Register
ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2017,Vol.33>> Issue(12)>> 2510-2516     doi: 10.3866/PKU.WHXB201705311         中文摘要
Lithium Ion Hybrid Supercapacitor Based on Three-Dimensional Flower-Like Nb2O5 and Activated Carbon Electrode Materials
JIA Zhao-Yang1,2, LIU Mei-Nan2, ZHAO Xin-Luo3, WANG Xian-Shu2, PAN Zheng-Hui2, ZHANG Yue-Gang2,4
1 Department of Chemistry, Shanghai University, Shanghai 200444, P. R. China;
2 Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, Jiangsu Province, P. R. China;
3 Department of Physics, Shanghai University, Shanghai 200444, P. R. China;
4 Department of Physics, Tsinghua University, Beijing 100084, P. R. China
Full text: PDF (1060KB) HTML Export: BibTeX | EndNote (RIS)

A lithium ion hybrid supercapacitor system with battery and supercapacitor characteristics has the potential to meet the increasing demand for an energy storage device with both high energy and power densities. In this work, orthorhombic Nb2O5 (T-Nb2O5) with three-dimensional (3D) flower-like structures was synthesized by a facile hydrothermal reaction and an annealing process. A lithium ion hybrid supercapacitor was constructed by using T-Nb2O5 as an anode and commercial activated carbon (AC) as a cathode. The electrochemical performance of these T-Nb2O5/AC hybrid capacitors was measured by cyclic voltammetry and galvanostatic charge/discharge tests. The results showed that the working voltage of the hybrid supercapacitor could reach 3.0 V in the organic carbonate electrolyte system. The as-assembled device showed impressive power density of 294 W·kg-1 and energy density of 53.79 W·h·kg-1 at a current density of 100 mA·g-1 with a voltage range of 0.5-3.5 V. Moreover, it also showed excellent cycling stability with a retention of 73% after 1000 cycles at 200 mA·g-1. These results demonstrate that this novel lithium ion hybrid supercapacitor based on T-Nb2O5 with 3D flower-like structures and AC is a promising candidate for high power density energy storage applications.



Keywords: Lithium ion hybrid supercapacitor   Three-dimensional flower-like structure   Orthorhombic Nb2O5   Organic electrolyte   Activate carbon  
Received: 2017-05-08 Accepted: 2017-05-25 Publication Date (Web): 2017-05-31
Corresponding Authors: LIU Mei-Nan, ZHANG Yue-Gang Email: ygzhang2012@sinano.ac.cn;mnliu2013@sinano.ac.cn

Fund: The project was supported by the National Natural Science Foundation of China (51402345).

Cite this article: JIA Zhao-Yang, LIU Mei-Nan, ZHAO Xin-Luo, WANG Xian-Shu, PAN Zheng-Hui, ZHANG Yue-Gang. Lithium Ion Hybrid Supercapacitor Based on Three-Dimensional Flower-Like Nb2O5 and Activated Carbon Electrode Materials[J]. Acta Phys. -Chim. Sin., 2017,33 (12): 2510-2516.    doi: 10.3866/PKU.WHXB201705311

(1) Winter, M.; Brodd, R. J. Chem. Rev. 2004, 104, 4245. doi: 10.1021/cr020730k
(2) Zheng, Z. M.; Zhang, P.; Yan, X. B. Chin. Sci. Bull. 2013, 58, 3115. [郑宗敏, 张鹏, 阎兴斌. 科学通报, 2013, 58, 3115.]doi: 10.1360/972013-760
