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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 0,Vol.>> Issue()>> 0-0     doi: 10.3866/PKU.WHXB201709112         中文摘要
Accepted manuscript
Star-Shaped Electron Acceptor based on Naphthalenediimide-Porphyrin for Non-Fullerene Organic Solar Cells
ZHOU Shichao1,2, FENG Guitao2, XIA Dongdong2, LI Cheng2, WU Yonggang1, LI Weiwei2
1 College of Chemistry and Environmental Science, Hebei University, Baoding 071002, Hebei Province, P. R. China;
2 CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
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Non-fullerene organic solar cells are of broad and current interest in the field of organic solar cells, and show promising application in high performance solar cells. When designing conjugated molecules as non-fullerene materials, several parameters, such as absorption, energy levels, charge transport, and crystallinity should be considered. Among them, absorption spectra are an important parameter that determine the efficiency of sun-light harvesting. In this work, we explore a new near-infrared electron acceptor naphthalenediimide-porphyrin (NDI-Por) by using electron-donating porphyrin as the core, and four NDI as end groups with ethynyl as linkers attached to the meso-position of porphyrin. This star-shaped molecule exhibits absorption spectra up to 900 nm. NDI-Por was incorporated into non-fullerene solar cells as an electron acceptor, and together with a wide-band gap polymer donor, an initial power conversion efficiency of 1.80% could be achieved. In particular, the solar cells exhibit a broad photo-response from 300 to 900 nm. Our results demonstrate that it is an efficient strategy to incorporate porphyrin into conjugated molecules to realize non-fullerene materials with near-infrared absorption spectra.



Keywords: Non-fullerene organic solar cells   Porphyrin   Naphthalenediimide   Electron acceptor   Near-infrared  
Received: 2017-08-11 Accepted: 2017-09-06 Publication Date (Web): 2017-09-11
Corresponding Authors: LI Cheng, WU Yonggang, LI Weiwei Email: licheng1987@iccas.ac.cn;wuyonggang@hbu.edu.cn;liweiwei@iccas.ac.cn

Fund: The project was supported by the National Natural Science Foundation of China (51773207, 21574138, 51603209, 91633301, 21474026) and the Strategic Priority Research Program (XDB12030200) of the Chinese Academy of Sciences.

Cite this article: ZHOU Shichao, FENG Guitao, XIA Dongdong, LI Cheng, WU Yonggang, LI Weiwei. Star-Shaped Electron Acceptor based on Naphthalenediimide-Porphyrin for Non-Fullerene Organic Solar Cells[J]. Acta Phys. -Chim. Sin., 0, (): 0-0.    doi: 10.3866/PKU.WHXB201709112

(1) (a) Li, Y. Acc. Chem. Res. 2012, 45, 723. doi: 10.1021/ar2002446
(b) Zhao, Y. F.; Zou, W. J.; Li, H.; Lu, K.; Yan, W.; Wei, Z. X. Chin. J. Polym. Sci. 2017, 35, 261. doi: 10.1007/s10118-017-1875-z
