ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(6)>> 1123-1129     doi: 10.3866/PKU.WHXB201703301         中文摘要
Preparation and Performance of Supported Bimetallic Catalysts for Hydrogen Production from Ammonia Decomposition by Plasma Catalysis
SUN Shuai-Qi1, YI Yan-Hui1, WANG Li1, ZHANG Jia-Liang2, GUO Hong-Chen1
1 State Key Laboratory of Fine Chemicals, Department of Catalytic Chemistry and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China;
2 School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China
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Bimetallic Fe-Co, Fe-Ni, Mo-Co, and Mo-Ni catalysts, with total metal contents of 10 wt% and bimetallic molar ratios of 1:1, were prepared by the incipient wetness impregnation method and their activities for ammonia decomposition in the presence of plasma were studied. The Fe-Ni bimetallic catalyst exhibited a better synergistic effect than the other three bimetallic catalysts. The effect of the Fe/Ni molar ratio on its catalytic activity was also investigated. A 6:4 Fe/Ni molar ratio resulted in the highest ammonia decomposition activity and stability. The catalysts were characterized by N2 adsorption-desorption, XRD, H2-TPR, and HRTEM. The characterization results indicated that NiFe2O4 with a spinel structure was formed in the optimal Fe-Ni bimetallic catalysts and this structure favors the reduction of Fe and Ni. In other words, it is easy to achieve the metallic state of active components for the Fe-Ni bimetallic catalysts, which could be the reason for the high catalytic activity of bimetallic catalysts for NH3 decomposition.

Keywords: Plasma   Fe-Ni   Bimetallic catalysts   Ammonia decomposition   Hydrogen  
Received: 2017-02-28 Accepted: 2017-03-27 Publication Date (Web): 2017-03-30
Corresponding Authors: GUO Hong-Chen Email:

Fund: The project was supported by the National Natural Science Foundation of China (20473016, 20673018)

Cite this article: SUN Shuai-Qi, YI Yan-Hui, WANG Li, ZHANG Jia-Liang, GUO Hong-Chen. Preparation and Performance of Supported Bimetallic Catalysts for Hydrogen Production from Ammonia Decomposition by Plasma Catalysis[J]. Acta Phys. -Chim. Sin., 2017,33 (6): 1123-1129.    doi: 10.3866/PKU.WHXB201703301

(1) Bell, T. E.; Torrente-Murciano, L. Top. Catal. 2016, 59, 1438. doi: 10.1007/s11244-016-0653-4
(2) Chang, J. F.; Xiao, Y.; Luo, Z. Y.; Ge, J. J.; Liu, C. P.; Xing, W. Acta Phys. -Chim. Sin. 2016, 32, 1556. [常进法, 肖 瑶, 罗兆艳, 葛君杰, 刘长鹏, 邢 巍. 物理化学学, 2016, 32, 1556.]doi: 10.3866/PKU.WHXB201604291
(3) García-Bordejé, E.; Armenise, S.; Roldán, L. Catal. Rev. 2014, 56, 220. doi: 10.1080/01614940.2014.903637
(4) Schüth, F.; Palkovits, R.; Schlögl, R.; Su, D. S. Energy Environ. Sci.2012, 5, 6278. doi: 10.1039/c2ee02865d
