Register
ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(6)>> 1230-1235     doi: 10.3866/PKU.WHXB201703311         中文摘要
Three-Dimensional Graphene-Based Pt-Cu Nanoparticles-Containing Composite as Highly Active and Recyclable Catalyst
WANG Mei-Song, ZOU Pei-Pei, HUANG Yan-Li, WANG Yuan-Yuan, DAI Li-Yi
College of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241, P. R. China
Full text: PDF (2564KB) HTML Export: BibTeX | EndNote (RIS)

A composite hydrogel consisting of well-dispersed Pt-Cu nanoparticles (NPs) supported on three-dimensional (3D) graphene (Pt-Cu@3DG) was successfully prepared by mild chemical reduction. The 3D interconnected macroporous structure of the graphene framework not only possesses large specific surface area that allows high metal loadings, but also facilitates mass transfer during the catalytic reaction. The Pt-Cu bimetallic alloy NPs show good catalytic activity compared with Pt NPs and reduce the content of Pt NPs used, thereby lowering costs. The morphology and composition of the Pt-Cu@3DG composite were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and energy-dispersive X-ray spectroscopy (EDX). The catalysis studies indicate that the resulting composites can be used as an efficient, inexpensive, recyclable, and stable catalyst for the reduction of 4-nitrophenol to 4-aminophenol under mild conditions.



Keywords: Three dimensional graphene   Pt-Cu nanoparticle   Catalytic reaction   Pore structure   Composite  
Received: 2016-12-12 Accepted: 2017-03-08 Publication Date (Web): 2017-03-31
Corresponding Authors: WANG Yuan-Yuan Email: ecnu_yywang@163.com

Fund: The project was supported by the Key Project of Shanghai Science and Technology Committee (14231200300) and Shanghai Key Laboratory of Green Chemistry and Chemical Processes.

Cite this article: WANG Mei-Song, ZOU Pei-Pei, HUANG Yan-Li, WANG Yuan-Yuan, DAI Li-Yi. Three-Dimensional Graphene-Based Pt-Cu Nanoparticles-Containing Composite as Highly Active and Recyclable Catalyst[J]. Acta Phys. -Chim. Sin., 2017,33 (6): 1230-1235.    doi: 10.3866/PKU.WHXB201703311

(1) Bai, X. J.; Hou, M.; Liu, C.; Wang, B.; Cao, H.; Wang, D. Acta Phys. -Chim. Sin. 2017, 33, 377.[白雪君, 侯敏, 刘婵, 王彪, 曹辉, 王东. 物理化学学报, 2017, 33, 377.]doi: 10.3866/PKU.WHXB201610272
(2) Liang, Y. Y.; Li, Y. G.; Wang, H. L.; Zhou, J. G.; Wang, J.; Regier, T.; Dai, H. J. Nat. Mater. 2011, 10, 780. doi: 10.1038/nmat3087
(3) Wu, Z. S.; Sun, Y.; Tan, Y. Z.; Yang, S. B.; Feng, X. L.; Müllen, K. J. Am. Chem. Soc. 2012, 134, 19532. doi: 10.1021/ja308676h
(4) Scheuermann, C. M.; Rumi, L.; Steurer, P.; Mvlhaupt, R. J. Am. Chem. Soc. 2009, 131, 8262. doi: 10.1021/ja901105a
(5) Subrahmanyam, K. S.; Manna, A. K.; Pati, S. K.; Rao, C. R. Chem. Phys. Lett. 2010, 497, 70. doi:10.1016/j.cplett.2010. 07.091
(6) Qiu, L.; Liu, J. Z.; Chang, S. L. Y.; Wu, Y. Z.; Li, D. Nat. Commun.2012, 3, 187. doi: 10.1038/ncomms2251
(7) Xu, Y. X.; Sheng, K. X.; Li, C.; Shi, G. Q. ACS Nano 2010, 4, 4324. doi: 10.1021/nn101187z
(8) Ji, X. L.; Lee, K. T.; Zhang, L.; Zhang, J. J.; Botton, G. A.; Couillard, M.; Nazar, L. F. Nat. Chem. 2010, 2, 286. doi: 10.1038/nchem.553
(9) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Katsnelson, M. I.; Grigorieva, I. V.; Dubonos, S. V.; Firsov, A. A. Nature 2005, 438, 197. doi: 10.1038/nature04233
(10) Li, Y. R; Chen, J.; Huang, L.; Li, C.; Shi, G. Q. Adv. Electron. Mater.2015, 1, 1. doi: 10.1002/aelm.201500004
(11) Geim, A. K. Science 2009, 324, 1530. doi: 10.1126/science.1158877
(12) Zhang, M.; Lu, X.; Wang, H. Y.; Liu, X.; Qin, Y. J.; Zhang, P.; Guo, Z.X. RSC Adv. 2016, 6, 35945. doi: 10.1039/c6ra01772j
(13) Stamenkovic, V. R.; Fowler, B.; Mun, B. S.; Wang, G.; Ross, P. N.; Lucas, C. A.; Markovic, N. M. Science 2007, 315, 493. doi: 10.1126/science.1135941
