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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 0,Vol.>> Issue()>> 0-0     doi: 10.3866/PKU.WHXB201711101         中文摘要
Accepted manuscript
Effects of Magnesium Modification on the Catalytic Performances of HZSM-5 Zeolite for the Conversion of Ethene to Propene
XU Lulu, ZHAO Zhenchao, ZHAO Rongrong, YU Rui, ZHANG Weiping
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China
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The ever-increasing demand for propene has driven some new strategies to produce propene, such as propane dehydrogenation, metathesis of ethene and 2-butene, catalytic cracking of C4 alkenes, conversion of methanol and ethanol, and direct conversion of ethene, instead of the conventional naphtha-cracking process. The transformation of ethene to propene (ETP) is of great interest owing to the abundant supply of ethylene from ethane crackers and shale gas recently. HZSM-5 zeolite is an effective ETP catalyst and the acid properties of HZSM-5 significantly affect ethene conversion and propene selectivity. A series of HZSM-5 zeolites modified with different amounts of Mg (0-1.0%) were prepared by an incipient impregnation method. Their structures and acidity were systematically characterized by X-ray diffraction (XRD), N2-adsorption/desorption analysis, 27Al magic-angle spinning nuclear-magnetic-resonance (27Al MAS NMR), 29Si MAS NMR, temperature-programmed desorption of NH3 (NH3-TPD), and Fourier transform infrared (FT-IR) of pyridine adsorption techniques. Their catalytic performances in the direct conversion of ethene to propene using a continuous-flow fixed-bed micro-reactor were evaluated. The effects of reaction conditions and Mg contents were thoroughly investigated. Ethene conversion is found to decrease with increasing reaction temperature and gaseous hourly space velocity (GHSV) of HZSM-5 zeolite, while the selectivities of propene show the opposite trend. The optimized reaction temperature is 550℃ and GHSV is 3000 h-1 for the maximum propene yield. After Mg modification, ethene conversion decreases, while propene selectivity increases for HZSM-5 with increasing Mg loading under the optimized reaction conditions. HZSM-5 modified with an appropriate amount of 0.5% Mg shows enhanced selectivity of propene exceeding 45%, and the propene yield is maintained above 20%. Moreover, the selectivity of by-product aromatics is less than 8%. 27Al and 29Si MAS NMR results indicate that the introduction of Mg will result in dealumination in HZSM-5. NH3-TPD and pyridine-IR results indicate that the addition of Mg will reduce both the total acid amount and strong Brønsted acid amount and that the proper amount of Mg leads to increase in the amount of medium-strong acid. By-products such as alkanes and aromatics are mainly formed at these strong Brønsted acid sites by oligomerization and hydrogen transfer reactions. Therefore, the introduction of Mg decreases the number of strong Brønsted acid sites and further enhances the selectivity of propene. Temperature-programmed oxidation (TPO) and 13C CP/MAS NMR analysis of the coked catalysts indicate that the addition of Mg not only inhibits coke deposition, but also changes the type of coke. However, excessive Mg modification results in a remarkable reduction of HZSM-5 activity owing to the significant decrease in the number of total acid and strong Brønsted acid sites.



Keywords: HZSM-5 zeolite   Mg modification   Acidity   Propene   ETP reaction  
Received: 2017-10-12 Accepted: 2017-11-03 Publication Date (Web): 2017-11-10
Corresponding Authors: ZHANG Weiping Email: wpzhang@dlut.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (21373035, 21673027) and the Fundamental Research Funds for the Central Universities in China (DUT16RC(3)002, DUT17TD04).

