN Xiao-Yun;LIU Shou-Xin;CHEN Xi;SUN Cheng-Lin.Characterization and Activity of TiO2 /wAC Composite Photocatalyst Prepared by Acid Catalyzed Hydrolysis Method[J]. Acta Phys. -Chim. Sin., 2006,22(05): 517-522
38. LIU Chun-ling; WEN Yue-hua; CHENG Jie; GUO Quan-gui; CAO Gao-ping; LIU Lang; YANG Yu-sheng.Influence of Pore Structure of Phenolic Resin Based Activated Carbon Fibers on the Electrochemical Performance of Electrical Double-layer Capacitors[J]. Acta Phys. -Chim. Sin., 2005,21(07): 786-791
39. WANG Xiao-Feng; WANG Da-Zhi; LIANG Ji.Pseudo-capacitance of Ultrafine Nickel Hydroxide Prepared by Sol-gel Method[J]. Acta Phys. -Chim. Sin., 2005,21(02): 117-122
40. Zhuang Xin-Guo;Yang Yu-Sheng;Ji You-Ju;Yang Dong-Ping;Tang Zhi-Yuan.The Influence of Porous Structure of Activated Carbons Used as Supercapacitor Electrode Materials on Its Properties[J]. Acta Phys. -Chim. Sin., 2003,19(08): 689-694
41. Xing Wei;Zhang Ming-Jie;Yan Zi-Feng.Synthesis and Activation Mechanism of Coke Based Super Activated Carbons[J]. Acta Phys. -Chim. Sin., 2002,18(04): 340-345
42. Liang Kui;Chen Ai;Feng Zhe-Sheng;Ye Zhi-Xiang.AC Impedance Analysis of Supercapacitors Utilizing Carbon Nanotube Electrodes[J]. Acta Phys. -Chim. Sin., 2002,18(04): 381-384
43. Liu Zhen-Yu;Zheng Jing-Tang;Wang Mao-Zhang;Zhang Bi-Jiang.Study for Nitrogen Adsorption of PAN-based Activated Carbon Fibers[J]. Acta Phys. -Chim. Sin., 2001,17(07): 594-599
44. Lu An-Hui;Li Wen-Cui;Zheng Jing-Tang.Preparation of PANbased Molecular Sieve ACF and Study of Surface Structure by XPS[J]. Acta Phys. -Chim. Sin., 2001,17(03): 216-221
45. Zhang Hui-Yuan, Wang Shu-Lan, Wang Rong-Shu, Lin Can-Sheng, Zhang Xian-Ye, Wang Xiao-Rong.New Ecomaterial Zireonyl Molybopyrophosphate for Cesium Removal from HLLW[J]. Acta Phys. -Chim. Sin., 2000,16(10): 952-955
46. Miao Rui-Ping,Dai Min-Ping.Study of Activatied Carbon on the Adsorption of Titan Yellow from Aqueous Solution[J]. Acta Phys. -Chim. Sin., 1996,12(02): 173-176
47. Wang Xin-Ping,Ye Xing-Kai,Wu Yue.Chemical Bonding between Heteropoly Acid and Oxygen-containing Groups on the Surface of Activated Carbon[J]. Acta Phys. -Chim. Sin., 1995,11(12): 1105-1109
48. Mu Guan-Nan, Yang Chun-Fen.Adsorption of Zinc(II) Ion and its Complexes from Solution by Activatied Charcoal[J]. Acta Phys. -Chim. Sin., 1995,11(02): 157-161
49. Wang Xin-Ping, Ye Xing-Kai, Wu Yue.A Study of the Heterogenization of Heteropoly Acid(II)[J]. Acta Phys. -Chim. Sin., 1994,10(04): 303-307
50. Jin Wen, Dong Shao-Jun.Characterization of 1:12 Phosphomolybdic Anions Doped Polypyrrole (PMo12/PPy) Film Electrode[J]. Acta Phys. -Chim. Sin., 1994,10(02): 183-187
51. Xue Yi; Du You-Ru; Ye Zhao-Hui; Kong Yu-Hua.The NMR Study of the Solid and Liquid Like Phases of Dioxane Adsorbed on Charcoals[J]. Acta Phys. -Chim. Sin., 1992,8(01): 113-116
52. ZHAO Li-Ping, MENG Wei-Shuai, WANG Hong-Yu, QI Li.MoS2-C Composite as Negative Electrode Materials for Sodium-Ion Supercapattery[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388 Email:whxb@pku.edu.cn
^ Top