(14) Liu, Y.; Li, D. C.; Stamenkovic, V. R.; Soled, S.; Henao, J. D.; Sun, S.H. ACS Catal. 2011, 1, 1719. doi: 10.1021/cs200430r
(15) Yang, H. Z.; Zhang, J.; Sun, K.; Zou, S. Z.; Fang. J. Y. Angew. Chem. Int. Edit. 2010, 49, 6848. doi: 10.1002/anie.201002888
(16) Stamenkovic, V. R.; Mun, B.; Arenz, S. M.; Mayrhofer, K. J. J.; Lucas, C. A.; Wang, G. F.; Ross, P. N.; Markovic, N. M. Nat. Mater. 2007, 6, 241. doi: 10.1038/nmat1840
(17) Jia, Y.; Su. J.; Chen, Z.; Tan, B.; Chen, Q.; Cao, Z.; Jiang, Y.; Xie, Z.; Zheng, L. RSC Adv. 2015, 5, 18153. doi: 10.1039/c4ra15673k
(18) Nie, R.; Shi, J.; Du, W.; Hou, Z. Appl. Catal. A: Gen. 2014, 473, 1. doi: 10.1016/j.apcata.2013.12.029
(19) Gümeci, C.; Cearnaigh, D. U.; Casadonte, D. J.; Korzeniewski, C. J. Mater. Chem. A 2013, 1, 2322. doi: 10.1039/c2ta00957a
(20) Dai, L.; Mo, S. G.; Qin, Q.; Zhao, X. J.; Zheng, N. F. Small 2016, 12, 1572. doi: 10.1002/smll.201502741
(21) Liu, Z.; Lee, J. Y.; Chen, W.; Han, M.; Can, L. M. Langmuir 2004, 20, 181. doi: 10.1021/la035204i
(22) Yu, X.; Wang, D.; Peng, Q.; Li, Y. Chem. Eur. J. 2013, 19, 233. doi: 10.1002/chem.201203332
(23) Hwang, B. J.; Tsai, Y. W.; Sarma, L. S.; Tseng, Y. L.; Liu, D. C.; Lee, J. F. J Phys. Chem. B 2004, 108, 20427. doi: 10.1021/jp0495592
(24) Gong, M. X.; Fu, C. T.; Chen, Y.; Tang, Y. W.; Lu, T. H. ACS Appl. Mater. Inter. 2014, 6, 7301. doi: 10.1021/am500656j
(25) Mott, D.; Luo, J.; Smith, A. Nano. Res. Lett. 2007, 2, 12. doi: 10.1007/s11671-006-9022-8
(26) Zhao, W. G.; Su, L.; Zhou, Z. N.; Zhang, H. J.; Lu, L. L.; Zhang, S. W. Acta Phys. -Chim. Sin. 2015, 31, 145.[赵万国, 苏丽, 周振宁, 张海军, 鲁礼林, 张少伟. 物理化学学报, 2015, 31, 145.] doi: 10.3866/PKU.WHXB201410241

1. HE Lei, ZHANG Xiang-Qian, LU An-Hui.Two-Dimensional Carbon-Based Porous Materials: Synthesis and Applications[J]. Acta Phys. -Chim. Sin., 2017,33(4): 709-728
2. ZHEN Xu, GUO Xue-Jing.Synthesis and Lithium Storage Performance of Three-Dimensional Mesostructured ZnCo2O4 Cubes[J]. Acta Phys. -Chim. Sin., 2017,33(4): 845-852
3. GUAN Yu-Qiao, CHEN Gang, SONG Juan, WANG Cheng-Xin, QIAN Yan, ZHANG Qin, DENG Ling-Ling, FENG Zeng-Qin, SHANG Wen-Juan, TAO You-Tian, CHEN Shu-Fen, WANG Lian-Hui, HUANG Wei.One-Step Synthesized Novel Spiro[fluorene-9,9'-xanthene]-Based Materials as Highly Efficient Blue Phosphorescent Hosts in Organic Light-Emitting Devices[J]. Acta Phys. -Chim. Sin., 2017,33(4): 816-822
4. LI Shen-Hui, LI Jing, ZHENG An-Min, DENG Feng.Solid-State NMR Characterization of the Structure and Catalytic Reaction Mechanism of Solid Acid Catalysts[J]. Acta Phys. -Chim. Sin., 2017,33(2): 270-282
5. TANG Yan-Ping, YUAN Sha, GUO Yu-Zhong, HUANG Rui-An, WANG Jian-Hua, YANG Bin, DAI Yong-Nian.Magnesiothermic Reduction Preparation and Electrochemical Properties of a Highly Ordered Mesoporous Si/C Anode Material for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2016,32(9): 2280-2286
6. LI Guang-Yong, WU Xiao-Han, HE Wei-Na, FANG Jian-Hui, ZHANG Xue-Tong.Controlled Assembly of Graphene-Based Aerogels[J]. Acta Phys. -Chim. Sin., 2016,32(9): 2146-2158
7. GUO Xing-Zhong, DING Li, YU Huan, SHAN Jia-Qi, YANG Hui.Construction and Preparation Mechanism of Hierarchically Porous SiO2 Monoliths[J]. Acta Phys. -Chim. Sin., 2016,32(7): 1727-1733
8. ZHOU Xiao, SUN Min-Qiang, WANG Geng-Chao.Synthesis and Supercapacitance Performance of Graphene-Supported π-Conjugated Polymer Nanocomposite Electrode Materials[J]. Acta Phys. -Chim. Sin., 2016,32(4): 975-982
9. ZHANG Pei-Zhi, YE Mei-Jun, HU Wei-Lian, WU Jun.Kinetics of Acid-Catalyzed Smiles Rearrangement of 2,6-Dimethoxy-2-pyrimidinyloxy-N-arylbenzylamine Derivatives[J]. Acta Phys. -Chim. Sin., 2016,32(2): 422-428
10. LI Wan-Li, LIU Xiao-Yun, MIAO Yan-Qin, YANG Jun-Li, WU Cong-Ling, LI Yuan-Hao, GUO Kun-Peng, WANG Hua, XU Bing-She.MgF2 Modified Alq3 Nanocomposite: Synthesis and Improvement of Anti-Aging Performance of OLED[J]. Acta Phys. -Chim. Sin., 2015,31(9): 1780-1786