Cite this article: XU Lulu, ZHAO Zhenchao, ZHAO Rongrong, YU Rui, ZHANG Weiping. Effects of Magnesium Modification on the Catalytic Performances of HZSM-5 Zeolite for the Conversion of Ethene to Propene[J]. Acta Phys. -Chim. Sin., 0, (): 0-0.    doi: 10.3866/PKU.WHXB201711101

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54. CHEN Lang, RAO Mu-Min, LI Wei-Shan, XU Meng-Qing, LIAO You-Hao, TAN Chun-Lin, YI Jin.Performance Improvement of Polyethylene-Supported PAMS Electrolyte Using Urea as Foaming Agent[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1689-1694
55. ZHANG Shao-Long, LI Bin, ZHANG Fei-Yue, MA Li, HAN Yan-Hua, FAN Min-Guang.Aromatization of Ethanol over Metal Modified P/HZSM-5 Zeolite[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1501-1508
56. JIANG Gui-Ming, GAO Bao-Jiao, XU Wen-Mei, WANG Xiao-Hua.Adsorption Behavior and Thermodynamics of Iminodiacetic Acid-Type Material IDAA-PGMA/SiO2 for Heavy Metal Ions and Rare Earth Ions[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1474-1481
57. DENG Ping, ZHANG Hai-Dong, JIANG Jun-Hao, JIANG Qi-Hua.Reaction Mechanism for Propylene Carbonate Prepared by KI/NH3 Catalysis from Propylene Oxide and CO2[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1386-1392
58. WANG Wang-Yin, PAN Ming-Xue, QIN Yu-Cai, WANG Ling-Tao, SONG Li-Juan.Effects of Surface Acidity on the Adsorption Desulfurization of Cu(I)Y Zeolites[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1176-1180
59. CHEN Hong, LI Er-Xiao, YE Zhong-Bin, HAN Li-Juan, LUO Ping-Ya.Interaction of Hydrophobically Associating Polyacrylamide with Gemini Surfactant[J]. Acta Phys. -Chim. Sin., 2011,27(03): 671-676
60. ZHOU Li-Min, SHANG Chao, LIU Zhi-Rong.Acid Dye Adsorption Properties of Ethylenediamine-Modified Magnetic Chitosan Nanoparticles[J]. Acta Phys. -Chim. Sin., 2011,27(03): 677-682
61. YU Chang-Lin, YANG Kai, YU Jimmy C, PENG Peng, CAO Fang-Fang, LI Xin, ZHOU Xiao-Chun.Effects of Rare Earth Ce Doping on the Structure and Photocatalytic Performance of ZnO[J]. Acta Phys. -Chim. Sin., 2011,27(02): 505-512
62. HU Xiao-Yan, LI Chun-Yi, YANG Chao-He.Catalytic Cracking Behavior of n-Heptane over HZSM-5 Catalyst[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3291-3298
63. LIU Bai-Jun, MENG Qing-Lei, WANG Hui, MENG Qing-Min.Synthesis and Characterization of Al MCM-41 Mesoporous Molecular Sieves[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3257-3262
64. SITU Yue, ZHOU Li-Zhuang, LAN Ren-Hua, XIA Zheng-Bin, CHEN Huan-Qin.Influencing Mechanism of Methacrylic Acid on the Redispersion Properties of Redispersible Polymer Powders[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3237-3242
65. YANG Xiao-Long, XIA Chun-Gu, TANG Li-Ping, XIONG Xu-Mao, MU Xin-Yuan, HU Bin.Effect of Alumina Support and Barium Oxide on the Structure and Catalytic Activity of Ruthenium Catalysts for Ammonia Synthesis[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3263-3272
66. ZONG Hua, WANG Lei, FANG Hong-Bo, MAO Lei-Ting, WANG Yu-Hui, ZHANG Lu, ZHAO Sui, YU Jia-Yong.Effect of Hydrophobically Modified Polyacrylamide on Interfacial Dilational Rheological Properties of Crude Oil Components[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2982-2988
