ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(10)>> 2064-2071     doi: 10.3866/PKU.WHXB201705103         中文摘要
Effect of Preparation Methods on Photo-Induced Formation of Peroxide Species on Nd2O3
WU Qian, WENG Wei-Zheng, LIU Chun-Li, HUANG Chuan-Jing, XIA Wen-Sheng, WAN Hui-Lin
State Key Laboratory of Physical Chemistry of Solid State Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
Full text: PDF (1553KB) HTML Export: BibTeX | EndNote (RIS)

Three Nd2O3 samples with cubic phase being the main component phase, denoted as Nd2O3-H, Nd2O3-HT, and Nd2O3-C, were synthesized by hydrolysis, hydrothermal, and combustion methods, respectively. A comparative study of the photo-induced formation of peroxide species on the three Nd2O3 samples was carried out using Raman spectroscopy with a 325 nm laser as the excitation source. After irradiation with the laser of the Raman spectrometer at room temperature in air, peroxide species was detected in all Nd2O3 samples. However, the rate of peroxide formation over Nd2O3-C was much greater than that over the other two samples. This observation can be explained by the differences in the structure and basicity of the surface lattice oxygen (O2-) species of the samples. As evidenced by the results of O2- and CO2-temperature-programmed desorption (TPD) characterizations, the Nd2O3-C sample contains greater number of surface lattice oxygen (O2-) species with low coordination numbers than the other two samples. Moreover, the basicity of the surface O2- species in Nd2O3-C is stronger than that in the Nd2O3-H and Nd2O3-HT samples. Both these factors are in favor of the reaction of lattice oxygen with molecular oxygen to generate peroxide species under photo irradiation.

Keywords: Nd2O3   Preparation method   Photo-induced   Peroxide species   Lattice oxygen  
Received: 2017-02-27 Accepted: 2017-04-24 Publication Date (Web): 2017-05-10
Corresponding Authors: WENG Wei-Zheng, WAN Hui-Lin Email:;

Fund: The project was supported by the National Key Basic Research Program of China (973) (2013CB933102), National Natural Science Foundation of China (21173173, 21473144), and Program for Innovative Research Team in University, China (IRT_14R31).

Cite this article: WU Qian, WENG Wei-Zheng, LIU Chun-Li, HUANG Chuan-Jing, XIA Wen-Sheng, WAN Hui-Lin. Effect of Preparation Methods on Photo-Induced Formation of Peroxide Species on Nd2O3[J]. Acta Phys. -Chim. Sin., 2017,33 (10): 2064-2071.    doi: 10.3866/PKU.WHXB201705103

(1) Panov, G. I.; Dubkov, K. A.; Starokon, E. V. Catal. Today 2006, 117 (1), 148. doi: 10.1016/j.cattod.2006.05.019
(2) Guo, Z.; Liu, B.; Zhang, Q.; Deng, W.; Wang, Y.; Yang, Y. Chem. Soc. Rev. 2014, 43 (10), 3480. doi: 10.1039/c3cs60282f
