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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(2)>> 344-355     doi: 10.3866/PKU.WHXB201611023         中文摘要
Structure and Kinetics of Thermal Decomposition Mechanism of Novel Silk Fibroin Films
YU Hai-Yang1,2, WANG Fang1, LIU Qi-Chun1,2, MA Qing-Yu3, GU Zheng-Gui2
1 Center of Analysis and Testing, Nanjing Normal University, Nanjing 210023, P. R. China;
2 School of Chemistry and Materials Science, Nanjing Normal University Jiangsu, Nanjing 210023, P. R. China;
3 School of Physics and Technology, Nanjing Normal University, Nanjing 210023, P. R. China
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A new CaCl2-formic acid dissolution method was used to prepare silk fibroin (SF) films. Films SF-1.5 and SF-3.0 were prepared using 1.50% (w, mass fraction) and 3.00% (w) CaCl2-formic acid solutions, respectively. The molecular conformations and crystal structures of the films were characterized by Fourier transform infrared spectroscopy and X-ray diffraction. The thermal stability, thermal decomposition properties, and effect of CaCl2 concentration on the thermodynamic parameters, kinetic parameters, and formation mechanism of the SF films were investigated using thermogravimetry techniques and the models of Kissinger, Ozawa, and Vyazovkin. The results showed that the SF-1.5 film mainly contained β-sheet structure, while the main molecular conformation in the SF-3.0 film was random coils. The decomposition temperature, activation energy, and activation enthalpy of SF-3.0 were lower than those of SF-1.5, while the thermal stability of SF-1.5 was higher than that of SF-3.0. In addition, the thermal decomposition of the SF films was studied by the Achar and Coats-Redfern methods. The mechanism of decomposition of these SF films followed the two-dimensional diffusion (cylindrical symmetry) law in the temperature range of 190.00-330.00℃.



Keywords: Silk fibroin   Thermal decomposition mechanism   Thermodynamics   Thermogravimetry   Fourier transform infrared spectroscopy  
Received: 2016-10-10 Accepted: 2016-11-02 Publication Date (Web): 2016-11-02
Corresponding Authors: WANG Fang, GU Zheng-Gui Email: wangfang@njnu.edu.cn;07160@njnu.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (11474166) and the College of Natural Science Foundation of Jiangsu Province, China (15KJB150018).

Cite this article: YU Hai-Yang, WANG Fang, LIU Qi-Chun, MA Qing-Yu, GU Zheng-Gui. Structure and Kinetics of Thermal Decomposition Mechanism of Novel Silk Fibroin Films[J]. Acta Phys. -Chim. Sin., 2017,33 (2): 344-355.    doi: 10.3866/PKU.WHXB201611023

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37. LOU Peng-Xiao, WANG Yu-Jie, BAI Guang-Yue, FAN Chao-Ying, Wang Yi-Lin.Direct Evidence for the Energy of Weak Interactions between Surfactant Molecules Using High Sensitivity Isothermal Titration Calorimetry[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1401-1407
