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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(10)>> 2064-2071     doi: 10.3866/PKU.WHXB201705103         中文摘要
Article
Effect of Preparation Methods on Photo-Induced Formation of Peroxide Species on Nd2O3
WU Qian, WENG Wei-Zheng, LIU Chun-Li, HUANG Chuan-Jing, XIA Wen-Sheng, WAN Hui-Lin
State Key Laboratory of Physical Chemistry of Solid State Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
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Three Nd2O3 samples with cubic phase being the main component phase, denoted as Nd2O3-H, Nd2O3-HT, and Nd2O3-C, were synthesized by hydrolysis, hydrothermal, and combustion methods, respectively. A comparative study of the photo-induced formation of peroxide species on the three Nd2O3 samples was carried out using Raman spectroscopy with a 325 nm laser as the excitation source. After irradiation with the laser of the Raman spectrometer at room temperature in air, peroxide species was detected in all Nd2O3 samples. However, the rate of peroxide formation over Nd2O3-C was much greater than that over the other two samples. This observation can be explained by the differences in the structure and basicity of the surface lattice oxygen (O2-) species of the samples. As evidenced by the results of O2- and CO2-temperature-programmed desorption (TPD) characterizations, the Nd2O3-C sample contains greater number of surface lattice oxygen (O2-) species with low coordination numbers than the other two samples. Moreover, the basicity of the surface O2- species in Nd2O3-C is stronger than that in the Nd2O3-H and Nd2O3-HT samples. Both these factors are in favor of the reaction of lattice oxygen with molecular oxygen to generate peroxide species under photo irradiation.



Keywords: Nd2O3   Preparation method   Photo-induced   Peroxide species   Lattice oxygen  
Received: 2017-02-27 Accepted: 2017-04-24 Publication Date (Web): 2017-05-10
Corresponding Authors: WENG Wei-Zheng, WAN Hui-Lin Email: wzweng@xmu.edu.cn;hlwan@xmu.edu.cn

Fund: The project was supported by the National Key Basic Research Program of China (973) (2013CB933102), National Natural Science Foundation of China (21173173, 21473144), and Program for Innovative Research Team in University, China (IRT_14R31).

Cite this article: WU Qian, WENG Wei-Zheng, LIU Chun-Li, HUANG Chuan-Jing, XIA Wen-Sheng, WAN Hui-Lin. Effect of Preparation Methods on Photo-Induced Formation of Peroxide Species on Nd2O3[J]. Acta Phys. -Chim. Sin., 2017,33 (10): 2064-2071.    doi: 10.3866/PKU.WHXB201705103

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