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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(3)>> 582-589     doi: 10.3866/PKU.WHXB201611292         中文摘要
A Solution-Based Self-Assembly Approach to Preparing Functional Supramolecular Hybrid Materials
YANG Hai-Kuan
School of Science, North University of China, Taiyuan 030051, P. R. China
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A hybrid molecule having a molecular structure of cholesterol-polyoxometalate-cholesterol, was created by covalently connecting two cholesterol molecules onto the two sides of an organically modified Anderson-type polyoxometalate (POM). This hybrid molecule could self-assemble into highly ordered hexagonally packed cylinders in a bulk sample. The POM cluster of the hybrid molecule dissolved well in N,N-dimethylformamide (DMF) solvent and cholesterol moieties had appropriate solubility in toluene. In mixed DMF/toluene solvents, the hybrid molecule self-assembled into fibril-shaped aggregates. These aggregates further twisted around each other to form the three-dimensional network structures. These formations were attributed to the solubility difference between the POM cluster and cholesterol moieties, van der Waals interactions among the cholesterol moieties, and electrostatic interactions among the POM clusters. Within the fibrous structure, the POM cluster and cholesterol moieties in the hybrid molecule assembled into a well-organized structure with alternatively arranged POM layer and cholesterol layer. The results described herein has potential application value toward design, assembly, and application of nanomaterials.



Keywords: Material design   Hybrid molecule   Polyoxometalates   Self-assembly   Fibrous structure  
Received: 2016-10-20 Accepted: 2016-11-29 Publication Date (Web): 2016-11-29
Corresponding Authors: YANG Hai-Kuan Email: haikuanyang@nuc.edu.cn

Fund: The project was supported by the Natural Science Foundation of North University of China (XJJ2016015)

Cite this article: YANG Hai-Kuan. A Solution-Based Self-Assembly Approach to Preparing Functional Supramolecular Hybrid Materials[J]. Acta Phys. -Chim. Sin., 2017,33 (3): 582-589.    doi: 10.3866/PKU.WHXB201611292

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69. XU Di; GAO Ai-Mei; DENG Wen-Li.Self-Assembly and Photocatalytic Properties of Clustered and Flowerlike CdS Nanostructures[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1219-1224
70. PAN Hai-Bo; WANG Fang; HUANG Jin-Ling; CHEN Nai-Sheng.Binding Characteristics of CoPc/SnO2 by In-situ Process and Photocatalytic Activity under Visible Light Irradiation[J]. Acta Phys. -Chim. Sin., 2008,24(06): 992-996
71. QIAN Li-Ping; DENG Wen-Li.Adsorption Characteristics of Self-assembled 1-Octadecanol Layer on HOPG[J]. Acta Phys. -Chim. Sin., 2008,24(03): 443-447
72. XU Qun-Jie; WAN Zong-Yue; YIN Ren-He; ZHU Lu-Jun; CAO Wei-Min; ZHOU Guo-Ding; LIN Chang-Jian.Inhibition Action of the Self-Assembled Monolayers of 3-Amino-1,2,4-triazole on Brass[J]. Acta Phys. -Chim. Sin., 2008,24(01): 115-120
73. SU Zhao-Hui; CHEN Qi-Yuan; LI Jie; LIU Shi-Jun.Preparation and Characterization of Mesoporous Silicon Dioxide Doped with Tungsten[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1760-1764
74. ZHOU Xue-Feng; LI Wei; ZHANG Yan; YANG Zhu-Hong; FENG Xin; LU Xiao-Hua.Hole Oxidation on TiO2 Films in Aqueous Solutions Studied by Using OTS SAMs as a Probe[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1113-1116
75. SUN Wei; YANG Mao-Xia; ZHONG Jiang-Hua; JIAO Kui.Electrochemical Behaviors of Brilliant Cresyl Blue on DNA Modified Gold Electrode[J]. Acta Phys. -Chim. Sin., 2007,23(04): 499-502
76. GAO Li-Ning;LU Feng-Ting;HU Jing; FANG; Yu.Progress in the Studies of Fluorescent Film Sensors[J]. Acta Phys. -Chim. Sin., 2007,23(02): 274-284