(c) Krebs, F. C.; Espinosa, N.; Hösel, M.; Søndergaard, R. R.; Jørgensen, M. Adv. Mater. 2014, 26, 29. doi: 10.1002/adma.201302031
(2) Lu, L.; Zheng, T.; Wu, Q.; Schneider, A. M.; Zhao, D.; Yu, L. Chem. Rev. 2015, 115, 12666. doi: 10.1021/acs.chemrev.5b00098
(3) (a) Yu, G.; Gao, J.; Hummelen, J. C.; Wudl, F.; Heeger, A. J. Science 1995, 270, 1789. doi: 10.1126/science.270.5243.1789
(b) Wienk, M. M.; Kroon, J. M.; Verhees, W. J. H.; Knol, J.; Hummelen, J. C.; van Hal, P. A.; Janssen, R. A. J. Angew. Chem. Int. Ed. 2003, 42, 3371. doi: 10.1002/anie.2003516547
(4) (a) Lin, Y.; Wang, J.; Zhang, Z. G.; Bai, H.; Li, Y.; Zhu, D.; Zhan, X. Adv. Mater. 2015, 27, 1170. doi: 10.1002/adma.201404317
(b) Jiang, W.; Ye, L.; Li, X.; Xiao, C.; Tan, F.; Zhao, W.; Hou, J.; Wang, Z. Chem. Commun. 2014, 50, 1024. doi: 10.1039/C3CC47204C
(c) Nielsen, C. B.; Holliday, S.; Chen, H. Y.; Cryer, S. J.; McCulloch, I. Acc. Chem. Res. 2015, 48, 2803. doi: 10.1021/acs.accounts.5b00199
(d) Zhang, S. Q.; Hou, J. H. Acta Phys. -Chim. Sin. 2017, 33, 2327. [张少青, 侯剑辉. 物理化学学报, 2017, 33, 2327.] doi: 10.3866/PKU.WHXB201706161
(e) Yang, F.; Li, C.; Feng, G.; Jiang, X.; Zhang, A.; Li, W. Chin. J. Polym. Sci. 2017, 35, 239. doi: 10.1007/s10118-017-1870-4
(f) Zhao, R. Y.; Dou, C. D.; Liu, J.; Wang, L. X. Chin. J. Polym. Sci. 2017, 35, 198. doi: 10.1007/s10118-017-1878-9
(g) Shao, R.; Yang, X. B.; Yin, S. W.; Wang, W. L. Acta Chim. Sin. 2016, 74, 676. [邵绒, 杨鑫博, 尹世伟, 王文亮. 化学学报 2016, 74, 676.] doi: 10.6023/a16050268
(h) Liu, Y.; Zhang, Z.; Feng, S.; Li, M.; Wu, L.; Hou, R.; Xu, X.; Chen, X.; Bo, Z. J. Am. Chem. Soc. 2017, 139, 3356. doi: 10.1021/jacs.7b00566
(5) Zhao, W.; Li, S.; Yao, H.; Zhang, S.; Zhang, Y.; Yang, B.; Hou, J. J. Am. Chem. Soc. 2017, 139, 7148. doi: 10.1021/jacs.7b02677
(6) (a) Liu, J.; Chen, S.; Qian, D.; Gautam, B.; Yang, G.; Zhao, J.; Bergqvist, J.; Zhang, F.; Ma, W.; Ade, H.; Inganäs, O.; Gundogdu, K.; Gao, F.; Yan, H. Nat. Energy 2016, 1, 16089. doi: 10.1038/nenergy.2016.89
(b) Meng, D.; Sun, D.; Zhong, C.; Liu, T.; Fan, B.; Huo, L.; Li, Y.; Jiang, W.; Choi, H.; Kim, T.; Kim, J. Y.; Sun, Y.; Wang, Z.; Heeger, A. J. J. Am. Chem. Soc. 2016, 138, 375. doi: 10.1021/jacs.5b11149
(c) Jiang, X.; Xu, Y.; Wang, X.; Yang, F.; Zhang, A.; Li, C.; Ma, W.; Li, W. Polym. Chem. 2017, 8, 3300. doi: 10.1039/C7PY00444C
(7) (a) Lin, Y.; He, Q.; Zhao, F.; Huo, L.; Mai, J.; Lu, X.; Su, C. J.; Li, T.; Wang, J.; Zhu, J.; Sun, Y.; Wang, C.; Zhan, X. J. Am. Chem. Soc. 2016, 138, 2973. doi: 10.1021/jacs.6b00853
(b) Cheng, P.; Zhang, M.; Lau, T. K.; Wu, Y.; Jia, B.; Wang, J.; Yan, C.; Qin, M.; Lu, X.; Zhan, X. Adv. Mater. 2017, 29, 1605216. doi: 10.1002/adma.201605216
(c) Yang, F.; Li, C.; Lai, W.; Zhang, A.; Huang, H.; Li, W. Mater. Chem. Front. 2017, 1, 1389. doi: 10.1039/C7QM00025A
(d) Yang, Y.; Zhang, Z. G.; Bin, H.; Chen, S.; Gao, L.; Xue, L.; Yang, C.; Li, Y. J. Am. Chem. Soc. 2016, 138, 15011. doi: 10.1021/jacs.6b09110
