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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(10)>> 2099-2105     doi: 10.3866/PKU.WHXB201705115         中文摘要
Synthesis of Colloidal Perovskite CH3NH3PbBr3-xClx Nanocrystals with Lead Acetate
WANG Ya-Nan1,2, MA Pin1,2, PENG Lu-Mei1, ZHANG Di1,2, FANG Yan-Yan1, ZHOU Xiao-Wen1, LIN Yuan1,2
1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, CAS Research/Education Center for Excellence in Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China
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Lead acetate, which is highly soluble in dimethylformamide, was used to synthesize mixed halide perovskite CH3NH3PbBr3-xClx (MA = CH3NH3, 0 ≤ x ≤ 3) nanocrystals (NCs). This method provides an approach to address the low solubility of lead halides, especially lead chloride. Different Br/Cl ratios in MAPbBr3-xClx lead to various optical properties. The photoluminescence emission peak can be tuned from 399 to 527 nm. Their full-widths at half-maxima (FWHM) are about 20 nm. MAPbBr3-xClx NCs have an average diameter of ~(11 ± 3) nm and have uniform dispersion in toluene. The MAPbBr3 NCs have a long average recombination lifetime (τave = 97.4 ns) and a photoluminescence quantum yield (PLQY) of up to 73%.



Keywords: Perovskite   CH3NH3PbBr3-xClx   Nanocrystal   Lead acetate  
Received: 2017-04-03 Accepted: 2017-05-02 Publication Date (Web): 2017-05-11
Corresponding Authors: LIN Yuan Email: linyuan@iccas.ac.cn

Fund: The project was supported by the National Natural Science Foundation of China (51303186, 51673204) and National Materials Genome Project, China (2016YFB0700600).

Cite this article: WANG Ya-Nan, MA Pin, PENG Lu-Mei, ZHANG Di, FANG Yan-Yan, ZHOU Xiao-Wen, LIN Yuan. Synthesis of Colloidal Perovskite CH3NH3PbBr3-xClx Nanocrystals with Lead Acetate[J]. Acta Phys. -Chim. Sin., 2017,33 (10): 2099-2105.    doi: 10.3866/PKU.WHXB201705115

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