67. LIU Yan-Yan, CHEN Pan-Ke, LUO Jian-Hui, ZHOU Ge, JIANG Bo.Molecular Simulation of Dilute Polyacrylamide Solutions[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2907-2914
68. SHU Qiao-Zhen, CHEN Xin, CHEN Kai-Hua, JIANG Jin-Qiang, NI Zhong-Bin, ZHANG Hong-Wu, LIU Xiao-Ya, CHEN Ming-Qing.Synthesis and Properties of Amphiphilic Photosensitive Telechelic Polymer C-PNIPAAm[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2845-2850
69. WU Na, DING Chao, YANG Rong-Jie, HAO Jian-Wei.Effect of Sepiolite on the Combustion and Thermal Decomposition of Intumescent Flame Retardant Polypropylene[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2429-2436
70. MAO Dong-Sen, GUO Qiang-Sheng, MENG Tao.Effect of Magnesium Oxide Modification on the Catalytic Performance of Nanoscale HZSM-5 Zeolite for the Conversion of Methanol to Propylene[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2242-2248
71. ZHANG Sa, LIU Shou-Xin, HAN Xiao-Yu, DANG Li, QI Xiao-Jun, YANG Xi.Synthesis of P(DEAM-co-NAS) and the Environmental Effects of Its Temperature Sensitivity[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2189-2194
72. YAO Wei, GUO Yang-Long, LU Guan-Zhong, GUO Yun, WANG Yan-Qin, ZHANG Zhi-Gang, HE Dan-Nong.Gas Phase Epoxidation of Propylene over a Modified Ag/α-Al2O3 Catalyst[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1579-1584
73. LIU Yi-Wu, YU Huan, ZHANG Xiao-Ming, SUO Ji-Shuan.Direct Gas-Phase Epoxidation of Propylene over Au/Ti-MCM-41(H) Catalysts[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1585-1592
74. QU Xiao-Hua, LIU Jie, WANG Zhao-Xiang, CAO Dian-Liang, FANG Xiang-Peng, ZHANG Ling, DUAN Jing-Lai, YAO Hui-Jun, CHEN Yan-Feng, SUN You-Mei, HOU Ming-Dong.Preparation of Microporous Membranes by Swift Heavy Ion Irradiation and Impedance Characterization[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1722-1726
75. HE Jie, FAN Yi-Ning.Dispersion and Acidity of Niobia on Nb2O5/γ-Al2O3[J]. Acta Phys. -Chim. Sin., 2010,26(03): 679-684
76. ZHANG Ai-Qin, YAN Wei, SHI Li-Qun, SHI Li-Yi, FANG Jian-Hui, JIN Lu-Jiang.Synthesis of Polypropylene/Silica Hybrid Materials by Supercritical CO2 Impregnation Using a Co-Solvent[J]. Acta Phys. -Chim. Sin., 2010,26(03): 643-648
77. JIANG Liu-Feng, ZHONG Chuan-Rong, XU Min, PENG Xiu-Hua.Solution Properties and Microstructure of Branched Acrylamide-Based Copolymers[J]. Acta Phys. -Chim. Sin., 2010,26(03): 535-540
78. FU Hong-Yan, GAO Bao-Jiao, NIU Qing-Yuan.Adsorption Behavior and Mechanism of Grafted PMAA-HEMA/NVP Microspheres toward Lysozyme[J]. Acta Phys. -Chim. Sin., 2010,26(02): 359-366
79. MAO Dong-Sen, GUO Qiang-Sheng, MENG Tao, LU Guan-Zhong.Effect of Hydrothermal Treatment on the Acidity and Catalytic Performance of Nanosized HZSM-5 Zeolites for the Conversion of Methanol to Propene[J]. Acta Phys. -Chim. Sin., 2010,26(02): 338-344
80. HE Shu-Heng, PU Min, LI Jun-Nan, HE Jing, EVANS David G..Assembly, Structure and Properties of Acid Orange 7-Pillared Zn/Al Hydrotalcite[J]. Acta Phys. -Chim. Sin., 2010,26(01): 259-264
