ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(6)>> 1205-1213     doi: 10.3866/PKU.WHXB201702222         中文摘要
Redox-Responsive Interfacial Properties of Se-Containing Sulfobetaine Surfactant
KONG Wei-Wei, GUO Shuang, ZHANG Yong-Min, LIU Xue-Feng
School of Chemical & Materials Engineering, Key Laboratory of Food Colloids and Biotechnology Ministry of Education, Jiangnan University, Wuxi 214122, Jiangsu Province, P. R. China
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Because of good biocompatibility using Se atom as the redox-responsive group has aroused considerable attention. However, only a few efforts have been devoted to Se-containing surfactant, especially for smart control of interfacial properties. This paper focuses on the redox-responsive behaviors of molecular structure, Krafft temperature, Surface/interfacial tension, foaming and emulsification of Se-containing zwitterionic surfactant, benzylselanyl-undecyl-dimethyl ammonium propane sulfonate (BSeUSB). The results show that after oxidization with a trace of H2O2 (≤0.056% of total mass), reduced form BSeUSB with one hydrophilic head and one hydrophobic tail transformed to Bola-type oxidized form BSeUSB-Ox due to the presence of a new hydrophilic group (selenoxide). And thus Krafft temperature decreased from (23.5±0.5)℃ to less than 0℃. The surface/interfacial tension at 5.00 mmol·L-1 increased from 45.15, 5.52 mN·m-1 to 61.63, 18.38 mN·m-1, respectively. Macroscopically, reduced form BSeUSB has good foaming and emulsification properties, while the foaming and emulsification abilities of oxidized form BSeUSB-Ox almost disappeared. Interestingly the molecular structure and the solution properties re-turned the initial states after reduction with a trace of Na2SO3 (≤0.060% of total mass). In a word, by the addition trace amounts of H2O2 and Na2SO3 alternately, we have achieved the smart control of the interfacial properties of the surfactant.

Keywords: Redox-responsive   Se-containing surfactant   Betaine   Interfacial property   Foam   Emulsion  
Received: 2016-12-27 Accepted: 2017-02-22 Publication Date (Web): 2017-02-22
Corresponding Authors: ZHANG Yong-Min, LIU Xue-Feng Email:;

Fund: The project was supported by the National Natural Science Foundation of China (21503094, 21673103), MOE & SAFEA for the 111 Project (B13025), Fundamental Research Funds for the Central Universities, China (JUSRP 51507), Natural Science Foundation of Jiangsu Province, China (BK20150128) and Qinglan Project of Jiangsu Province, China.

Cite this article: KONG Wei-Wei, GUO Shuang, ZHANG Yong-Min, LIU Xue-Feng. Redox-Responsive Interfacial Properties of Se-Containing Sulfobetaine Surfactant[J]. Acta Phys. -Chim. Sin., 2017,33 (6): 1205-1213.    doi: 10.3866/PKU.WHXB201702222

(1) Liu, Y. X.; Jessop, P. G.; Cunningham, M.; Eckert, C. A.; Liotta, C. L. Science 2006, 313, 958. doi: 10.1126/science.1128142
