纳米片自组装的(BiO)2CO3单分散微米绒球的绿色可控合成及其光催化性能

doi:10.3866/PKU.WHXB201702101

Abstract

Abstract:

This work reports a controlled green synthesis of highly monodisperse bismuth subcarbonate (BS) micropompons self-assembled by nanosheets using a simple and facile hydrothermal route in which deionized water, bismuth nitrate pentahydrate (BNP), and urea were used as the solvent, bismuth source, and carbon source respectively. Trisodium citrate dihydrate (TCD) was used as a coordination agent to fabricate a complex precursor. The structure and morphology of the BS materials can be finely modulated by adjusting the initial concentration ratios of the reactants or the reaction time. The presence of TCD decreased the formation rate of BS due to a direct competitive interaction for the BiO⁺ ions between a coordination equilibrium and a precipitation equilibrium. Urea played a crucial role (e.g., carbon source, alkaline source, morphology control agent, and crystal growth control agent) in the formation of the BS microstructures. We obtained three kinds of BS crystals with preferred orientations along [001], [110], and [013] by adjusting the concentration of urea. Our synthesis approach has the advantages of low cost, high reaction yields, monodisperse particles, controlled morphologies and orientations, and not requiring the use of organic solvents, templates, surfactants, high phototemperatures, and long reaction times. Particularly, when compared with those reported by other investigators, the micropompon material exhibited improved photocatalytic performance for Rhodamine B due to a unique microstructure (large specific surface area, high efficiency of photoelectric conversion, small interfacial chargetransfer resistance, and active {001} exposed facets). These results indicate a major advance in the controlled green synthesis and the application of inorganic micro-and nano-materials.

Key words: Bismuth subcarbonate, Controlled green synthesis, Photocatalytic performance, Micropompons, Trisodium citrate dihydrate

MSC2000:

O643

Click here to download Supporting Info material in PDF type

Mao-Mao RUAN,Le-Xin SONG,Qing-Shan WANG,Juan XIA,Zun YANG,Yue TENG,Zhe-Yuan XU. Facile Green Synthesis of Highly Monodisperse Bismuth Subcarbonate Micropompons Self-assembled by Nanosheets: Improved Photocatalytic Performance[J].Acta Phys. -Chim. Sin., 2017, 33(5): 1033-1042.

