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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 0,Vol.>> Issue()>> 0-0     doi: 10.3866/PKU.WHXB201704141         中文摘要
Accepted manuscript
Preparation of MoS2/TiO2 Composite Catalyst and Its Photocatalytic Hydrogen Production Activity under UV Irradiation
ZHANG Chi1,2, WU Zhi-Jiao2, LIU Jian-Jun1, PIAO Ling-Yu2
1 State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China;
2 CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, P. R. China
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To study the activity of a composite photocatalyst for photocatalytic hydrogen production, we prepared and loaded MoS2 nanosheets with TiO2 nanoparticles using a hydrothermal method, thus forming a MoS2/TiO2 heterojunction composite catalyst. The structural and optical properties of the catalyst were characterized and analyzed by field-emission scanning electron microscopy, high-resolution transmission electron microscopy, X-ray powder diffraction, UV-Vis absorption spectra, Raman spectroscopy, and X-ray photoelectron spectroscopy. The activity of the photocatalyst was evaluated by its photocatalytic hydrogen production rate. The corresponding MoS2 content of the catalyst was found to be 30%, and upon the exposure to 365nm UV light, a high photocatalytic hydrogen production rate of 1004 μmol-1·h-1·g-1 was obtained. The catalytic rate is much greater than that obtained with MoS2 or TiO2 catalysts. The high hydrogen production rate indicated that the use of a MoS2/TiO2 composite catalyst can significantly improve the UV-induced photocatalytic hydrogen production performance. Because of the excellent photocatalytic hydrogen production performance of the MoS2/TiO2 composite, we studied and analyzed the hydrogen production mechanism.



Keywords: TiO2   MoS2   Composite structure   Heterojunction   Photocatalytic hydrogen production  
Received: 2017-01-16 Accepted: 2017-04-11 Publication Date (Web): 2017-04-14
Corresponding Authors: LIU Jian-Jun, PIAO Ling-Yu Email: 13611012376@163.com,ljj-717@163.com;piaoly@nanoctr.cn

Fund: The project was supported by the Ministry of Science and Technology of China (2016YFA0200900, 2016YFF0203803).

Cite this article: ZHANG Chi, WU Zhi-Jiao, LIU Jian-Jun, PIAO Ling-Yu. Preparation of MoS2/TiO2 Composite Catalyst and Its Photocatalytic Hydrogen Production Activity under UV Irradiation[J]. Acta Phys. -Chim. Sin., 0, (): 0-0.    doi: 10.3866/PKU.WHXB201704141

(1) Balat, M. International Journal of Hydrogen Energy 2008, 33 (15), 4013. doi: 10.1016/j.ijhydene.2008.05.047
(2) Zheng, J. Y.; Zhang, J. F.; Chen, L. X.; W, G.; Gu, C. H.; Zhao, Y. Z.; Meng, B. J. Saf. Environ. 2016, 16 (6), 144. [郑津洋, 张俊峰, 陈霖新, 王赓, 顾超华, 赵永志, 蒙波. 安全与环境学报, 2016, 16 (6), 144.] doi: 10.13637/j.issn.1009-6094.2016.06.029
(3) Bai, S.; Wang, L. M.; Chen, X. Y.; Du, J. T.; Xiong, Y. J. Nano Res. 2015, 8 (1), 175. doi: 10.1007/s12274-014-0606-9
(4) Liu, Y. M.; Zhang, W. G.; Liang, W.; Wang, H. X.; Yu, B. Rare Metal Mat. Eng. 2015, 44 (7), 1754. [刘一鸣, 张王刚, 梁伟, 王红霞, 余彬. 稀有金属材料与工程, 2015, 44 (7), 1754.]
(5) Yang, J. H.; Wang, D. G.; Han, H. X.; Li, C. Acc. Chem. Res. 2013, 46 (8), 1900. doi: 10.1021/ar300227e
(6) Gu, P. C.; Zhang, K. L.; Feng, Y. L.; Wang, F.; Miao, Y. P.; Han, Y. M.; Zhang, H. X. Acta Phys. Sin. 2016, 65 (1), 18102. [顾品超, 张楷亮, 冯玉林, 王芳, 苗银萍, 韩叶梅, 张韩霞. 物理学报, 2016, 65 (1), 18102.] doi: 10.7498/aps.65.018102
(7) Wang, C. X.; Lin, H. H.; Liu, Z. Y.; Wu, J. P.; Xu, Z. Z.; Zhang, C. Part. Part. Syst. Charact. 2016, 33 (4), 221. doi: 10.1002/ppsc.201500222
(8) Wang, X.; Song, L.; Chen, L.; Song, H. H.; Zhang, Y. P. Adv. Mater. Chem. 2015, 2 (4), 49. [王轩, 宋礼, 陈露, 宋欢欢, 张永平. 材料化学进展, 2015, 2 (4), 49.] doi: 10.12677/AMC.2014.24008
(9) Yuan, Y. J.; Ye, Z. J.; Lu, H. W.; Hu, B.; Li, Y. H.; Chen, D. Q.; Zhong, J. S.; Yu, Z. T.; Zou, Z. G. ACS Catal. 2015, 6 (2), 532. doi: 10.1021/acscatal.5b02036
(10) He, H. Y.; Lin, J. H.; Fu, W.; Wang, X. L.; Wang, H.; Zeng, Q. S.; Gu, Q.; Li, Y. M.; Yan, C.; Tay, B. K.; Xue, C.; Hu, X.; Liu, Z. Adv. Energy Mater. 2016, 6 (14). doi: 10.1002/aenm.201600464