38. SHI Lin, YU Tie, WANG Xin-Quan, WANG Jun, SHEN Mei-Qing.Properties and Roles of Adsorbed NH3 and NOx over Cu/SAPO-34 Zeolite Catalyst in NH3-SCR Process[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1550-1557
39. ZHANG Xiao-Tong, YU Wen-Guang, QIN Yu-Cai, DONG Shi-Wei, PEI Ting-Ting, WANG Lin, SONG Li-Juan.Influence of Surface Acidity of Y Zeolites on the Adsorption of Organic Molecules by In situ Fourier Transform Infrared Spectroscopy[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1273-1280
40. CAO Jia, WANG Wen-Liang, GAO Lou-Jun, FU Feng.Mechanism and Thermodynamic Properties of CH3SO3 Decomposition[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1161-1167
41. YE Yong-Wei, WANG Xi, ZHENG Wan-Fang, LI Mei-Chao, MA Chun-An.Electrooxidation Reaction of 3-Bromobenzoic Acid on Pt Electrode[J]. Acta Phys. -Chim. Sin., 2013,29(03): 553-558
42. GE Dong-Lai, FAN Ying-Ju, YIN Long, SUN Zhong-Xi.Determination of the Adsorption of Xanthate on Mesoporous CuAl2O4 Using a Continuous Online In situ ATR-FTIR Technology[J]. Acta Phys. -Chim. Sin., 2013,29(02): 371-376
43. LIU Bei-Ping, TAN Zhi-Cheng.Thermodynamic Properties of Nd(Gly)2Cl3·3H2O and Pr(Ala)3Cl3·3H2O[J]. Acta Phys. -Chim. Sin., 2013,29(01): 17-22
44. ZHOU En-Nian, YU Zhi-Hui, QU Jing-Kui, Qi Tao, Han Xiao-Ying, ZHANG Guo-Qing.Equilibrium Solubility Modeling of CO2 in Na2Cr2O7 Solutions[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2567-2573
45. ZHOU Liang-Chun, MENG Xiang-Guang, LI Jian-Mei, HU Wei, LIU Bo, DU Juan.Kinetics and Thermodynamics of Adsorption of Chlorophenols onto β-Cyclodextrin Modified Chitosan[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1615-1622
46. ZHOU Zhi-You, LIN Jian-Long, SHANG Shu-Jing, REN Jie, SUN Shi-Gang.Preparation of Dendritic Pt Thin Films and Their Anomalous Infrared Effects[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1745-1750
47. PENG Yu-Ling, WANG Shu-Jun, FU Li, ZHANG Cheng-Gen, LIU Xin-Gang.Synthesis of Tailed Porphyrin Modified with Nicotinic Acid and Interactions with Human Serum Albumin[J]. Acta Phys. -Chim. Sin., 2012,28(05): 1054-1062
48. FAN Xiao-Li, LIU Yan, LIU Chong, LAU Woon-Ming.Reaction Pathways of Acetylene Adsorption on the Ge(001) Surface[J]. Acta Phys. -Chim. Sin., 2012,28(05): 1107-1112
49. ZHANG Jie, WANG Juan-Fen, ZHANG Jian-Jun.Synthesis, Characterization and Thermal Decomposition Mechanism of Rare Earth Complexes with 5-Chloro-2-methoxybenzoic Acid and 1,10-Phenanthroline[J]. Acta Phys. -Chim. Sin., 2012,28(02): 290-296
50. ZHU Ying-Hong, ZENG Hong-Yan, LI Shan-Shan, LU Zai-Xiang, MA Chun-An.Electrochemical Oxidation of p-Methoxy Toluene in BMIMBF4 Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2012,28(02): 421-426
51. CAO Zhan-Min, WANG Kun-Peng, QIAO Zhi-Yu, DU Guang-Wei.Thermodynamic Reoptimization of the Fe-P System[J]. Acta Phys. -Chim. Sin., 2012,28(01): 37-43