(2) Zhang, Y.; Zhang, Y.; Wang, C.; Liu, X.; Fang, Y.; Feng, Y. Green Chem. 2016, 18 (2), 392. doi: 10.1039/C5GC01411E
(3) Zhang, Y.; Kong, W.; An, P.; He, S.; Liu, X. Langmuir 2016, 32 (10), 2311. doi: 10.1021/acs.langmuir.5b04459
(4) Wu, J.; Xu, Y.; Dabros. T.; Hamza, H. Energy Fuels 2003, 17 (6), 1554. doi: 10.1021/ef030113e
(5) Feng, X.; Mussone, P.; Gao, S.; Wang, S.; Wu, S.Y.; Masliyah, J. H.; Xu, Z. Langmuir 2010, 26 (5), 3050. doi: 10.1021/la9029563
(6) Lin, C.; He, G.; Dong, C.; Liu, H.; Xiao, G.; Liu, Y. Langmuir 2008, 24 (10), 5291. doi: 10.1021/la704079s
(7) Krebs, T.; Schroën, C. G. P. H.; Boom, R. M. Chem. Eng. Sci. 2012, 71, 118. doi: 10.1016/j.ces.2011.10.057
(8) Zhang, Y.; Han, Y.; Chu, Z.; He, S.; Zhang, J.; Feng, Y. J. Colloid Interface Sci. 2013, 394, 319. doi: 10.1016/j.jcis.2012.11.032
(9) Takahashi, Y.; Koizumi, N.; Kondo, Y. Langmuir 2016, 32 (3), 683. doi: 10.1021/acs.langmuir.5b03912
(10) Brown, P.; Butts, C. P.; Cheng, J.; Eastoe, J.; Russell, C. A.; Smith, G. N. Soft Matter 2012, 8 (29), 7545. doi: 10.1039/C2SM26077H
(11) Zhang, Y.; Feng, Y.; Wang, J.; He, S.; Guo, Z.; Chu, Z.; Dreiss, C. A. Chem. Commun. 2013, 49 (43), 4902. doi: 10.1039/C3CC41059E
(12) Tsuchiya, K.; Orihara, Y.; Kondo, Y.; Yoshino, N.; Ohkubo, T.; Sakai, H.; Abe, M. J. Am. Chem. Soc. 2004, 126 (39), 12282. doi: 10.1021/ja0467162
(13) Fan, H.; Han, F.; Liu, Z.; Qin, L.; Li, Z.; Liang, D.; Ke, F.; Huang, J.; Fu, H. J. Colloid Interface Sci. 2008, 321 (1), 227. doi: 10.1016/j.jcis.2008.01.039
(14) Xu, H. B. Biological trace elements-selenium; Huazhong institute of technology press: Wuhan, 1984:104. [徐辉碧. 生物微量元素—硒. 华中工学院出版社:武汉,1984: 104.]
(15) Combs, G. F. Jr. West.J. Med. 1990, 153 (2), 192.
(16) Ip, C.; Hayes, C.; Budnick, R. M.; Ganther, H. E. Cancer Res. 1991, 51 (2), 595.
(17) Zhang, Y.; Yang, C.; Guo, S.; Chen, H.; Liu, X. Chem. Commun. 2016, 52 (86), 12717. doi: 10.1039/C6CC06699B
(18) Tan, X.; Yu, Y.; Liu, K.; Xu, H.; Liu, D.; Wang, Z.; Zhang, X. Langmuir 2012, 28 (25), 9601. doi: 10.1021/la301703t
(19) Wang, L.; Cao, W.; Yi, Y.; Xu, H. Langmuir 2014, 30 (19), 5628. doi: 10.1021/la501054z
(20) Xu, H.; Cao, W.; Zhang, X. Acc. Chem. Res. 2013, 46 (7), 1647. doi: 10.1021/ar4000339
(21) Wang, Y.; Xu, H.; Ma, N.; Wang, Z.; Zhang, X.; Liu, J.; Shen, J. Langmuir 2006, 22 (13), 5552. doi: 10.1021/la060711w
(22) Zhang, Y.; Kong, W.; Wang, C.; An, P.; Fang, Y.; Feng, Y.; Qin, Z.; Liu, X. Soft Matter 2015, 11 (38), 7469. doi: 10.1039/C5SM01515D
(23) Vermather, M.; Stiles, P.; Bachofer, S. J.; Simonis, U. Langmuir 2002, 18 (4), 1030. doi: 10.1021/la0109765
(24) Lin, Y.; Qiao, Y.; Yan, Y.; Huang, J. Soft Matter 2009, 5 (16), 3047. doi: 10.1039/B906960G
(25) Sköld, R. O.; Tunius, M. A. R. J. Colloid Interface Sci. 1992, 152 (1), 183. doi: 10.1016/0021-9797(92)90018-H
(26) Gallardo, B. S.; Hwa, M. J.; Abbott, N. L. Langmuir 1995, 11 (11), 4209. doi: 10.1021/la00011a008
(27) Szymanowski, J.; Szewczyk, H.; Hetper, J. Tenside Deterg. 1981, 18, 333.