(11) Zhou, W. J.; Yin, Z. Y.; Du, Y. P.; Huang, X.; Zeng, Z. Y.; Fan, Z. X.; Liu, H.; Wang, J. Y.; Zhang, H. Small 2013, 9 (1), 140. doi: 10.1002/smll.201201161
(12) Wang, J.; Liu, J. L.; Chao, D. L.; Yan, J. X.; Lin, J. Y.; Shen, Z. X. Adv. Mater. 2014, 26 (42), 7162. doi: 10.1002/adma.201402728
(13) Li, Y. G.; Wang, H. L.; Xie, L. M.; Liang, Y. Y.; Hong, G. S.; Dai, H. Y. J. Am. Chem. Soc. 2011, 133 (19), 7296. doi: 10.1021/ja201269b
(14) Zhang, C, X.; Zhang, X. X.; Tao, H. J. Acta Phys. -Chim. Sin. 2014, 30 (10), 1963. [张传香, 张晓雪, 陶海军. 物理化学学报, 2014, 30 (10), 1963.] doi: 10.3866/PKU.WHXB201408043
(15) Tye, C. T.; Smith, K. J. Catal. Today 2006, 116 (4), 461. doi: 10.1016/j.cattod.2006.06.028
(16) Shen, M.; Yan, Z. P.; Yang, L.; Du, P. W.; Zhang, J. Y.; Xiang, B. Chem. Commun. 2014, 50 (97), 15447. doi: 10.1039/C4CC07351G
(17) Li, H. D.; Wang, Y.; Chen, G. H.; Sang, Y. H.; Jiang, H. D.; He, J. T.; Li, X.; Liu, H. Nanoscale 2016, 8 (11), 6101. doi: 10.1039/C5NR08796A
(18) Lin, T. Z.; Kang, B. T.; Jeon, M. H.; Huffman, C.; Jeon, J. H.; Lee, S. J.; Kim, K. N. ACS Appl. Mater. Interfaces 2015, 7 (29), 15892. doi: 10.1021/acsami.5b03491
(19) Ho, W. K.; Yu, J. C.; Lin, J.; Yu, J. G.; Li, P. S. Langmuir 2004, 20 (14), 5865. doi: 10.1021/la049838g
(20) Li, D. F.; Zheng, J.; Chen, X. Y.; Zou, Z. G. Prog. Chem. 2007, 19 (4), 464. [李敦钫, 郑菁, 陈新益, 邹志刚. 化学进展, 2007, 19 (4), 464.]
(21) Liu, H.; Lv, T.; Zhu, C. K.; Su, X.; Zhu, Z. F. J. Mol. Catal. A: Chem. 2015, 396, 136. doi: 10.1016/j.molcata.2014.10.002
(22) Lee, Y. H.; Zhang, X. Q.; Zhang, W. J.; Chang, M. T.; Lin, C. T.; Chang K, D.; Li, L. J.; Lin, T. W. Adv. Mater. 2012, 24 (17), 2320. doi: 10.1002/adma.201104798
(23) Chen, Z.; Cummins, D.; Reinecke, B. N.; Clark, E.; Sunkara, M. K.; Jaramillo, T. F. Nano Lett. 2011, 11 (10), 4168. doi: 10.1021/nl2020476
(24) Wang, H. W.; Skeldon, P.; Thompson, G. E. Surf. Coat. Technol. 1997, 91 (3), 200. doi: 10.1016/S0257-8972(96)03186-6
(25) Xie, J. F.; Zhang, H.; Li, S.; Wang. R. X.; Sun, X.; Zhou, M.; Zhou, J. F.; Xie, Y. Adv. Mater. 2013, 25 (40), 5807. doi: 10.1002/adma.201302685
(26) Karunadasa, H. I.; Montalvo, E.; Sun, Y. J.; Majda, M.; Long, J. R. Chang, C. J. Science 2012, 335 (6069), 698. doi: 10.1126/science.1215868
(27) Hinnemann, B.; Moses, P. G.; Bonde, J.; Jorgensen, K. P.; Nielsen, J H.; Horch, S.; Norskov, J. K. J. Am. Chem. Soc. 2005, 127, 5308. doi: 10.1021/ja0504690
(28) Chang, K.; Mei, Z. W.; Wang, T.; Kang, Q.; Ouyang, S. X.; Ye, J. H. ACS Nano 2014, 8 (7), 7078. doi: 10.1021/nn5019945
(29) Yan, Y.; Xia, B. Y.; Ge, X. M.; Liu, Z. L.; Wang, J. Y.; Wang, X. ACS Appl. Mater. Interfaces 2013, 5, 12794. doi: 10.1021/am404843b
(30) Wang, Y.; Li, G.; Li, P. W.; Hu, J.; Zhao, Q. H. Semicond Opt. 2016, No. 4, 461. [王毅, 李刚, 李朋伟, 胡杰, 赵清华. 半导体光电, 2016, No. 4, 461.] doi: 10.16818/j.issn1001-5868.2016.04.002

1. WANG Hui, ZOU De-Chun.Polyol-Mediated Synthesis of MoS2 Nanosheets Using Sulfur Powder as the Sulfur Source[J]. Acta Phys. -Chim. Sin., 2017,33(5): 1027-1032
2. DAI Wei-Guo, HE Dan-Nong.Selective Photoelectrochemical Oxidation of Chiral Ibuprofen Enantiomers[J]. Acta Phys. -Chim. Sin., 2017,33(5): 960-967
3. ZHAO Li-Ping, MENG Wei-Shuai, WANG Hong-Yu, QI Li.MoS2-C Composite as Negative Electrode Material for Sodium-Ion Supercapattery[J]. Acta Phys. -Chim. Sin., 2017,33(4): 787-794
4. XING Lei, JIAO Li-Ying.Recent Advances in the Chemical Doping of Two-Dimensional Molybdenum Disulfide[J]. Acta Phys. -Chim. Sin., 2016,32(9): 2133-2145
5. TANG Wei, WANG Jing.Enhanced Gas Sensing Mechanisms of Metal Oxide Heterojunction Gas Sensors[J]. Acta Phys. -Chim. Sin., 2016,32(5): 1087-1104
6. WANG Yan-Juan, SUN Jia-Yao, FENG Rui-Jiang, ZHANG Jian.Preparation of Ternary Metal Sulfide/g-C3N4 Heterojunction Catalysts and Their Photocatalytic Activity under Visible Light[J]. Acta Phys. -Chim. Sin., 2016,32(3): 728-736
7. XU Zheng-Xia, YANG Ji-Tao, LIU Kang, GUO Xiao-Qiang.Shape Evolution Behavior of Anatase Titania Nanocrystals via the Solvothermal Method[J]. Acta Phys. -Chim. Sin., 2016,32(2): 581-588
8. ZHAO Zong-Yan, TIAN Fan.Theoretical Study of the Interfacial Structure and Properties of a CdS/FeP Composite Photocatalyst[J]. Acta Phys. -Chim. Sin., 2016,32(10): 2511-2517