(5) Boisen, A.; Dahl, S.; Norskov, J. K.; Christensen, C. H. J. Catal. 2005, 230, 309. doi:10.1016/j.jcat.2004.12.013
(6) Zhang, J.; Muller, J. O.; Zheng, W. Q.; Wang, D.; Su, D. S.; Schlogl, R. Nano Lett. 2008, 8, 2738. doi: 10.1021/nl8011984
(7) Liang, C. H.; Li, W. Z.; Wei, Z. B.; Xin, Q.; Li, C. Ind. Eng. Chem. Res. 2000, 39, 3694. doi: 10.1021/ie990931n
(8) Duan, X. Z.; Qian, G.; Zhou, X. G.; Chen, D.; Yuan, W. K. Chem. Eng. J. 2012, 207, 103. doi: 10.1016/j.cej.2012.05.100
(9) Wang, L.; Zhao, Y.; Liu, C. Y.; Gong, W. M.; Guo, H. C. Chem. Commun. 2013, 49, 3787. doi: 10.1039/c3cc41301b
(10) Wang, L.; Yi, Y. H.; Zhao, Y.; Zhang, R.; Zhang, J. L.; Guo, H. C. ACS Catal. 2015, 5, 4167. doi: 10.1021/acscatal.5b00728
(11) Lee, M. S.; Lee, J. Y.; Lee, D. W.; Moon, D. J.; Lee, K. Y. Int. J. Hydrog. Energy 2012, 37, 11218. doi: 10.1016/j.ijhydene.2012.04.130
(12) Zheng, W. Q.; Zhang, J.; Ge, Q. J.; Xu, H. Y.; Li, W. Z. Appl. Catal. B-Environ. 2008, 80, 98. doi: 10.1016/j.apcatb.2007.11.008
(13) Lorenzut, B.; Montini, T.; Bevilacqua, M.; Fornasiero. P. Appl. Catal. B-Environ. 2012, 125, 409. doi: 10.1016/j.apcatb.2012.06.011
(14) Zhang, L. F.; Li, M.; Ren, T. Z.; Liu, X. Y.; Yuan, Z. Y. Int. J. Hydrog. Energy 2015, 40, 2648. doi: 10.1016/j.ijhydene.2014.12.079
(15) Wang, L. J.; Zhang, C. L.; Li, S.; Wu, T. H. Chin. J. Inorg. Chem. 1996, 12, 377. [王力军, 张春雷, 李 爽, 吴通好. 无机化学学报, 1996, 12, 377.]
(16) Qin, W. Q.; Yang, C. R.; Yi, R.; Gao, G. H. J. Nanomater. 2011, 2011, 1. doi: 10.1155/2011/1592

1. WANG Li, LU Dan-Feng, GAO Ran, CHENG Jin, ZHANG Zhe, QI Zhi-Mei.Theoretical Analyses and Chemical Sensing Application of Surface Plasmon Resonance Effect of Nanoporous Gold Films[J]. Acta Phys. -Chim. Sin., 2017,33(6): 1223-1229
2. FAN Zhi-Bo, GONG Xiao-Qing, LU Dan-Feng, GAO Ran, QI Zhi-Mei.Benzo[a]pyrene Sensing Properties of Surface Plasmon Resonance Imaging Sensor Based on the Hue Algorithm[J]. Acta Phys. -Chim. Sin., 2017,33(5): 1001-1009
3. FAN Xiang-Xiang, HE Xiu-Li, LI Jian-Ping, GAO Xiao-Guang, JIA Jian, QI Zhi-Mei.Fabrication and Surface-Enhanced Raman Scattering Properties of an Ag-Coated Polyimide Nanorod Array[J]. Acta Phys. -Chim. Sin., 2016,32(4): 1036-1042
4. CHEN Xu-Dong, CHEN Zhao-Long, SUN Jing-Yu, ZHANG Yan-Feng, LIU Zhong-Fan.Graphene Glass: Direct Growth of Graphene on Traditional Glasses[J]. Acta Phys. -Chim. Sin., 2016,32(1): 14-27
5. LIU Jin-Long, LIU Sheng, GUO Jian-Chao, HUA Chen-Yi, CHEN Liang-Xian, WEI Jun-Jun, HEI Li-Fu, WANG Jing-Jing, FENG Zhi-Hong, LIU Qing, LI Cheng-Ming.Formation Mechanism of the H-terminated Diamond Surface[J]. Acta Phys. -Chim. Sin., 2015,31(9): 1741-1746
6. WANG Hao, SONG Ling-Jun, LI Xing-Hu, YUE Li-Meng.Hydrogen Production from Partial Oxidation of Methane by Dielectric Barrier Discharge Plasma Reforming[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1406-1412