(3) An, B. K. H.; Kim, W. S.; Park, Y. S.; Moon, J. M.; Bea, D. J.; Lim, S. C.; Lee, Y. S.; Lee, Y. H. Adv. Funct. Mater. 2001, 11, 387. doi: 10.1002/1616-3028(200110)11:53.3.CO;2-7
(4) Yoshino, A. Angew. Chem. Int. Ed. 2012, 51, 5798. doi: 10.1002/anie.201105006
(5) Simon, P.; Gogotsi, Y. Nat. Mater. 2008, 7, 845. doi: 10.1038/nmat2297
(6) Miller J R, Simon P. Science. 2008, 321, 651. doi: 10.1126/science.1158736
(7) Su, Y. F.; Wu, F.; Bao, L. Y.; Xu, B.; Chen, S. Acta Chim. Sin. 2008, 66, 591 [苏岳峰, 吴锋, 包丽颖, 徐斌, 陈实. 化学学报, 2008, 66, 591. ]
(8) Jiang, J. M.; Nie, P.; Dong, S. P; Wu, Y. T; Zhang, X. G. Acta Phys. -Chim. Sin. 2017, 33, 780. [将江民, 聂平, 董升阳, 吴宇婷, 张校刚. 物理化学学报, 2017, 33, 780.]. doi: 10.3866/PKU.WHXB201612291
(9) Naoi, K.; Naoi, W.; Aoyagi, S.; Miyamoto, J. I.; Kamino, T. Acc. Chem. Res. 2012, 46, 1075. doi: 10.1021/ar200308h
(10) Liu, H. J.; Xia, Y. Y. Prog. Chem. 2011, 23, 595. [刘海晶, 夏永姚. 化学进展, 2011, 23, 595. ]
(11) Naoi, K.; Ishimoto, S.; Miyamoto, J. I.; Naoi, W. Energy Environ. Sci. 2012, 5, 9363. doi: 10.1039/C2ee21675b
(12) Cheng, L.; Liu, H. J.; Zhang, J. J.; Xiong, H. M.; Xia, Y.Y. J. Electrochem. Soc. 2006, 153, A1472. doi: 10.1149/1.2204872
(13) Naoi, K. Fuel. Cells. 2010, 10, 825. doi: 10.1002/fuce.201000041
(14) Chen, Z.; Augustyn, V.; Wen, J.; Zhang, Y. W.; Shen, M. Q.; Dunn, B.; Lu, Y. F. Adv. Mater. 2011, 23, 791. doi: 10.1002/adma.201003658
(15) Aravindan, V.; Sundaramurthy, J.; Jain, A.; Kumar, S.; Ling, W.C.; Ramarkrishna, S.; Srinivasan, M. P.; Madhavi, S. ChemSusChem. 2014, 7, 1858. doi: 10.1002/cssc.201400157
(16) Augustyn, V.; Come, J.; Lowe, M. A.; Kim, J. W.; Taberna, P. L.; Tolbert, S. H.; Abrüna, H. D.; Simon, P.; Dunn, B. Nat. Mater. 2013, 12, 518. doi: 10.1038/NMAT3601
(17) Viet, A. L.; Reddy, M. V.; Jose, R.; Chowdari, B. V. R.; Ramakrishna, S. J. Phys. Chem. C. 2014, 114, 664. doi: 10.1021/jp9088589
(18) Liu, M. N.; Yan, C.; Zhang, Y. G. Sci. Rep. 2015, 5, 8326. doi: 10.1038/srep08326
(19) Come, J.; Augustyn, V.; Kim, J. W.; Rozier, P.; Taberna, P. L.; Gogotsi, P.; Log, J. W; Dunn, B.; Simon, P. J. Electrochem. Soc. 2014, 161, A718. doi: 10.1149/2.040405jes
(20) Li, G. Z.; Qiu, Y. C.; Hou, Y.; Li, H. F.; Zhou, L. S.; Deng, H.; Zhang, Y.G. J. Mater. Chem. A. 2015, 3, 1103. doi: 10.1039/c4ta04864d
(21) Kim, S. I.; Lee, J. S.; Ahn, H. J.; Song, H. K.; Jang, J. H. ACS Appl. Mat. Interfaces 2013, 5, 1596. doi: 10.1021/am3021894
(22) Tang, Y. X.; Rui, X. H.; Zhang, Y. Y.; Lim, T. M.; Dong, Z. L.; Hng, H. H.; Chen, X. D.; Yan, Q. Y.; Chen, Z. J. Mater. Chem. A. 2013, 1, 82. doi: 10.1039/c2ta00351a
(23) Griffith, K. J.; Forse, A. C.; Griffin, J. M.; Grey, C. P. J. Am. Chem. Soc. 2016, 138, 8888. doi: 10.1021/jacs.6b04345
(24) Arunkumar, P.; Ashish, A. G.; Babu, B.; Sarang, S.; Suresh, A.; Sharma, C. H.; Thalakulam, M.; Shaijumon, M. M. RSC Adv. 2015, 5, 59997. doi: 10.1039/c5ra07895d.