9. GUO Qing, ZHOU Chuan-Yao, MA Zhi-Bo, REN Ze-Feng, FAN Hong-Jun, YANG Xue-Ming.Fundamental Processes in Surface Photocatalysis on TiO2[J]. Acta Phys. -Chim. Sin., 2016,32(1): 28-47
10. LI Xiao-Kun, MA Dong-Dong, ZHENG Yan-Ping, ZHANG Hong, DING Ding, CHEN Ming-Shu, WAN Hui-Lin.Performance of CO Oxidation over Highly Dispersed Gold Catalyst on TiOx/SiO2 Composite Supports[J]. Acta Phys. -Chim. Sin., 2015,31(9): 1753-1760
11. SHI Chen-Yang, HE Hui-Bin, HONG Zan-Fa, ZHAN Hong-Bing, FENG Miao.Effect of HCl Post-Treatment on Morphology of Hydrothermally Prepared Titanate Nanomaterials with Optical Limiting Properties[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1430-1436
12. QIAO Zhi, XIE Xin-Jian, XUE Jun-Ming, LIU Hui, LIANG Li-Min, HAO Qiu-Yan, LIU Cai-Chi.Optimization of Intrinsic Silicon Passivation Layers in nc-Si:H/c-Si Silicon Heterojunction Solar Cells[J]. Acta Phys. -Chim. Sin., 2015,31(6): 1207-1214
13. ZHANG Qiao-Ling, LI Lei, LIU You-Zhi, WEI Bing, GUO Jia-Xin, FENG Yu-Jie.Grafting Dynamics, Structures and Properties of Nano TiO2-SA Photocatalytic Materials[J]. Acta Phys. -Chim. Sin., 2015,31(6): 1015-1024
14. XU Jing, YANG De-Zhi, LIAO Xiao-Zhen, HE Yu-Shi, MA Zi-Feng.Electrochemical Performances of Reduced Graphene Oxide/Titanium Dioxide Composites for Sodium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2015,31(5): 913-919
15. LIU Xing, LI Yue-Xiang, PENG Shao-Qin, LAI Hua.Progress in Visible-Light Photocatalytic Hydrogen Production by Dye Sensitization[J]. Acta Phys. -Chim. Sin., 2015,31(4): 612-626
16. LI Xiang-Qi, FAN Qing-Fei, LI Guang-Li, HUANG Yao-Han, GAO Zhao, FAN Xi-Mei, ZHANG Chao-Liang, ZHOU Zuo-Wan.Syntheses of ZnO Nano-Arrays and Spike-Shaped CuO/ZnO Heterostructure[J]. Acta Phys. -Chim. Sin., 2015,31(4): 783-792
17. YU Jian-Hua, FAN Min-Guang, LI Bin, DONG Li-Hui, ZHANG Fei-Yue.Preparation and Photocatalytic Activity of Mixed Phase TiO2-Graphene Composites[J]. Acta Phys. -Chim. Sin., 2015,31(3): 519-526
18. CHEN Hong, WANG Shi-Xian, ZHAO Wan-Long, ZHANG Neng-Neng, ZHENG Ying-Ping, SUN Yue-Ming.Preparation of Pt/TiO2 Nanofibers and Their Electrocatalytic Activity towards Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2015,31(2): 302-308
19. SHAO Yan, OUYANG Fang-Ping, PENG Sheng-Lin, LIU Qi, JIA Zhi-An, ZOU Hui.First-Principles Calculations of Electronic Properties of Defective Armchair MoS2 Nanoribbons[J]. Acta Phys. -Chim. Sin., 2015,31(11): 2083-2090
20. WANG Li-Guo, ZHANG Xiao-Dan, WANG Feng-You, WANG Ning, JIANG Yuan-Jian, HAO Qiu-Yan, XU Sheng-Zhi, WEI Chang-Chun, ZHAO Ying.Influence of Different Pyramidal Structural Morphologies of Crystalline Silicon Wafers for Surface Passivation and Heterojunction Solar Cells[J]. Acta Phys. -Chim. Sin., 2014,30(9): 1758-1763
21. ZHANG Jian-Fang, WANG Yan, SHEN Tian-Kuo, SHU Xia, CUI Jie-Wu, CHEN Zhong, WU Yu-Cheng.Visible Light Photocatalytic Performance of Cu2O/TiO2 Nanotube Heterojunction Composites Prepared by Pulse Deposition[J]. Acta Phys. -Chim. Sin., 2014,30(8): 1535-1542
22. TIAN Hong, WANG Hui-Xiang, SHI Wei-Mei, XU Yao.Microwave-Assisted Solvothermal Synthesis of In-Si Co-Modified TiO2 Photocatalysts with Enhanced Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2014,30(8): 1543-1549
23. ZHAO Wei-Rong, SHI Qiao-Meng, LIU Ying.Performance, Deactivation and Regeneration of SnO2/TiO2 Nanotube Composite Photocatalysts[J]. Acta Phys. -Chim. Sin., 2014,30(7): 1318-1324
24. YAN Jing-Sen, WANG Hai-Yan, ZHANG Jing-Ru, XU Hui-Juan.Effect of TiO2-Al2O3 Support Preparation Technique on Hydrodenitrogenation of Ni2P/TiO2-Al2O3 Catalysts[J]. Acta Phys. -Chim. Sin., 2014,30(7): 1309-1317
25. WANG Shi-Mao, DONG Wei-Wei, FANG Xiao-Dong, DENG Zan-Hong, SHAO Jing-Zhen, HU Lin-Hua, ZHU Jun.Modification of Single-Crystal TiO2 Nanorod Arrays and Its Application in Quantum Dot-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2014,30(5): 873-880
26. AO Ping, XU Xiang-Sheng, XU Xiao-Xiao, LI Jia-Heng, YAN Xin-Huan.Low-Temperature Total Oxidation of Toluene over Assembled Pt/TiO2 Catalyst[J]. Acta Phys. -Chim. Sin., 2014,30(5): 950-956