7. REN Zhong-Hua, LU Yue-Xiang, YUAN Hang, WANG Zhe, YU Bo, CHEN Jing.Charge-Transfer Reactions at the Interface between Atmospheric- Pressure Microplasma Anode and Ionic Solution[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1215-1218
8. QIAO Zhi, XIE Xin-Jian, XUE Jun-Ming, LIU Hui, LIANG Li-Min, HAO Qiu-Yan, LIU Cai-Chi.Optimization of Intrinsic Silicon Passivation Layers in nc-Si:H/c-Si Silicon Heterojunction Solar Cells[J]. Acta Phys. -Chim. Sin., 2015,31(6): 1207-1214
9. CHEN Chen, LU Dan-Feng, CHENG Jin, QI Zhi-Mei.Simulation of Surface Plasmon Coupled Emission with Silver Film[J]. Acta Phys. -Chim. Sin., 2015,31(11): 2023-2028
10. ZHANG Zhe, LIU Jie, LU Dan-Feng, QI Zhi-Mei.Wavelength-Interrogated Surface Plasmon Resonance Sensor Based on Au-Ag Alloy Film[J]. Acta Phys. -Chim. Sin., 2014,30(9): 1771-1777
11. ZHAO Yue, WANG Li, ZHANG Jia-Liang, GUO Hong-Chen.Influence of Non-Thermal Plasma Discharge Mode and Reactor Structure on Ammonia Decomposition to Hydrogen[J]. Acta Phys. -Chim. Sin., 2014,30(4): 738-744
12. LI Jing-Jing, LI Yuan, WANG Ai-Ling, QU Yan-Rong, YUE Bin, ZHOU Dan, CHU Hai-Bin, ZHAO Yong-Liang.Surface Plasmon Resonance Enhanced Luminescence of Europium Complexes with Ag@SiO2 Core-Shell Structure[J]. Acta Phys. -Chim. Sin., 2014,30(12): 2328-2334
13. LI Yu-Ling, KAN Cai-Xia, WANG Chang-Shun, LIU Jin-Sheng, XU Hai-Ying, NI Yuan, XU Wei, KE Jun-Hua, SHI Da-Ning.Surface Plasmon Resonance Coupling Effect of Assembled Gold Nanorods Based on the FDTD Simulation[J]. Acta Phys. -Chim. Sin., 2014,30(10): 1827-1836
14. WANG Yue-Hui, WANG Ting, ZHOU Ji.Studies of Enhanced Fluorescence Effects of Europium(Ⅲ) Dipicolinic Acid Complex by Silver Nanoparticles[J]. Acta Phys. -Chim. Sin., 2014,30(1): 28-33
15. XU Yong, JIANG Pei-Wen, LI Quan-Xin.Carbon Nanofibers-Supported Ni Catalyst for Hydrogen Production from Bio-Oil through Low-Temperature Reforming[J]. Acta Phys. -Chim. Sin., 2013,29(05): 1041-1047
16. ZHONG Bei-Jing, XIONG Peng-Fei, YANG Fan, YU Ya-Wei.Thermal and Chemical Effects of Hydrogen in Catalytic Ignition of n-Butane/Air Mixture[J]. Acta Phys. -Chim. Sin., 2013,29(05): 897-902
17. ZHAO Jian, ZHOU Wei, XU Jun-Ke, MA Jian-Xin.Effect of Pretreatment Routes on the Performance and Structure of Ni-Co Bimetallic Catalysts[J]. Acta Phys. -Chim. Sin., 2013,29(04): 806-812
18. ZHANG Zhe, LU Dan-Feng, QI Zhi-Mei.Surface Plasmon Resonance Sensing Properties of Nanoporous Gold Thin Films[J]. Acta Phys. -Chim. Sin., 2013,29(04): 867-873
19. CHANG Da-Lei, LI Xiao-Song, ZHAO Tian-Liang, ZHU Ai-Min.Diagnosis of Emission Spectra on Chemical Vapor Deposition of TiO2 System with Atmospheric-Pressure Radio Frequency Plasma[J]. Acta Phys. -Chim. Sin., 2013,29(03): 625-630