77. YANG Zhao-Hui;ZHANG Mao-Feng;CAO Wei-Xiao.Self-assembly Films of Poly(4-diazosulfonate Styrene-co-4-vinylpyridine) with Polyaniline and Their Photoelectric Conversion Properties[J]. Acta Phys. -Chim. Sin., 2007,23(01): 1-5
78. ZHOU Zhen;YAN Tian-Ying;GAO Xue-Ping.Simulation and Design for Energy Storage Materials[J]. Acta Phys. -Chim. Sin., 2006,22(09): 1168-1174
79. YU Zhi- Hui;TIAN Mi;JIAO Qing-Ying;XIA Ding- Guo.Self-assembling Nanobimetallic Particles of Au-Pt on Glassy Carbon Electrode[J]. Acta Phys. -Chim. Sin., 2006,22(08): 1015-1020
80. DIAO Yu-Xia;ROHDE Dirk;WAN Li-Jun.Ordered Self-assembled Monolayers of β-dicarbonyl Derivatives Studied by STM[J]. Acta Phys. -Chim. Sin., 2006,22(06): 691-695
81. ZHU Jian-Hua; SHI Jin-Xia; LI Heng; HE Ping-Sheng.Self-assembling of Microsphere through Template[J]. Acta Phys. -Chim. Sin., 2006,22(03): 350-354
82. GAN Zhi-ping; GUAN Jian-guo.Chemical Self-assembly Route to Fabricate Hollow Barium Ferrite Submicrospheres[J]. Acta Phys. -Chim. Sin., 2006,22(02): 189-192
83. SHI Jian-zhen; FANG Jing-huai; MU Ren-wang; LI Ya-li.Preparation of Au Core-Ag Shell Nanoparticles Film and Its SERS Activity Study[J]. Acta Phys. -Chim. Sin., 2006,22(02): 135-140
84. ZHAO Jian-wei; KAN Rong-rong; ZHANG Yan; CHEN Hong-yuan.Applications of Scanning Probe Microscopy in Nanolithography on Alkanethiol Self-assembled Monolayers[J]. Acta Phys. -Chim. Sin., 2006,22(01): 124-130
85. DENG Xiang-Hui;KAN Xian-Wen;YU Yan;ZHANG Wen-Zhi;LIU Hong-Ying;FANG Bin.Electrochemical and Catalytic Properties of Ferrocene/L-cysteine Modified Electrode[J]. Acta Phys. -Chim. Sin., 2005,21(12): 1399-1402
86. ZHOU Xiao-shun; XU Xiaomi; ZHONG Hui-ping; LONG La-sheng; HUANG Rong-bin; XIE Zhao-xiong; ZHENG Lan-sun; MAO Bing-wei.Adsorption of Metal-Organic Complex Molecule on Au(111) Surface[J]. Acta Phys. -Chim. Sin., 2005,21(09): 949-951
87. AN Shi-yan; XU Shan-dong; ZENG Qing-dao; TAN Zhong-yin; WANG Chen; WAN Li-jun; BAI Chun-li.The Self-assembly Structure of Pyrazine Derivative on Highly Oriented Pyrolytic Graphite[J]. Acta Phys. -Chim. Sin., 2005,21(08): 925-928
88. MA Hui-ru; GUAN Jian-guo; LU Guo-jun; YUAN Run-zhang.The Preparation and Characterization of PAn-PEG-PAn Rod-coil Triblock Copolymers[J]. Acta Phys. -Chim. Sin., 2005,21(06): 627-631
89. CAO Jie-Ming; CHANG Xin; ZHENG Ming-Bo; HUANG Hai-Bin; JI Hong-Mei; LIU Jin-Song; KE Xing-Fei.Three-dimensional Silica Opals Templating for Synthesis of ZnS Photonic Crystals via Solvothermal Approach[J]. Acta Phys. -Chim. Sin., 2005,21(05): 560-564
90. DIAO Peng; MEI Gang; HOU Qun-Chao; YU Feng; XIANG Min; ZHANG Qi.Electrochemical Properties of Thiol Monolayers Prepared by Constant-Potential Assembly[J]. Acta Phys. -Chim. Sin., 2005,21(03): 291-295
91. Chen Zhi-Chun;Xu Shan-Hao;Lin Han-Feng;Yang Shao-Ming;Lin Xian-Fu.Glucose Oxidase Modified Electrode Fabricated by Layer-by-layer Molecular Deposition[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1267-1270
92. Li Di;Li Jing-Hong.Electrochemistry of Monolayer Protected Nanoclusters[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 982-988
93. Wang Chen;Fan Xiao-Lin;Liu Yu-Hong;Wan Li-Jun;Bai Chun-Li.Recent Progress of Electrical Conductivity of Single Molecule[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 1003-1009
94. Fu Chong-Gang;Su Chang-Hua;Shan Rui-Feng.Electrochemical Properties of L-cysteine Self-assembled Membrane Modified Gold Electrode[J]. Acta Phys. -Chim. Sin., 2004,20(02): 207-210
95. Li Yang-Mei;Jiang Xiu-Ming;Chen Zhi-Chun;Fu Shui-Yu;Lin Xian-Fu.Construction of Ordered Films of Horseradish Peroxidase through Lectin-glycogenReaction and Its Application in Enzyme Electrode[J]. Acta Phys. -Chim. Sin., 2004,20(02): 216-220