52. DONG Zhi-Long, DING Wei, LIU Kun, ZHANG Zhi-Wei, QU Guang-Miao, YU Tao.Adsorption Performance of Tetradecyl Aryl Sulfonates on Oil Sand from the Daqing Oilfield[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2767-2772
53. ZHAO Liu-Jie, RAN Jing-Yu, WU Sheng.Thermodynamic Study of the Humidity Ratio for Methane Reforming at Low Temperature in a Micro-Combustor[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2027-2034
54. YU Chao, QIU Ke-Qiang, CHEN Qi-Yuan.Thermodynamic Analysis of Silicothermic Reduction Zinc Oxide in Vacuum[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1312-1318
55. LONG Jin-Xing, GUO Bin, LI Xue-Hui, WANG Fu-Rong, WANG Le-Fu.Catalytic Decomposition of Cellulose in Cooperative Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2011,27(05): 995-999
56. ZHANG Jian-Jun, ZU Hui, GAO Yuan.Formation Thermodynamics of Adefovir Dipivoxil-Saccharin Co-Crystals[J]. Acta Phys. -Chim. Sin., 2011,27(03): 547-552
57. LIU Bo, HUANG Shi-Ping, ZHU Ji-Qin, WANG Peng, TIAN Hui-Ping.Effect of Temperature on the Structural and Thermodynamic Properties of Aqueous Dimethyl Sulfoxide[J]. Acta Phys. -Chim. Sin., 2011,27(02): 289-294
58. AN Ting, ZHAO Feng-Qi, YI Jian-Hua, FAN Xue-Zhong, GAO Hong-Xu, HAO Hai-Xia, WANG Xiao-Hong, HU Rong-Zu, PEI Qing.Preparation, Characterization, Decomposition Mechanism and Non-Isothermal Decomposition Reaction Kinetics of the Super Thermite Al/CuO Precursor[J]. Acta Phys. -Chim. Sin., 2011,27(02): 281-288
59. LU Xue-Bin, GUO Zhao-Hui, HUANG Rong, CHEN Ming-An.Preparation of a (3-Mercaptopropyl)triethoxylsilane Film on Copper and Its Corrosion Protective Performance[J]. Acta Phys. -Chim. Sin., 2011,27(01): 108-112
60. BAI Ming-Ze, CHENG Li, TANG Hong, DOU Yu-Sheng.Molecular Dynamics Simulation of the Laser-Induced Melting of an Al Nanofilm[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3143-3149
61. MENG Gen, KONG De-Jin, QI Xiao-Lan, XU Zhong-Qiang.Carbon Deposition on a Toluene Disproportionation and Transalkylation Catalyst[J]. Acta Phys. -Chim. Sin., 2010,26(11): 3017-3022
62. RAN Jing-Yu, ZHAO Liu-Jie.Thermodynamic Analysis of Low Temperature Methane Wet-Air Reforming in a Microcombustor[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2899-2906
63. XIONG Zhen-Hu, WANG Lu, ZHOU Jian-Guo, LIU Jian-Ming.Thermodynamics and Kinetics of Adsorption of Diclofenac on Magnetic Multiwalled Carbon Nanotubes in an Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2890-2898
64. ZOU Yan, WANG Jia, ZHENG Ying-Ying.Electrochemical Corrosion Behaviors of Rusted Carbon Steel[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2361-2368
65. HU Yan-Fei, JIANG Gang, MENG Da-Qiao, KONG Fan-Jie.Phase Transition and Thermodynamic Properties of TiO2[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1664-1668