References

1	(a) Chen, X.; Li, C.; Gr?tzel, M.; Kostecki, R.; Mao, S. S.Chem. Soc. Rev. 2012, 41, 7909. doi: 10.1039/C2CS35230C
1	(b) Xiang, Q.; Yu, J.; Jaroniec, M. Chem. Soc. Rev. 2012, 41, 782. doi: 10.1039/C1CS15172J
2	(a) Chen, X.; Shen, S.; Guo, L.; Mao, S. S. Chem. Rev. 2010, 110, 6503. doi: 10.1021/cr1001645
2	(b) Li, X. J.; Sheng, J. Y.; Chen, H. H.; Xu, Y. M. ActaPhys. -Chim. Sin. 2015, 31, 540. [李晓金,盛珈怡,陈海航,许宜铭.物理化学学报, 2015, 31, 540.] doi: 10.3866/PKU.WHXB201501131
3	(a) Hou, Y.; Laursen, A. B.; Zhang, J.; Zhang, G.; Zhu, Y.; Wang, X.; Dahl, S.; Chorkendorff, I. Angew. Chem. Int. Ed. 2013, 52, 3621. doi: 10.1002/anie.201210294
3	(b) Li, J.; Zhang, L.; Li, Y.; Yu, Y. Nanoscale 2013, 6, 167.doi: 10.1039/C3NR05246J
3	(c) Zhang, N.; Ciriminna, R.; Pagliaro, M.; Xu, Y. J. Chem. Soc.Rev. 2014, 43, 5276. doi: 10.1039/C4CS00056K
4	(a) Zhou, L.; Wang, W.; Liu, S.; Zhang, L.; Xu, H.; Zhu, W.J. Mol. Catal. A: Chem. 2006, 252, 120. doi: 10.1016/j.molcata.2006.01.052
4	(b) Singh, M. K.; Ryu, S.; Jang, H. M. Phys. Rev. B, 2005, 72, 132101. doi: 10.1103/PhysRevB.72.132101
4	(c) Yu, J.; Kudo, A. Adv. Funct. Mater. 2006, 16, 2163.doi: 10.1002/adfm.200500799
4	(d) He, R. A.; Cao, S.W.; Zhou, P.; Yu, J. G. Chin. J. Catal. 2014, 35, 989. doi: 10.1016/S1872-2067(14)60075-9
5	(a) Huo, Y.; Hou, R.; Chen, X.; Yin, H.; Gao, Y.; Li, H. J. Mater.Chem. A 2015, 3, 14801. doi: 10.1039/C5TA03279B
5	(b) Huo, Y.; Zhang, J.; Miao, M.; Jin, Y. Appl. Catal. B 2012, 111, 334. doi: 10.1016/j.apcatb.2011.10.016
5	(c) Xia, J.; Yin, S.; Li, H.; Xu, H.; Xu, L.; Xu, Y. Dalton Trans. 2011, 40, 5249. doi: 10.1039/C0DT01511C
5	(d)Wu, Y.; Yuan, B.; Li, M.; Zhang, W. H.; Liu, Y.; Li, C.; Chem. Sci. 2015, 6, 1873. doi: 10.1039/C4SC03229B
6	(a) Huang, H.; Wang, J.; Dong, F.; Guo, Y.; Tian, N.; Zhang, Y.; Zhang, T. Cryst. Growth Des. 2015, 15, 534. doi: 10.1021/cg501527k
6	(b) Dong, F.; Ho, W. K.; Lee, S.; Wu, Z.; Fu, M.; Zou, S.; Huang, Y. J. Mater. Chem. 2011, 21, 12428. doi: 10.1039/C1JM11840D
7	Liang N. ; Zai J. ; Xu M. ; Zhu Q. ; Wei X. ; Qian X. J. Mater.Chem. A 2014, 2, 4208.
8	Tang J. ; Zhao H. ; Li G. ; Lu Z. ; Xiao S. ; Chen R. Ind. Eng.Chem. Res. 2013, 52, 12604.
9	Cao X. F. ; Zhang L. ; Chen X. T. ; Xue Z. L. CrystEngComm 2011, 13, 1939.
10	Xiong T. ; Dong F. ; Wu Z. B. RSC Adv. 2014, 4, 56307.
11	Xiong T. ; Huang H.W. ; Sun Y. J. ; Dong F. J. Mater. Chem. A 2015, 3, 6118.
12	Dong F. ; Xiong T. ; Sun Y. J. ; Huang H.W. ; Wu Z. B. J. Mater. Chem. A 2015, 3, 18466.
13	Zhao Z. Y. ; Zhou Y. ; Wang F. ; Zhang K. H. ; Yu S. ; Cao K. ACS Appl. Mater. Interfaces 2014, 7, 730.
14	(a) Madhusudan, P.; Zhang, J.; Cheng, B.; Liu, G.CrystEngComm 2013, 15, 231. doi: 10.1039/C2CE26639C
14	(b) Dong, F.; Lee, S. C.; Wu, Z. B.; Huang, Y.; Fu, M.; Ho, W.K.; Zou, S. C.; Wang, B. J. Hazard. Mater. 2011, 195, 346. doi: 10.1016/j.jhazmat.2011.08.050