(28) W. Kong, S. Guo, S. Wu, X. Liu and Y. Zhang, Langmuir 2016, 32 (38), 9846. doi: 10.1021/acs.langmuir.6b02616
(29) Brown, P.; Butts, C. P.; Eastoe, J. Soft Matter 2013, 9 (8), 2365. doi: 10.1039/C3SM27716J
(30) Rosen, M. J.; Kunjappu, J. T. Surfactants and Interfacial Phenomena, 4th ed.; John Wiley & Son: Hoboken, NJ, 2012.

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2. SUN Xiao-Xiang, CHEN Yu, ZHAO Jian-Xi.Foams Stabilized by Fumed Silica Particles with a Quaternary Ammonium Gemini Surfactant[J]. Acta Phys. -Chim. Sin., 2016,32(8): 2045-2051
3. WU Wei, LIU Dan-Dan, XU Zhi-Cheng, GONG Qing-Tao, HUANG Jian-Bin, ZHANG Lei, ZHANG Lu.Adsorption and Wettability of Branched Betaine and Cationic Surfactants on a Poly(methyl methacrylate) Surface[J]. Acta Phys. -Chim. Sin., 2016,32(5): 1214-1220
4. CHEN Fang, CHEN Zhu-Guo, SUN Hui-Zhao, MENG Fan-Xiang, MA Xiao-Yan.Anion Effect on the Tunable Stability of a Thermoresponsive Pickering Emulsion Based on SiO2-PNIPAM[J]. Acta Phys. -Chim. Sin., 2016,32(3): 763-770
5. LIN You-Cheng, ZHONG Xin-Xian, HUANG Han-Xing, WANG Hong-Qiang, FENG Qi-Peng, LI Qing-Yu.Preparation and Application of Polyaniline Doped with Different Sulfonic Acids for Supercapacitor[J]. Acta Phys. -Chim. Sin., 2016,32(2): 474-480
6. LIANG Mei-Qing, YIN Hong-Yao, FENG Yu-Jun.Smart Aqueous Foams: State of the Art[J]. Acta Phys. -Chim. Sin., 2016,32(11): 2652-2662
7. CHEN Xiang, PAN Jian-Ming, YAN Yong-Sheng.Adsorption of λ-Cyhalothrin onto Macroporous Polymer Foams Derived from Pickering High Internal Phase Emulsions Stabilized by Halloysite Nanotube Nanoparticles[J]. Acta Phys. -Chim. Sin., 2016,32(11): 2794-2802
8. ZHU Qing-Gong, SUN Xiao-Fu, KANG Xin-Chen, MA Jun, QIAN Qing-Li, HAN Bu-Xing.Cu2S on Cu Foam as Highly Efficient Electrocatalyst for Reduction of CO2 to Formic Acid[J]. Acta Phys. -Chim. Sin., 2016,32(1): 261-266
9. ZHANG Qiao-Ling, LI Lei, LIU You-Zhi, WEI Bing, GUO Jia-Xin, FENG Yu-Jie.Grafting Dynamics, Structures and Properties of Nano TiO2-SA Photocatalytic Materials[J]. Acta Phys. -Chim. Sin., 2015,31(6): 1015-1024
10. SONG Bing-Lei, ZHAI Zhao-Lan, ZHAO Jian-Xi, SUN Guo-Jing.Interfacial Adsorption, Dilational Visco-Elasticity and Foam Stability in a Mixed System of Gemini Surfactant/C12En[J]. Acta Phys. -Chim. Sin., 2015,31(12): 2324-2331
11. XU Wen-Li, CHEN Qing-De, SHEN Xing-Hai.Synthesis of BaSO4 Nanofibers Controlled by the Yield of Hydrated Electrons in AOT-Based Microemulsions[J]. Acta Phys. -Chim. Sin., 2014,30(6): 1194-1200
12. FENG Xing-Xing, XIE Jing, HU Geng-Shen, JIA Ai-Ping, XIE Guan-Qun, LUO Meng-Fei.Preparation of Pentaethylenehexamine-Functionalized Mesocellular Silica Foams and Their Application for CO2 Adsorption[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1266-1272
