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Acta Physico-Chimica Sinca  2018, Vol. 34 Issue (4): 344-347    DOI: 10.3866/PKU.WHXB201709112
Special Issue: Nonfullerene Organic Solar Cells
COMMUNICATION     
Star-Shaped Electron Acceptor based on Naphthalenediimide-Porphyrin for Non-Fullerene Organic Solar Cells
ZHOU Shichao1,2, FENG Guitao2, XIA Dongdong2, LI Cheng2, WU Yonggang1, LI Weiwei2
1 College of Chemistry and Environmental Science, Hebei University, Baoding 071002, Hebei Province, P. R. China;
2 CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
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Abstract  

Non-fullerene organic solar cells are of broad and current interest in the field of organic solar cells, and show promising application in high performance solar cells. When designing conjugated molecules as non-fullerene materials, several parameters, such as absorption, energy levels, charge transport, and crystallinity should be considered. Among them, absorption spectra are an important parameter that determine the efficiency of sun-light harvesting. In this work, we explore a new near-infrared electron acceptor naphthalenediimide-porphyrin (NDI-Por) by using electron-donating porphyrin as the core, and four NDI as end groups with ethynyl as linkers attached to the meso-position of porphyrin. This star-shaped molecule exhibits absorption spectra up to 900 nm. NDI-Por was incorporated into non-fullerene solar cells as an electron acceptor, and together with a wide-band gap polymer donor, an initial power conversion efficiency of 1.80% could be achieved. In particular, the solar cells exhibit a broad photo-response from 300 to 900 nm. Our results demonstrate that it is an efficient strategy to incorporate porphyrin into conjugated molecules to realize non-fullerene materials with near-infrared absorption spectra.



Key wordsNon-fullerene organic solar cells      Porphyrin      Naphthalenediimide      Electron acceptor      Near-infrared     
Received: 11 August 2017      Published: 11 September 2017
MSC2000:  O646  
Fund:  

The project was supported by the National Natural Science Foundation of China (51773207, 21574138, 51603209, 91633301, 21474026) and the Strategic Priority Research Program (XDB12030200) of the Chinese Academy of Sciences.

Corresponding Authors: LI Cheng, WU Yonggang, LI Weiwei     E-mail: licheng1987@iccas.ac.cn;wuyonggang@hbu.edu.cn;liweiwei@iccas.ac.cn
Cite this article:

ZHOU Shichao, FENG Guitao, XIA Dongdong, LI Cheng, WU Yonggang, LI Weiwei. Star-Shaped Electron Acceptor based on Naphthalenediimide-Porphyrin for Non-Fullerene Organic Solar Cells. Acta Physico-Chimica Sinca, 2018, 34(4): 344-347.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB201709112     OR     http://www.whxb.pku.edu.cn/Y2018/V34/I4/344

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