(25) Xie, S. B.; Iglesia, E.; Bell, A. T. J. Phys. Chem. B. 2001, 105, 5144. doi: 10.1021/jp004434s
(26) Wang, X. L.; Li, G.; Chen, Z.; Augustyn, V.; Ma, X.M.; Wang, G.; Dunn, B.; Lu, Y. F. Adv. Energy Mater. 2011, 1, 1089. doi: 10.1002/aenm.201100332
(27) Tang, C. H.; Tang, Z.; Gong, H. J. Electrochem. Soc. 2012, 159, A651. doi: 10.1149/2.074205jes
(28) Deng, L. J.; Zhu, G.; Wang, J. F.; Kang, L. P.; Liu, Z. H.; Yang, Z.P.; Wang, Z. L. J. Power Sources .2011, 196, 10782. doi: 10.1016/j.jpowsour.2011.09.005
(29) Aravindan, V.; Shubha, N.; Ling, W. C.; Madhavi, S. J. Mater. Chem. A. 2013, 1, 6145. doi: 10.1039/C3TA11103B
(30) Chen, Z.; Augustyn, V.; Wen, J.; Zhang, Y. W.; Shen, M. Q.; Dunn, B.; Lu, Y. F. Adv. Energy Mater. 2011, 23, 791. doi: 10.1002/adma.201003658

1. ZHAO Li-Ping, MENG Wei-Shuai, WANG Hong-Yu, QI Li.MoS2-C Composite as Negative Electrode Material for Sodium-Ion Supercapattery[J]. Acta Phys. -Chim. Sin., 2017,33(4): 787-794
2. YIN Jin-Ling, LIU Jia, WEN Qing, WANG Gui-Ling, CAO Dian-Xue.Phosphomolybdic Acid as a Mediator for Indirect Carbon Electrooxidation in LowTemperature Carbon Fuel Cell[J]. Acta Phys. -Chim. Sin., 2017,33(2): 370-376
3. LI Dao-Yan, ZHANG Ji-Chen, WANG Zhi-Yong, JIN Xian-Bo.Preparation of Activated Carbon from Honeycomb-Like Porous Gelatin for High-Performance Supercapacitors[J]. Acta Phys. -Chim. Sin., 2017,33(11): 2245-2252
4. WANG Yong-Fang, ZUO Song-Lin.Electrochemical Properties of Phosphorus-Containing Activated Carbon Electrodes on Electrical Double-Layer Capacitors[J]. Acta Phys. -Chim. Sin., 2016,32(2): 481-492
5. TONG Li, XU Wen-Qing, QI Hao, ZHOU Xuan, LIU Rui-Hui, ZHU Ting-Yu.Enhanced Effect of O/N Groups on the Hg0 Removal Efficiency over the HNO3-Modified Activated Carbon[J]. Acta Phys. -Chim. Sin., 2015,31(3): 512-518
6. YANG Jie-Yang, HUANG Zhang-Gen, HAN Xiao-Jin, JING Wen, ZENG Ze-Quan.Effect of Activated Carbon Pore Structure on the Adsorption of Pb(II) from Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2015,31(10): 1956-1962
7. XIAO Bo, LIU Shou-Qing.Photocatalytic Oxidation of Ammonia via an Activated Carbon-Nickel Ferrite Hybrid Catalyst under Visible Light Irradiation[J]. Acta Phys. -Chim. Sin., 2014,30(9): 1697-1705
8. SUN Xian-Zhong, HUANG Bo, ZHANG Xiong, ZHANG Da-Cheng, ZHANG Hai-Tao, MA Yan-Wei.Experimental Investigation of Electrochemical Impedance Spectroscopy of Electrical Double Layer Capacitor[J]. Acta Phys. -Chim. Sin., 2014,30(11): 2071-2076
9. HUANG Bo, SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei.Organic Electrolytes for Activated Carbon-Based Supercapacitors with Flexible Package[J]. Acta Phys. -Chim. Sin., 2013,29(09): 1998-2004