(8) Lin, Y.; Zhao, F.; Wu, Y.; Chen, K.; Xia, Y.; Li, G.; Prasad, S. K. K.; Zhu, J.; Huo, L.; Bin, H.; Zhang, Z. G.; Guo, X.; Zhang, M.; Sun, Y.; Gao, F.; Wei, Z.; Ma, W.; Wang, C.; Hodgkiss, J.; Bo, Z.; Inganäs, O.; Li, Y.; Zhan, X. Adv. Mater. 2017, 29, 1604155. doi: 10.1002/adma.201604155
(9) Zhang, A.; Li, C.; Yang, F.; Zhang, J.; Wang, Z.; Wei, Z.; Li, W. Angew. Chem. Int. Ed. 2017, 56, 2694. doi: 10.1002/anie.201612090
(10) (a) Yen, W. N.; Lo, S. S.; Kuo, M. C.; Mai, C. L.; Lee, G. H.; Peng, S. M.; Yeh, C. Y. Org. Lett. 2006, 8, 4239. doi: 10.1021/ol061478w
(b) Guo, Y.; Zhang, A.; Li, C.; Li, W.; Zhu, D. Chin. Chem. Lett. 2017. doi: 10.1016/j.cclet.2017.08.006
(11) Liu, Y.; Zhang, L.; Lee, H.; Wang, H. W.; Santala, A.; Liu, F.; Diao, Y.; Briseno, A. L.; Russell, T. P. Adv. Energy Mater. 2015, 5, 1500195. doi: 10.1002/aenm.201500195

1. WANG Yi, JIA Nan-Fang, QI Sheng-Li, TIAN Guo-Feng, WU De-Zhen.Synthesis, Characterization and Memory Performance of Naphthalimides Containing Various Electron-Withdrawing Moieties[J]. Acta Phys. -Chim. Sin., 2017,33(11): 2227-2236
2. MA Ren-Jun, GUO Qian-Jin, LI Bo-Xuan, XIA An-Dong.Triplet Excited State Dynamics of Porphyrin in Ionic Liquid [Bmim][BF4][J]. Acta Phys. -Chim. Sin., 2017,33(11): 2191-2198
3. SHI Nai-En, SONG Chuan-Yuan, ZHANG Jun, HUANG Wei.Preparation and Optoelectronic Applications of Two-Dimensional Nanocrystals Based on Metallo-Porphyrins[J]. Acta Phys. -Chim. Sin., 2016,32(10): 2447-2461
4. YIN Hai-Feng, ZHANG Hong, YUE Li.Near-Infrared Plasmon Study on N-Doped Hexagonal Graphene Nanostructures[J]. Acta Phys. -Chim. Sin., 2014,30(6): 1049-1054
5. LIU Huan, ZANG Na, ZHAO Fang-Yao, LIU Kun, LI Yue, RUAN Wen-Juan.Synthesis and Nonlinear Optical Properties of Porphyrin-Salen Type Homo- and Hetero-Binuclear Metal Complexes[J]. Acta Phys. -Chim. Sin., 2014,30(10): 1801-1809
6. YANG Le-Le, LIU Jia, LI Yue, LIU Kun, RUAN Wen-Juan.Molecular Recognition of Glycoconjugated Porphyrin with Chiral Amino Acid Methyl Ester[J]. Acta Phys. -Chim. Sin., 2013,29(09): 1877-1885
7. CUI Li-Li, ZHOU Dan-Hong, LI Miao-Miao.Photophysical Properties of a Red-Shift Cu(II) Ratiometric Fluorescent Chemosensor[J]. Acta Phys. -Chim. Sin., 2013,29(04): 745-753
8. GU Lai-Yuan, GAO Bao-Jiao, FANG Xiao-Lin.Characterization of Immobilized Composite Catalysts of Cationic Metalloporphyrin and Heteropoly Anion in Oxidation of Ethyl Benzene by Molecular Oxygen[J]. Acta Phys. -Chim. Sin., 2013,29(01): 191-198
9. WANG Guan-Yao, YAN Wei-Wei, ZHANG Xiao-Hong, RUAN Wen-Juan, ZHU Zhi-Ang.Synthesis and Spectral Properties of Salen-Porphyrin Type Homo- and Hetero-Binuclear Complexes with π-Conjugate Configuration[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2774-2782
10. SHEN Jian-Lei, YANG Xin-Guo, HUANG Liao, SHEN Qi-Li, LIU Zhen-Hui, ZHANG Feng-Ju.Synthesis and Photophysical Behavior of Two Novel Bis(1,8-naphthalimides) Containing Triazine Spacers[J]. Acta Phys. -Chim. Sin., 2012,28(08): 1992-1999