13. HAN Ying, ZHU Lu, SHEN Ming, LI Heng-Heng.Synthesis of a Novel Surfactant with Two Alkyl Tail-Chains (DDOBA) and Fabrication of Hydrophobic Gold Nanoparticles with High Monodispersity[J]. Acta Phys. -Chim. Sin., 2013,29(01): 131-138
14. WU Xiao-Na, ZOU Wen-Sheng, ZHAO Jian-Xi.Highly Stable Foams Generated by the Gemini Surfactant Ethanediyl-α,ω-bis(tetradecyldimethylammonium bromide)[J]. Acta Phys. -Chim. Sin., 2012,28(05): 1213-1217
15. LIANG Xiao-Fei, HU Jing-Ying, CHEN Fu-Hua, LI Zong-Hai, CHANG Jin.Characterization of Chitosan Polymeric Ethosomes Capable of Encapsulating Hydrophobic and Hydrophilic Drugs Prepared by a Microemulsion Method[J]. Acta Phys. -Chim. Sin., 2012,28(04): 897-902
16. ZHOU Dan, YU Wen, XU Qin-Qin, YIN Jian-Zhong.Solubilization of Polyalcohol in Supercritical CO2 Microemulsion[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1300-1304
17. PENG Xu-Hong, ZHENG Pei-Zhu, MA Yuan-Ming, YIN Tian-Xiang, AN Xue-Qin, SHEN Wei-Guo.The Second Virial Coefficient and Droplet Interaction of AOT/Water/Toluene Microemulsion[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1026-1030
18. YU Li-Qiu, CHEN Shu-Li, CHANG Sha, LI Yun-Hu, GAO Yin-Yi, WANG Gui-Ling CAO Dian-Xue.Supercapacitance of NiCo2O4 Nanowire Arrays Grown on Nickel Foam[J]. Acta Phys. -Chim. Sin., 2011,27(03): 615-619
19. JIN Shu-Ping, FENG Lei, HE Wen-Yan, HAN Yu-Qi, WEI Yu-Juan.Preparation and Release Behavior in vitro of Aspirin/Chitosan Nanospheres by Nucleation and Ionic Crosslinking in Emulsion[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2581-2588
20. ZHU Wen-Qing, XU Lei, MA Jin, REN Jian-Mei, CHEN Ya-Shao.Size Controlled Synthesis of CeO2 Nanoparticles by a Microemulsion Method[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1284-1290
21. LIU Xiang-Zhi, PIAO Ling-Yu, MAO Li-Juan, HAO Shi-Jie, YANG Lei, JU Si-Ting.Preparation of High Specific Surface Area Nano-Alumina by Vacuum Freeze Drying[J]. Acta Phys. -Chim. Sin., 2010,26(04): 1171-1176
22. MA Li, LI Xiao-Feng, GAN Meng-Yu, LIU Xing-Min, LUO Lai-Zheng, SU Wen-Yi, LIU Yan.Magnetic Field Effects on the Phase Behavior of a Microemulsion System during Aniline Polymerization[J]. Acta Phys. -Chim. Sin., 2010,26(03): 541-546
23. ZHANG Xiao-Guang, LIU Jie-Xiang, WANG Hai-Ying, WANG Man-Yi, FAN Zhi-Jin.Stability of Avermyctin Emulsion in Water[J]. Acta Phys. -Chim. Sin., 2010,26(03): 617-625
24. YU Tao, LI Zhong, DING Wei, LUO Shi-Qiong, LUAN Huo-Xin, TONG Wei, QU Guang-Miao, CHENG Jie-Cheng.Molecular Organized Assemblies Formed by Tetradecyl Aryl Sulfonate[J]. Acta Phys. -Chim. Sin., 2010,26(02): 317-323
25. PIAO Ling-Yu, LIU Xiang-Zhi, MAO Li-Juan, JU Si-Ting.Preparation of Nano-Alumina by Reverse Microemulsion Method[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2232-2236