11. PAN Jian-Ming, YANG Wei, SUN Hai-Biao, ZHENG Xiang, LI Guo-Hua.Preparation and Electrocatalytic Activity of Tungsten Carbide-Montmorillonite Composite[J]. Acta Phys. -Chim. Sin., 2015,31(5): 998-1006
12. OUYANG Mi, HUANG Sen-Biao, HAN Yan-Gang, Lü Xiao-Jing, YANG Yuan, DAI Yu-Yu, Lü Yao-Kang, ZHANG Cheng.Enhanced Electrochromic Performance of Ordered Porous Monolayer PBTB Film Using Amine-Modified Polystyrene Spheres as a Template[J]. Acta Phys. -Chim. Sin., 2015,31(3): 476-482
13. DU Xue-Lian, CONG Ye, JIANG Lu, LI Xuan-Ke, CUI Zheng-Wei, DONG Zhi-Jun, YUAN Guan-Ming, ZHANG Jiang.Preparation and Structure Regulation of Silicon Carbide-Derived Carbon/ Spherical Natural Graphite Composites[J]. Acta Phys. -Chim. Sin., 2015,31(3): 583-588
14. YANG Jie-Yang, HUANG Zhang-Gen, HAN Xiao-Jin, JING Wen, ZENG Ze-Quan.Effect of Activated Carbon Pore Structure on the Adsorption of Pb(II) from Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2015,31(10): 1956-1962
15. LIU Jian-Hua, LIU Bin-Hong, LI Zhou-Peng.Fe3O4/Graphene Composites with a Porous 3D Network Structure Synthesized through Self-Assembly under Electrostatic Interactions as Anode Materials of High-Performance Li-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2014,30(9): 1650-1658
16. SONG Gen-Ping, XIA Dong-Xiang.One-Step Preparation of Superhydrophobic Polyaniline/Sodium Dodecylbenzenesulfonate Composites[J]. Acta Phys. -Chim. Sin., 2014,30(3): 583-588
17. ZHANG Qing-Qing, LI Rong, ZHANG Meng-Meng, GOU Xing-Long.Synthesis and Electrochemical Lithium Storage Performance of WO3 Nanorods/Graphene Nanocomposites[J]. Acta Phys. -Chim. Sin., 2014,30(3): 476-484
18. WANG Jian-Tao, WANG Yao, HUANG Bin, YANG Juan-Yu, TAN Ao, LU Shi-Gang.Silicon Supported on Stable Si-O-C Skeleton in High-Performance Lithium-Ion Battery Anode Materials[J]. Acta Phys. -Chim. Sin., 2014,30(2): 305-310
19. LIN Xue, GUO Xiao-Yu, WANG Qing-Wei, CHANG Li-Min, ZHAI Hong-Ju.Hydrothermal Synthesis and Efficient Visible Light Photocatalytic Activity of Bi2MoO6/BiVO4 Heterojunction[J]. Acta Phys. -Chim. Sin., 2014,30(11): 2113-2120
20. TANG Jia-Yong, CAO Pei-Qi, FU Yan-Bao, LI Peng-Hui, MA Xiao-Hua.Synthesis of a Mesoporous Manganese Dioxide-Graphene Composite by a Simple Template-Free Strategy for High-Performance Supercapacitors[J]. Acta Phys. -Chim. Sin., 2014,30(10): 1876-1882
21. LUAN Yun-Bo, FENG Yu-Jie, WANG Wen-Xin, XIE Ming-Zheng, JING Li-Qiang.Synthesis of BiOBr-TiO2 Nanocrystalline Composite by Microemulsion-Like Chemical Precipitation Method and Its Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2013,29(12): 2655-2660
22. GUI Ming-Sheng, WANG Peng-Fei, YUAN Dong, TANG Miao-Miao.Preparation and Visible Light Photocatalytic Activity of 3D-NiO/Bi7.47Ni0.53O11.73 Photocatalysts[J]. Acta Phys. -Chim. Sin., 2013,29(12): 2608-2614
23. LI Le, HE Yun-Qiu, CHU Xiao-Fei, LI Yi-Ming, SUN Fang-Fang, HUANG He-Zhou.Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K2Mn4O8 Nanocomposites as Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1681-1690
24. CHEN Peng-Peng, WANG Jing, ZHANG Chun-Li, HAO Yu-Wen, DU Hai-Ying.Preparation of Electrospun In2O3/CdO Composite and Its Formaldehyde-Sensing Properties[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1827-1836
25. PENG Jin-Ping, ZHANG Dong-Dong, GUAN Li, ZHANG Hui, ZHANG Zhong, QIU Xiao-Hui.An Electrostatic Force Microscopy Investigation of the Dynamic Properties of Microscopic Interface in Nanocomposites[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1603-1608
26. ZHANG Xiao-Tong, YU Wen-Guang, QIN Yu-Cai, DONG Shi-Wei, PEI Ting-Ting, WANG Lin, SONG Li-Juan.Influence of Surface Acidity of Y Zeolites on the Adsorption of Organic Molecules by In situ Fourier Transform Infrared Spectroscopy[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1273-1280