10. JIN Wei-Yang, CHENG Dang-Guo, CHEN Feng-Qiu, ZHAN Xiao-Li.Synthesis of MFI-Type Zeolite Membrane Encapsulated Activated Carbon Particles Using a Modified Seeded Method[J]. Acta Phys. -Chim. Sin., 2013,29(01): 139-143
11. ZhONG Hao-Xiang, ZHAO Chun-Bao, LUO Hao, ZHANG Ling-Zhi.Novel Organosilicon Ionic Liquid Based Electrolytes for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2641-2647
12. PING Li-Na, ZHENG Jia-Ming, SHI Zhi-Qiang, WANG Cheng-Yang.Electrochemical Performance of Lithium Ion Capacitors Using Li+-Intercalated Mesocarbon Microbeads as the Negative Electrode[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1733-1738
13. TANG Jing, ZENG Qiao, CHEN Zhen-Dong, HUANG Xiang-Qian.Electrochemical Indirect Measurement for the Study of Glutathione Adsorption on Multiwalled Carbon Nanotubes and Activated Carbon[J]. Acta Phys. -Chim. Sin., 2012,28(05): 1269-1274
14. ZHAO Lei, XU Xiang-Sheng, ZHANG Kai-Chao, YAN Xin-Huan.Selective Hydrogenation of Cinnamaldehyde with Efficient Assembled Pt-Fe/C Catalysts[J]. Acta Phys. -Chim. Sin., 2012,28(04): 923-927
15. SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei.Activated Carbon-Based Supercapacitors Using Li2SO4 Aqueous Electrolyte[J]. Acta Phys. -Chim. Sin., 2012,28(02): 367-372
16. XU San-Kui, LI Li-Min, GUO Nan-Nan, SU Yun-Lai, ZHANGPeng.Hydrogenation of Glucose Using Ru/Activated Carbon Catalysts: Effects of Modification Methods on Surface Properties of Activated Carbon[J]. Acta Phys. -Chim. Sin., 2012,28(01): 177-183
17. LU Sheng-Yong, HUANG Yi-Long, WANG Qiu-Lin, LI Xiao-Dong, YAN Jian-Hua.Photocatalytic Degradation of Gaseous 1,2-Dichlorobenzene over TiO2/AC Photocatalysts[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2191-2199
18. CAO Guo-Fei, LIAO Yi, ZHANG Xiao-Hua, CHEN Jin-Hua.Preparation and Characterization of Peasecod-Based Activated Carbons as Electrode Materials for Electrochemical Double-Layer Capacitors[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1679-1684
19. ZHOU Jin, LI Wen, XING Wei, ZHUO Shu-Ping.Capacitive Performance of Tunable Ordered Mesoporous Carbons in Organic and H2SO4 Electrolytes[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1431-1438
20. ZHAN Wang-Cheng, ZHOU Guo-Jun, CHU Guo-Hai, SHEN Kai, YU Jun, WANG Ai-Yong, SU Na, LU Guan-Zhong, GUO Yang-Long.Effect of Supports on the Catalytic Performance of Pd-Cu/Activated Carbon Catalyst for Eliminating CO in Cigarette Smoke[J]. Acta Phys. -Chim. Sin., 2011,27(03): 705-710
21. SUN Gang-Wei, SONG Wen-Hua, LIU Xiao-Jun, QIAO Wen-Ming, LING Li-Cheng.Asymmetric Capacitance Behavior Based on the Relationship between Ion Dimension and Pore Size[J]. Acta Phys. -Chim. Sin., 2011,27(02): 449-454