66. GUO Li-Qin, SHI Xiu-Li, RUAN Wen-Juan, ZHANG Xiao-Hong, ZHU Zhi-Ang.Synthesis and Characterization of Novel Salen-Type Complexes and Their Axial Coordination Thermodynamics[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1195-1201
67. LI Xue-Liang, CHEN Jie-Jie, LUO Mei, CHEN Xiang-Ying, LI Pei-Pei.Quantum Chemical Calculation of Hydroxyalkyl Ammonium Functionalized Ionic Liquids for Absorbing SO2[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1364-1372
68. YU Tao, LI Zhong, DING Wei, LUO Shi-Qiong, LUAN Huo-Xin, TONG Wei, QU Guang-Miao, LI An-Jun, CHENG Jie-Cheng.Enthalpy-Entropy Compensation of Micellization of Alkyl Aryl Sulfonates in Aqueous Solutions[J]. Acta Phys. -Chim. Sin., 2010,26(03): 638-642
69. YANG Zhi-Bin, ZHANG Yu-Wen, ZHANG Yun-Yan, DING Wei-Zhong, SHEN Pei-Jun, LIU Yong, ZHOU Yu-Ding, HUANG Shao-Qing.Hydrogen Production fromCoke Oven Gas byMethane Reforming: Thermodynamic Analysis and Experimental Study[J]. Acta Phys. -Chim. Sin., 2010,26(02): 350-358
70. LV Ran, GAO Tao, LI Xi-Bo, LUO Jiang-Shan, TANG Yong-Jian.Elastic and Thermodynamic Properties of Zinc-Blende ZnTe under High Temperature and Pressure[J]. Acta Phys. -Chim. Sin., 2010,26(01): 13-17
71. WANG Wei-Bin, YIN Jian-Zhong, SUN Li-Hua, FENG En-Min.Molecular Dynamics Simulation of Thermodynamic Properties for CO2/Ionic Liquid Systems[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2291-2295
72. LI Zhen-Hua, JIANG Yuan, ZHAO Pei, SHANG Xue-Fu, YANG Hui, WANG Miao.Synthesis of Single-Walled Carbon Nanotube Films with Large Area and High Purity by Arc-Discharge[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2395-2398
73. GUO Qing-Lian, LI Ran, JIANG Feng-Lei, TU Jian-Cheng, LI Lin-Wei, LIU Yi.Characterization of the Interactions between Itraconazole and Human and Bovine Serum Albumins by a Spectroscopic Method[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2147-2154
74. LV Xue-Chuan, TAN Zhi-Cheng, GAO Xiao-Han.Synthesis and Thermochemical Properties of New Ternary Lanthanum Complex La(Glu)(Im)6(ClO4)3·4HClO4·4H2O[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1945-1950
75. ZHAO Wei-Tao, CHEN Hai-Xiang, ZHOU Jian-Jun, LIU Nai-An.Characteristics and Kinetics of Forest Peat Pyrolysis[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1756-1762
76. FANG Xiang, SHEN Pei-Kang.Mechanism of Ethanol Electrooxidation on Pd Electrode[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1933-1938
77. LING Jin-Long, JI Bing, MO Qin-Hua, SUN Lai-Yu.Micellization Behavior and Thermodynamic Properties of Triton X-100/CTAB Mixtures in Ethylene Glycol and Water Solvent Mixtures[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1297-1302
78. LI Jun, FENG Jie, LI Wen-Ying.Thermochemical Reaction Representation of Shenfu Dongshen Inertinite and Vitrinite[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1311-1319
79. DONG Dian-Quan, LIU Wei-Na, LIU Yi-Fan.Synthesis of LiNi0.05Mn1.95O4 and Its Ion-Exchange Thermodynamics for Li+[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1279-1284