27. WU Hong-Bin, ZHANG Ying, YUAN Cong-Li, WEI Xiao-Pei, YIN Jin-Ling, WANG Gui-Ling, CAO Dian-Xue, ZHANG Yi-Ming, YANG Bao-Feng, SHE Pei-liang.Synthesis and Electrochemical Performance of Li4Ti5O12/CMK-3 Nanocomposite Negative Electrode Materials for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1247-1252
28. CHEN Hong-Li, DING Jian, WANG Yi-Meng.Synthesis of Hierarchical MgO-Containing Silicalite-1 Zeolites with High Hydrothermal Stability[J]. Acta Phys. -Chim. Sin., 2013,29(05): 1035-1040
29. LIU Li, JIANG Wei, YANG Xi-Wen, CHEN Bin-Hua, WU Shi-Xi, LI Feng-Sheng.Facile Fabrication of Novel Magnetic and Fluorescent Fe3O4-CdSe Nanocomposites[J]. Acta Phys. -Chim. Sin., 2013,29(05): 1088-1096
30. ZHONG Bei-Jing, XIONG Peng-Fei, YANG Fan, YU Ya-Wei.Thermal and Chemical Effects of Hydrogen in Catalytic Ignition of n-Butane/Air Mixture[J]. Acta Phys. -Chim. Sin., 2013,29(05): 897-902
31. HAO Min-Min, LI Chen, YU Min, ZHANG Ying.Synthesis and Catalytic Activity of Silver Nanoparticles Immobilized onto Composite Microspheres[J]. Acta Phys. -Chim. Sin., 2013,29(04): 785-791
32. PAN Hui, ZHAO Tian, ZHANG Yu-Dong, ZHANG Zhi-Jun.Preparation, Characterization and Properties of Titania/Graphite Oxide Nanocomposite[J]. Acta Phys. -Chim. Sin., 2013,29(03): 660-666
33. XU Gui-Yin, DING Bing, NIE Ping, LUO Hong-Jun, ZHANG Xiao-Gang.Preparation and Electrochemical Performance of Carbon Nanotubes/ Graphene Oxide/Sulfur Complex Cathode Material[J]. Acta Phys. -Chim. Sin., 2013,29(03): 546-552
34. CHEN Fu-Xiao, FAN Wei-Qiang, ZHOU Teng-Yun, HUANG Wei-Hong.Core-Shell Nanospheres (HP-Fe2O3@TiO2) with Hierarchical Porous Structures and Photocatalytic Properties[J]. Acta Phys. -Chim. Sin., 2013,29(01): 167-175
35. LIU Meng, GUO Xiang-Fei, WANG Jing-Ming, JIANG Lei.Behavior of Bubbles on Electrodes with Hierarchical Microporous Structures and Different Wettability[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2931-2938
36. HU Si, ZHANG Qing, XIA Zhi, GONG Yan-Jun, XU Jun, DENG Feng, DOU Tao.Catalytic Conversion of Methanol to Propylene over (NH4)2SiF6-Modified Nanosized HZSM-5 Zeolite[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2705-2712
37. LI Song-Mei, WANG Bo, LIU Jian-Hua, YU Mei, AN Jun-Wei.Synthesis and Microwave Absorption Properties of Nickel Nanoparticles-Graphene Composites with Different Morphologies[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2754-2760
38. LI Guo-Hua, CHEN Dan, ZHENG Xiang, XIE Wei-Miao, CHENG Yuan.Preparation and Electrocatalytic Activity of WC/W2C Nanocomposite with Core-Shell Structure[J]. Acta Phys. -Chim. Sin., 2012,28(09): 2077-2083
39. FAN Hai-Bin, ZHANG Dong-Feng, GUO Lin.Fabrication, Formation Mechanism and the Photocatalytic Properties of Hierarchical Porous Hematite Networks[J]. Acta Phys. -Chim. Sin., 2012,28(09): 2214-2220
40. YUE Ming-Bo, YANG Na, WANG Yi-Meng.Synthesis of Shaped ZSM-5 Zeolites by Dry-Gel Conversion with Seed Gel as Directing Agent[J]. Acta Phys. -Chim. Sin., 2012,28(09): 2115-2121
41. CHEN Peng-Peng, WANG Jing, YAO Peng-Jun, DU Hai-Ying, LI Xiao-Gan.Synthesis and Gas Sensitivity of In2O3/CdO Composite[J]. Acta Phys. -Chim. Sin., 2012,28(06): 1539-1544
42. YUAN Zheng, CUI Yong-Li, SHEN Ming-Fang, QIANG Ying-Huai, ZHUANG Quan-Chao.Preparation and Electrochemical Performance of LiTi2(PO4)3/C Composite Cathode for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2012,28(05): 1169-1176
43. LIU Dong, SHEN Jun, LI Ya-Jie, LIU Nian-Ping, LIU Bin.Pore Structures of Carbon Aerogels and Their Effects on Electrochemical Supercapacitor Performance[J]. Acta Phys. -Chim. Sin., 2012,28(04): 843-849
44. LIU Kong-Hua, LIU Lan, GAO Hong, LUO Yuan-Fang, JIA De-Min.In situ Preparation of Epoxy-Based Conductive Nanocomposites Containing Nanosilver-Decorated Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2012,28(03): 711-719