15	Zhao T. ; Zai J. ; Xu M. ; Zou Q. ; Su Y. ; Wang K. ; Qian X. CrystEngComm 2011, 13, 4010.
16	(a) Dong, F.; Sun, Y. J.; Fu, M.; Ho, W. K.; Lee, S. C.; Wu, Z. B.Langmuir 2011, 28, 766. doi: 10.1021/la202752q
16	(b) Chen, L.; Huang, R.; Yin, S. F.; Luo, S. L.; Au, C. T. Chem.Eng. J. 2012, 193, 123. doi: 10.1016/j.cej.2012.04.023
17	Qin F. ; Li G. ; Wang R. ; Wu J. ; Sun H. ; Chen R. Chem. Eur.J. 2012, 18, 16491.
18	Dong F. ; Zheng A. M. ; Sun Y. J. ; Fu M. ; Jiang B. Q. ; Ho W.K. ; Lee S. C. ; Wu Z. B. CrystEngComm 2012, 14, 3534.
19	Zheng Y. ; Duan F. ; Chen M. Q. ; Xie Y. J. Mol. Catal. A:Chem. 2010, 317, 34.
20	Ma D. ; Huang S. ; Chen W. ; Hu S. ; Shi F. ; Fan K. J. Phys.Chem. C 2009, 113, 4369.
21	Li X. ; Tang C. J. ; Ai M. ; Dong L. ; Xu Z. Chem. Mater. 2010, 22, 4879.
22	Peng S. ; Li L. ; Tan H. ; Wu Y. ; Cai R. ; Yu H. ; Huang X. ; Zhu P. ; Ramakrishna S. ; Srinivasan M. J. Mater. Chem. A 2013, 1, 7630.
23	Xiong M. ; Chen L. ; Yuan Q. ; He J. ; Luo S. L. ; Au C. T. ; Yin S. F. Dalton Trans. 2014, 43, 8331.
24	Chen J. ; Guan M. ; Cai W. ; Guo J. ; Xiao C. ; Zhang G. Phys.Chem. Chem. Phys. 2014, 16, 20909.
25	Zhang D. ; Li J. ; Wang Q. ; Wu Q. J. Mater. Chem. A 2013, 1, 8622.
26	(a) Zhang, H.; Ji, Y.; Ma, X.; Xu, J.; Yang, D. Nanotechnology, 2003, 14, 974. doi: 0957-4484/14/9/307
26	(b) Kudo, A.; Omori, K.; Kato, H. J. Am. Chem. Soc. 1999, 121, 11459. doi: 10.1021/ja992541y
27	Huang H. ; Li X. ; Wang J. ; Dong F. ; Chu P. K. ; Zhang T. ; Zhang Y. ACS Catalysis 2015, 5, 4094.
28	Teng Y. ; Song L. X. ; Ponchel A. ; Yang Z. K. ; Xia J. Adv. Mater. 2014, 26, 6238.
29	Teng Y. ; Song L. X. ; Liu W. ; Xu Z. Y. ; Wang Q. S. ; Ruan M. M. J. Mater. Chem. C 2016, 4, 3113.
30	Jiang J. ; Zhao K. ; Xiao X. ; Zhang L. J. Am. Chem. Soc. 2012, 134, 4473.
31	Lee W. ; Kim E. ; Choi J. ; Lee K. B. Cryst. Growth Des. 2015, 15, 884.
32	(a)Wang, B.; Chen, J. S.; Wang, Z.; Madhavi, S.; Lou, X.W. D.Adv. Energy Mater. 2012, 2, 1188. doi: 10.1002/aenm.201200008
32	(b) Zhan, J. Lin, H. P.; Mou, C. Y. Adv. Mater. 2003, 15, 621.doi: 10.1002/adma.200304600
33	(a) Ye, Y.; Chen, J.; Ding, Q.; Lin, D.; Dong, R.; Yang, L.; Liu, J. Nanoscale 2013, 5, 5887. doi: 10.1039/C3NR01273E
33	(b)Wang, B.; Zhu, T.; Wu, H. B.; Xu, R.; Chen, J. S.; Lou, X.W. D. Nanoscale 2012, 4, 2145. doi: 10.1039/C2NR11897A
34	Xuan S. ; Hao L. ; Jiang W. ; Gong X. ; Hu Y. ; Chen Z. Nanotechnology 2007, 18, 035602.
35	Wang W. ; Lu C. ; Ni Y. ; Su M. ; Xu Z. Appl. Catal. B 2012, 127, 28.
36	Mullin, J. W. Crystallization, 3rd ed. ; Butterworth-Heinemaan: Oxford, 1997.
37	Voorhees P. W. J. Stat. Phys. 1985, 38, 231.