27. ZHAO Wei-Rong, ZENG Wan-Yun, XI Hai-Ping, YU Xian-Xian.Photocatalytic Degradation of Gas-Phase Toluene over CuO Loaded BiVO4 Hollow Nanospheres under Visible-light Irradiation[J]. Acta Phys. -Chim. Sin., 2014,30(4): 761-767
28. TANG Wei, WANG Jing, YAO Peng-Jun, DU Hai-Ying, SUN Yan-Hui.Preparation, Characterization and Gas Sensing Mechanism of ZnO-Doped SnO2 Nanofibers[J]. Acta Phys. -Chim. Sin., 2014,30(4): 781-788
29. NI Ting, ZOU Fan, JIANG Yu-Rong, YANG Sheng-Yi.To Improve the Efficiency of Bulk Heterojunction Organic Solar Cells by Incorporating CdSe/ZnS Quantum Dots[J]. Acta Phys. -Chim. Sin., 2014,30(3): 453-459
30. PEI Juan, HAO Yan-Zhong, SUN Bao, LI Ying-Pin, FAN Long-Xue, SUN Shuo, WANG Shang-Xin.Heterojunction Interface Modification and Its Effect on the Photovoltaic Performance of Hybrid Solar Cells[J]. Acta Phys. -Chim. Sin., 2014,30(3): 397-407
31. LAN Ben-Yue, SHI Hai-Feng.Review of Systems for Photocatalytic Conversion of CO2 to Hydrocarbon Fuels[J]. Acta Phys. -Chim. Sin., 2014,30(12): 2177-2196
32. JIANG Chun-Xiang, HU Yu-Xiang, DONG Wen, ZHENG Fen-Gang, SU Xiao-Dong, FANG Liang, SHEN Ming-Rong.Bias-Determined Cu2O and Cu Growth on TiO2 Surface and Their Photoelectrochemical Properties[J]. Acta Phys. -Chim. Sin., 2014,30(10): 1867-1875
33. ZHANG Yu, LIN Shen, ZHANG Yu, SONG Xi-Ming.Properties of Photogenerated Charge Carriers and Visible-Light Surface Photocurrent of Heterogeneous ZnO/BiVO4-V2O5 Structures[J]. Acta Phys. -Chim. Sin., 2013,29(11): 2399-2404
34. YANG Zhi-Xiong, YANG Jin-Xin, LIU Qi, XIE Yu-Xing, XIONG Xiang, OUYANG Fang-Ping.Electronic Structure and Edge Modification of Armchair MoS2 Nanoribbons[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1648-1654
35. SHANG Yang, CHEN Yang, SHI Zhan-Bin, ZHANG Dong-Feng, GUO Lin.Synthesis and Visible Light Photocatalytic Activities of Au/Cu2O Heterogeneous Nanospheres[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1819-1826
36. WEI Mei-Ju, JIA De-Qiang, CHEN Fei-Wu.Geometric Structures, Excitation Energies and Dipole Moments of the Ground and Excited States of TiO2[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1441-1452
37. LONG Mei, CONG Ye, LI Xuan-Ke, CUI Zheng-Wei, DONG Zhi-Jun, YUAN Guan-Ming.Hydrothermal Synthesis and Photocatalytic Activity of Partially Reduced Graphene Oxide/TiO2 Composite[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1344-1350
38. LI Na, CHEN Qiu-Yan, LUO Meng-Fei, LU Ji-Qing.Kinetics Study of CO Oxidation Reaction over Pt/TiO2 Catalysts[J]. Acta Phys. -Chim. Sin., 2013,29(05): 1055-1062
39. TANG Peng, XIAO Jian-Jian, ZHENG Chao, WANG Shi, CHEN Run-Feng.Graphene-Like Molybdenum Disulfide and Its Application in Optoelectronic Devices[J]. Acta Phys. -Chim. Sin., 2013,29(04): 667-677
40. LIU Su-Qin, DAI Gao-Peng, LIANG Ying, LIU Hua-Jun, LIANG Gui-Jie.Fabrication and Visible-Light Photocatalytic Activity of In situ Carbon and Nitrogen Co-Doped TiO2 Hollow Sphere[J]. Acta Phys. -Chim. Sin., 2013,29(03): 585-589
41. LONG Ming-Ce, WAN Lei, ZENG Ceng, LIU Yi-Yi, CHEN Yuan-Yuan.Enhanced Visible Light Activity of BiVO4 by Treating in HCl Aqueous Solution and Its Mechanism[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2917-2923
42. JIN Tao, XU Di, DIAO Peng, XIANG Min.Preparation and Photoelectrocatalytic Water Oxidation Properties of FeO(OH)-TiO2/CoPi Composite Photoanodes[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2276-2284
43. GAO Ji-Ning, ZHAO Hua-Bo, QI Li-Min.Synthesis of Silver Sulfide Hollow Sphere-Silver Nanoparticle Heterostructures Based on Reactive Templates[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2487-2492
44. DAI Gao-Peng, LIU Su-Qin, PENG Rong, LUO Tian-Xiong.Fabrication of Bi2O3/Bi2O3 Nanotube Arrays with High Visible-Light Photocatalytic Activity by Impregnation-Decomposition Method[J]. Acta Phys. -Chim. Sin., 2012,28(09): 2169-2174
45. LIU Hao, LIN Meng-Hai, TAN Kai.A Tight-Binding Density Functional Theory Study on Single-Walled Nanotubes from Anatase TiO2 (101) Sheets[J]. Acta Phys. -Chim. Sin., 2012,28(08): 1843-1848