20. YANG Fang, XU Xiang-Sheng, GU Hui-Zi, CHEN Ao-Ang, YAN Xin-Huan.Heterogeneously Catalyzed One-Pot Synthesis of N-alkyl anilines from Nitroaromatics by Assembled Pt3Sn/Al2O3 Catalyst[J]. Acta Phys. -Chim. Sin., 2012,28(09): 2141-2147
21. KE Shan-Lin, KAN Cai-Xia, MO Bo, CONG Bo, ZHU Jie-Jun.Research Progress on the Optical Properties of Gold Nanorods[J]. Acta Phys. -Chim. Sin., 2012,28(06): 1275-1290
22. TIAN Xiang-Gui, ZHANG Yue, YANG Tai-Sheng.First-Principles Study of H2 Dissociative Adsorption Reactions on WO3 Surfaces[J]. Acta Phys. -Chim. Sin., 2012,28(05): 1063-1069
23. LI Cao-Long, CHEN Wei, YUAN Jian, SHANGGUAN Wen-Feng.Hydrogen Evolution by Photocatalytic Steam Reforming of Methane over Pt/TiO2[J]. Acta Phys. -Chim. Sin., 2012,28(02): 450-456
24. WANG Chuan-Ge, ZENG Fan-Gui, PENG Zhi-Long, LI Xia, ZHANG Li.Kinetic Analysis of a Pyrolysis Process and Hydrogen Generation of Humic Acids of Yimin Lignite Fusain Using the Distributed Activation Energy Model[J]. Acta Phys. -Chim. Sin., 2012,28(01): 25-36
25. NIE Long-Hui, HU Yao, ZHANG Wang-Xi.Preparation of a Ag@AgCl-Modified TiO2-xCx Photocatalyst and Its Performance for Degradation of Pollutants under Visible Light[J]. Acta Phys. -Chim. Sin., 2012,28(01): 154-160
26. YUAN Wen-Hui, LI Bao-Qing, LI Li.Superior Graphene for Hydrogen Adsorption Prepared by the Improved Liquid Oxidation-Reduction Method[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2244-2250
27. ZHANG Xuan-Zhou, YANG Jun-Zhi, SONG Ping, TIAN Wen-Huai, LI Xing-Guo.Synthesis and Cyclic Hydrogenation Properties of Magnesium Ultrafine Nanoparticles Prepared by Acetylene Plasma[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1707-1711
28. LIANG Jian-Ming, ZHANG Ri-Guang, ZHAO Qiang, DONG Jin-Xiang, WANG Bao-Jun, LI Jin-Ping.Hydrogen Adsorption on Zeolite Na-MAZ and Li-MAZ Clusters[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1647-1653
29. ZHANG Rong-Jun, QI Zhi-Mei, ZHANG Zhe.In situ Study of Self Assembly of Gold Nanoparticles and Cytochrome c by Polarized Optical Waveguide Spectroscopy[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1757-1762
30. XU Jun-Ke, SHEN Li-Hong, ZHOU Wei, MA Jian-Xin.Mechanism of Biogas Reforming for Hydrogen Production over Ni-Co Bimetallic Catalyst[J]. Acta Phys. -Chim. Sin., 2011,27(03): 697-704
31. CHEN Hua-Rong, CHANG Ran-Ran, LI Li, YUAN Wen-Hui.High Performance NaA Zeolite Membrane for Hydrogen Separation Synthesized on an Organic-Functionalized α-Al2O3 Ceramic Hollow Fiber Surface[J]. Acta Phys. -Chim. Sin., 2011,27(01): 241-247
32. LI Zhao-Hu, ZHANG Zhi-Kun, GUO Deng-Zhu.Fabrication of Al2O3 Nanoparticles by Cathodic Plasma Electrolysis[J]. Acta Phys. -Chim. Sin., 2010,26(11): 3106-3112