81. YANG Bai-Qin, CHEN Kai, XING Hang, XIAO Jin-Xin.Perfluorobutyl-Based Fluorinated Surfactant with High Surface Activity[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2409-2412
82. SHAN Xin-Li, WANG Jian-Ping, LIU Yan, ZHANG Xing-Xiang.Fabrication and Characterization of Microencapsulated n-Octadecane with an Acrylic Co-polymeric Shell[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2590-2596
83. LIU Bai-Jun, ZENG Xian-Jun.Catalytic Conversion of Mixed C4 Hydrocarbons over ZSM-5/ZSM-57 Composite Zeolite Catalyst[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2055-2060
84. LIU Jie-Xiang, WEI Xian, ZHANG Xiao-Guang, HAN En-Shan.Acidities of Cu-[M’]MORand Ag-[M’]MOR (M’=B, Al, Ga, Fe)[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2123-2129
85. WANG Huan-Xia, LIU Shou-Xin, FANG Yu, HAN Xiao-Yu, ZHANG Sa.Synthesis of Poly(N,N-diethylacrylamide) and the Effect of Salts on the Thermosensitivity of Its Aqueous Solutions[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1911-1915
86. WANG Fei-Yu; GAO Bao-Jiao; WANG Rui-Xin.Simultaneous Synthesis and Linkage of Porphyrin onto Side Chain of Copolymer P(GMA-co-MMA)[J]. Acta Phys. -Chim. Sin., 2009,25(02): 341-346
87. JIANG Cai-Yun, WENG Xiao-Lei, QIAN Wei-Ping.Preparation and Thermoresponsive Properties of AuNPs/PNIPAM Composite Particles[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2159-2164
88. WANG Wen-Lan; LIU Bai-Jun; ZENG Xian-Jun.Catalytic Cracking of C4 Hydrocarbons on ZSM-5 Molecular Sieves with Low SiO2/Al2O3 Molar Ratio[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2102-2107
89. CHEN Zhi-Ping; GAO Bao-Jiao; YANG Xiao-Feng.Adsorption Mechanism of Bilirubin on Aminated Crosslinking Microspheres of PGMA[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1417-1424
90. XUAN Wei-Min; ZOU Fang; CHEN Lei-Qi; FANG Xue-Ming; LIAN Wei; ZHANG Hui.Mechanism of Absolute Asymmetric Synthesis and Solid-State CD Spectroscopy of BPOB[J]. Acta Phys. -Chim. Sin., 2008,24(06): 955-960
91. LI Jin-Huan; KANG Wan-Li; YAN Wen-Hua; GUO Yi-Hang; GAO Hong-Feng; LIU Zhong-He.Preparation of Eu3+ Doped Titania Nanocrystals and Photocatalytic Degradation Partially Hydrolyzed Polyacrylamide[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1030-1034
92. PEI Su-Peng; ZHANG Bin; JIAO Kun; BAO Ren-Lie; YUE Bin; HE He-Yong.Nanostructured CoMoO4 Supported on Mesoporous SBA-15 for Catalytic Oxidative Dehydrogenation of Propane to Propene[J]. Acta Phys. -Chim. Sin., 2008,24(04): 561-564
93. WANG Fang-Ping; DU Xin-Zhen; WANG Chun; DONG Xiao-Li; CHEN Hui.Synthesis, Characterization and Micellization of Poly(acrylic acid)-g-Octylphenyl Polyoxylethylene Ether[J]. Acta Phys. -Chim. Sin., 2008,24(02): 350-354
94. WANG Jian; GAO Bao-Jiao; GUO Hao-Peng.Adsorption Mechanism of Grafting Particle PMAA/SiO2 for Pirimicarb in Water Medium[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1905-1911
95. ZHANG Lan; ZHANG Shi-Chao.Preparation and Characterization of Poly(acrylonitrile-methoxy polyethylene glycol (350) monoacrylate-lithium acrylate)[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1943-1947