80. WEI Xian-Jun, LI Hui-Zhen, LI Jing, ZHOU Neng, TANG Hong-Wei.Vis-Spectrum Investigation of Thermo-Solvatochromic Behaviors of a Mixed Diamine and β-Diketonate Ligand Ni(II) Complex in Different Alcoholic Solutions[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1449-1454
81. XIAO Gu-Qing; XIE Xiang-Lin; XU Man-Cai.Adsorption Performances for Vanillin from Aqueous Solution by the Hydrophobic-Hydrophilic Macroporous Polydivinylbenzene/Polyacrylethylenediamine IPN Resin[J]. Acta Phys. -Chim. Sin., 2009,25(01): 97-102
82. ZHANG Heng, ZHAO Feng-Qi, YI Jian-Hua, ZHANG Xiao-Hong, HU Rong-Zu, XU Si-Yu, REN Xiao-Ning.Preparation, Thermal Behavior and Non-isothermal Decomposition Reaction Kinetics of Zr(3-NO2-PHT)2·2H2O[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2263-2267
83. HU Yan-Fei; KONG Fan-Jie; ZHOU Chun.Structures and Thermodynamic Properties of 3C-SiC Compound[J]. Acta Phys. -Chim. Sin., 2008,24(10): 1845-1849
84. TONG Bo; TAN Zhi-Cheng; WANG Shao-Xu.Thermodynamic Properties of 1-Docosanol[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1699-1702
85. ZHANG Lin-Nan; ZHANG Li; WANG Ming-Yu; CHE Yin-Chang; SUI Zhi-Tong.Thermodynamics of Phase Transformations in Oxidation Process of CaO-FeOx-SiO2 Systemwith High Iron Content[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1540-1546
86. XU Si-Yu; ZHAO Feng-Qi; YI Jian-Hua; HU Rong-Zu; GAO Hong-Xu; LI Shang-Wen; HAO Hai-Xia; PEI Qing.Thermal Behavior and Non-Isothermal Decomposition Reaction Kinetics of Composite Modified Double Base Propellant Containing CL-20[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1371-1377
87. ZHANG Jing-Nan; TAN Zhi-Cheng; LIU Bei-Ping; SHI Quan; TONG Bo.Low-Temperature Heat Capacities and Thermochemistry Properties of Sm(Val)Cl3·6H2O[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1378-1382
88. LI Chun-Hong; QIU Wei-Hua; KANG Xiao-Li; CHOU Kuo-Chih; LU Xiong-Gang; LI Fu-Shen.Kinetics of Synthesis of Ba1.0Co0.7Fe0.2Nb0.1O3-δ through Solid-Solid Reaction[J]. Acta Phys. -Chim. Sin., 2008,24(05): 767-771
89. LIANG Chu; LI Guang-Xu; LAN Zhi-Qiang; LIU Yi-Xin; WEI Wen-Lou; GUO Jin.Bond Characters and Thermodynamic Stabilities of LiAlH4 and Li3AlH6[J]. Acta Phys. -Chim. Sin., 2008,24(04): 686-690
90. WANG Shao-Xu; ZHAO Zhe; TAN Zhi-Cheng; LI Yan-Sheng; TONG Bo; SHI Quan; LI Ying.Thermal Stability and Kinetics of Thermal Decomposition for Protionamide[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1459-1462
91. SUN Jing; HU Sheng-Liang; DU Xi-Wen; LEI Yi-Wen; JIANG Lei.Ultra-fine Nanodiamonds Synthesized Using Millisecond-pulsed Laser[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1105-1108
92. CHEN Jian; HUANG Zheng-Ren; DONG Shao-Ming; JIANG Dong-Liang.Adsorption of Polyethylene Glycol on Silicon Carbide Measured by Thermal Gravimetric and Differential Thermal Analysis[J]. Acta Phys. -Chim. Sin., 2007,23(06): 926-928