33. SUN Wen-Li, XU Jun, LU Wen-Qi.Chemical Structure and Growth Mechanism of a-SixC1-x:H Films Prepared by Plasma Enhanced Magnetron Sputtering[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2311-2316
34. WANG Yue-Hui, WANG Ting, ZHOU Ji.Effect of Silver Nanoparticles on the Spectroscopy Properties of [Ru(bpy)3]2+ and Electrolyte Effect[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1607-1616
35. ZHAO Xiong-Yan.Synthesis and Characterization of a Polyquinoline Derivative Thin Film with a Low Dielectric Constant[J]. Acta Phys. -Chim. Sin., 2010,26(04): 1164-1170
36. CHEN Jingguang G, QI Sui-Tao, HUMBERT Michael P, MENNING Carl A, ZHU Yue-Xiang.Rational Design of Low-Temperature Hydrogenation Catalysts: Theoretical Predictions and Experimental Verification[J]. Acta Phys. -Chim. Sin., 2010,26(04): 869-876
37. XU Hui-Yuan, CHU Wei, DENG Si-Yu.Preparation of Copper-Cobalt-Silicon Catalysts for Higher Alcohol Synthesis by Glow Discharge Plasma[J]. Acta Phys. -Chim. Sin., 2010,26(02): 345-349
38. MA Chun-An, LIU Ting, CHEN Li-Tao.CO and H Adsorption on Pt/WC(0001) Surface[J]. Acta Phys. -Chim. Sin., 2010,26(01): 155-162
39. BAI Mei-Gui, TAO Xu-Mei, WU Qing-You, HUANG Zhi-Jun, LI Yu-Liang, YIN Yong-Xiang, DAI Xiao-Yan.Effect of Different Feeding Modes on CO2 Reforming of CH4 by Thermal Plasma[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2455-2460
40. LI Mei-Fen, ZENG Fan-Gui, SUN Bei-Lei, QI Fu-Hui.Evolution Kinetics of Hydrogen Generation from Low Rank Coal Pyrolysis and Its Relation to the First Coalification Jump[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2597-2603
41. DU Xiao-Ming, WU Er-Dong.Modeling the Supercritical Adsorption of Hydrogen on A-and X-Type Zeolites with a Lattice Density Function[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1823-1828
42. CHEN Wei, DONG Xin-Fa, CHEN Zhi-Shan, CHEN Sheng-Zhou, LIN Wei-Ming.Effect of Fe3+ Doping on Photocatalytic Activity of K2La2Ti3O10 for Water Decomposition to Hydrogen under Visible Light[J]. Acta Phys. -Chim. Sin., 2009,25(06): 1107-1110
43. DU Xiao-Ming, WU Er-Dong.Behavior of Adsorbed Hydrogen Molecules on Zeolites[J]. Acta Phys. -Chim. Sin., 2009,25(03): 549-554
44. YAO Hui-Jun; MO Dan; DUAN Jing-Lai; CHEN Yan-Feng; ZHANG Ling; LIU Jie; HOU Ming-Dong; SUN You-Mei.Preparation and Optical Properties of Gold Nanowire Arrays[J]. Acta Phys. -Chim. Sin., 2008,24(10): 1922-1926
45. WANG Bin-Bin; QIU Rong; JIANG Yong.Effects of Hydrogen Enhancement in LPG/Air Premixed Flame[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1137-1142
46. XU Hui-Yuan; CHU Wei; SHI Li-Min; ZHANG Hui; ZHOU Jun.Preparation of Copper-Cobalt Catalyst by Glow Discharge Plasma for Lower Alcohols Synthesis[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1085-1089