96. YAO Jia; WANG Qing; TONG Da-Jun; LI Hao-Ran.Self-aggregation Behavior of PEG-b-PDMAEMA Copolymers with Different Block Ratios in Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2007,23(10): 1612-1616
97. LI Jing-Yi; MA Jun-Hua; BAI Tu-Ya; SUYOU Le-Ma.Effect of Fluoride Ion on the Photocatalytic Degradation of Sulforhodamine B on TiO2/Bentonite[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1213-1218
98. HE Yi-Ming; YI Xiao-Dong; HUANG Chuan-Jing; YING Fang; ZHANG Xiao-Bing; WENG Wei-Zheng; WAN Hui-Lin.Role of Te on Selective Oxidation of Propane to Acrolein over MoBiTeO/SiO2 Catalysts[J]. Acta Phys. -Chim. Sin., 2007,23(06): 851-855
99. PENG Shun-Jin; ZHAO Lei; WU Li-Min.Surface Properties of Fluorinated Acrylate Polymers Latex Films[J]. Acta Phys. -Chim. Sin., 2007,23(04): 531-536
100. JIANG Li-Ding;GAO Bao-Jiao;LI Gang.Interaction between Cationic Gemini Surfactant with Hydrophobically Associatied Polyacrylamide of a New Family[J]. Acta Phys. -Chim. Sin., 2007,23(03): 337-342
101. ZHANG Yue-Wei;SHEN Mei-Qing;WU Xiao-Dong;WENG Duan;ZHANG Zhi-Hua;TIAN Ran;CHI Ke-Bin.Modification of the Structure and Properties of SAPO-11 Using Rare Earths[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1495-1500
102. JIA Long;XU Yong-Fu;GE Mao-Fa;DU Lin;WANG Geng-Chen;ZHUANG Guo-Shun.Kinetic Study of the Gas-phase Ozonolysis of Propylene[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1260-1265
103. JIN Guo-Jie;GUO Yang-Long;LIU Xiao-Hui;YAO Wei;GUO Yun;WANG Yun-Song;YUAN Fang;LU Guan-Zhong.In situ FT-IR Study on the Direct Gas Phase Epoxidation of Propylene over Ag-MoO3 Catalyst[J]. Acta Phys. -Chim. Sin., 2006,22(07): 809-814
104. ZHANG Yi-Wei;ZHOU Yu-Ming;QIU An-Ding;WANG Yu;XU Yi;WU Pei-Cheng.Effect of Na Addition on Catalytic Performance of PtSn/ZSM-5 Catalyst for Propane Dehydrogenation[J]. Acta Phys. -Chim. Sin., 2006,22(06): 672-678
105. LI Xue-Hui;ZHANG Lei;WANG Le-Fu;TANG Ying-Biao.Characterization of N-carboxyl Appended Pyridine Task-Specific Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2006,22(04): 430-435
106. YU Ya-Ming;WANG Zhong-Hua;GAO Bao-Jiao;WANG Rui-Xin.Effect of Micellization Behavior of Surface Active Monomer NaAMC14S on Copolymerization Process[J]. Acta Phys. -Chim. Sin., 2006,22(04): 496-501
107. GAN Zhi-ping; GUAN Jian-guo.Chemical Self-assembly Route to Fabricate Hollow Barium Ferrite Submicrospheres[J]. Acta Phys. -Chim. Sin., 2006,22(02): 189-192
108. GENG Wei-guo; LI Xue-hui; WANG Le-fu; DUAN Hong-li; PAN Wei-ping.Acidic Characterization of Polycarboxyl Imidazolium Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2006,22(02): 230-233
109. FENG Jia-Chun; DUAN Yu; JIAO Ying; ZHANG Xiu-Ju; CHEN Ming-Cai.Effect of Lanthanum Complex on Isothermal Crystallization Kinetics of Isotatic Polypropylene[J]. Acta Phys. -Chim. Sin., 2005,21(12): 1431-1435
110. TANG Ding-guo; LIU Jian-hong; CI Yun-xiang; QI Lu.Preparation and Performances of a Novel Gel Polymer Electrolyte[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1263-1268