38	(a) Gokulakrishnan, N.; Peru, G.; Rio, S.; Blach, J.; Léger, ;B.; Grosso, D.; Monflier, E.; Ponchel, A. J. Mater. Chem. A 2014, 2, 6641. doi: 10.1039/C4TA00038Bb(b) Bleta, R.; Menuel, S.; Léger, B.; Da Costa, A.; Monflier, E.; Ponchel, A. RSC Adv. 2014, 4, 8200. doi: 10.1039/C3RA47765G
39	Brunauer S. ; Emmett P. H. ; Teller E. J. Am. Chem. Soc. 1938, 60, 309.
40	Dong F. ; Liu H. ; Ho W. K. ; Fu M. ; Wu Z. Chem. Eng. J. 2013, 214, 198.
41	(a) Yang, Z. K.; Song, L. X.; Teng, Y.; Xia, J. J. Mater. Chem. A 2014, 2, 20004. doi: 10.1039/C4TA04232H
41	(b)Wang, Q. S.; Song, L. X.; Teng, Y.; Xia, J.; Zhao, L.; Ruan, M. M. RSC Adv. 2015, 5, 80853. doi: 10.1039/C5RA16571G
42	(a) Ye, L.; Zan, L.; Tian, L.; Peng, T.; Zhang, J. Chem. Commun. 2011, 47, 6951. doi: 10.1039/C1CC11015B
42	(b) He, R. A.; Cao, S.W.; Yu, J. G. Acta Phys. -Chim.Sin. 2016, 32, 2841. [赫荣安,曹少文,余家国.物理化学学报, 2016, 32, 2841.] doi: 10.3866/PKU.WHXB201611021
43	(a) Zhang, X.; Wang, X. B.; Wang, L.W.; Wang, W. K.; Long, L. L.; Li, W.W.; Yu, H. Q. ACS Appl. Mater. Interfaces 2014, 6, 7766. doi: 10.1021/am5010392
43	(b) Li, H.; Shang, J.; Ai, Z.; Zhang, L. J. Am. Chem. Soc. 2015, 137, 6393. doi: 10.1021/jacs.5b03105
44	Yu Y. ; Cao C. ; Liu H. ; Li P. ; Wei F. ; Jiang Y. ; Song W. J. Mater. Chem. A 2014, 2, 1677.
45	Li F. T. ; Wang Q. ; Ran J. ; Hao Y. J. ; Wang X. J. ; Zhao D. ; Qiao S. Z. Nanoscale 2015, 7, 1116.
46	(a) Hu, J.; Xu, G.; Wang, J.; Lv, J.; Zhang, X.; Zheng, Z.; Xie, T.; Wu, Y. New J. Chem. 2014, 38, 4913. doi: 10.1039/C4NJ00794H
46	(b) Xiong, J.; Cheng, G.; Li, G.; Qin, F.; Chen, R. RSC Adv. 2011, 1, 1542. doi: 10.1039/C1RA00335F
47	(a) Lagunas-Allué, L.; Martínez-Soria, M. T.; Sanz-Asensio, J.; Salvador, A.; Ferronato, C.; Chovelon, J. M. Appl. Catal. B 2010, 98, 122. doi: 10.1016/j.apcatb.2010.05.020
47	(b) Zhuang, J.; Tian, Q.; Zhou, H.; Liu, Q.; Liu, P.; Zhong, H. J.Mater. Chem. 2012, 22, 7036. doi: 10.1039/C2JM16924J
48	(a) Kortüm, G.; Braun, W.; Herzog, G. Angew. Chem. Int. Ed. 1963, 2, 333. doi: 10.1002/anie.196303331
48	(b) Sakthivel, S.; Kisch, H. Angew. Chem. Int. Ed. 2003, 42, 4908. doi: 10.1002/anie.200351577
49	(a) Li, G.; Long, G.; Chen, W.; Hu, F.; Chen, Y.; Zhang, Q.Asian J. Org. Chem. 2013, 2, 852. doi: i
49	(b) Cui, W.; Yuen, J.; Wudl, F. Macromolecules 2011, 44, 7869.doi: 10.1021/ma2017293
49	(c) Leclerc, N.; Michaud, A.; Sirois, K.; Morin, J. F.; Leclerc, M. Adv. Funct. Mater. 2006, 16, 1694. doi: 10.1002/adfm.200600171
50	(a) Fu, H.; Pan, C.; Yao, W.; Zhu, Y. J. Phys. Chem. B 2005, 109, 22432. doi: 10.1021/jp052995j
50	(b) Zhao, Y.; Tan, X.; Yu, T.; Wang, S. Mater. Lett. 2016, 164, 243. doi: 10.1016/j.matlet.2015.10.155
51	(a) Guo, Y. X.; Huang, H.W.; He, Y.; Tian, N.; Zhang, T. R.; Chu, P. K.; An, Q.; Zhang, Y. H. Nanoscale 2015, 7, 11702.doi: 10.1039/C5NR02246K
51	(b) Zhao, Y.; Yu, T.; Tan, X.; Xie, C.; Wang, S. Dalton Trans. 2015, 44, 20475. doi: 10.1039/C5DT03315B