47. YUE Qiao-Hong; SHAO Xiao-Hong; CAO Da-Peng.Separation of Hydrogen and Carbon Dioxide in Activated Mesocarbon Microbeads with High Specific Surface[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1080-1084
48. XU Hui-Yuan; CHU Wei; CI Zhi-Min.Effect of Glow Discharge Plasma on Copper-based Catalysts for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1042-1046
49. DU Xiao-Ming; WU Er-Dong.Application of the Adsorption Potential Theory to Hydrogen Adsorption on Zeolites above Critical Temperature[J]. Acta Phys. -Chim. Sin., 2007,23(06): 813-819
50. YAN Zong-Cheng; CHEN Li; WANG Hong-Lin.Glow Discharge Plasma Electrolysis of Methanol Solutions[J]. Acta Phys. -Chim. Sin., 2007,23(06): 835-840
51. LIU De-Rong; XIONG Wei; YANG Chao-Fen; WANG Jin-Bo; CHEN Hua; LI RUI-Xiang; LI Xian-Jun.Asymmetric Hydrogenations of Acetophenone and Its Derivatives over RuRh/γ-Al2O3 Modified by (1S, 2S)-DPEN and PPh3[J]. Acta Phys. -Chim. Sin., 2007,23(04): 479-483
52. FANG Shu-Mei; OU Yan; LIN Jing-Dong; LIAO Dai-Wei.Preparation of Cu/Sr3Ti2O7 and Its Photocatalytic Activity of Watersplitting for Hydrogen Evolution[J]. Acta Phys. -Chim. Sin., 2007,23(04): 601-604
53. HU Xiao-Tu;WANG Yi;ZHU Tian-Le;JIANG Xue-Dong;LI Rui-Nian.Oxidation of Ammonium Sulfite in Aqueous Solutions with Streamer Plasmas[J]. Acta Phys. -Chim. Sin., 2007,23(03): 384-388
54. ZOU Ji-Jun;LIU Chang-Jun.Preparation of NiO/SrTiO3 with Cold Plasma Treatment for PhotocatalyticWater Splitting[J]. Acta Phys. -Chim. Sin., 2006,22(08): 926-931
55. LIU Jing;NIU Jin-Hai;XU Yong;ZHU Ai-Min;SUN Qi;NIE Long-Hui.Optical Emission Spectroscopy Diagnosis on Decomposition of NO in NO/N2 Mixtures in Dielectric Barrier Discharge Plasma[J]. Acta Phys. -Chim. Sin., 2005,21(12): 1352-1356
56. WANG Da-wang; MA Teng-cai; CUI Jin-hua.Methane Coupling in Atmospheric Pressure Glow Discharge Plasma with a Rotary Helix Electrode[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1291-1294
57. WANG Sheng-gao; ZHAO Xiu-jian; HAN Jian-jun; WANG Jian-hua.Integration of Carbon Nanotubes Electrodes on Glass Substrate[J]. Acta Phys. -Chim. Sin., 2005,21(09): 1050-1054
58. PEI Mei-Xiang; LIN He; SHANGGUAN Wen-Feng; HUANG Zhen.The Effects of Plasma on Simultaneously Catalytic Removal of NOx and Soot[J]. Acta Phys. -Chim. Sin., 2005,21(03): 255-260
59. SUN Qi;ZHU Ai-Min;NIU Jin-Hai;XU Yong;SONG Zhi-Min.Plasma-induced Conversion of Nitrogen Oxides in a Dielectric Barrier Discharge Reactor[J]. Acta Phys. -Chim. Sin., 2005,21(02): 192-196
60. Ren Jia-Rong;Liu Ji-Xin;Li Rui-Nian;Zhao Bi-Ying;Xie You-Chang.Influences on Oxidation of SO2 and SO32- by Gas Discharge[J]. Acta Phys. -Chim. Sin., 2004,20(09): 1078-1082
61. Gao Li-Zhen;Zhang Xing-Tang;Dai Shu-Xi;Li Yun-Cai;Huang Ya-Bin;Du Zu-Liang;Li Tie-Jin.Preparation of PyDDP-modified Gold Nanoparticles and Mechanism for Red-shift in the Surface Plasma Resonance Absorption[J]. Acta Phys. -Chim. Sin., 2004,20(06): 647-650