111. JIN Sheng-ming; QIU Guan-zhou; YANG Hua-ming; DENG Zhen-xia.Preparation of HMS and AlSBA Mesoporous Materials from Sepiolite[J]. Acta Phys. -Chim. Sin., 2005,21(07): 796-799
112. LIU Wan-qiang; WANG Xue-ye; LI Xin-fang; LONG Qing-ping; WEN Xiao-hong; LI Jianjun.Quantum Chemistry-ANN Methods Study on Tg of Polyacrylates[J]. Acta Phys. -Chim. Sin., 2005,21(06): 596-601
113. ZHANG Kai; FU Qiang; HUANG Yu-hong; ZHOU De-hui.Study on Acrylonitrile Graft Copolymerization on Surfaces of Polystyrene Microspheres[J]. Acta Phys. -Chim. Sin., 2005,21(06): 673-676
114. WANG Xiao-Hua; TAO Guo-Hong; WU Xiao-Mu; KOU Yuan.Investigation of the Acidity of Ionic Liquids by IR Spectroscopy[J]. Acta Phys. -Chim. Sin., 2005,21(05): 528-533
115. ZHENG Jun-Lin; ZHAI Shang-Ru; YANG Dong-Jiang; ZHANG Ye; WU Dong; SUN Yu-Han.Comparison on the Catalytic Cracking and Alkylation Activities between MSU-SMFI and MCM-41 Aluminosilicates[J]. Acta Phys. -Chim. Sin., 2005,21(03): 324-327
116. Zhao Feng;Du Yu-Kou;Li Xing-Chang;Tang Ji-An;Yang Ping.Study on Viscoelastic Properties of Partially Hydrolyzed Polyacrylamide Solution[J]. Acta Phys. -Chim. Sin., 2004,20(11): 1385-1388
117. Piao Ling-Yu;Han Yang;Kou Yuan.The Reuse of Acidic Ionic Liquids as Catalysts in Diphenyl Oxide Alkylation with Dodecene[J]. Acta Phys. -Chim. Sin., 2004,20(09): 1083-1088
118. Zhang Ying;Fang Yu;Lin Shu-Yu;Liu Jing;Yang Juan-Ling.Preparation of Spherical Nano-structured PMAA/CdS Composites by a Microgel Template Method[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 897-901
119. Wang Zheng-Wu;Li Ying;Li Gan-Zuo;Gu Ming-Yan.Surface Activity and Micellization of LSmn in Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2004,20(08): 816-820
120. Chen Ming-An;Zhang Xin-Ming;Xie Xuan.Interphase Analysis of Adhesion Bonded Aluminum Sheet/polypropylene and Maleic Anhydride Grafted Polypropylene by XPS[J]. Acta Phys. -Chim. Sin., 2004,20(08): 882-886
121. Chen Hong-Lin;Shen Bao-Jian;Pan Hui-Fang.Physicochemical and Catalytic Properties of ZSM-5/Y Composite Zeolites Dealuminated by the Steaming[J]. Acta Phys. -Chim. Sin., 2004,20(08): 854-859
122. Bian Feng-Ling;Liu Ming-Zhu;Sheng Fen-Ling.A Study of Solution Properties of Poly(N-isopropylacrylamide) and Poly(N,N-diethylacrylamide) in Mixed Solvent of Water-Methanol[J]. Acta Phys. -Chim. Sin., 2004,20(04): 337-343
123. Xu Xiao-Ping;Andreas Hüther;Gerd Maurer.Correlation and Prediction of Swelling Behavior of N-isopropyl- acrylamide Based Hydrogels in Aqueous Solution of Acetone[J]. Acta Phys. -Chim. Sin., 2004,20(03): 244-250
124. Yi Xiao-Dong;Lin Hong;He Yi-Ming;Huang Chuan-Jing;Weng Wei-Zheng;Wan Hui-Lin.Selective Oxidation of Propane over Mo-V-Zr-O Catalysts[J]. Acta Phys. -Chim. Sin., 2004,20(03): 309-312
125. Lin Mei-Qin;Sun Ai-Jun;Dong Zhao-Xia;Tang Ya-Lin;Li Ming-Yuan;Wu Zhao-Liang.Study on Properties of the Linked Polymer Solution with Low Polymer Concentration[J]. Acta Phys. -Chim. Sin., 2004,20(03): 285-289