46. ZHAO Peng-Jun, WU Rong, HOU Juan, CHANG Ai-min, GUAN Fang, ZHANG Bo.One-Step Hydrothermal Synthesis and Visible-Light Photocatalytic Activity of Ultrafine Cu-Nanodot-Modified TiO2 Nanotubes[J]. Acta Phys. -Chim. Sin., 2012,28(08): 1971-1977
47. HU Wen-Liang, XU Gang, MA Jian-Wei, XIONG Bin, SHI Ji-Fu.Optical and Phase Transition Properties of TixV1-xO2 Thin Films[J]. Acta Phys. -Chim. Sin., 2012,28(06): 1533-1538
48. LIU Qiu-Ping, HUANG Hui-Juan, ZHOU Yang, DUAN Yan-Dong, SUN Qing-Wen, LIN Yuan.Photovoltaic Performance of Dye-Sensitized Solar Cells Based on Al-Doped TiO2 Thin Films[J]. Acta Phys. -Chim. Sin., 2012,28(03): 591-595
49. SONG Hua, ZHANG Yong-Jiang, SONG Hua-Lin, DAI Min.Effect of Citric Acid on the Hydrodesulfurization Performance of Ni2P/TiO2-Al2O3 Catalyst[J]. Acta Phys. -Chim. Sin., 2012,28(03): 661-666
50. XIAO Yao-Ming, WU Ji-Huai, YUE Gen-Tian, LIN Jian-Ming, HUANG Miao-Liang, FAN Le-Qing, LAN Zhang.Preparation of Single-Crystalline TiO2 Nanowires and Their Application in Flexible Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2012,28(03): 578-584
51. GAO Yue-Jun, XU Yi-Ming.Effect of Fluoride Doping and Adsorption on the Photocatalytic Activity of TiO2[J]. Acta Phys. -Chim. Sin., 2012,28(03): 641-646
52. YAN Bing-Xi, LUO Sheng-Yun, SHEN Jie.Photoelectric Properties of Mo Doped TiO2 Thin Films Deposited by DC Reactive Magnetron Sputtering[J]. Acta Phys. -Chim. Sin., 2012,28(02): 381-386
53. DONG Hua-Qing, PAN Xi, XIE Qin, MENG Qiang-Qiang, GAO Jian-Rong, WANG Jian-Guo.CO Adsorption and Oxidation on Metal-Doped TiO2 Nanotube Arrays[J]. Acta Phys. -Chim. Sin., 2012,28(01): 44-50
54. LI Bo.Investigation on Photocurrent Polarity of a Bulk Heterojunction Organic Photovoltaic Device Using a Ferroelectric Thin Film[J]. Acta Phys. -Chim. Sin., 2012,28(01): 217-222
55. NIE Long-Hui, HU Yao, ZHANG Wang-Xi.Preparation of a Ag@AgCl-Modified TiO2-xCx Photocatalyst and Its Performance for Degradation of Pollutants under Visible Light[J]. Acta Phys. -Chim. Sin., 2012,28(01): 154-160
56. PENG Jing, FANG Xiao-Ming, CHEN Zhi-Hong, ZHANG Zheng-Guo.Effects of CdSe Layer Number on the Optical Properties and Microstructures of CdTe/CdSe (II) Core/Shell Quantum Dots[J]. Acta Phys. -Chim. Sin., 2012,28(01): 232-238
57. HU Xian-Chao, CHEN Dan, SHI Bin-Bin, LI Guo-Hua.Preparation of Tungsten Carbide and Titania Nanocomposite and Its Electrocatalytic Activity for Methanol[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2863-2871
58. CHEN Shu-Hai, XU Yao, LÜ Bao-Liang, WU Dong.Microwave-Assisted Hydrothermal Synthesis of Ag-Loaded Titania Nanotubes and Their Photocatalytic Performance[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2933-2938
59. YAN Shi, HUANG Qin-Dong, LIN Jing-Dong, YUAN You-Zhu, LIAO Dai-Wei.Photocatalytic Activity of Cobalt Doped Titania for H2 Evolution[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2406-2410
60. TONG Xin, CHEN Rui, CHEN Tie-Hong.Photocatalytic Activity of TiO2 with Micrometer-Sized Macropores[J]. Acta Phys. -Chim. Sin., 2011,27(08): 1941-1946
61. CONG Ye, QIN Yun, LI Xuan-Ke, DONG Zhi-Jun, YUAN Guan-Ming, CUI Zheng-Wei.Preparation and Visible Light Photocatalytic Activity of Titanium Dioxide Coated Multiwalled Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1509-1515
62. LI Huan-Huan, CHEN Run-Feng, MA Cong, ZHANG Sheng-Lan, AN Zhong-Fu, HUANG Wei.Titanium Oxide Nanotubes Prepared by Anodic Oxidation and Their Application in Solar Cells[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1017-1025
63. JIANG Jing-Jing, LONG Ming-Ce, WU De-Yong, CAI Wei-Min.Preparation of F-Modified Nanosized TiO2 and Its Methyl Orange Photodegradation Mechanism[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1149-1156
64. LAO Chun-Feng, CHU Zeng-Ze, ZOU De-Chun.Self-Assembly of 3-Aminopropyltrimethoxysilane to Improve the Efficiency of Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2011,27(02): 419-424
65. LIU Jia, YANG Hao-Tian, ZHANG Jing-Bo, ZHOU Xiao-Wen, LIN Yuan.Room Temperature Synthesis of Rutile TiO2 and Its Application in Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2011,27(02): 408-412