11. PENG Yu-Ling, WANG Shu-Jun, FU Li, ZHANG Cheng-Gen, LIU Xin-Gang.Synthesis of Tailed Porphyrin Modified with Nicotinic Acid and Interactions with Human Serum Albumin[J]. Acta Phys. -Chim. Sin., 2012,28(05): 1054-1062
12. ZHAO Ping, XU Lian-Cai, MA Li.Spectral Research into Intramolecular Photoinduced Electron Transfer of Porphyrin-Anthraquinone Hybrids[J]. Acta Phys. -Chim. Sin., 2011,27(11): 2541-2546
13. XU Hui-Ying, WANG Wei.Interaction between Mg-Porphyrin and Nitrogen, Oxygen Heterocyclic Compounds[J]. Acta Phys. -Chim. Sin., 2011,27(11): 2565-2570
14. XIAO Quan-Lan, MENG Jian-Xin, XIE Li-Juan, ZHANG Rui.Near-Infrared Luminescence Enhancement by Co-Doped Bi3+ in YVO4:Yb3+[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2427-2431
15. WU Xiao-Lin, SUN Rong, ZHU Peng-Li, DU Ru-Xu.Near Infrared Spectrum Analysis of Organic/Inorganic Composite Microcapsule Phase Change Materials[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1039-1044
16. ZHANG Xiao-Hong, GUO Hong-Rui, JIAO Zhi, YAN Wei-Wei, RUAN Wen-Juan, ZHU Zhi-Ang.Weak Interactions in Asymmetric Porphyrin Systems[J]. Acta Phys. -Chim. Sin., 2011,27(04): 774-780
17. ZHONG Ai-Guo, HUANG Ling, JIANG Hua-Jiang.Structure, Spectroscopy and Reactivity of H2S Bonding to Metal(II) Porphyrins[J]. Acta Phys. -Chim. Sin., 2011,27(04): 837-845
18. QI Zheng-Jian, WEI Bin, WANG Xue-Mei, KANG Feng, HONG Man-Xin, TANG Lan-Lan, SUN Yue-Ming.Synthesis, Optical and Electrochemical Properties of Novel 3,4-Dialkyloxythiophene-Based D-A-D Organic Conjugated Molecules[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3310-3316
19. WEN Xiao-Nan, ZHANG Jing, GU Wen-Xiu, JIN He-Hua, LI Hong-Bo, LI Qing-Wen.Effects of NaCl on the Separation of Single-Walled Carbon Nanotubes by Agarose Gel Electrophoresis[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2757-2762
20. ZHONG Ai-Guo, HUANG Ling, LI Bai-Lin, JIANG Hua-Jiang, LIU Shu-Bin.Structure, Spectroscopy and Reactivity Properties of Helically Chiral Metal(II)-Bisdipyrrin Complexes[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2763-2771
21. ZHANG Xiao-Hong, JIAO Zhi, YAN Wei-Wei, RUAN Wen-Juan, ZHU Zhi-Ang.Synthesis and Nonlinear Optical Properties of Porphyrin Modified by Imidazole and Its Zinc, Copper Complexes[J]. Acta Phys. -Chim. Sin., 2010,26(03): 701-706
22. LI Ye, HAN Wei-Wei, LIAO Ming-Xia.Spectroscopic and Crystal Structural Analyses of Zinc (II) Tetraphenylporphyrin J-aggregates[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2493-2500
23. WANG Rui-Xin, JIAO Wei-Zhou, GAO Bao-Jiao.Catalytic Performance of P(4VP-co-St)/SiO2-Supported Co Tetraphenylporphyrins for the Aerobic Oxidation of Phenylethane[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1791-1798