26. LI Fen, XU Xian-Zhi, SONG Hui, XIONG Jin, WU Fei.Impact of Polytetrafluoroethylene Emulsion Binder Pretreatment with Ethanol on the Performance of Gas Diffusion Electrodes[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2205-2210
27. WANG Run-Han, JIANG Ji-Sen, HU Ming.Controlled Syntheses of FeNi3 Alloy Nanostructures via Reverse Microemulsion-Directed Hydrothermal Motheds[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2167-2172
28. LI Zhen-Quan, ZHANG Lei, YAN Feng, ZHANG Lu, ZHAO Sui, YU Jia-Yong.Surface Dilational Properties of N-Acyltaurate Amphiphiles with Aromatic Side Chains[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1939-1944
29. CAI Hong-Lan, AN Xue-Qin, ZHU Yin-Yan, LV Hui-Hong, SHEN Wei-Guo.Effects of DMA/AOT Molar Ratio on Critical Behavior of Nonaqueous Microemulsion[J]. Acta Phys. -Chim. Sin., 2009,25(05): 911-914
30. LU Xia; TANG Jing; FAN Yu-Bing; HU Jun; LIU Hong-Lai.Synthesis of Mesoporous Polystyrene Using Reversed Microemulsion Template Method[J]. Acta Phys. -Chim. Sin., 2009,25(01): 178-182
31. ZHANG Liang-Miao, LU Wen-Cong, FENG Yong-Li, NI Ji-Peng, LV Yong, SHANG Xing-Fu.Facile Synthesis of Leaf-like Cu(OH)2 and Its Conversion into CuO with Nanopores[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2257-2262
32. ZHENG Yong-Jun; ELI Wumanjiang.Phase Behavior of Tween80/BmimPF6/Alcohol/Toluene Systems[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2143-2148
33. GENG Shou-Hua; ZHU Wen-Qing; CHANG Peng-Mei; CHEN Ya-Shao.Preparation of Sm2O3 Nanoparticles in the Media of Reverse Microemulsions[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1609-1614
34. YE Xiang-Guo; ZHANG Xiao-Gang; MI Hong-Yu; YANG Su-Dong.Hydrothermal Microemulsion Synthesis of Co3O4 with Different Morphologies and Their Electrochemical Capacitance[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1105-1110
35. ZHOU Yong-Hua; YE Hong-Qi.Deposition of Pd Nano-Particles in W/O Microemulsion by Chemical Demulsifying[J]. Acta Phys. -Chim. Sin., 2008,24(03): 487-491
36. ZHU Chen-Hua; SHEN He-Bai; XU Rui-Yun; WANG Hao-Yue; HAN Ji-Mei.The Adsorption of Bovine Serum Albumin onto Magnetic Chitosan Microspheres[J]. Acta Phys. -Chim. Sin., 2007,23(10): 1583-1588
37. FAN Xiao-Yong; ZHUANG Quan-Chao; JIANG Hong-Hong; HUANG Ling; DONG Quan-Feng; SUN Shi-Gang.Three-dimensional Porous Cu6Sn5 Alloy Anodes for Lithium-ion Batteries[J]. Acta Phys. -Chim. Sin., 2007,23(07): 973-977
38. LIU Hong-Jing; HE Gao-Hong; LIN Chang; ZHAO Wei; XIAO Gong-Kui.Controlling Water Transport in W/O/W Multiple Emulsion[J]. Acta Phys. -Chim. Sin., 2007,23(06): 935-939
39. CAI Hong-Lan; AN Xue-Qin; SHEN Wei-Guo.Critical Phenomena of Three-component Nonaqueous Microemulsion Systemof DMA+AOT+n-octane[J]. Acta Phys. -Chim. Sin., 2007,23(06): 921-925
40. ZENG Wei; ZHOU Hai-Hui; YING Xiao-Fang; ZENG Qing-Liang; HU Wei-Ya; KUANG Ya-Fei.Electrodeposition of Gold Nanoparticles Coatings from Electrode/ReverseMicroemulsion System[J]. Acta Phys. -Chim. Sin., 2007,23(05): 769-773