45. CHEN Yang, WANG Cheng-Guo, ZHAO Wei.Fabrication of a Self-Healing Pure SiC Coating by a Two-Step Technique[J]. Acta Phys. -Chim. Sin., 2012,28(01): 239-244
46. HU Xian-Chao, CHEN Dan, SHI Bin-Bin, LI Guo-Hua.Preparation of Tungsten Carbide and Titania Nanocomposite and Its Electrocatalytic Activity for Methanol[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2863-2871
47. XIONG Peng-Fei, ZHONG Bei-Jing, YANG Fan.Heterogeneous Mechanism of C1-C4 on a Platinum Catalyst[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2200-2208
48. TONG Xin, CHEN Rui, CHEN Tie-Hong.Photocatalytic Activity of TiO2 with Micrometer-Sized Macropores[J]. Acta Phys. -Chim. Sin., 2011,27(08): 1941-1946
49. LI Jian-Sheng, GU Juan, LING Xiao-Feng, SUN Xiu-Yun, SHEN Jin-You, HAN Wei-Qing, WANG Lian-Jun.Synthesis of Ordered Mesoporous Carbon Loaded Fe, Co, Ni Nanocrystals by the Soft Templating Route and Their Characterization[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1772-1776
50. ZHAO Xing, ZHUANG Quan-Chao, QIU Xiang-Yun, XU Shou-Dong, SHI Yue-Li, CUI Yong-Li.Electrochemical Performance of Cr2O3/TiO2 Composite Material for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1666-1672
51. YAO Zhen-Dong, WEI Wei, WANG Jiu-Lin, YANG Jun, NULI Yan-Na.Review of Sulfur-Based Cathodes for High Performance Lithium Rechargeable Batteries[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1005-1016
52. WU Xiao-Lin, SUN Rong, ZHU Peng-Li, DU Ru-Xu.Near Infrared Spectrum Analysis of Organic/Inorganic Composite Microcapsule Phase Change Materials[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1039-1044
53. ZHANG Yi, CHEN Biao, YANG Zu-Pei, ZHANG Zhi-Jun.Controlled Synthesis and Characterization of the Structure and Property of Fe3O4 Nanoparticle-Graphene Oxide Composites[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1261-1266
54. CHEN Jin-Yi, LI Nian, LI Jing, ZHU Liang, PENG Chang-Jun.Synthesis and Visible Light Photocatalytic Activity of Cross-Linked Sodium Rectorite/Cu2O Nanocomposites[J]. Acta Phys. -Chim. Sin., 2011,27(04): 932-938
55. KONG De-Shuai, WANG Jian-Ming, PI Ou-Yang, SHAO Hai-Bo, ZHANG Jian-Qing.Electrochemical Fabrication and Pseudocapacitive Performance of a Porous Nanostructured Nickel-Based Complex Film Electrode[J]. Acta Phys. -Chim. Sin., 2011,27(04): 764-768
56. LI Guo-Xian, WANG Tao, HE Jian-Ping, ZHOU Jian-Hua, XUE Hai-Rong, MAYi-Ou, HU Yuan-Yuan.Synthesis and Infrared Emissivity of Ordered Mesoporous C-Al2O3-TiO2 Nanocomposites with a Dual Pore System[J]. Acta Phys. -Chim. Sin., 2011,27(01): 248-254
57. ZHANG Lei-Yong, HE Shui-Jian, CHEN Shui-Liang, GUO Qiao-Hui, HOU Hao-Qing.Preparation and Electrochemical Properties of Polyaniline/Carbon Nanofiber Composite Materials[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3181-3186
58. ZHANG Dong-Feng, NIU Li-Ya, GUO Lin.Solution Synthesis Strategies for Hierarchical Nanostructures[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2865-2876
59. WANG Zheng-Ke, HU Qiao-Ling.Chitosan Rods Reinforced by N-Carboxyl Propionyl Chitosan Sodium[J]. Acta Phys. -Chim. Sin., 2010,26(07): 2053-2056
60. CAO Yin-Di, DANG Li-Qin, BAI Dan, LEI Zhi-Bin, LIU Mei-Ying.Adsorption of Lysozymes on Fe/CMK-5 Composites Synthesized by Chemical Vapor Deposition[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1593-1598
61. WU Li-Na, HUANG Yu-Dong, WANG Zhi-Jiang, LIU Li.Preparation and Characterization of Monolithic Silica Fiber/Al2O3 Aerogel Composites by Non-Supercritical Drying[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1717-1721
62. YAO Guo-Xin, SHI Bin-Bin, LI Guo-Hua, ZHENG Yi-Fan.Preparation and Electrocatalytic Activity of Tungsten Carbide and Zeolite Nanocomposite[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1317-1322