[1]	Zhicong Sun, Ergui Luo, Qinglei Meng, Xian Wang, Junjie Ge, Changpeng Liu, Wei Xing. High-Performance Palladium-Based Catalyst Boosted by Thin-layered Carbon Nitride for Hydrogen Generation from Formic Acid [J]. Acta Physico-Chimica Sinica, 0, (): 2003035-0.
[2]	Xiaoqing Yang, Hualin Yang, Huan Lu, Haoxuan Ding, Yanxin Tong, Fei Rao, Xin Zhang, Qian Shen, Jianzhi Gao, Gangqiang Zhu. 2D/2D Ti₃C₂/Bi₄O₅Br₂ Nanosheet Heterojunction with Enhanced Visible Light Photocatalytic Activity for NO Removal [J]. Acta Physico-Chimica Sinica, 0, (): 2005008-0.
[3]	Jin-Liang Lin, Yamin Zhang, Hao-Li Zhang. Novel Electrostatic Effects in Single-Molecule Devices [J]. Acta Physico-Chimica Sinica, 0, (): 2005010-0.
[4]	Xinmei Ding, Yanli Liang, Hailong Zhang, Ming Zhao, Jianli Wang, Yaoqiang Chen. Preparation of Reduced Pt-Based Catalysts with High Dispersion and Their Catalytic Performances for NO Oxidation [J]. Acta Physico-Chimica Sinica, 0, (): 2005009-0.
[5]	Yujie Tang, Mo Zheng, Chunxing Ren, Xiaoxia Li, Li Guo. Visualized Reaction Tracking and Physical Property Analysis for a Picked 3D Area in a Reactive Molecular Dynamics Simulation System [J]. Acta Physico-Chimica Sinica, 0, (): 2003037-0.
[6]	Ping An, Yu Fu, Danlei Wei, Yanglong Guo, Wangcheng Zhan, Jinshui Zhang. Hollow Nitrogen-Rich Carbon Nanoworms with High Activity for Metal-Free Selective Aerobic Oxidation of Benzyl Alcohol [J]. Acta Physico-Chimica Sinica, 0, (): 2001025-0.
[7]	Sai Zhang, Mingkai Zhang, Yongquan Qu. Solid Frustrated Lewis Pairs Constructed on CeO₂ for Small-Molecule Activation [J]. Acta Physico-Chimica Sinica, 2020, 36(9): 1911050-0.
[8]	Jian Zhang, Liang Wang, Zhiyi Wu, Chengtao Wang, Zerui Su, Feng-Shou Xiao. Rational Design of a Core-Shell Rh@Zeolite Catalyst for Selective Diene Hydrogenation [J]. Acta Physico-Chimica Sinica, 2020, 36(9): 1912001-0.
[9]	Tianyi Yang, Cheng Cui, Hongpan Rong, Jiatao Zhang, Dingsheng Wang. Recent Advances in Platinum-based Intermetallic Nanocrystals: Controlled Synthesis and Electrocatalytic Applications [J]. Acta Physico-Chimica Sinica, 2020, 36(9): 2003047-0.
[10]	Chao Zhang, Sihan Li, Chenliang Wu, Xiaoqing Li, Xinhuan Yan. Preparation and Characterization of Pt@Au/Al₂O₃ Core-Shell Nanoparticles for Toluene Oxidation Reaction [J]. Acta Physico-Chimica Sinica, 2020, 36(8): 1907057-0.
[11]	Xiaoxiao Lai, Jie Feng, Xiaoying Zhou, Zhongyan Hou, Tao Lin, Yaoqiang Chen. Catalytic Oxidation of Toluene Over Potassium Modified Mn/Ce_0.65Zr_0.35O₂ Catalyst [J]. Acta Physico-Chimica Sinica, 2020, 36(8): 1905047-0.
[12]	Yimeng Wang, Shenping Zhang, Yu Ge, Chenhui Wang, Jun Hu, Honglai Liu. Highly Efficient Photocatalytic Degradation of Tetracycline Using a Bimetallic Oxide/Carbon Photocatalyst [J]. Acta Physico-Chimica Sinica, 2020, 36(8): 1905083-0.
[13]	Jiu Wang,Nanshi Wu,Tao Liu,Shaowen Cao,Jiaguo Yu. MnCo Oxides Supported on Carbon Fibers for High-Performance Supercapacitors [J]. Acta Physico-Chimica Sinica, 2020, 36(7): 1907072-0.
[14]	Yu Guiyun,Hu Fengxian,Cheng Weiwei,Han Zitong,Liu Chao,Dai Yong. ZnCuAl-LDH/Bi₂MoO₆ Nanocomposites with Improved Visible Light-Driven Photocatalytic Degradation [J]. Acta Physico-Chimica Sinica, 2020, 36(7): 1911016-0.
[15]	Liang Wang,Chenglu Zhu,Lisha Yin,Wei Huang. Construction of Pt-M (M = Co, Ni, Fe)/g-C₃N₄ Composites for Highly Efficient Photocatalytic H₂ Generation [J]. Acta Physico-Chimica Sinica, 2020, 36(7): 1907001-0.

Facile Green Synthesis of Highly Monodisperse Bismuth Subcarbonate Micropompons Self-assembled by Nanosheets: Improved Photocatalytic Performance

RichHTML

PDF (PC)

Like

Knowledge

Abstract

Supporting Info

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 0