24. YING Xiao, PENG Chun-Chao, TANG An-Min, WANG Xiao-Chun, LIU Hai-Yang, CHANG Chi-Kwong.Electronic Spectra and Second-Order Nonlinear Optical Properties of Binaphthyl Bridged Chiral Bis-Porphyrins[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1895-1905
25. QI Qi, SUN Yue-Ming, HA Yong-Quan.Structures and UV-Vis Absorption Spectra of 1,8-Naphthalimide Derivatives[J]. Acta Phys. -Chim. Sin., 2009,25(06): 1143-1148
26. WANG Fei-Yu; GAO Bao-Jiao; WANG Rui-Xin.Simultaneous Synthesis and Linkage of Porphyrin onto Side Chain of Copolymer P(GMA-co-MMA)[J]. Acta Phys. -Chim. Sin., 2009,25(02): 341-346
27. HE Yuan-Hang; HUI Ren-Jie; YI Yuan-Ping; SHUAI Zhi-Gang.Multiphoton Absorption in Expanded Porphyrins[J]. Acta Phys. -Chim. Sin., 2008,24(04): 565-570
28. WANG Shu-Jun; ZANG Na; RUAN Wen-Juan; ZHU Zhi-Ang.Molecular Recognition of Chiral Zinc Porphyrin with Amino Acid Ester Derivatives[J]. Acta Phys. -Chim. Sin., 2008,24(03): 507-512
29. ZHANG Peng-Yan; ZHANG Jian-Bin; YU Xi-Chang; ZHANG Ling-Wei; WEI Xiong-Hui.Synthesis, Characterization and Photochemical Characteristic of Magnesium Tetraphenyl Porphyrin[J]. Acta Phys. -Chim. Sin., 2008,24(01): 143-146
30. WANG Shu-Jun;ZHANG Ying-Hui;RUAN Wen-Juan;LUO Dai-Bing;ZHU Zhi-Ang;TIAN Jian-Guo;LIU Zhi-Bo .Studies on the Synthesis and Characters of a Novel Chiral Metalloprophyrin[J]. Acta Phys. -Chim. Sin., 2006,22(08): 981-986
31. ZHANG Ying-Hui;RUAN Wen-Juan;WU Yang.DFT Study on the Geometric Structure and Raman Spectrum of meso-monophenylporphyrin (H2MPP)[J]. Acta Phys. -Chim. Sin., 2005,21(12): 1390-1394
32. LIU Shi-jun; CHEN Qi-yuan; FUNAHASHI Shigenobu.Kinetic Study of the Reactions of Porphyrin with Co(II), Ni(II) and Zn(II) Compounds in Supercritical Carbon Dioxide[J]. Acta Phys. -Chim. Sin., 2005,21(08): 893-897
33. WANG Shu-jun; LUO Dai-bing; RUAN Wen-juan; ZHU Zhi-ang; MA Yi.Nonlinear Optical Properties and Conformational Study on Molecular Recognition of Imidazole Derivatives by Chiral Zinc Porphyrins[J]. Acta Phys. -Chim. Sin., 2005,21(08): 834-839
34. Hou An-Xin;Qu Song-Sheng;Wong Wai-Kwok;Liu Yi.Microcalorimetric Study of the Action of Two Kinds of Lanthanide Monoporphyrinate Complexes on Growth Metabolism of Escherichia Coli[J]. Acta Phys. -Chim. Sin., 2003,19(02): 134-138
35. Xu Si-Chuan;Zhang Hui-Juan;Sun Zhao-Yong;Feng Juan;Ai Xi-Cheng;Zhang Qi-Yuan;Zhang Xing-Kang;Liu Yan-Qin;Han Shi-Tian.Synthesis and Spectroscopy Characteristics of 5-fluorouracil Porphyrin Compounds[J]. Acta Phys. -Chim. Sin., 2001,17(10): 879-886
36. Peng Qing-Jing;Duan You-Gou;Ouyang Yu-Zhu;Fu Wei-Chang.Regioselective Oxidation of Phenylethane with Air Catalyzed by μ-oxo-bis-manganese Porphyrins[J]. Acta Phys. -Chim. Sin., 2001,17(04): 292-294
37. Peng Xiao-Bin;Liang Shi-Qiang.CD Spectrum of Chiral Threonine Modified Porphyrinatozinc (II)[J]. Acta Phys. -Chim. Sin., 2001,17(03): 234-237
38. Li Zhen;Xia Chun-Gu.Rapid-Mixing Stopped-Flow Spectra Studies on Water-soluble Manganese Porphyrin Enzyme-Mimic Systems[J]. Acta Phys. -Chim. Sin., 2001,17(02): 101-106