66. WU Tao, TAO Jie, DENG Jie, TANG Yu-Xin, ZHU Hong, GAO Peng.Preparation and Characterization of One-Dimensional TiO2 Nanowire Films on a Flexible Stainless Steel Substrate[J]. Acta Phys. -Chim. Sin., 2010,26(11): 3087-3094
67. QIAN Di-Feng, ZHANG Qing-Hong, WAN Jun, LI Yao-Gang, WANG Hong-Zhi.Enhancing the Photovoltaic Performance of Dye Sensitized Solar Cells with the TiO2 Sol Infiltrated Nanocrystalline Electrode[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2745-2751
68. LIU Yu-Liang, YOU Cui-Rong, LI Yang, HE Tao, ZHANG Xiang-Qin, SUO Zhang-Huai.Preparation of Au@TiO2 Catalyst Using Escherichia Coil as the Template and Its Oxidation Reaction Activity toward CO[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2455-2460
69. SONG Hua,GUO Yun-Tao, LI Feng ,YU Hong-Kun.Preparation, Hydrodesulfurization and Hydrodenitrogenation Performance of a Ni2P/TiO2-Al2O3 Catalyst[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2461-2467
70. XU Ping-Chang, LIU Yang, WEI Jian-Hong, XIONG Rui, PAN Chun-Xu, SHI Jing.Solvothermal Preparation of Ag/TiO2 Nanoparticles and Their Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2261-2266
71. ZHANG Qiong, HE Yun-Qiu, CHEN Xiao-Gang, HU Dong-Hu, LI Lin-Jiang, YIN Ting, JI Ling-Li.Intercalated Structure and Photocatalytic Properties of TiO2-Graphite Oxide Composite[J]. Acta Phys. -Chim. Sin., 2010,26(03): 654-662
72. ZHOU Bo, LIU Zhi-Guo, WANG Hong-Xia, HUANG Xi-Qiang, SUI Yu, WANG Xian-Jie, LV Zhe, SU Wen-Hui.Hydrothermal Preparation and Visible Photocatalytic Activity of Flower-Like Cu2O/Cu Nanocomposites[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1841-1846
73. ZHANG Xiao-Yan, CUI Xiao-Li.Preparation and Photocatalytic Hydrogen Evolution Performance of C-N Co-doped Nano TiO2 Photocatalysts[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1829-1834
74. DONG Xiang, TAO Jie, LI Ying-Ying, WANG Tao, ZHU Hong.Photoelectrochemical Properties of Three-Dimensional Network TiO2 Nanowire Film Prepared by Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1874-1882
75. DU Wei-Ping, LI Zhen, LENG Wen-Hua, XU Yi-Ming.Photocatalytic Reduction of Silver Ions on Ferric Oxides and Ferric Hydroxides[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1530-1534
76. FENG Li-Li, ZHAO Wei, LIU Yang, JIAO Liang, LI Xing-Guo.Photocatalytic Degradation of Rhodamine B by Nanocrystalline TiO2 Loaded into MCM-41 Molecular Sieves[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1347-1351
77. LEI Jian-Fei, LI Wei-Shan.Photoelectrocatalytic Performance of Arrayed Porous TiO2/Ti[J]. Acta Phys. -Chim. Sin., 2009,25(06): 1173-1178
78. YU Zhi-Yong; ZHANG Wei; MA Ming; CUI Xiao-Li.Visible Light Photoelectrochemical Response of Nitrogen-Doped TiO2 Thin Films Prepared by Anodic Oxidation of Titanium Nitride Films[J]. Acta Phys. -Chim. Sin., 2009,25(01): 35-40
79. CHANG Guo-Qing, ZHENG Xi, CHEN Ri-Yao, CHEN Xiao, CHEN Li-Qin, CHEN Zhen.Silver Nanoparticles Filling in TiO2 Hollow Nanofibers by Coaxial Electrospinning[J]. Acta Phys. -Chim. Sin., 2008,24(10): 1790-1796
80. ZHENG Bo; LI He-Xian; WANG Guo-Chang; LIU Kun; YUAN Wei; LI He; LIANG Bo.Supramolecular Complexation in Water-Methanol Mixtures[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1503-1506
81. LI Hai-Long; LUO Wu-Lin; CHEN Tao; TIAN Wen-Yu; SUN Mao; LI Chun; ZHU Di; LIU Ran-Ran; ZHAO Yu-Liang; LIU Chun-Li.Preparation and Photocatalytic Performance of Titania Nanotubes Loaded with Ag Nanoparticles[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1383-1386
82. SHI Jian; LI Jun; CAI Yun-Fa.Fabrication of C, N-Codoped TiO2 Nanotube Photocatalysts with Visible Light Response[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1283-1286
83. LUO Da-Chao; ZHANG Lan-Lan; LONG Hui-Jin; CHEN Yong-Mei; CAO Ya-An.Effect of Surface Modification by Ni2+ on Photocatalysis Activity of TiO2[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1095-1099
84. FENG Cai-Xia; WANG Yan; JIN Zhen-Sheng; ZHANG Shun-Li.Kinetic Behavior of Visible Light Photocatalytic Oxidation of Propylene for N-Doped Nano-TiO2[J]. Acta Phys. -Chim. Sin., 2008,24(04): 633-638