96. Li Yang-Mei;Chen Zhi-Chun;Lü De-Shui;Lin Xian-Fu.Topography and Electro-catalysis Property of Horseradish Peroxidase Assembly Active Films[J]. Acta Phys. -Chim. Sin., 2003,19(05): 474-477
97. Cao Lin-You;Diao Peng;Liu Zhong-Fan.Preparation of Au (core)-Cu (shell) Nanoparticles Assembly by Electrodeposition[J]. Acta Phys. -Chim. Sin., 2002,18(12): 1062-1067
98. Wang Ning;Ding Ke-Qiang;Tong Ru-Ting;Shao Hui-Bo.The Electrochemical Behavior of Self-assembled Monolayers of Schiff Base[J]. Acta Phys. -Chim. Sin., 2002,18(09): 846-849
99. Zhu Xiao-Yang.Organic Monolayers on Silicon:Microprinting, Micromachines, and Microarrrays[J]. Acta Phys. -Chim. Sin., 2002,18(09): 855-864
100. Ding Ke-Qiang;He Xiao-Ling;Wang Qing-Fei;Jiang Dian-Lu;Bai Juan;Tong Ru-Ting;Wang Xin-Kui.The AC Impedance Study of Calmodulin Modified on Au Electrode[J]. Acta Phys. -Chim. Sin., 2002,18(08): 741-745
101. Gu Guo-Tuan;Zhang Zhi-Jun;Dang Hong-Xin.Preparation and Tribological Behavior of Perfluoroctanoxamidepropyltrioxylmethyl Silane SAM[J]. Acta Phys. -Chim. Sin., 2002,18(07): 669-672
102. Li Zhi-Wei;Zhou Jing-Fang;Zhang Zhi-Jun;Dang Hong-Xin.Preparation and Self-assembly on Glasses of Surface-functional Polystyrene Nanoparticles[J]. Acta Phys. -Chim. Sin., 2002,18(06): 550-553
103. Zhang Sheng-Mao;Gao Yong-Jian;Zhang Zhi-Jun;Dang Hong-Xin;Liu Wei-Min;Xue Qun-Ji.Preparation and Characterization of Selfassembly Nanocomposite Thin Film[J]. Acta Phys. -Chim. Sin., 2002,18(05): 451-454
104. Xu Li-Na;Xu Hong-Fei;Zhou Kai-Chang;Xu Ai-Qun;Yue Zeng-Quan;Gu Ning;Zhang Hai-Qian;Liu Ju-Zheng;Chen Kun-Ji.Study on a New Activation Method for Initiating Electroless Plating on Alumina Powders Based on SAMs Bonded Palladium[J]. Acta Phys. -Chim. Sin., 2002,18(03): 284-288
105. Wang Sheng-Fu;Du Dan;Zou Qi-Chao.Electrochemical Properties of L-cysteine Self-assembled Monolayers Modified[J]. Acta Phys. -Chim. Sin., 2001,17(12): 1102-1106
106. Yu Hai-Hu;Wu Hong-Biao;Li Xiao-Fu;Zhu Yun-Zhou;Jiang De-Sheng.Self-assembly and Optical Properties of Silica Nanoparticulate Thin Films[J]. Acta Phys. -Chim. Sin., 2001,17(12): 1057-1061
107. Dong Dong;Zhang Sheng;Zhu Tao;Gan Liang-Bing;Liu Zhong-Fan.FullereneTerminated SAMs on Gold(111):Formation and Characterization[J]. Acta Phys. -Chim. Sin., 2001,17(11): 978-981
108. Li Dong-Sheng;Lu Gong-Xuan.Synthesis of Conductive Polymer/Semiconductor Nanocomposite Films by Layerbylayer Assembly Techniques[J]. Acta Phys. -Chim. Sin., 2001,17(03): 252-256
109. Ren Si-Li;Yang Sheng-Rong;Xue Qun-Ji.Perfluorodecanoic Acid Ultrathin Film on Single Crystal Silicon Substrate Coated with Polyethyleneimine[J]. Acta Phys. -Chim. Sin., 2001,17(02): 97-100
110. Chen Zhao-Hui, Ma Ying, Yao Jian-Nian.High-Efficlent Photochromic WO3-polymer/1,10-DAD Self-assembly Films Modified by Organic Molecules[J]. Acta Phys. -Chim. Sin., 2000,16(12): 1057-1061
111. Wang Zhen, Zhang Hao-Li, Li Hu-Lin.Self-assembly Behavior of Azobenzene Derivative β-Cyclodextrin Inclusion Complex on Gold[J]. Acta Phys. -Chim. Sin., 1999,15(07): 606-612
112. Zhang Hao-Li, Zhang Hua, Zhang Jin, Wu Bin, Liu Zhong-Fan, Li Hu-Lin.Fbrication and Structural Evaluation of Self-assembled Monolayer of Quinoline Derivative on Gold[J]. Acta Phys. -Chim. Sin., 1999,15(07): 657-661
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119. Hou Shi-Feng, Yang Ke-Sheng, Fang Hui-Qun, Chen Hong-Yuan.Electron Transfer Mechanism Characteristics of 2,3,5,6-tetrachloride-quinone Anchored on the Self-assembled Monolayers of Dithiol[J]. Acta Phys. -Chim. Sin., 1998,14(07): 640-644
120. Xiao Zhong-Dang, Huang Dan, Gu Jian-Hua, Lu Zu-Hong.X-ray Photoelectron Spectroscopy Study of the Deposition of TiO2 Thin Films on Self-assembly Monolayer[J]. Acta Phys. -Chim. Sin., 1998,14(01): 57-62
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