63. ZHANG Ai-Qin, YAN Wei, SHI Li-Qun, SHI Li-Yi, FANG Jian-Hui, JIN Lu-Jiang.Synthesis of Polypropylene/Silica Hybrid Materials by Supercritical CO2 Impregnation Using a Co-Solvent[J]. Acta Phys. -Chim. Sin., 2010,26(03): 643-648
64. ZHANG Qiong, HE Yun-Qiu, CHEN Xiao-Gang, HU Dong-Hu, LI Lin-Jiang, YIN Ting, JI Ling-Li.Intercalated Structure and Photocatalytic Properties of TiO2-Graphite Oxide Composite[J]. Acta Phys. -Chim. Sin., 2010,26(03): 654-662
65. JU Xiu-Fang, JIN Ling-Ling, MA Tao, CHEN Xiao- Lu, SONG Li-Juan.Effects of 1,5-Hexadiene and Benzene on the Desulfurization Property of NiYZeolites[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2256-2260
66. SUN Jian-Ping, WENG Jia-Bao, LIN Ting, MA Lin-Pu.Synthesis and Optical Effects of Poly(2-methoxy-5-butoxy)-p-phenylene Vinylene/Eu2O3 Nanocomposites[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2385-2390
67. WANG Tao, ZHOU Jian-Hua, WANG Dao-Jun, SUN Dun, DI Zhi-Yong, HE Jian-Ping.Syntheses and Infrared Emissivities of Ordered Mesoporous C-Al2O3 Nanocomposites[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2155-2160
68. ZHAO Yan-Chun, LAN Huang-Xian, TIAN Jian-Niao, YANG Xiu-Lin, WANG Feng-Yang.Electrocatalytic Oxidation of Methanol on Pt Nanoparticles Supported on Porous Poly(N-acetylaniline) Nanofibrils[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2050-2054
69. LI Chang-Yu, LIU Shou-Xin, MA Yue.Preparation of Visible-Light Response Cu-Cu2+1O Composites by a One-Step Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1555-1560
70. HUANG Zhi-Hai, DONG Yin-Sheng, LIN Ping-Hua.Depositing an Apatite Coating in/on Massive Chitosan Porous Scaffolds by an Alternate Soaking Method[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1285-1289
71. DUAN Jun-Yuan, ZHANG Qiao-Xin, WANG Yi-Long, GUAN Jian-Guo.Facile Synthesis and Formation Mechanism of Silver Nanoplates with Edge Lengths of Several Micrometers[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1405-1408
72. ZHOU Jing-Hong, HAN Wei-Wei, SUI Zhi-Jun, GUO Rong, FANG Xiang-Chen, ZHOU Xing-Gui.Preparation and Characterization of Tri-Lobular Alumina/Carbon Nanofiber Composites[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1455-1460
73. MA Ruo-Biao, FU Yan-Bao, MA Xiao-Hua.Preparation and Electrochemical Performance of Tin-Dioxide Filled Multi-Walled Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2009,25(03): 441-445
74. CHEN Ran, GONG Yan-Jun, LI Qiang, DOU Tao, ZHAO Zhen, XU Qing-Hu.Direct Synthesis and Characteristics of NH4-βZeolite with Hierarchical Pore Structure[J]. Acta Phys. -Chim. Sin., 2009,25(03): 539-544
75. DU Bing, JIANG Qi, ZHAO Xiao-Feng, LIN Sun-Zhong, MU Pei-Shan, ZHAO Yong.Preparation of PPy/CNTs Composite Based on the Electrostatic Absorption Effect[J]. Acta Phys. -Chim. Sin., 2009,25(03): 513-518
76. CHEN Xi-Liang; MA Ming-Wang; YANG Xiao-Min; YANG Kang; JI Te; WU Sheng-Wei; ZHU Zhi-Yong.Electrical and Optical Properties of MWNTs/HDPE Composites in THz Region[J]. Acta Phys. -Chim. Sin., 2008,24(11): 1969-1974
77. WU Hua-Tao; ZHANG Ying; NING Xiang-Li; LIANG Hong-Lian; FANG Yu.Preparation of P(AM-co-MAA)-W-Ag Composite Microspheres with Core-Shell Structures[J]. Acta Phys. -Chim. Sin., 2008,24(04): 646-652
78. LIU Shou-Xin; CHEN Xiao-Yun.Effect of Pore Structure of Activated Carbon on the Photocatalytic Activity of TiO2/AC Composite Photocatalyst[J]. Acta Phys. -Chim. Sin., 2008,24(03): 533-538
79. SHI Zhi-Qiang; CHEN Ming-Ming; ZHAO Shuo; WANG Cheng-Yang.Structure and Electrochemical Capacitive Behavior of Novel Crystallite Carbon[J]. Acta Phys. -Chim. Sin., 2008,24(02): 237-242
80. WANG Yi; JIANG Wei; CHENG Zhi-Peng; ZHANG Xian-Feng; AN Chong-Wei; SONG Xiao-Lan; LI Feng-Sheng.Thermal Performance Investigation of Core-Shell Cu/Al Micron-Nano Composites with WO3[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1753-1759