41. HE Yong-Jun; YU Xiang-Yang; ZHAO Xiao-Ling.Surface Modification and Assembly of Cu2(OH)2CO3 Microspheres[J]. Acta Phys. -Chim. Sin., 2007,23(05): 774-778
42. GUO Wen-Jing;SUN Lei;ZHANG Ping-Yu;WU Zhi-Shen;ZHANG Zhi-Jun.Preparation and Antiwear Property of Monodisperse Silver Nanoparticles in Microemulsion[J]. Acta Phys. -Chim. Sin., 2007,23(03): 367-372
43. PENG Chun-Yu;ZHOU Hai-Hui;ZENG Wei;JIAO Shu-Qiang;LUO Sheng-Lian;KUANG Ya-Fei.Studies on the Conductivity of Reverse Microemulsion[J]. Acta Phys. -Chim. Sin., 2006,22(04): 409-413
44. ZHAO Hui;LU Fu-Sui;LI Pei-Qiang.Effect of Different Factors on Phase Behavior in Cyhalothrin Microemulsion[J]. Acta Phys. -Chim. Sin., 2006,22(04): 475-480
45. ZHANG Xiao-guang; DONG Jin-feng; ZHANG Gao-yong; ZHOU Xiao-hai; HONG Xinlin.The Effect of Organic Salts on the Conductance of the Water/AOT/Alkanol W/O Microemulsion[J]. Acta Phys. -Chim. Sin., 2006,22(01): 22-27
46. PENG Jing; ZHU Yi-cai; ZHAI Mao-lin; QIAO JIN-liang; WEIG en-shuan.Influence of OH Radicals on the Radiation Effect of Polydimethylsiloxane Latex[J]. Acta Phys. -Chim. Sin., 2005,21(08): 873-877
47. LU Yang-Yan;XIA Qiang;XIA Yong;MA Quan-Hong;GU Ning.Studies on the Phase Behaviors of Drug-loading Microemulsions[J]. Acta Phys. -Chim. Sin., 2005,21(01): 98-101
48. LIU Yan;GUO Xia;GUO Rong.Interaction between N, N-diethylaniline and SDS/n-C5H11OH/H2O Microemulsion[J]. Acta Phys. -Chim. Sin., 2005,21(01): 38-41
49. Chen Wei-Ping;Feng Xin;Wang Chang-Song;Sun Sheng-Hua;Lu Xiao-Hua.The Interface Properties of Potassium Titanate Whiskers[J]. Acta Phys. -Chim. Sin., 2004,20(08): 868-870
50. Duan Chun-Ying;Zhou Jing-Fang;Wu Zhi-Shen;Dang Hong-Xin.Preparation and Characterization of the Polystyrene/silver Core-shell Structure Nanospheres[J]. Acta Phys. -Chim. Sin., 2003,19(11): 1049-1053
51. Luo Shi-Zhong;Zhang Feng-Mei;Tang Ye-Cang;Fu Zhong;Sun Yi-Min.The Constitution,Monodispersity and Stability of the Soapless Macromolecule Particles[J]. Acta Phys. -Chim. Sin., 2003,19(08): 774-778
52. Guo Xia;Xu Hui;Guo Rong.The Fluorescence Quenching of Anthracene by Phenothiazine in Sodium Dodecyl Sulfate / Benzyl Alcohol / Water Microemulsion[J]. Acta Phys. -Chim. Sin., 2002,18(06): 500-503
53. Hu Wei;Ye Ru-Qiang;Wu Shu-Sen;Liu Hong-Lai.Influence of Alcohol on the Properties of Colloidal Liquid Aphrons[J]. Acta Phys. -Chim. Sin., 2002,18(02): 122-126
54. Zhang Zhi-Qing;Xu Gui-Ying;Ye Fan;Zheng Li-Qiang;Luan Yu-Xia.Surface Activity of Mixed System of Dodecyl Betaine and Sodium Dodecyl Sulphate[J]. Acta Phys. -Chim. Sin., 2001,17(12): 1122-1125
55. Guo Xia;Liu Yan;Guo Rong.The Location of Phenothiazine in SDS/BA/H2O Microemulsion[J]. Acta Phys. -Chim. Sin., 2001,17(11): 982-985
