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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(3)>> 500-505     doi: 10.3866/PKU.WHXB201611111         中文摘要
Multiphoton Dissociation and Ionization Dynamics of Allyl Chloride Using Femtosecond Laser Pulses
LIU Ning-Liang1,2, SHEN Huan1,2
1 College of Science, Huazhong Agricultural University, Wuhan 430070, P. R. China;
2 Institute of Applied Physics, Huazhong Agricultural University, Wuhan 430070, P. R. China
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The dissociation and photoionization dynamics of C3H5Cl were studied at 200, 400, and 800 nm with femtosecond laser pulses. The time-of-flight mass spectra, laser power index and photoelectron images were recorded. At short wavelength (200 nm), ionization of the parent molecule was found to be the dominant channel, while other ions were generated by the dissociation of C3H5Cl+. With the shift to long wavelength (e.g., 800 nm), fragment ions became dominant, and were generated through the multiphoton ionization of neutral fragments after the photodissociation of C3H5Cl. These results imply that photodissociation plays a significant role at long wavelength, because neutral fragments are supposed to be generated from the intermediate states reached by 800 nm photons. At 400 nm, the dissociation on the intermediate states is also critical, but is not as high as that at 800 nm. Taken together, our results demonstrate that the dissociation/ionization behaviors of allyl chloride are wavelength-dependent, and reveal the complex dynamics of allyl chloride at 200, 400 and 800 nm.



Keywords: Femtosecond laser pulse   Time-of-flight mass spectrometry   Photoelectron imaging   Allyl chloride   Multiphoton dissociation and ionization  
Received: 2016-10-12 Accepted: 2016-11-11 Publication Date (Web): 2016-11-11
Corresponding Authors: SHEN Huan Email: shenhuan@mail.hzau.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (21403080,61308028) and Specialized Research Fund for the Doctoral Program of Higher Education,China (20130146120015)

Cite this article: LIU Ning-Liang, SHEN Huan. Multiphoton Dissociation and Ionization Dynamics of Allyl Chloride Using Femtosecond Laser Pulses[J]. Acta Phys. -Chim. Sin., 2017,33 (3): 500-505.    doi: 10.3866/PKU.WHXB201611111

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