81. LI Guo-Hua; TIAN Wei; TANG Jun-Yan; MA Chun-An.Preparation and Electrocatalytic Property for Methanol Oxidation of WC/CNT Nanocomposite[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1370-1374
82. FAN Xiao-Yong; ZHUANG Quan-Chao; JIANG Hong-Hong; HUANG Ling; DONG Quan-Feng; SUN Shi-Gang.Three-dimensional Porous Cu6Sn5 Alloy Anodes for Lithium-ion Batteries[J]. Acta Phys. -Chim. Sin., 2007,23(07): 973-977
83. SONG Yu-Feng;ZHU Zhi-Yong;JI Te;GE Min;CHEN Xi-Liang;LIU Qi .THz time-domain spectroscopic study of polyethylene-carbon black composites[J]. Acta Phys. -Chim. Sin., 2007,23(02): 177-180
84. ZHOU Yu-Ming1;ZHONG Ai-Min;HE Man;CUI Yi-Ping;ZHANG Tong .Preparation and Characterization of Novel PUT/SiO2 Nanocomposite Material[J]. Acta Phys. -Chim. Sin., 2007,23(02): 223-227
85. ZHU Lu-Ping;HUANG Wen-Ya;MA Li-Li;FU Shao-Yun;YU Ying;JIA Zhi-Jie.Synthesis and Characteristics of ZnO-CNTs Nanocomposites[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1175-1180
86. BIAN Cheng-Xiang;XU Xue-Cheng;YU Wei;CHEN Yi-Wei;CHENG Rong-Ming;SHI Yan;LI Xiang-Mei;JIN Sheng-Song.Study on Conductive Mechanism of Composites―Sulfonated Polyphenylacetylene / Multiwalled Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1185-1190
87. ZHAO Chun-Xia;CHEN Wen;LIU Qi;TIAN Gao.Influence of HCl on the Mesostructure and Morphology of the Ordered Mesoporous Silica[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1201-1205
88. LEI Zhong-Li;FAN You-Hua .Preparation and Characterization of Silver Nanocomposites Based on Copolymers[J]. Acta Phys. -Chim. Sin., 2006,22(08): 1021-1024
89. GUAN Hong-Bo;WANG Pei;WANG Hui;ZHAO Bi-Ying;ZHU Yue-Xiang;XIE You-Chang.Preparation of Nanometer Magnesia with High Surface Area and Study on the Influencing Factors of the Preparation Process[J]. Acta Phys. -Chim. Sin., 2006,22(07): 804-808
90. HU Jun;WANG Jian-Jun;ZHOU Li-Hui;XIE Song-Hai;LIU Hong-Lai.The Mechanism of Mesoporous Phase Transition of Titanic-Silica Mesoporous Materials[J]. Acta Phys. -Chim. Sin., 2006,22(06): 679-683
91. SUN Bo;MENG Xiang-Ju;WANG Shi-Chao;SUN Shu-Qing;XIAO Feng-Shou.High-throughput Color-screening of Heterogeneous Catalysts[J]. Acta Phys. -Chim. Sin., 2006,22(04): 441-444
92. LI Zhi; GONG Qian-Ming; LIANG Ji; HUANG Qi-Zhong; HUANG Bai-Yun.Study on Oxidation Properties of New ACNT/C Nanocomposites[J]. Acta Phys. -Chim. Sin., 2006,22(03): 316-321
93. LIU Chun-ling; WEN Yue-hua; CHENG Jie; GUO Quan-gui; CAO Gao-ping; LIU Lang; YANG Yu-sheng.Influence of Pore Structure of Phenolic Resin Based Activated Carbon Fibers on the Electrochemical Performance of Electrical Double-layer Capacitors[J]. Acta Phys. -Chim. Sin., 2005,21(07): 786-791
94. Lin Li;Lin Wei;Wang Pei;Zhu Yue-Xiang;Zhao Bi-Yin;Xie You-Chang.Uniform Carbon-covered Alumina Synthesized by Pyrolysis of Sucrose/γ-Al2O3[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1179-1181
95. He He-Yong;Zou Yan;Ma Zhuo-Na;Yue Bin.In situ MAS NMR Spectroscopy Study on Catalytic Reaction Mechanism of Light Alkanes[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 1024-1031
96. Zhang Ying;Fang Yu;Lin Shu-Yu;Liu Jing;Yang Juan-Ling.Preparation of Spherical Nano-structured PMAA/CdS Composites by a Microgel Template Method[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 897-901
97. Chen Ming-An;Zhang Xin-Ming;Xie Xuan.Interphase Analysis of Adhesion Bonded Aluminum Sheet/polypropylene and Maleic Anhydride Grafted Polypropylene by XPS[J]. Acta Phys. -Chim. Sin., 2004,20(08): 882-886
98. Zhuang Xin-Guo;Yang Yu-Sheng;Ji You-Ju;Yang Dong-Ping;Tang Zhi-Yuan.The Influence of Porous Structure of Activated Carbons Used as Supercapacitor Electrode Materials on Its Properties[J]. Acta Phys. -Chim. Sin., 2003,19(08): 689-694
99. Wang Shan;Fang Yu;Zhang Ying;Wang MingZhen;Hu DaoDao;Liao YiKun.Preparation of Chitosan/CdS Composite Films and Their Sensing Properties to Pyridine[J]. Acta Phys. -Chim. Sin., 2003,19(06): 514-518