56. Ding Wen;Fan Zhi-Kang;Xu Chuan-Xiang;Lu Feng-Ji.Metal Core/Polymer Coating Compounded Suspension for Electrorheologic Fluid[J]. Acta Phys. -Chim. Sin., 2001,17(06): 496-500
57. Wang Gui-Qing;Chen Qiao-Yun;Li Rong-Xi;Luo Qi-Zhi.Solubization of Microemulsion of Naphthenic Acid Saponified by NH3•H2O and Theory of Cohesive Energies[J]. Acta Phys. -Chim. Sin., 2001,17(06): 560-564
58. Li Peng;An Xue-Qin;Shen Wei-Guo.Density, Turbidity and Microscopic Structure of AOT/H2O/oil Microemulsions[J]. Acta Phys. -Chim. Sin., 2001,17(02): 144-149
59. Xu Gui-Ying;Zhang Li;Mao Hong-Zhi;Bao Meng;Lu Yan.The State of Solubilized Water in W/O Microemulsions in the Presence of[J]. Acta Phys. -Chim. Sin., 2001,17(01): 37-42
60. Zhao Yan-Bao, Zhou Jing-Fang, Lv Ying, Zhang Zhi-Jun, Dang Hong-Xin.Preparation and Characterization of PS/TiO2 Composite Nanospheres[J]. Acta Phys. -Chim. Sin., 2000,16(11): 1035-1038
61. Wang Gui-Ping, Chen Qiao-Yun, Li Rong-Xi, Zeng Ping.Physico-chemical Properties of Microemulsion of 2-ethylhexylphosphonic Acid Mono 2-ethylhexyl Ester Saponified by Sodium Hydroxide[J]. Acta Phys. -Chim. Sin., 2000,16(10): 936-940
62. Chen Yong-Mei, Wang Han-Hui, Yu Jia-Yong.Study of Middle Phase Microemulsion Formed by Petroleum Sulfonate[J]. Acta Phys. -Chim. Sin., 2000,16(08): 724-728
63. Guo Rong, Yu Wei-Li, Zhang Xiao-Hong.Effect of VC on the Phase Behavior of Surfactant System[J]. Acta Phys. -Chim. Sin., 2000,16(04): 325-330
64. Zhang Wen-Min, Wu Qi, Wei Tao, Liu Zhan-Hua.Preparation of High Content Surfactant-free Narrowly Distributed Macromolecule Nanoparticle Latex[J]. Acta Phys. -Chim. Sin., 2000,16(02): 116-120
65. Zeng Hong-Xia, Li Zhi-Ping, Wang Min, Wang Han-Qing.Structure Study of Liquid Crystal in Sodium Dodecylsulfonate Middle Phase Microemulsion[J]. Acta Phys. -Chim. Sin., 2000,16(01): 60-64
66. Qian Jun-Hong, Zhang Xiao-Hong, Guo Rong.Inhibition of Microemulsion of CTAB/n-C5H11OH/H2O System on the Hydrolysis of Penicillin-G Potassium[J]. Acta Phys. -Chim. Sin., 2000,16(01): 80-86
67. Zhai Mu-Heng, Zhang Wen-Min, Sheng En-Hong, Fu Zhong, Zhang Feng.Preparation of Monodispersed Macromolecule Microspheres by Microwve Irradiation and Research on the Mechanism of Its Formation[J]. Acta Phys. -Chim. Sin., 1999,15(08): 747-751
68. Zeng Hong-Xia, Li Zhi-Ping, Wang Han-Qing.Physical Chemistry Property of Water/TX-100/Hexanol/Octane Reverse Microemulsion[J]. Acta Phys. -Chim. Sin., 1999,15(06): 522-527
69. Guo Rong, Zhang Xiao-Hong, Liu Tian-Qing.Phase Behavior and Phase Structure of lgepal CO 520/CnH2n+1OH/H2O System[J]. Acta Phys. -Chim. Sin., 1999,15(04): 319-326
70. Guo Rong, Shen Ming, Liu Tian-Qing.Thermodynamical and Electrochemical Properties of CTAB/CnH2n+1OH/H2O[J]. Acta Phys. -Chim. Sin., 1999,15(03): 269-273