22. TIAN Ying, YAN Jing-Wang, XUE Rong, YI Bao-Lian.Influence of Electrolyte Concentration and Temperature on the Capacitance of Activated Carbon[J]. Acta Phys. -Chim. Sin., 2011,27(02): 479-485
23. TIAN Ying, YAN Jing-Wang, LIU Xiao-Xue, XUE Rong, YI Bao-Lian.Electrochemical Capacitance of Composites with MnOx Loaded on the Surface of Activated Carbon Electrodes[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2151-2157
24. DING Liang-Xin, WANG Shi-Rui, ZHENG Xiao-Long, CHEN Yu, LU Tian-Hong, CAO Dian-Xue, TANG Ya-Wen.Effect of Carbon Modification on Electrocatalytic Performance of Carbon Supported Pd Catalysts[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1311-1316
25. ZHANG Tian-Yong, YANG Qiu-Sheng, SHI Hui-Xian, HAN Cong, LIU Xu.Adsorption of Naphthalene on a Viscose-Based Activated Carbon Fiber[J]. Acta Phys. -Chim. Sin., 2010,26(02): 367-372
26. XU Xin, WANG Xiao-Jing, HU Zhong-Hua, LIU Ya-Fei, WANG Chen-Chen, ZHAO Guo-Hua.Influence of Sol-Gel and Dip-Hydrothermal Preparation Methods on Structure and Performance of TiO2/AC Photocatalysts[J]. Acta Phys. -Chim. Sin., 2010,26(01): 79-86
27. JIANG Qi, ZHAO Xiao-Feng, HUANG Bin, DU Bing, ZHAO Yong.Effect of the Activated Carbon Reactivation on Its Electrochemical Capacitance[J]. Acta Phys. -Chim. Sin., 2009,25(04): 757-761
28. GAO Qiang; LIU Ya-Fei; HU Zhong-Hua; ZHENG Xiang-Wei; WEN Zu-Biao.Electrochemical Properties of Manganese Oxide Surface-Modified Activated Carbon Electrode Materials[J]. Acta Phys. -Chim. Sin., 2009,25(02): 229-236
29. CHEN Yu-Juan; HU Zhong-Hua; WANG Xiao-Jing; ZHAO Guo-Hua; LIU Ya-Fei; LIU Wei.Influence of Pore Size and Surface Area of Activated Carbon on the Performance of TiO2/AC Photocatalyst[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1589-1596
30. LIU Ya-Fei; HU Zhong-Hua; XU Kun; ZHENG Xiang-Wei; GAO Qiang.Surface Modification and Performance of Activated Carbon Electrode Material[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1143-1148
31. GUO Liang; WU Zhan-Song.Mechanism of Methane’s Adsorption on Nanometer Active Carbon at Supercritical State[J]. Acta Phys. -Chim. Sin., 2008,24(05): 737-742
32. LIU Shou-Xin; CHEN Xiao-Yun.Effect of Pore Structure of Activated Carbon on the Photocatalytic Activity of TiO2/AC Composite Photocatalyst[J]. Acta Phys. -Chim. Sin., 2008,24(03): 533-538
33. YANG Jing; LIU Ya-Fei; CHEN Xiao-Mei; HU Zhong-Hua; ZHAO Guo-Hua.Carbon Electrode Material with High Densities of Energy and Power[J]. Acta Phys. -Chim. Sin., 2008,24(01): 13-19
