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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(6)>> 1123-1129     doi: 10.3866/PKU.WHXB201703301         中文摘要
Preparation and Performance of Supported Bimetallic Catalysts for Hydrogen Production from Ammonia Decomposition by Plasma Catalysis
SUN Shuai-Qi1, YI Yan-Hui1, WANG Li1, ZHANG Jia-Liang2, GUO Hong-Chen1
1 State Key Laboratory of Fine Chemicals, Department of Catalytic Chemistry and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China;
2 School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China
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Bimetallic Fe-Co, Fe-Ni, Mo-Co, and Mo-Ni catalysts, with total metal contents of 10 wt% and bimetallic molar ratios of 1:1, were prepared by the incipient wetness impregnation method and their activities for ammonia decomposition in the presence of plasma were studied. The Fe-Ni bimetallic catalyst exhibited a better synergistic effect than the other three bimetallic catalysts. The effect of the Fe/Ni molar ratio on its catalytic activity was also investigated. A 6:4 Fe/Ni molar ratio resulted in the highest ammonia decomposition activity and stability. The catalysts were characterized by N2 adsorption-desorption, XRD, H2-TPR, and HRTEM. The characterization results indicated that NiFe2O4 with a spinel structure was formed in the optimal Fe-Ni bimetallic catalysts and this structure favors the reduction of Fe and Ni. In other words, it is easy to achieve the metallic state of active components for the Fe-Ni bimetallic catalysts, which could be the reason for the high catalytic activity of bimetallic catalysts for NH3 decomposition.



Keywords: Plasma   Fe-Ni   Bimetallic catalysts   Ammonia decomposition   Hydrogen  
Received: 2017-02-28 Accepted: 2017-03-27 Publication Date (Web): 2017-03-30
Corresponding Authors: GUO Hong-Chen Email: hongchenguo@163.com

Fund: The project was supported by the National Natural Science Foundation of China (20473016, 20673018)

Cite this article: SUN Shuai-Qi, YI Yan-Hui, WANG Li, ZHANG Jia-Liang, GUO Hong-Chen. Preparation and Performance of Supported Bimetallic Catalysts for Hydrogen Production from Ammonia Decomposition by Plasma Catalysis[J]. Acta Phys. -Chim. Sin., 2017,33 (6): 1123-1129.    doi: 10.3866/PKU.WHXB201703301

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85. Li Wen-Ying; Huang Rong-Bin; Zhuang Ma-Zhan; Zheng Lan-Sun.Analysis and Comparison of Laser-Plasma Mass Spectra of Anthracene and Phenanthrene[J]. Acta Phys. -Chim. Sin., 1992,8(03): 410-412
86. Huang Rong-Bin; Zhang Peng; Su Zhao-Hui; Su Jian-Rui; Zheng Lan-Sun.Mass Specmetry of Linear CnB- Generated With Laser Vaporization[J]. Acta Phys. -Chim. Sin., 1992,8(02): 145-147
87. Huang Rong-Bin; Zhang Peng; Zhu Yong-Bao; Zheng Lan-Sun.Mass Spectrometry of Niobium and Sulfur Mixed Cluster Ions Generated in Laser Plasma[J]. Acta Phys. -Chim. Sin., 1992,8(01): 8-9
88. Gong Xiao-Yi; Huang Yu-Hui; Cong Guang-Min.The Effect of Plasma Treatment of Mica Powder on its Surface Characteristics and Interface Behavior with Linear Macromolecules[J]. Acta Phys. -Chim. Sin., 1991,7(05): 605-608
89. Zhang Peng; Huang Rong-Bin; Li Wen-Ying; Su Jian-Rui; Zheng Lan-Sun.Mass Spectrometry of Laser Generated Negative InP Cluster Ions[J]. Acta Phys. -Chim. Sin., 1991,7(04): 394-395
90. CHEN Xiao-Yu, WANG Jing-Dong, YU An-Chi.Effect of Surrounding Media on Ultrafast Plasmon Dynamics of Gold Nanoparticles[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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