ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(7)>> 1492-1498     doi: 10.3866/PKU.WHXB201704141         中文摘要
Preparation of MoS2/TiO2 Composite Catalyst and Its Photocatalytic Hydrogen Production Activity under UV Irradiation
ZHANG Chi1,2, WU Zhi-Jiao2, LIU Jian-Jun1, PIAO Ling-Yu2
1 State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China;
2 CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, P. R. China
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To study the activity of a composite photocatalyst for photocatalytic hydrogen production, we prepared and loaded MoS2 nanosheets with TiO2 nanoparticles using a hydrothermal method, thus forming a MoS2/TiO2 heterojunction composite catalyst. The structural and optical properties of the catalyst were characterized and analyzed by field-emission scanning electron microscopy, high-resolution transmission electron microscopy, X-ray powder diffraction, UV-Vis absorption spectra, Raman spectroscopy, and X-ray photoelectron spectroscopy. The activity of the photocatalyst was evaluated by its photocatalytic hydrogen production rate. The corresponding MoS2 content of the catalyst was found to be 30%, and upon the exposure to 365nm UV light, a high photocatalytic hydrogen production rate of 1004 μmol-1·h-1·g-1 was obtained. The catalytic rate is much greater than that obtained with MoS2 or TiO2 catalysts. The high hydrogen production rate indicated that the use of a MoS2/TiO2 composite catalyst can significantly improve the UV-induced photocatalytic hydrogen production performance. Because of the excellent photocatalytic hydrogen production performance of the MoS2/TiO2 composite, we studied and analyzed the hydrogen production mechanism.

Keywords: TiO2   MoS2   Composite structure   Heterojunction   Photocatalytic hydrogen production  
Received: 2017-01-16 Accepted: 2017-04-11 Publication Date (Web): 2017-04-14
Corresponding Authors: LIU Jian-Jun, PIAO Ling-Yu Email:,;

Fund: The project was supported by the Ministry of Science and Technology of China (2016YFA0200900, 2016YFF0203803).

Cite this article: ZHANG Chi, WU Zhi-Jiao, LIU Jian-Jun, PIAO Ling-Yu. Preparation of MoS2/TiO2 Composite Catalyst and Its Photocatalytic Hydrogen Production Activity under UV Irradiation[J]. Acta Phys. -Chim. Sin., 2017,33 (7): 1492-1498.    doi: 10.3866/PKU.WHXB201704141