62. Ren Jia-Rong;Liu Ji-Xin;Li Rui-Nian;Wei Ji-Ying;Zhao Bi-Ying;Xie You-Chang.Oxidation of High Concentration Sulfites by Gas Discharge[J]. Acta Phys. -Chim. Sin., 2004,20(06): 656-658
63. Yun Hong;Chen Jian-Hua;Zhang Hui;Lin Jing-Dong;Chen Hong-Bo;Lin Chang-Jian.The Effects of ZrO2 on Cu-ZnO-ZrO2 Catalysts for Hydrogen Generation by Steam Reforming of Methanol[J]. Acta Phys. -Chim. Sin., 2004,20(05): 550-553
64. Cui Jin-Hua;Xu Gen-Hui;Liu Chang-Jun.Novel Plasma Reactor with Rotary Multi-tip Electrode Used in CH4 Coupling[J]. Acta Phys. -Chim. Sin., 2004,20(05): 557-560
65. Niu Dong-Mei;Zhang Shu-Dong;Zhang Xian-Yi;Li Hai-Yang.Gas Phase Reaction of Laser Ablated Cu Plasma with Ethanol Clusters[J]. Acta Phys. -Chim. Sin., 2003,19(12): 1114-1118
66. Yang Kai;Wu Feng;Li Li;Wang Jing.Research on the Surface Modification of the Metal-Hydride Electrode[J]. Acta Phys. -Chim. Sin., 2003,19(12): 1167-1170
67. Wang Sheng-Gao;Wang Jian-Hua;Wang Chuan-Xin;Ma Zhi-Bin;Man Wei-Dong.Self-bias Induced Aligned Growth of Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2003,19(09): 864-866
68. Zheng Qing-Rong;Gu An-Zhong;Lin Wen-Sheng;Li Ming;Lu Xue-Sheng.Theoretical Study on the Adsorbed Hydrogen Molecules on Multi-Walled Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2003,19(02): 139-143
69. Zhang Xin-Rong;Shi Peng-Fei.Catalytic Production of Hydrogen from Steam Reforming of Methanol on CeO2 Promoted Cu/Al2O3 Catalysts[J]. Acta Phys. -Chim. Sin., 2003,19(01): 85-89
70. Zou Ji-Jun;Li Yang;Zhang Yue-Ping;Liu Chang-Jun.Product Distribution of Conversions of Methane and Carbon Dioxide Using Dielectric Barrier Discharge[J]. Acta Phys. -Chim. Sin., 2002,18(08): 759-763
71. Cui Jin-Hua;Xu Gen-Hui;Han Sen.Eliminating Coke Formed in CH4 Coupling under Plasma via Pure H2 Discharge in the System[J]. Acta Phys. -Chim. Sin., 2002,18(03): 276-278
72. Huang Wei-Ping;Zheng Xiu-Cheng;Zhang Shou-Min;Qiu Xiao-Hang;Li Bao-Qing;Wu Shi-Hua.Structure and Activity of Polymer Immobilized Co-Pd Catalysts[J]. Acta Phys. -Chim. Sin., 2002,18(03): 243-247
73. Xi Jing-Yu;Wang Zhi-Fei;Wang Wei-Ping;Lü Gong-Xuan.In-situ XPS Study for Reaction Mechanism of Methanol Decomposition over Cu-Ni/Zn Catalyst[J]. Acta Phys. -Chim. Sin., 2002,18(01): 82-86
74. Xi Jing-Yu;Lv Gong-Xuan;Wang Zhi-Fei.Partial Oxidation of Methanol to Hydrogen over Cu/Zn and Cu/Zn/Ni Catalysts[J]. Acta Phys. -Chim. Sin., 2001,17(07): 655-658
75. Zhang Yu, Jin Xin-Yu, Chen Kang-Sheng.Simulation Analysis of Active Particles in Plasma Polymerization Film Deposition[J]. Acta Phys. -Chim. Sin., 2000,16(10): 892-898
76. Zhu Ai-Min, Zhang Xiu-Ling, Gong Wei-Min, Zhang Bao-An.Study on Coupling of Methane under Pulse Corona Plasma in the Presence of Oxygen[J]. Acta Phys. -Chim. Sin., 2000,16(09): 839-843