(3) Weng, W. Z.; Wan, H. L.; Li, J. M.; Cao, Z. X. Angew. Chem. Int. Ed. 2004, 43 (8), 975. doi: 10.1002/anie.200351706
(4) Jing, X. L.; Chen, Q. C.; He, C.; Zhu, X. Q.; Weng, W. Z.; Xia, W. S.; Wan, H. L. Phys. Chem. Chem. Phys. 2012, 14 (19), 6898. doi: 10.1039/c2cp40086c
(5) Jing, X. L.; She, W. Y.; Weng, W. Z.; Li, J. M.; Xia, W. S.; Wan, H. L. Chin. J. Catal. 2014, 35 (8), 1385. [景孝廉, 佘雯瑜, 翁维正, 李建梅, 夏文生, 万惠霖. 催化学报, 2014, 35 (8), 1385.] doi: 10.1016/S1872-2067(14)60153-4
(6) Li, J. M.; Jing, X. L.; Weng, W. Z.; Chang, Z. Y.; An, D. L.; Xia, W. S.; Wan, H. L. Scientia Sinica Chimica 2014, 44 (12), 1931. [李建梅, 景孝廉, 翁维正, 常泽英, 安冬丽, 夏文生, 万惠霖. 中国科学: 化学, 2014, 44 (12), 1931.]doi: 10.1360/N032014-00222
(7) Jing, X. L.; She, W. Y.; Li, J. M.; Chen, Q. C.; Weng, W. Z.; An, D. L.; Wan, H. L. Chem. Asian J. 2015, 10 (10), 2162. doi: 10.1002/asia.201500312
(8) Bazzi, R.; Flores-Gonzalez, M. A.; Louis, C.; Lebbou, K.; Dujardin, C.; Brenier, A.; Zhang, W.; Tillement, O.; Bernstein, E.; Perriat, P. J. Lumin. 2003, 102-103, 445. doi: 10.1016/S0022-2313(02)00588-4
(9) Qian, H.; Lin, G.; Zhang, Y.; Gunawan, P.; Xu, R. Nanotechnology 2007, 18 (35), 355602. doi: 10.1088/0957-4484/18/35/355602
(10) Zawadzki, M.; Kepinski, L. J. Alloys Compd. 2004, 380 (1), 255. doi: 10.1016/j.jallcom.2004.03.053
(11) Zeng, W. W.; Huang, K. L.; Yang, Y. P.; Liu, S. Q.; Liu, R. S. Acta Phys. -Chim. Sin. 2008, 24 (2), 263. [曾雯雯, 黄可龙, 杨幼平, 刘素琴, 刘人生. 物理化学学报, 2008, 24 (2), 263.]doi: 10.3866/PKU.WHXB20080214
(12) Kepinski, L.; Zawadzki, M.; Mista, W. Solid State Sci. 2004, 6(12), 1327. doi: 10.1016/j.solidstatesciences.2004.07.003
(13) Hayashi, H.; Hakuta, Y. Mater. 2010, 3 (7), 3794. doi: 10.3390/ma3073794
(14) Hu, H. F.; He, T. Acta Phys. -Chim. Sin. 2016, 32 (2), 543.[胡海峰, 贺涛. 物理化学学报, 2016, 32 (2), 543.]doi: 10.3866/PKU.WHXB201511194
(15) Chavan, S. V.; Sastry, P. U. M.; Tyagi, A. K. J. Alloys Compd. 2008, 456 (1), 51. doi: 10.1016/j.jallcom.2007.02.019
(16) Umesh, B.; Eraiah, B.; Nagabhushana, H.; Nagabhushana, B.M.; Nagaraja, G.; Shivakumara, C.; Chakradhar, R. P. S. J. Alloys Compd. 2011, 509 (4), 1146. doi: 10.1016/j.jallcom.2010.09.143
(17) Yu, R. B.; Yu, K. H.; Wei, W.; Xu, X. X.; Qiu, X. M.; Liu, S.; Huang, W.; Tang, G.; Ford, H.; Peng, B. Adv. Mater. 2007, 19(6), 838. doi: 10.1002/adma.200600936
(18) Sreethawong, T.; Chavadej, S.; Ngamsinlapasathian, S.; Yoshikawa, S. Solid State Sci. 2008, 10 (1), 20. doi: 10.1016/j.solidstatesciences.2007.08.010
(19) Duhan, S.; Aghamkar, P. Acta Phys. Pol. A 2008, 113 (6), 1671. doi: 10.12693/APhysPolA.113.1671
(20) Shafer, M. W.; Roy, R. J. Am. Ceram. Soc. 1959, 42 (11), 563. doi: 10.1111/j.1151-2916.1959.tb13574.x