93. SUN Xi-Yuan; KONG Fan-Jie; JIANG Gang; ZHU Zheng-He.Thermodynamics of Water Adsorbed on Palladium Surface[J]. Acta Phys. -Chim. Sin., 2007,23(05): 651-654
94. LAI Wei-Peng; XUE Yong-Qiang; LIAN Peng; GE Zhong-Xue; WANG Bo-Zhou; ZHANG Zhi-Zhong.Effects of Particle Size on Properties of Chemical Reaction Thermodynamics of Nanosystems[J]. Acta Phys. -Chim. Sin., 2007,23(04): 508-512
95. LIU Hong-Li;LIU Shi-Jun;XIAO Zhong-Liang;CHEN Qi-Yuan.Thermodynamic Properties of Binary Mixture of Tributylphosphate and n-Alkanols[J]. Acta Phys. -Chim. Sin., 2007,23(01): 124-128
96. YUE Dan-Ting;TAN Zhi-Cheng;LI Yan-Sheng .Low-Temperature Heat Capacity and Thermodynamic Functions of Nano Fe[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1427-1430
97. WANG Hai-Long;WANG Xiu-Xi;WANG Yu;LIANG Hai-Yi .Molecular Dynamics Simulations of Low Index Surfaces Melting Behaviors for Metal Cu[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1367-1371
98. WU Shu-Ying;YANG Li-Xin;SONG Chun-Xia;WANG Wen-Bo .Simulating Calculation of the Dissociation-Association Equilibrium of Dimer and Monomer of Trimethylaluminum in Gas Phase[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1393-1398
99. WU Xin-Min;LIU Jian-Hua;LI Wei;QI Chuan-Song .Thermal Decomposition Kinetics of Complexes of Rare Earths (RE = Nd, Sm) with Amino Acid RE(Val)Cl3•6H2O[J]. Acta Phys. -Chim. Sin., 2006,22(08): 942-946
100. HU Bing-wen; ZHAO Xue-zhou; ZONG Xiao-hong; ZHOU Ping.EPR Spectral Simulation for Silk Fibroin-Cu(II) Complexes with Multiple Components[J]. Acta Phys. -Chim. Sin., 2006,22(02): 167-171
101. ZHU Yu;JIANG Gang;YU Gui-Feng;ZHU Zheng-He;WANG He-Yi;FU Yi-Bei.Adsorption Behavior of N2 on Pd Surface[J]. Acta Phys. -Chim. Sin., 2005,21(12): 1343-1346
102. CHEN Yu-yin; LIU Fan; LIU Yong-chun.A Model of Stoichiometric Displacement for the Adsorption of Benzoic Acid and Benzene by Silica Gel from Cyclohexane Solution[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1211-1216
103. SHAN Hai-wei CHEN Dong-hua TANG Wan-jun.Thermodynamics and Thermal Analysis Kinetics of MC2O4 (M=Mn, Fe, Co, Ni, Cu, Zn)[J]. Acta Phys. -Chim. Sin., 2005,21(09): 1001-1005
104. LIU Wei; YE Tao; GUO Rong.Influence of CTAB on the Reaction between Cobalt Tetrasulphonated Phthalocyanine and Sodium Sulfide[J]. Acta Phys. -Chim. Sin., 2005,21(07): 763-768
105. WANG Mei-Han; TAN Zhi-Cheng; SUN Xiao-Hong; SUN Li-Xian; LIU Yuan-Fa; ZHANG Tao.Thermodynamic Studies of 4-pyridinemethanol[J]. Acta Phys. -Chim. Sin., 2005,21(05): 573-576
106. YUE Dan-Ting; TAN Zhi-Cheng; DONG Li-Na; SUN Li-Xian; ZHANG Tao.Low-temperature Heat Capacity and Thermodynamic Functions of Nano ZnO[J]. Acta Phys. -Chim. Sin., 2005,21(04): 446-449
107. HUANG Yong-Zhang; YUAN Wen-Xia; ZHU Hong-Min; QIAO Zhi-Yu.Thermodynamic Properties of Nonstoichiometric Intermetallic Compounds Fe3Al with DO3 Structure[J]. Acta Phys. -Chim. Sin., 2005,21(03): 273-277