39. Liu Shu-Qing;Xu Ji-Qing;Sun Hao-Ran;Li Dong-Mei;Zeng Qing-Xin;Song Yu-Jiang.Spectra and Electrocatalytic Reduction of Dioxygen of Mesotetrakis (4Nbenzylpyridyl)porphyrinmetaloxo Cluster Supramolecular Complex[J]. Acta Phys. -Chim. Sin., 2001,17(02): 128-133
40. Li Zhen, Xia Chun-Gu, Wei Chi-Li, Li Shu-Ben.Rapid-Mixing Stopped-Flow Spectra of Manganese(Pentafluorophenyl) Porphyrin Enzyme-Mimic Systems[J]. Acta Phys. -Chim. Sin., 1999,15(08): 715-719
41. Xia Chun-Gu, Li Zhen, Wei Chi-Li, Li Shu-Ben.Rapid-Mixing Stopped-Flow Studies of lron Porphrin Enzyme-Mimic Systems[J]. Acta Phys. -Chim. Sin., 1999,15(03): 253-258
42. Huang Cheng-Zhi, Li Yuan-Fang, Huang Xin-Hua, Liu Shao-Pu.Spectral Features of the Aggregation of TPPS4 in the Presence of Cation Surfactant[J]. Acta Phys. -Chim. Sin., 1998,14(08): 731-736
43. Ruan Wen-Juan,Zhu Zhi-Ang,Chen Hong-Wei,Bu Xian-He,Zhang Zhi-Hui,Shao Ying,Chen.The Visible Spectra and Electronic Effects in Axial Coordination Reaction of Zinc Porphyrin Complexes[J]. Acta Phys. -Chim. Sin., 1997,13(07): 603-611
44. Liu Zhi-Xian,Shi Shuang-Qun,Zhang Jian-Jun,Song Xin-Fang,Meng Min-Quan.Coordinating Properties of Nickel(II) tetra(4-N-benzylpyridyl) porphyrin in Aqueous Solution[J]. Acta Phys. -Chim. Sin., 1997,13(07): 659-662
45. Ruan Wen-Juan,Zhu Zhi-Ang,Lin Hua-Kuan,Chen Zheng-Hua,Chen Hong-Wei,Yang Xiu-Lin.Kinetic Studies on the Formation Reaction of Zinc(II)、Cadmium(II) and Mercury(II) with Porphyrins[J]. Acta Phys. -Chim. Sin., 1997,13(04): 335-343
46. Mou Chun-Bo,He Tian-Jing,Wang Xiu-Yan,Liu Fan-Zhen,Jiang Ji-Sen,Chen Long-Wu.Surface Enhanced Raman Scattering(SERS) from H2TSPP and Ag(II)TSPP Adsorbed on Uniform Fe3O4 Colloids[J]. Acta Phys. -Chim. Sin., 1996,12(09): 841-844
47. Xiong Ya,Huang Su-Qiu,Wu Ding-Quan,Qu Song-Sheng.Studies on the Interactions of Two Kinds of Water-Soluble Porphyrins with DNA[J]. Acta Phys. -Chim. Sin., 1996,12(06): 543-546
48. Chen Hong-Wei,Zhu Zhi-Ang,Ruan Wen-Juan,Zhang Zhi-Hui,Chen Zheng-Hua,Chen Rong-T.Thermodynamic Study of Coordination Reaction of Zinc Tetraphenylporphyrins with Substituted Lmidazoles[J]. Acta Phys. -Chim. Sin., 1996,12(06): 568-572
49. Zhu Zhi-Ang, Yan Xi, Zhang Zhi-Hui, Ma Gang, Lin Hua-Kuan, Chen Rong-Ti.Thermodynamics and Kinetics of Coordination Reaction of Imidazolates with Cobalt(II) Porphyrin[J]. Acta Phys. -Chim. Sin., 1996,12(04): 372-376
50. Hu Zhen-Zhu,Hu Zong-Qiu,Liu Fa-Bin,Huang Su-Qiu.Overall Protonation Constants of Bridged Crowned Porphyrins and Porphyrin-cholesterol Ester[J]. Acta Phys. -Chim. Sin., 1996,12(04): 325-328
51. Zhong Qing-Hua,Wang Zhao-Hui,Zhu Qi-He,Kong Fan-Ao.Study of the Ultrafast Processes of TPP,BuPc and NtBuPc[J]. Acta Phys. -Chim. Sin., 1996,12(03): 193-195
52. Xiao Shao-Rong,Wang Ying,Wang Bao-Chen.Studies of Oxygen Reduction on Polycobaltprotoporphyrin Film with RRDE[J]. Acta Phys. -Chim. Sin., 1996,12(02): 141-145