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64. JIANG Jing-Jing, LONG Ming-Ce, WU De-Yong, CAI Wei-Min.Preparation of F-Modified Nanosized TiO2 and Its Methyl Orange Photodegradation Mechanism[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1149-1156
65. LAO Chun-Feng, CHU Zeng-Ze, ZOU De-Chun.Self-Assembly of 3-Aminopropyltrimethoxysilane to Improve the Efficiency of Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2011,27(02): 419-424
66. LIU Jia, YANG Hao-Tian, ZHANG Jing-Bo, ZHOU Xiao-Wen, LIN Yuan.Room Temperature Synthesis of Rutile TiO2 and Its Application in Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2011,27(02): 408-412
67. WU Tao, TAO Jie, DENG Jie, TANG Yu-Xin, ZHU Hong, GAO Peng.Preparation and Characterization of One-Dimensional TiO2 Nanowire Films on a Flexible Stainless Steel Substrate[J]. Acta Phys. -Chim. Sin., 2010,26(11): 3087-3094
68. QIAN Di-Feng, ZHANG Qing-Hong, WAN Jun, LI Yao-Gang, WANG Hong-Zhi.Enhancing the Photovoltaic Performance of Dye Sensitized Solar Cells with the TiO2 Sol Infiltrated Nanocrystalline Electrode[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2745-2751
69. LIU Yu-Liang, YOU Cui-Rong, LI Yang, HE Tao, ZHANG Xiang-Qin, SUO Zhang-Huai.Preparation of Au@TiO2 Catalyst Using Escherichia Coil as the Template and Its Oxidation Reaction Activity toward CO[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2455-2460
70. SONG Hua,GUO Yun-Tao, LI Feng ,YU Hong-Kun.Preparation, Hydrodesulfurization and Hydrodenitrogenation Performance of a Ni2P/TiO2-Al2O3 Catalyst[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2461-2467
71. XU Ping-Chang, LIU Yang, WEI Jian-Hong, XIONG Rui, PAN Chun-Xu, SHI Jing.Solvothermal Preparation of Ag/TiO2 Nanoparticles and Their Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2261-2266
72. ZHANG Qiong, HE Yun-Qiu, CHEN Xiao-Gang, HU Dong-Hu, LI Lin-Jiang, YIN Ting, JI Ling-Li.Intercalated Structure and Photocatalytic Properties of TiO2-Graphite Oxide Composite[J]. Acta Phys. -Chim. Sin., 2010,26(03): 654-662
73. ZHOU Bo, LIU Zhi-Guo, WANG Hong-Xia, HUANG Xi-Qiang, SUI Yu, WANG Xian-Jie, LV Zhe, SU Wen-Hui.Hydrothermal Preparation and Visible Photocatalytic Activity of Flower-Like Cu2O/Cu Nanocomposites[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1841-1846
74. ZHANG Xiao-Yan, CUI Xiao-Li.Preparation and Photocatalytic Hydrogen Evolution Performance of C-N Co-doped Nano TiO2 Photocatalysts[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1829-1834
75. DONG Xiang, TAO Jie, LI Ying-Ying, WANG Tao, ZHU Hong.Photoelectrochemical Properties of Three-Dimensional Network TiO2 Nanowire Film Prepared by Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1874-1882
76. DU Wei-Ping, LI Zhen, LENG Wen-Hua, XU Yi-Ming.Photocatalytic Reduction of Silver Ions on Ferric Oxides and Ferric Hydroxides[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1530-1534
77. FENG Li-Li, ZHAO Wei, LIU Yang, JIAO Liang, LI Xing-Guo.Photocatalytic Degradation of Rhodamine B by Nanocrystalline TiO2 Loaded into MCM-41 Molecular Sieves[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1347-1351
78. LEI Jian-Fei, LI Wei-Shan.Photoelectrocatalytic Performance of Arrayed Porous TiO2/Ti[J]. Acta Phys. -Chim. Sin., 2009,25(06): 1173-1178
79. YU Zhi-Yong; ZHANG Wei; MA Ming; CUI Xiao-Li.Visible Light Photoelectrochemical Response of Nitrogen-Doped TiO2 Thin Films Prepared by Anodic Oxidation of Titanium Nitride Films[J]. Acta Phys. -Chim. Sin., 2009,25(01): 35-40
80. CHANG Guo-Qing, ZHENG Xi, CHEN Ri-Yao, CHEN Xiao, CHEN Li-Qin, CHEN Zhen.Silver Nanoparticles Filling in TiO2 Hollow Nanofibers by Coaxial Electrospinning[J]. Acta Phys. -Chim. Sin., 2008,24(10): 1790-1796
81. ZHENG Bo; LI He-Xian; WANG Guo-Chang; LIU Kun; YUAN Wei; LI He; LIANG Bo.Supramolecular Complexation in Water-Methanol Mixtures[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1503-1506
82. LI Hai-Long; LUO Wu-Lin; CHEN Tao; TIAN Wen-Yu; SUN Mao; LI Chun; ZHU Di; LIU Ran-Ran; ZHAO Yu-Liang; LIU Chun-Li.Preparation and Photocatalytic Performance of Titania Nanotubes Loaded with Ag Nanoparticles[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1383-1386
83. SHI Jian; LI Jun; CAI Yun-Fa.Fabrication of C, N-Codoped TiO2 Nanotube Photocatalysts with Visible Light Response[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1283-1286
84. LUO Da-Chao; ZHANG Lan-Lan; LONG Hui-Jin; CHEN Yong-Mei; CAO Ya-An.Effect of Surface Modification by Ni2+ on Photocatalysis Activity of TiO2[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1095-1099
85. FENG Cai-Xia; WANG Yan; JIN Zhen-Sheng; ZHANG Shun-Li.Kinetic Behavior of Visible Light Photocatalytic Oxidation of Propylene for N-Doped Nano-TiO2[J]. Acta Phys. -Chim. Sin., 2008,24(04): 633-638
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87. ZHANG Jun-Jie; WU Min; QIN Yan-Tao; CHEN Rui; JIANG Yin-Hua; SUN Yue-Ming; YANG Zhao-Hui.Study on Zn(II) Tetracarboxy Phthalocyanine Doped TiO2 Electrode Using Electrochemical Impedance Spectrum[J]. Acta Phys. -Chim. Sin., 2008,24(01): 79-84
88. CHEN Qi-Yuan; TONG Hai-Xia; YIN Zhou-Lan; HU Hui-Ping; LI Jie; LIU Liang-Liang.Preparation, Characterization and Photo-catalytic Behavior of TiO2 Catalysts with Oxygen Vacancies[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1917-1921
89. ZHU Lei; CUI Xiao-Li; SHEN Jie; YANG Xi-Liang; ZHANG Zhuang-Jian.Visible Light Photoelectrochemical Response of Carbon-doped TiO2 Thin Films Prepared by DC Reactive Magnetron Sputtering[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1662-1666
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