85. WU Yu-Cheng; LIU Xiao-Lu; YE Min; XIE Ting; HUANG Xin-Min.Preparation and Properties of Carbon Nanotube-TiO2 Nanocomposites[J]. Acta Phys. -Chim. Sin., 2008,24(01): 97-102
86. ZHANG Jun-Jie; WU Min; QIN Yan-Tao; CHEN Rui; JIANG Yin-Hua; SUN Yue-Ming; YANG Zhao-Hui.Study on Zn(II) Tetracarboxy Phthalocyanine Doped TiO2 Electrode Using Electrochemical Impedance Spectrum[J]. Acta Phys. -Chim. Sin., 2008,24(01): 79-84
87. CHEN Qi-Yuan; TONG Hai-Xia; YIN Zhou-Lan; HU Hui-Ping; LI Jie; LIU Liang-Liang.Preparation, Characterization and Photo-catalytic Behavior of TiO2 Catalysts with Oxygen Vacancies[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1917-1921
88. ZHU Lei; CUI Xiao-Li; SHEN Jie; YANG Xi-Liang; ZHANG Zhuang-Jian.Visible Light Photoelectrochemical Response of Carbon-doped TiO2 Thin Films Prepared by DC Reactive Magnetron Sputtering[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1662-1666
89. YANG Hui; SHEN Qian-Hong; GAO Ji-Wei.Morphology Control of Anatase TiO2 Films Prepared at Low Temperature Using 4,4’-isopropylidenediphenol[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1269-1274
90. HUANG Dong-Sheng; ZENG Ren-Jie; CHEN Chao-Feng; LI Yu-Hua.Hydrophilicity of TiO2 Thin Films Codoped with Iron and Nitrogen[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1037-1041
91. YAN Zhi-Ying; WU Li-Yan; SUN Gui-Xiang; ZHANG Ning; ZHENG Wen-Jun.Structural Characterization of Nanocrystalline TiO2 fromIonic Liquid-Water Solvent Mixture and Its Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1032-1036
92. DING Ying-Ying; LI Kui-Ying.Photoacoustic and Surface Photovoltaic Characters of Nanocrystalline TiO2[J]. Acta Phys. -Chim. Sin., 2007,23(04): 569-574
93. GU Hong;XU Bo-Lian;ZHOU Jing;LI Yuan-Zhi;FAN Yi-Ning.Catalytic Properties of Supported Pd/TiO2 and Pd-Ag/TiO2 Catalysts for Selective Hydrogenation of Acetylene[J]. Acta Phys. -Chim. Sin., 2006,22(06): 712-715
94. ZHANG Xue-Hong;TANG Xing-Hua;CHENG Xin-Sun.Synthesis and Application of Ce-doped Mesoporous TiO2[J]. Acta Phys. -Chim. Sin., 2006,22(05): 532-537
95. WANG Peng; CHEN Dong; LIU Jian-Shu; TANG Fang-Qiong.Synthesis and Characterization of Monodisperse TiO2 Colloid Particles[J]. Acta Phys. -Chim. Sin., 2006,22(03): 365-368
96. LI Zhi-Jie; HOU Bo; XU Yao; WU Dong; SUN Yu-Han.Preparation and Characterization of Silica-modified Titanium Dioxide Nanoparticles by Co-precipitation Method[J]. Acta Phys. -Chim. Sin., 2005,21(03): 229-233
97. YAN Qing-Zhi;SU Xin-Tai;ZHOU Yan-Ping;GE Chang-Chun.Controlled Synthesis of TiO2 Nanometer Powders by Sol-gel Auto-igniting Process and Their Structural Property[J]. Acta Phys. -Chim. Sin., 2005,21(01): 57-62
98. Li Yue-Xiang; Wang Tian-Hui; Peng Shao-Qin1 Lü Gong-Xuan; Li Shu-Ben.Synergistic Effect of Eu3+ and Si4+ Co-doping on Photocatalytic Activity of Titanium Dioxide[J]. Acta Phys. -Chim. Sin., 2004,20(12): 1434-1439
99. Shen Jie;Wo Song-Tao;Cui Xiao-Li;Cai Zhen-Wei;Yang Xi-Liang;Zhang Zhuang-Jian.Photoelectrochemical Characteristics of Nano-Titanium Dioxide Thin Films Prepared by RF Magnetron Sputtering[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1191-1195
100. Liu Xiang-Yang;Zhang Zhong-Suo;Zhang Xing-Tang;Cheng Ke;Huang Ya-Bin;Wang De-Jun;Du Zu-Liang.Photovoltage Property about Heterojunction Composite Film with 1,4-bis (ferrocene) Thiophene and SnO2 Nanoparticles[J]. Acta Phys. -Chim. Sin., 2004,20(09): 1167-1171
101. Zhang Qi;Li Xin-Jun;Li Fang-Bai;Chang Jie.Investigation on Visible -light Activity of WOx/TiO2 Photocatalyst[J]. Acta Phys. -Chim. Sin., 2004,20(05): 507-511
102. Liu Shou-Xin;Sun Cheng-Lin.Mechanism of Silver Modification for the Enhanced Photocatalytic Activity of Cr(VI) Reduction on TiO2 Photocatalyst[J]. Acta Phys. -Chim. Sin., 2004,20(04): 355-359
103. Zhang Jin-Long;Zhao Wen-Juan;Chen Hai-Jun;Xu Hua-Sheng;Chen Ai-Ping;Anpo Masa-Kazu.Study of Loaded Photocatalysts by Precious Metals on the Photocatalytic Reactivity[J]. Acta Phys. -Chim. Sin., 2004,20(04): 424-427
104. Wu ShuXin;Ma Zhi;Qin Yong-Ning;Qi Xiao-Zhou;Liang Zhen-Cheng.Photocatalytic Redox Activity of Doped Nanocrystalline TiO2[J]. Acta Phys. -Chim. Sin., 2004,20(02): 138-143