53. Tian Hong-Jian,Zhou Qing-Fu,Shen Shu-Yin,Xu Hui-Jun.The Studies of the Supramolecular System of Porphyrin-Phthalocyanine Formed by Molecular Self-assembly and Its Photoinduced Electron Transfer Processes[J]. Acta Phys. -Chim. Sin., 1996,12(01): 44-48
54. CHEN Jian-Xin, TIAN Hong-Jian, ZHANG Hong-Hao, ZHOU Qiang-Fu, HU Hui-Jun, XU Guang-Zhi.Study on the Intramolecular Electron Transfer of TTP-(CH2)n-Pc[J]. Acta Phys. -Chim. Sin., 1996,12(01): 12-17
55. Xiong Ya,Huang Su-Qiu,Wu Ding-Quan,Qu Song-Sheng.The Interaction of Water-soluble Quaternary Ammonium Pridine Pophyrins with DNA Studied by Microcalorimetry[J]. Acta Phys. -Chim. Sin., 1995,11(10): 957-960
56. Guo Jin-Liang,Sun Feng,Li Yong,Dong Chang-Xiong.Crystal Structure of Dichloro-(5,10,15,20-tetraphenylporphinato) phosphorus(V) Chloride Dichloromethane Solvate[J]. Acta Phys. -Chim. Sin., 1995,11(04): 360-364
57. Suo Ji-Shuan, Li Shu-Ben, Wang Hong-Li.Propylene Epoxidation Catalyzed by a Biomimetic System of Cytochrome P450 Supported Metalloporphyrin on SiO2[J]. Acta Phys. -Chim. Sin., 1995,11(02): 101-106
58. Zheng Guo-Dong, Yan Yan, Gao Sai, Tong Shan-Ling, Gao De.Ellectrocarboxylation of Organic Compounds with Carbon Dioxide Catalyzed by Metalloporphyrins III.Effects of Axial Ligands on Catalytic Activity of CoTPP[J]. Acta Phys. -Chim. Sin., 1994,10(11): 1035-1039
59. Zheng Guo-Dong, Yan Yan, Wang Ying, Huang Chu-Bao, Gao De, An Qing-Da.Studies on the Production and Dissociation of Coenzyme B12 Models by Electrochemistry and Spectroelectrochemistry(II)[J]. Acta Phys. -Chim. Sin., 1994,10(09): 831-837
60. Zhou Xiao-Hai, Zhang Shao-Hui, Huang Su-Qiu, Qu Song-Sheng.Thermodnamics of Oxygen Binding to Dicobalt Diporphyrin in N,N-Dimethylformamide[J]. Acta Phys. -Chim. Sin., 1994,10(05): 391-395
61. Ruan Wen-Juan, Zhu Zhi-Ang, Huang Xiao-Qun, Chen Rong-Ti, Jiang Dong-Qing.Kinetic Study on Porphinatoiron(III) Catalyzing Decomposition of β-Carotene[J]. Acta Phys. -Chim. Sin., 1994,10(04): 312-318
62. Song Shi-Zhe, Li Wei-Ming.Chemical and Electrochemical Modification of Porphyrin on Pure Iron Surface[J]. Acta Phys. -Chim. Sin., 1994,10(02): 135-140
63. Zhu Zhi-Ang; Huang Xiao-Qun; Chen Rong-Ti.Kinetic Study of the Electrophilic Substitution Reaction of Copper ion with Meso-tetrakis (Meta-methylphenyl) Porphyrin Cadmium (II)[J]. Acta Phys. -Chim. Sin., 1993,9(05): 635-641
64. Wang Lei; Liu Jie; Feng Xu-Sheng; Yang Kong-Zhang; Wu Xing; Yao Rong.Studies on the Oriented Effect of Substituents in the L-B Films Built up of Metalloporphyrins or Metallophthalocyanines[J]. Acta Phys. -Chim. Sin., 1993,9(04): 466-472
65. Zhu Zhi-Ang; Xia Xin; Chen Rong-Ti.Kinetics of the Formation of (Para-Substituted Tetraphenylporphinato)-Copper(II) and the Catalytic Effect of Other Matal Ions[J]. Acta Phys. -Chim. Sin., 1991,7(04): 456-461
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