100. Zhang Guo-Lin;Pan Xian-Hua;Kan Jin-Qing;Zhang Jing-Hui;Li Yong-Fang.Studies on Conducting Composite MaterialGlucose Oxidase Biosensor[J]. Acta Phys. -Chim. Sin., 2003,19(06): 533-537
101. Ruan Sheng-Ping;Wu Feng-Qing;Wang Yong-Wei;Zhang Li;Wu Ri-Na;Xuan Li.Synthesis and Microwave Absorbing Properties of Nanocrystalline Barium Ferrite Composite Material[J]. Acta Phys. -Chim. Sin., 2003,19(03): 275-277
102. Song Hui-Hua;Fang Zhen;Guo Hai-Qing.Synthesis and Characterization of CdSe/Poly (4-vinylpyridine) Quaternary Ammonium Nanocomposite[J]. Acta Phys. -Chim. Sin., 2003,19(01): 9-12
103. Chen Song-Zhe;Zhong Shun-He.The Photo Stimulated Surface Reaction of Synthesis of Methanol from Carbon Dioxide and Water on Cu/TiO2-NiO[J]. Acta Phys. -Chim. Sin., 2002,18(12): 1099-1103
104. Zhang Hong-Lin;Yu Xiu-Fang;Zhang Gang.Thermokinetics of Activation of Metal Ions to Amylase Catalyzed Reaction[J]. Acta Phys. -Chim. Sin., 2002,18(12): 1125-1128
105. Zhao Liang-Zhong;Liu Fen;Li Jian-Zhang;Xu Yong-Tong.XPS Study of Three Dimensional C/SiC Composites[J]. Acta Phys. -Chim. Sin., 2001,17(09): 802-805
106. Zhai Gao-Hong;Wang Hui;Yang Hai-Feng;Ran Xin-Quan;Wang Yu-Bin;Wen Zhen-Yi.Pyrolysis Mechanism of Cyclohexane[J]. Acta Phys. -Chim. Sin., 2001,17(04): 348-355
107. Zhang Zhi-Hua, Guo Hai-Qing, Lv Mei-Hua, Liu Shu-Man, Wang Zhan-Guo.Assembly of Side-functional Monomers with lnorganic Nanometer Particles[J]. Acta Phys. -Chim. Sin., 2000,16(11): 968-971
108. Yu Xing-Wen, Cao Chu-Nan, Lin Hai-Chao, Zhou Yu-Hong, Zhou De-Rui, Yin Zhong-Da.Composition,Structure and Properties of Rare Earth Metal Conversion Coating on Al6061/SiCp[J]. Acta Phys. -Chim. Sin., 2000,16(06): 547-552
109. Jiang Dian-Lu, Weng Yong-Liang, Tong Ru-Ting.Preparation and Characterization of Polyaniline/Bentonite Layered Nanocomposites[J]. Acta Phys. -Chim. Sin., 1999,15(01): 69-72
110. Qiu Shi-Lun, Zhai Qing-Zhou, Xiao Feng-Shou, Zhang Zong-Tao, Han Yu.The Developments of the Studies of New Type Zeolite Molecular Sieve Host-nanoguest Composite Materials[J]. Acta Phys. -Chim. Sin., 1998,14(12): 1116-1122
111. Zeng Jian-Qing, Zhang Jing-Cheng, Zhong Bing.Monte Carlo Simulation of the Phase Transition and Self-oscillation in A+B2 Surface Catalytic Reaction[J]. Acta Phys. -Chim. Sin., 1998,14(02): 103-108
112. Cao Nai-Zhen,Shen Wan-Ci,Wen Shi-Zhu.The Characterization of the Porous Structure of Expanded Graphite[J]. Acta Phys. -Chim. Sin., 1996,12(08): 766-768
113. Luo Meng-Fei,Zhu Bo,Chen Min,Ding Yun-Jie,Yuan Xian-Xin.The CO-NO Reaction and the NO-TPSR on Pt/HM and Pd/HM Catalysts[J]. Acta Phys. -Chim. Sin., 1996,12(05): 472-475
114. Fan Ye-Mei, Xu Heng-Yong, Shi Ke-Ying, Shang Yong-Chen, Ye Qing, Xu Guo-Lin, Huang Ren-Cai, Guo Wei-Song, Zhou Pei-Heng.A New Route for the Chemical Utilization of CO2[J]. Acta Phys. -Chim. Sin., 1995,11(03): 283-286
115. Kan Jin-Qing , Mu Shao-Lin.The Effect of O-phenanthroline on the Kinetics of the Immobilized Uricase Catalyzed Reaction[J]. Acta Phys. -Chim. Sin., 1994,10(07): 648-653
116. Tang Yi; Hua Wei-Ming; Gao Zi.Pore Structure and Catalytic Behavior of Modified Y Zeolites[J]. Acta Phys. -Chim. Sin., 1992,8(05): 595-601
117. Pei Zhan-Fen; Liu Xing-Yun; Li Xuan-Wen.The Studies of Pore Structures of High-Silica Y Zeolites by N2 Adsorption[J]. Acta Phys. -Chim. Sin., 1992,8(05): 613-618
118. Dong Shao-Jun; Xie Yuan-Wu; Che Guang-Li.Determination of Rate Constants of Catalytic Reaction by Spectroelectrochemistry with Microelectrodes[J]. Acta Phys. -Chim. Sin., 1991,7(05): 531-535
119. CHENG Ruo-Lin, JIN Xi-Xiong, FAN Xiang-Qian, WANG Min, TIAN Jian-Jian, ZHANG Ling-Xia, SHI Jian-Lin.Incorporation of N-Doped Reduced Graphene Oxide into Pyridine-Copolymerized g-C3N4 for Greatly Enhanced H2 Photocatalytic Evolution[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388 Email:whxb@pku.edu.cn
^ Top