105. Ding Zheng-Xin;Hou Yi-Dong;Li Dan-Zhen;Wang Xu-Xu;Fu Xian-Zhi;Liu Ping.Effect of Morphological Structure and Photoelectric Properties on Photocatalytic Performance of TiO2[J]. Acta Phys. -Chim. Sin., 2003,19(10): 978-981
106. Wu Shu-Xin;Ma Zhi;Qin Yong-Ning;He Fei;Jia Li-Shan;Zhang Yan-Jun.XPS Study of Copper Doping TiO2 Photocatalyst[J]. Acta Phys. -Chim. Sin., 2003,19(10): 967-969
107. Ren Da-Sen;Cui Xiao-Li;Zhang Qun;Wo Song-Tao;Yang Xi-Liang;Zhang Zhuang-Jian;Lu Ming.Characteristics of SiO2-TiO2 Complex Thin Films Prepared by Sol Method[J]. Acta Phys. -Chim. Sin., 2003,19(09): 829-833
108. Zhang Sheng-Mao;Zhang Zhi-Jun;Dang Hong-Xin;Liu Wei-Min;Xue Qun-Ji.Preparation and Characterization of TiO2/Poly(butyl acrylate) Nanocomposite Film[J]. Acta Phys. -Chim. Sin., 2003,19(02): 171-173
109. Qin Cao;Wang Ting-Jie;Jin Yong.The Coating Process of Nano-scale Hydrous Silica Film on TiO2 Particles by Chemical Deposition in Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2002,18(10): 884-889
110. Kuang Han-Mao;Deng Zhao-Xiang;Li Chun-Hui;Sun Xiao-Ming;Zhuang Jing;Li Ya-Dong.Synthesis and Photoluminescent Properties of CdS/SiO2 Nanorod[J]. Acta Phys. -Chim. Sin., 2002,18(05): 477-480
111. Li Dan-Zhen;Zheng Yi;Fu Xian-Zhi.Study on the Effect and Mechanism of the Coupling between Microwave and Photocatalysis[J]. Acta Phys. -Chim. Sin., 2002,18(04): 332-335
112. Chen Hong-Ling;Wang Yan-Ru;Shi Jun.Preparation of Monodispersed Superfine Titanium Dioxide Particles and Size Control[J]. Acta Phys. -Chim. Sin., 2001,17(08): 713-717
113. Zou Ling;Wu Xue-Dong;Chen Hai-Gang;Wang Da-Pu.Structural Characterization and Formation Mechanism of SurfaceModified Titanium Dioxide Nanoparticles[J]. Acta Phys. -Chim. Sin., 2001,17(04): 305-309
114. Guo Yuan;Li Yong-Jun;Xia Xi;Zhang Xiao-Gang;He Mao-Xia.Effect of Extrinsic Factors on the CPE Behavior of Film TiO2 Electrode[J]. Acta Phys. -Chim. Sin., 2001,17(04): 372-376
115. Liu Hong;Wu Ming;Wu He-Jin;Sun Fu-Xia;Zheng Yun;Li Wen-Zhao.Photocatalytic Activity and Electrochemical Impedance Spectroscopy of TiO2 Thermally Treated by Hydrogen[J]. Acta Phys. -Chim. Sin., 2001,17(03): 286-288
116. Li Dan-Zhen;Zheng Yi;Fu Xian-Zhi;Liu Ping.SO2-4/TiO2 Catalyst Prepared by Microwave Method and the Research of its Photocatalytic Oxidation Activity[J]. Acta Phys. -Chim. Sin., 2001,17(03): 270-272
117. Su Wen-Yue;Fu Xian-Zhi;Wei Ke-Mei.Effect of Sulfation on Structure and Photocatalytic Performance of TiO2[J]. Acta Phys. -Chim. Sin., 2001,17(01): 28-31
118. Li Fang-Bai, Gu Guo-Bang, Li Xin-Jun, Wan Hong-Fu.Preparation,Characterization and Photo-catalytic Behavior of WO3/TiO2 Nanopowder[J]. Acta Phys. -Chim. Sin., 2000,16(11): 997-1002
119. Shui Miao, Yue Lin-Hai, Xu Zhu-De.Effect of Lanthanum Doping on the Photocatalytic Activity of Titanium Dioxide[J]. Acta Phys. -Chim. Sin., 2000,16(05): 459-463
120. Zhao Wen-Kuan, Fang You-Ling, Dong Qing-Hua, Wang Yi-Zhong.Preparation of High Photocatalytic Activity Nano-crystalline Titanium Dioxide by High Temperature Thermo-Hydrolysis Method[J]. Acta Phys. -Chim. Sin., 1998,14(05): 424-428
121. Luo Jin, Su Lian-Yong, Xie Lei, Zhou Jing, Zu Yan-Bing, Lin Zhong-Hua.Studies on Photoelectrochemical Behaviors of Nanocrystalline TiO2 Films[J]. Acta Phys. -Chim. Sin., 1998,14(04): 315-319
122. Wang Li-Ying,Zhang Yan,Zeng Guang-Fu,Xi Shi-Quan.Preparation of TiO2 Film through Hydrolysis of Titanium Butoxide and Interaction between Sensitizing Dyes and the Film[J]. Acta Phys. -Chim. Sin., 1997,13(08): 752-755
123. Zhang Jun,Luo Sheng-Cheng,Gui Lin-Lin,Tang You-Qi.Synthesisi and Characterization of New PMMA-TiO2 Organic-Lnorganic Hybrid Glasses[J]. Acta Phys. -Chim. Sin., 1996,12(04): 289-292
124. Li Rong-Sheng; Yang Hua; Zhang Wu-Yang; Wei Quan.Investigation of the Behavior of Ammonium Sulfate on the Surface of TiO2[J]. Acta Phys. -Chim. Sin., 1993,9(06): 819-822
125. ZHANG Wei, SU Yu, LIU Fang-Hui, YANG Hui, WANG Jin-Ben.Study of Interactions between 3,4-Dihydroxyphenylalanine and Surfaces with Nano-, Micro- and Hierarchical Structures Using Colloidal Probe Technology[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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