71. Shen Qiang, Li Gan-Zuo, Huang Yan-Zhang, Ye Jian-Ping.The Influence of Alcohol on the Aggregation Behavior of DDAHPS Molecules in Water[J]. Acta Phys. -Chim. Sin., 1999,15(03): 216-221
72. Shi Shuo, Wang Tao-Tao, Lu Run-Hua, Wang Han-Qing.The Bicontinuous Structures of Middle-phase Microemulsions of the SDBS/n-C4OH/n-C8H18//brine System[J]. Acta Phys. -Chim. Sin., 1999,15(01): 73-77
73. Li Yan, Li Quan, Zhou Wei-Jin, Wu Jin-Guang.Spectroscopic Properties of Potassium Saponified HEHPEHE and the Formation of w/o Microemulsions[J]. Acta Phys. -Chim. Sin., 1998,14(09): 794-798
74. Gan Li-Hua, Yue Tian-Yi, Chen Long-Wu, Li Guang-Ming, Zhu Da-Zhang, Zhou En-Xuan.Studies on the Preparation of Cupric Oxalate Uniform Colloidal Particles by the Method of Microemulsion Reaction[J]. Acta Phys. -Chim. Sin., 1998,14(02): 97-102
75. Li Quan,Li Wei-Hong,Weng Shi-Fu,Wu Jin-Guang,Xu Guang-Xian.FT-IR Study of Water Structure in Water/AOT/n-Heptane Microemulsion System[J]. Acta Phys. -Chim. Sin., 1997,13(05): 438-444
76. Liu Tian-Qing,Guo Rong,Yu Wei-Li,Shen Ming.Diffusion Coefficient and Structure Properties of SDS/BA/H2O System[J]. Acta Phys. -Chim. Sin., 1997,13(05): 401-406
77. Shen Ming,Liu Tian-Qing,Guo Rong.The Phase Behavior and Structure of SDS/BA/H2O System[J]. Acta Phys. -Chim. Sin., 1996,12(10): 885-891
78. Song Gen-Ping,Guo-Rong,Yan Peng-Quan.Preparation of Fine Particles of Polyaniline in O/W Microemulsion[J]. Acta Phys. -Chim. Sin., 1996,12(09): 812-815
79. Zhou Qing-Ye,Li Han,Zhang Bang-Hua,Song Mou-Dao,He Bing-Lin.Synthesis and Rheology of Polyurethane Latex[J]. Acta Phys. -Chim. Sin., 1996,12(08): 751-754
80. Li Gan-Zuo,Hao Jing-Cheng,Li Fang,Liu Shang Ying,Wang Han-Qing.The Formation and Characteristics of Middle Phase Microemulsions in Cationic Surfactant Systems[J]. Acta Phys. -Chim. Sin., 1995,11(06): 553-557
81. Chen Long-Wu, Gan Li-Hua, Yue Tian-Yi, Jiang Ji-Sen, Yang Xie-Long.Studies on the Pareparation of α-Fe2O3 Ultrafine Particles by Microemulsion Reaction Method[J]. Acta Phys. -Chim. Sin., 1994,10(08): 750-754
82. Shen Xing-Hai, Wang Wen-Qing, Wang Shuang, Li Gai-Ling, Gao Hong-Cheng.The Structural Parameters of P507(K)-alcohol-heptane-water Microemulsions[J]. Acta Phys. -Chim. Sin., 1994,10(07): 585-590
83. Yan Peng-Quan , Guo Rong, Liu Zheng-Ming, Zhu Xia-Shi, Shen Ming.Microemulsion and Lyotropic Liquid Crystal of Triton X-100/C10H21OH/H2O System[J]. Acta Phys. -Chim. Sin., 1994,10(05): 468-471
84. Hao Ce; Sun Zhi-Gang; Chen Zong-Qi; Shi Cai-Yun.Effect of the Length of Alkane Skeleton on the Thermodynamic Function of Microemulsion with Nonionic Surfactant[J]. Acta Phys. -Chim. Sin., 1993,9(02): 229-232
85. Yan Peng-Quan; Guo Rong; Zhu Xia-Shi; Shen Ming.Microemulsion and Lamellar Liquid Crystal of CTMAB-C5H11OH-H2O System and Their Solubilization[J]. Acta Phys. -Chim. Sin., 1992,8(05): 690-693
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