126. Shi Xi-E;Zhai Shang-Ru;Dai Li-Yi;Shan Yong-Kui;He Ming-Yuan;Wei Wei;Wu Dong;Sun Yu-Han.Synthesis of Mesoporous Aluminosilicate Nanoparticles and Its Performance in Catalytic Cracking[J]. Acta Phys. -Chim. Sin., 2004,20(03): 265-270
127. Dong Xiang-Ting;He Ying;Yan Jing-Hui;Xue Bo-Fei;Feng Xiu-Li;Hong Guang-Yan.Preparation and Characterization of Nanosized AgBr/PMMA Photochromic Hybrid Material[J]. Acta Phys. -Chim. Sin., 2003,19(12): 1159-1162
128. Chen Hong;Han Li-Juan;Xu Peng;Luo Ping-Ya.The Thickening Mechanism Study of Hydrophobically Modified Polyacrylamide[J]. Acta Phys. -Chim. Sin., 2003,19(11): 1020-1024
129. Zheng Jun-Lin;Zhang Ye;Wei Wei; Wu Dong;Sun Yu-Han;Deng Feng;Luo Qing;Yue Yong.Hydrothermally Stable Mesoporous Aluminosilicates with Strongly Acidic Sites[J]. Acta Phys. -Chim. Sin., 2003,19(10): 907-912
130. Zhang Xin;Wan Hui-Lin;Weng Wei-Zheng;Yang Le-Fu;Yi Xiao-Dong.Role of Ce on Selective Oxidation of Propane to Acrolein over Ce-Ag-Mo-P-O Catalysts[J]. Acta Phys. -Chim. Sin., 2003,19(06): 492-497
131. Zhang Sheng-Mao;Zhang Zhi-Jun;Dang Hong-Xin;Liu Wei-Min;Xue Qun-Ji.Preparation and Characterization of TiO2/Poly(butyl acrylate) Nanocomposite Film[J]. Acta Phys. -Chim. Sin., 2003,19(02): 171-173
132. Zhang Xin;Wan Hui-Lin;Weng Wei-Zheng;Yi Xiao-Dong.The Effect of MoO3 in Ag-Mo-P-O Catalysts on Oxidative Dehydrogenation of Propane[J]. Acta Phys. -Chim. Sin., 2002,18(10): 878-883
133. Bian Feng-Ling;Liu Ming-Zhu.The Temperature Dependence of the Viscosity of Poly (N,N-diethylacrylamide) Solutions[J]. Acta Phys. -Chim. Sin., 2002,18(09): 776-780
134. Pu Min;Wang Hai-Xia;Feng Xiao;Wu Dong;Sun Yu-Han.Research on the Rotation Rearrangement of C=C Double Bond of 3-Hydroxy Acrolein by Density Function Theory[J]. Acta Phys. -Chim. Sin., 2002,18(06): 522-526
135. Wang Zhan-Liang;Tang Zhi-Yuan;Geng Xin;Xue Jian-Jun.Research on Novel PMMAbased Gel Electrolyte for Lithium Ion Battery[J]. Acta Phys. -Chim. Sin., 2002,18(03): 272-275
136. Yuan Shu-Ping;Wang Jian-Guo;Li Yong-Wang;Peng Shao-Yi.Ab initio Study on B, Al or Ga Isomorphously Substituted Mordenites[J]. Acta Phys. -Chim. Sin., 2001,17(09): 811-816
137. Yin Yi-Qing;Fang Yu;Hu Dao-Dao;Gao Gai-Ling.Fluorescence Properties of N-vinylcarbazole Labeled Methacrylic Acid-Acenaphthylene Copolymers[J]. Acta Phys. -Chim. Sin., 2001,17(09): 776-780
138. Xie Jian-Chun;Luo Hong-Peng;Zhu Li-Li;Zhou Li;Li Chong-Xi;Xu Xiao-Jie.Extracting Active Compounds from Herbs Using Molecular Imprinting Technology[J]. Acta Phys. -Chim. Sin., 2001,17(07): 582-585
139. Tao Yue-Wu;Zhong Shun-He.Laser Stimulated Isobutane Selective Oxidation Reaction on the Surface of Li and Bi Mixed Phosphate[J]. Acta Phys. -Chim. Sin., 2001,17(04): 356-360
140. Lu An-Hui;Li Wen-Cui;Zheng Jing-Tang.Preparation of PANbased Molecular Sieve ACF and Study of Surface Structure by XPS[J]. Acta Phys. -Chim. Sin., 2001,17(03): 216-221
141. Zhao Ri-GeTu, Ge Qing-Jie, Li Wen-Zhao, Yu Chun-Ying, Jia Mei-Lin, Xu Heng-Yong.In Situ Electrical Conductivity Study of Ni-V-O Catalysts Used in Oxidative Dehydrogenation of Propane[J]. Acta Phys. -Chim. Sin., 2000,16(09): 798-803
