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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 0,Vol.>> Issue()>> 0-0     doi: 10.3866/PKU.WHXB201704174         中文摘要
Accepted manuscript
Core-Shell Co3Fe7@C Composite as Efficient Microwave Absorbent
LI Guo-Min1, ZHU Bao-Shun1, LIANG Li-Ping1, TIAN Yu-Ming1, LÜ Bao-Liang2, WANG Lian-Cheng2
1 School of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, P. R. China;
2 Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, P. R. China
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To reduce the density of the absorbent Co3Fe7, a core-shell Co3Fe7@C microwave absorbent was synthesized by preparing an iron/cobalt-containing carbon precursor followed by high-temperature carbonization. According to the X-ray diffraction (XRD) and transmission electron microscopy (TEM) results, Co3Fe7 particles were coated with graphitized carbon layers to form a core-shell structure. Furthermore, the Co3Fe7@C composite with a surface area and density of 358.5 m2·g-1 and 2.25 g·cm-3, respectively, exhibited excellent microwave absorbability. A minimum reflection loss (RL) of -43.5 dB and an effective bandwidth (RL below -10 dB) of 4.1 GHz were obtained at the coating thickness of 2 mm, which could be mainly attributed to the effective impedance match and multiple interfacial polarizations. Owing to the low density and remarkable microwave absorption, we believe that the Co3Fe7@C composite can be a promising candidate for use as a lightweight and efficient microwave absorbent.



Keywords: Core-shell structure   Composite   Lightweight   Microwave absorption  
Received: 2016-12-06 Accepted: 2017-04-03 Publication Date (Web): 2017-04-17
Corresponding Authors: TIAN Yu-Ming, WANG Lian-Cheng Email: tym1654@126.com;wanglc@sxicc.ac.cn

Fund: The project was supported by the Doctoral Scientific Research Foundation of Taiyuan University of Science and Technology, China (20152030).

Cite this article: LI Guo-Min, ZHU Bao-Shun, LIANG Li-Ping, TIAN Yu-Ming, LÜ Bao-Liang, WANG Lian-Cheng. Core-Shell Co3Fe7@C Composite as Efficient Microwave Absorbent[J]. Acta Phys. -Chim. Sin., 0, (): 0-0.    doi: 10.3866/PKU.WHXB201704174

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