108. Xu Fen;Sun Li-Xian;Tan Zhi-Cheng;Liang Jian-Guo;Zhou Dan-Hong;Di You-Ying;Lan Xiao-Zheng;Zhang Tao.Studies on Thermal Decomposition Mechanism and Kinetics of Aspirin[J]. Acta Phys. -Chim. Sin., 2004,20(01): 50-54
109. Si Wei-Jiang;Zhuo Shu-Ping;Ju Guan-Zhi.Thermodynamic and Kinetic Investigations on NH+O3→ONH+O2 Reaction[J]. Acta Phys. -Chim. Sin., 2003,19(10): 974-977
110. Zhou Bao-Xue;Cai Wei-Min;Zou Li-Zhuang.Thermodynamic Functions of Transfer of Naphthalene from Water to Water-t-butyl Alcohol Solutions[J]. Acta Phys. -Chim. Sin., 2003,19(09): 867-870
111. Nan Zhao-Dong;Tan Zhi-Cheng;Sun Li-Xian.Thermodynamic Investigation of the High Efficient Working Fluid Used for a Heat Pipe[J]. Acta Phys. -Chim. Sin., 2003,19(09): 883-885
112. Wang Hong-Yan;Chen Chang-An;Sun Ying;Zhu Zheng-He.Structure and Thermodynamic Properties of UO2, UC2 and UCO[J]. Acta Phys. -Chim. Sin., 2003,19(07): 651-653
113. Wang Xin-Qing;Wang Miao;Li Zhen-Hua;Zhu Hai-Bin;Wang Feng-Fei.Purification and Characterization of Single-Walled Carbon Nanotubes Produced by Arc-Discharge[J]. Acta Phys. -Chim. Sin., 2003,19(05): 428-431
114. Liu Bei-Ping;Tan Zhi-Cheng;Yu Hua-Guang;Lan Xiao-Zheng;Zhang Da-Shun;Liu Ping;Sun Li-Xian.Thermodynamic Properties of [Ho2(Ala)4(H2O)8]Cl6 (Ala=alanine)[J]. Acta Phys. -Chim. Sin., 2003,19(05): 445-449
115. Nan Zhao-Dong;Tan Zhi-Cheng;Sun Li-Xian.Low Temperature Heat Capacities and Thermodynamic Functions of Potassium Dichromate[J]. Acta Phys. -Chim. Sin., 2002,18(10): 947-951
116. Li Quan;Xu Cheng-Gang;Wang Hong-Yan;Zhu Zheng-He.Thermodynamic Stability of PuH2 (g) Molecules[J]. Acta Phys. -Chim. Sin., 2002,18(10): 952-955
117. Tan Jin-Zhi;Xiao He-Ming;Gong Xue-Dong;Li Jin-Shan.Comparison of DFT with Ab initio Method on the Study of Intermolecular Interaction of (CH3ONO2)2[J]. Acta Phys. -Chim. Sin., 2002,18(04): 307-314
118. Liu Feng-Ling.DFT Studies on the UnsaturatedCarbenoid H2C=CLiF[J]. Acta Phys. -Chim. Sin., 2002,18(03): 228-231
119. Lu Qin-Ying;Song Yong-Ji;Meng Shuang-He;Xing Jun;Tan Zhi-Cheng.Low Temperature Heat Capacities and Thermal Analysis of N-(p-methylphenyl)-N′-(2-pyridyl)urea[J]. Acta Phys. -Chim. Sin., 2002,18(02): 166-169
120. Chen Yu-Yin;Liu Fan.Stoichiometric Displacement Model for the Adsorption of Propionic Acid and nButyric Acid by Silica Gel from Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2002,18(01): 62-65
121. Li Yong-Hui;Huang Jian-Bin;Wang Chuan-Zhong;Mao Min.The Surface Chemical Properties of Hydrolytic Surfactants[J]. Acta Phys. -Chim. Sin., 2001,17(11): 972-977
122. Wang Qin-Ping;Lü Dian-Zhen;Shen Li;Yang Jia-Zhen.Thermodynamic Properties of Dissociation of Amino Acid in Mixed Solvents[J]. Acta Phys. -Chim. Sin., 2001,17(10): 952-955
123. Luo De-Li;Jiang Gang;Zhu Zheng-He;Meng Da-Qiao;Xue Wei-Dong.Ab initio of the Thermodynamic Function for the Hydrogenating of Zirconium-Cobalt Alloy[J]. Acta Phys. -Chim. Sin., 2001,17(10): 913-917