34. QIU Kai-Dong;LI Wei-Bin.Adsorption of Hexavalent Chromium Ions on Multi-wall Carbon Nanotubes in Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1542-1546
35. CHEN Xiao-Yun;LIU Shou-Xin;CHEN Xi;SUN Cheng-Lin.Characterization and Activity of TiO2 /wAC Composite Photocatalyst Prepared by Acid Catalyzed Hydrolysis Method[J]. Acta Phys. -Chim. Sin., 2006,22(05): 517-522
36. LIU Chun-ling; WEN Yue-hua; CHENG Jie; GUO Quan-gui; CAO Gao-ping; LIU Lang; YANG Yu-sheng.Influence of Pore Structure of Phenolic Resin Based Activated Carbon Fibers on the Electrochemical Performance of Electrical Double-layer Capacitors[J]. Acta Phys. -Chim. Sin., 2005,21(07): 786-791
37. WANG Xiao-Feng; WANG Da-Zhi; LIANG Ji.Pseudo-capacitance of Ultrafine Nickel Hydroxide Prepared by Sol-gel Method[J]. Acta Phys. -Chim. Sin., 2005,21(02): 117-122
38. Zhuang Xin-Guo;Yang Yu-Sheng;Ji You-Ju;Yang Dong-Ping;Tang Zhi-Yuan.The Influence of Porous Structure of Activated Carbons Used as Supercapacitor Electrode Materials on Its Properties[J]. Acta Phys. -Chim. Sin., 2003,19(08): 689-694
39. Xing Wei;Zhang Ming-Jie;Yan Zi-Feng.Synthesis and Activation Mechanism of Coke Based Super Activated Carbons[J]. Acta Phys. -Chim. Sin., 2002,18(04): 340-345
40. Liang Kui;Chen Ai;Feng Zhe-Sheng;Ye Zhi-Xiang.AC Impedance Analysis of Supercapacitors Utilizing Carbon Nanotube Electrodes[J]. Acta Phys. -Chim. Sin., 2002,18(04): 381-384
41. Liu Zhen-Yu;Zheng Jing-Tang;Wang Mao-Zhang;Zhang Bi-Jiang.Study for Nitrogen Adsorption of PAN-based Activated Carbon Fibers[J]. Acta Phys. -Chim. Sin., 2001,17(07): 594-599
42. Lu An-Hui;Li Wen-Cui;Zheng Jing-Tang.Preparation of PANbased Molecular Sieve ACF and Study of Surface Structure by XPS[J]. Acta Phys. -Chim. Sin., 2001,17(03): 216-221
43. Miao Rui-Ping,Dai Min-Ping.Study of Activatied Carbon on the Adsorption of Titan Yellow from Aqueous Solution[J]. Acta Phys. -Chim. Sin., 1996,12(02): 173-176
44. Wang Xin-Ping,Ye Xing-Kai,Wu Yue.Chemical Bonding between Heteropoly Acid and Oxygen-containing Groups on the Surface of Activated Carbon[J]. Acta Phys. -Chim. Sin., 1995,11(12): 1105-1109
45. Mu Guan-Nan, Yang Chun-Fen.Adsorption of Zinc(II) Ion and its Complexes from Solution by Activatied Charcoal[J]. Acta Phys. -Chim. Sin., 1995,11(02): 157-161
46. Wang Xin-Ping, Ye Xing-Kai, Wu Yue.A Study of the Heterogenization of Heteropoly Acid(II)[J]. Acta Phys. -Chim. Sin., 1994,10(04): 303-307
47. Xue Yi; Du You-Ru; Ye Zhao-Hui; Kong Yu-Hua.The NMR Study of the Solid and Liquid Like Phases of Dioxane Adsorbed on Charcoals[J]. Acta Phys. -Chim. Sin., 1992,8(01): 113-116
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388 Email:whxb@pku.edu.cn
^ Top