77. Zhong Shun-He, Li Han-Sehng, Wang Jian-Wei, Xiao Xiu-Fen.Cu-Ni/V2O5-SiO2 Catalyst for the Direct Synthesis of Dimethyl Carbonate from Carbon Dioxide and Methanol[J]. Acta Phys. -Chim. Sin., 2000,16(03): 226-231
78. Zhang Gui-Qiu,Sha Guo-He,Xu Ji-Jun,Knott W.Proch D.Abnormal Pressure Effects of H2 Three-photon Resonant Enhanced Ionization Spectroscopy[J]. Acta Phys. -Chim. Sin., 1997,13(07): 617-620
79. Wang Rui,Jin Xin-Yu,Cheng Kang-Sheng,Liang Su-Zhen.Study of Organic Silicon Protection Film by Magnetic-Controlling Plasma Polymerization on the Y-Ba-Cu-O Superconductor[J]. Acta Phys. -Chim. Sin., 1996,12(09): 769-772
80. Lin Meng-Hai, Liu zhao-Yang, Zheng Lan-Sun.Structure Analysis of AgP+n and AumP+n Generated by Laser Plasma Reactions[J]. Acta Phys. -Chim. Sin., 1995,11(03): 266-269
81. Huang Rong-Bin, Huang Feng, Liu Zhao-Yang, Wang Chun-Ru, Lin Feng-Chen, Zheng Lan-Sun.Aggregations of Fullerene Anions in Laser Plasma[J]. Acta Phys. -Chim. Sin., 1994,10(10): 925-927
82. Huang Rong-Bin; Su Zhao-Hui; Zheng Lan-Sun; Wang Yong-Jun; Qin Qi-Zong.Laser Plasma Mass Spectrometry of YBa2Cu3O7-x Superconducting Sample[J]. Acta Phys. -Chim. Sin., 1993,9(06): 823-826
83. Huang Rong-Bin; Zheng Lan-Sun; Zhu Yong-Bao; Zhang Qian-Er.Generation of a New Type of Borane Anions with Laser Ablation[J]. Acta Phys. -Chim. Sin., 1992,8(04): 438-440
84. Zhang Wei-Ping; Chen Jing; Fang Rong-Chun; Hu Ke-Liang.Optical Emission Spectroscopy in Diamond-Like Carbon Film Deposition[J]. Acta Phys. -Chim. Sin., 1992,8(03): 383-388
85. Li Wen-Ying; Huang Rong-Bin; Zhuang Ma-Zhan; Zheng Lan-Sun.Analysis and Comparison of Laser-Plasma Mass Spectra of Anthracene and Phenanthrene[J]. Acta Phys. -Chim. Sin., 1992,8(03): 410-412
86. Huang Rong-Bin; Zhang Peng; Su Zhao-Hui; Su Jian-Rui; Zheng Lan-Sun.Mass Specmetry of Linear CnB- Generated With Laser Vaporization[J]. Acta Phys. -Chim. Sin., 1992,8(02): 145-147
87. Huang Rong-Bin; Zhang Peng; Zhu Yong-Bao; Zheng Lan-Sun.Mass Spectrometry of Niobium and Sulfur Mixed Cluster Ions Generated in Laser Plasma[J]. Acta Phys. -Chim. Sin., 1992,8(01): 8-9
88. Gong Xiao-Yi; Huang Yu-Hui; Cong Guang-Min.The Effect of Plasma Treatment of Mica Powder on its Surface Characteristics and Interface Behavior with Linear Macromolecules[J]. Acta Phys. -Chim. Sin., 1991,7(05): 605-608
89. Zhang Peng; Huang Rong-Bin; Li Wen-Ying; Su Jian-Rui; Zheng Lan-Sun.Mass Spectrometry of Laser Generated Negative InP Cluster Ions[J]. Acta Phys. -Chim. Sin., 1991,7(04): 394-395
90. CHEN Xiao-Yu, WANG Jing-Dong, YU An-Chi.Effect of Surrounding Media on Ultrafast Plasmon Dynamics of Gold Nanoparticles[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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