124. Luo De-Li;Zhu Zheng-He;Jiang Gang;Meng Da-Qiao;Xue Wei-Dong.Quantum Mechanical Calculation of the Adsorption of Hydrogen Isotopes on Metallic Zirconium[J]. Acta Phys. -Chim. Sin., 2001,17(07): 626-630
125. Liang Shi-Qiang;Zhang Bing-Jian;Lu Ying-Hong;Hu Wen-Xuan;Jin Zhi-Jun.New Perturbation Theory Model for Chainlike Molecule Fluid and the Predicted Heat Capacity[J]. Acta Phys. -Chim. Sin., 2001,17(05): 416-421
126. Wu Hai-Shun;Xu Xiao-Hong;Zhang Cong-Jie;Jin Zhi-Hao.Structure and Thermodynamic Properties of (Cl2AlNH2)n and (H2AlNH2)n Clusters[J]. Acta Phys. -Chim. Sin., 2001,17(04): 324-328
127. Zhang Jian-Guo, Zhang Tong-Lai.Synthesis,Structural Characterization and Thermal Decomposition Mechanism of {[Ag(ATO)2]ClO4}n[J]. Acta Phys. -Chim. Sin., 2000,16(12): 1110-1114
128. Wang Li, Bian Xiu-Fang, Li Hui.Liquid-Solid Transition and Crystal Growth of Metal Cu by Molecular Dynamics Simulation[J]. Acta Phys. -Chim. Sin., 2000,16(09): 825-829
129. Lv Chun-Hua, Zhang Tong-Lai, Qiao Xiao-Jing, Cai Rui-Jiao, Yu Kai-Bei.Structure and Thermal Decomposition Mecharism of [Pb2(TNR)2(CHZ)2(H2O)2]4H2O[J]. Acta Phys. -Chim. Sin., 2000,16(05): 441-446
130. Wu Man-Jiang, Ai Li, Chen Wen-Hai, Chen Wei, Xue Qun-Ji.The Association of Anionic Surfactants with β-cyclodextrin[J]. Acta Phys. -Chim. Sin., 1999,15(12): 1115-1118
131. Sun De-Kun, Bao Shu-Lin, Xu Qin, Xu Qin-Hua.Synthesis and Adsorption Thermodynamic Properties of High-Silica Y Zeolite[J]. Acta Phys. -Chim. Sin., 1999,15(11): 1041-1044
132. Gong Xue-Dong, Xiao He-Ming.Calculations of the Structure,Vibrational Spectrum and Thermodynamic Properties of Succinimide[J]. Acta Phys. -Chim. Sin., 1999,15(08): 688-692
133. Liu Sheng-Feng, Lin Jian-Hua, Su Mian-Zeng.Thermodynamics of Deoxidation of High Purity Niobium[J]. Acta Phys. -Chim. Sin., 1999,15(03): 228-233
134. Zhou Pei-Jiang, Hu Yun-Chu, Ling Xing-Yuan, Yang Feng, Song Zhao-Hua, Qu Song-Sheng, Zhu Ying-Guo.Microcalorimetric and Nonequlibrium Thermodynamic Studies on the Gemination and Growth of Seeds[J]. Acta Phys. -Chim. Sin., 1999,15(03): 274-278
135. Qi Bin, Su Ke-He, Wang Yu-Bin, Wen Zhen-Yi, Tang Xiao-Yan.Gaussian-2 Calculations of the Thermochemistry of Criegee Intermediates in Gas Phsae Reactions[J]. Acta Phys. -Chim. Sin., 1998,14(11): 1033-1039
136. Zhu Bu-Yao, Wu Li-Jun, Huang Jian-Bin, He Xu.Surface Chemical lnvestigation on Aqueous Solution of Sodeum Undecanoate and Sodium Undecenoate[J]. Acta Phys. -Chim. Sin., 1998,14(11): 1025-1029
137. Yu Yun, Wang Tian-Zhi, Qu Song-Sheng.Thermodynamic Properties of a Double Salt K2Mg(IO3)4 2H2O[J]. Acta Phys. -Chim. Sin., 1998,14(10): 936-939
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139. Chen Zhao-Xu, Xiao He-Ming, Gao Bao-Hua.Theoretical Study on Tetrazole and its Derivatives(6)[J]. Acta Phys. -Chim. Sin., 1998,14(08): 757-764
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