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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(6)>> 1114-1122     doi: 10.3866/PKU.WHXB201702213         中文摘要
Design and Application of a Precise Isoperibol Combus-tion-Solution-Reaction Microcalorimeter
LI Xu1, LI Qiang-Guo1, JIANG Jian-Hong1, GU Hui-Wen2, LI Chuan-Hua1, XIAO Sheng-Xiong1, LI Xia1
1 College of Chemistry Biology and Environmental Engineering, Xiangnan University, Chenzhou 423043, P. R. China;
2 College of Chemistry and Environmental Engineering, Yangtze University, Jingzhou 434023, P. R. China
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The SRC-100 type solution-reaction calorimeter was improved to a more precise and versatile isoperibol combustion-solution-reaction microcalorimeter. The energy equivalent of the calorimeter was calibrated to be Ccalor=(987.63±0.61)J·K-1 by the electric calibration method. The standard massic energy of combustion of benzoic acid and succinic acid were determined by the developed isoperibol combustion-solution-reaction microcalorimeter as △CUm,Bθ(cr,T=298.15K)=-(26425.99±10.70)J·g-1 and △CUm,Sθ(cr,T=298.15K)=-(12621.97±5.30)J·g-1, respec-tively. The uncertainty of the measurement was less than 0.04% and the accuracy was higher than 0.05%.



Keywords: Combustion-solution-reaction microcalorimeter   Standard massic energy of combustion   Benzoic acid   Succinic acid  
Received: 2016-12-26 Accepted: 2017-02-20 Publication Date (Web): 2017-02-21
Corresponding Authors: LI Qiang-Guo, GU Hui-Wen Email: liqiangguo@163.com;gugo@yangtzeu.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (21273190) and Science and Technology Plan Projects of Hunan Province, China (2014TT2026).

Cite this article: LI Xu, LI Qiang-Guo, JIANG Jian-Hong, GU Hui-Wen, LI Chuan-Hua, XIAO Sheng-Xiong, LI Xia. Design and Application of a Precise Isoperibol Combus-tion-Solution-Reaction Microcalorimeter[J]. Acta Phys. -Chim. Sin., 2017,33 (6): 1114-1122.    doi: 10.3866/PKU.WHXB201702213

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