(21) Tong, J.; Eyring, L. J. Alloys Compd. 1995, 225 (1-2), 139. doi: 10.1016/0925-8388(94)07079-2
(22) Ubaldini, A.; Carnasciali, M. M. J. Alloys Compd. 2008, 454(1-2), 374. doi: 10.1016/j.jallcom.2006.12.067
(23) Abrashev, M. V.; Todorov, N. D.; Geshev, J. J. Appl. Phys. 2014, 116 (10), 103508. doi: 10.1063/1.4894775
(24) Lunsford, J. H.; Yang, X.; Haller, K.; Laane, J.; Mestl, G.; Knozinger, H. J. Phys. Chem. 1993, 97 (51), 13810. doi: 10.1021/j100153a061
(25) Boldish, S. I.; White, W. B. Spectrochim. Acta 1979, 35 (11), 1235. doi: 10.1016/0584-8539(79)80204-4
(26) Gopinatht, C. R.; Brown, I. D. J. Raman Spectrosc. 1982, 12(3), 278. doi: 10.1002/jrs.1250120315
(27) Turcotte, R. P.; Sawyer, J. O.; Eyring, L. J. Inorg. Chem. 1969, 8 (2), 238. doi: 10.1021/ic50072a012
(28) Klingenberg, B.; Vannice, M. A. J. Chem. Mater. 1996, 8 (12), 2755. doi: 10.1021/cm9602555
(29) Jiang, G. J.; Zhuang, H. R.; Li, W. L.; Wu, F. Y.; Zhang, B. L. Prog. Chem. 1998, 10 (3), 327. [江国健, 庄汉锐, 李文兰, 邬凤英, 张宝林. 化学进展, 1998, 10 (3), 327.]doi: 10.3321/j.issn:1005-281X.1998.03.011
(30) Auroux, A.; Gervasini, A. J. Phys. Chem. 1990, 94 (16), 6371. doi: 10.1021/j100379a041
(31) Choudhary, V. R.; Uphade, B. S.; Mulla, S. A. R. Ind. Eng. Chem. Res. 1997, 36 (9), 3594. doi: 10.1021/ie960676w
(32) Choudhary, V. R.; Mulla, S. A. R.; Uphade, B. S. Fuel 1999, 78 (4), 427. doi: 10.1016/S0016-2361(98)00168-9
(33) Yamazoe, N.; Teraoka, Y.; Seiyama, T. Chem. Lett. 1981, 10(12), 1767. doi: 10.1246/cl.1981.1767
(34) Kung, H. H. Transition Metal Oxides: Surface Chemistry and Catalysis, Elsevier: Amsterdam, 1989; pp 112-113.
(35) Ding, W.; Chen, Y.; Fu, X. Catal. Lett. 1994, 23 (1), 69. doi: 10.1007/BF00812132
(36) You, R.; Zhang, Y.; Liu, D.; Meng, M.; Zheng, L.; Zhang, J.; Hu, T. J. Phys. Chem. C 2014, 118 (44), 25403. doi: 10.1021/jp505601x
(37) Huang, S. J.; Walters, A. B.; Vannice, M. A. J. Catal. 2000, 192 (1), 29. doi: 10.1006/jcat.2000.2846
(38) Jiang, X. Y.; Zhou, R. X.; Pan, P.; Zhu, B.; Yuan, X. X.; Zheng, X. M. Appl. Catal. A: Gen. 1997, 150 (1), 131. doi: 10.1016/S0926-860X(96)00293-1

1. ZHANG Ying-Jie, ZHU Zi-Yi, DONG Peng, QIU Zhen-Ping, LIANG Hui-Xin, LI Xue.New Research Progress of the Electrochemical Reaction Mechanism, Preparation and Modification for LiFePO4[J]. Acta Phys. -Chim. Sin., 2017,33(6): 1085-1107
2. ZHANG Xue, HAN Yang, CHAI Shuang-Zhi, HU Nan-Tao, YANG Zhi, GENG Hui-Juan, WEI Hao.Advances in Cu2ZnSn(S,Se)4 Thin Film Solar Cells[J]. Acta Phys. -Chim. Sin., 2016,32(6): 1330-1346
3. ZHANG Jie, ZHANG Jiang-Hao, ZHANG Chang-Bin, HE Hong.Complete Catalytic Oxidation of Ethanol over MnO2 with Different Crystal Phase Structures[J]. Acta Phys. -Chim. Sin., 2015,31(2): 353-359
4. DENG Tao-Li, YAN Shi-Run, HU Jian-Guo.Preparation and Up-Conversion Photoluminescence Properties of GdAlO3:Er3+, Yb3+ Phosphors[J]. Acta Phys. -Chim. Sin., 2014,30(4): 773-780
5. HU Xiao-Yan, LI Chun-Yi, YANG Chao-He.Influences of V2O5 Loadings on V2O5/Al2O3 Oxidative Activation Performances for n-Heptane Catalytic Cracking[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2209-2216
6. YE Qing, ZHAO Jian-Sheng, LI Dong-Hui, ZHAO Jun, CHENG Shui-Yuan, KANG Tian-Fang.Au/SnO2 and M-Au (M=Pt, Pd)/SnO2 Bimetallic Catalysts for the Low-Temperature Catalytic Oxidation of CO[J]. Acta Phys. -Chim. Sin., 2011,27(01): 169-176
7. LI Lei, ZHAN Ying-Ying, CHEN Chong-Qi, SHE Yu-Sheng, LIN Xing-Yi, ZHENG Qi.Effect of CeO2 Support Preparaed with Different Methods on the Activity and Stability of CuO/CeO2 Catalysts for the Water-Gas Shift Reaction[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1397-1404
8. DENG Zheng-Hua; LI Ren-Gui; WANG Lu; DENG Jia-Min; GAO Jian-Dong; MA Zhi-Gang; DU Hong-Chang; SUO Ji-Shuan.Research and Development of Separators for Lithium-ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 90-93
9. HU Yi-Hua;LIN Jia-Yong;WU Hua;CHEN Ren;WANG Xiao-Juan;YANG Shi-He.Photo-induced Reaction of the Complex Mg+-S2(CH3)2[J]. Acta Phys. -Chim. Sin., 2006,22(06): 744-746
10. Wang Hai-Shui;Wang Yi-Bing;Xi Shi-Quan.A Review for the Preparation and Structural Characterization of Thin Films of Charge-Transfer Complexes[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1281-1286
11. Meng Xiang-Ju;Xiao Feng-Shou.Novel Copper Phosphates with High Catalytic Activities under Mild Conditions[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 939-945
12. Liu Yu, Yang Xiang-Guang, Liu Yu-Min, Wu Yue.Study on the Synthesis of Mixed Oxide La2CuO4 and the Effect on the Catalytic Activity to Catalytic Removal of NO[J]. Acta Phys. -Chim. Sin., 1999,15(06): 506-511
13. Li Jing,Wang Jing-Chun,Dou Bo-Sheng,Wu Yue.Preparation of Cu-Co Catalyst for Alcohols Synthesis[J]. Acta Phys. -Chim. Sin., 1997,13(03): 278-282
14. Li Xu-Yuan,Zhang Zi-Ping,Ma Jian-Tai,Zhu Zong-Zhen,Meng Yi-Min.The Catalytic Activity for CO Oxidation and Characterization of Perovskite-type Oxides Catalysts La1+X/2Sr1-x/2Co1-xCuxO3[J]. Acta Phys. -Chim. Sin., 1996,12(06): 502-507
15. Wang Bi-Xun,Fu Yi-Lu,Fang Shu-Nong.A Study of [Cu-O-Cu]2+ Species on Cu-ZSM-5 Zeolite by in situ Infrared Spectroscopy[J]. Acta Phys. -Chim. Sin., 1995,11(11): 974-978
16. Yu Lin,Xu Yi-De,Guo Xie-Xian.A FT-IR Study on the Interaction of CH4 and O2 with the Surface of SrO-La2O3/CaO Catalysts[J]. Acta Phys. -Chim. Sin., 1995,11(10): 902-906
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388
^ Top