142. Liu Shou-Xin, Fang Yu, Hu Dao-Dao, Lv Hong-Wang.Complexation between Poly(methacrylic acid) and Cationically Modified Polyacrylamide[J]. Acta Phys. -Chim. Sin., 2000,16(03): 214-220
143. Zhang Wen-Min, Wu Qi, Wei Tao, Liu Zhan-Hua.Preparation of High Content Surfactant-free Narrowly Distributed Macromolecule Nanoparticle Latex[J]. Acta Phys. -Chim. Sin., 2000,16(02): 116-120
144. Zhou Li-Xin, Mang Chao-Yong, Zhang Yong-Fan.Gas-phase Acidity and Aromaticity of 1,2-dithiosquaric Acid[J]. Acta Phys. -Chim. Sin., 2000,16(01): 15-21
145. Dai Le-Rong, Su Xiao-Yan, Chen Hui-Ying, Wu Pei-Qiang.Lyotropic Liquid Crystal of Poly(Sodium Sulfoalky Methacrylate)[J]. Acta Phys. -Chim. Sin., 1999,15(12): 1060-1063
146. Cao Wan-Qiang, Li Jing-De.Effect of Polarization Cooling in Polypropylene[J]. Acta Phys. -Chim. Sin., 1999,15(10): 943-947
147. Zhai Mu-Heng, Zhang Wen-Min, Sheng En-Hong, Fu Zhong, Zhang Feng.Preparation of Monodispersed Macromolecule Microspheres by Microwve Irradiation and Research on the Mechanism of Its Formation[J]. Acta Phys. -Chim. Sin., 1999,15(08): 747-751
148. He Li-Zhen, Chen Guang-Ju, Liu Ruo-Zhang.Investigation of the Thermal Reaction of Propene Forming Methylcyclopentane[J]. Acta Phys. -Chim. Sin., 1999,15(04): 308-312
149. Chen Li-Tao, Chen Guang-Ju, Fu Xiao-Yuan.AM1 Studies of Two Pathways of Vinylacetylene React with Nitric Oxide[J]. Acta Phys. -Chim. Sin., 1998,14(11): 1001-1006
150. Tang Yong-Zheng, Tang Ye-Cang, Luo Shi-Zhong, Fu Zhong, Zhang Wen-Min.Microwave Preparation of Narrowly Distributed Surfactant-free Macromolecular Nanospheres[J]. Acta Phys. -Chim. Sin., 1998,14(07): 620-623
151. Bian Guo-Zhu, Fan Li, Fu Yi-Lu, Teng Yuan-Xun.Surface Acidity and Catalytic Properties of Sulfided K-Mo Based Catalysts for Mixed Alcohols Synthesis[J]. Acta Phys. -Chim. Sin., 1998,14(05): 401-406
152. Hu Hai-Quan, Liu Cheng-Bu.Mechanism of the Isomerization of Difluorosilacyclopropene[J]. Acta Phys. -Chim. Sin., 1998,14(04): 349-352
153. Wang Xin-Ping, Zhang Jia-Yun, Tang Ji-An, Jiang Long.Interfacial Rheology Investigation of Polyacrylamide-Surfactant Interactions[J]. Acta Phys. -Chim. Sin., 1998,14(01): 88-92
154. Zhang Yu,Wu Fan-Xin,Zhang Hong-Bin,Lin Guo-Dong,Yuan You-Z.Hydroformylation of Propene over Carbon Nanotubes-Supported Rh-Catalyst[J]. Acta Phys. -Chim. Sin., 1997,13(12): 1057-1060
155. Qian Ying,Wang Yan,Feng Wen-Lin,Liu Ruo-Zhuang.Theoretical Calculation on the Canonical Rate Constants for the Addition Reaction of 1,3-cyclohexa-diene with Propylene[J]. Acta Phys. -Chim. Sin., 1997,13(12): 1084-1089
156. Wu De-Yi.Adsorption of Weak Organic Bases on 1:1 and 2:1 Type Layer Silicates without Layer Charge from Non-polar Organic Solvents[J]. Acta Phys. -Chim. Sin., 1997,13(11): 978-983
157. Han Yu-Wang,Shen Jian-Yi,Chen Yi.Microcalorimetric Study on Surface Acidity of B-P-O Catalysts[J]. Acta Phys. -Chim. Sin., 1997,13(10): 916-920
158. Cao Wan-Qiang,Wang Yong,Liu Jun-Diao,Xiao Zhong-Mo,Li Jing-De.The Frozen and Thermally Stimulated Polarization in Polymer[J]. Acta Phys. -Chim. Sin., 1997,13(10): 921-924
159. Jiang Kui-Yang,Zhang Jun,Gui Lin-Lin.Synthesis and Characterization of PMMA-ZrO2(SiO2,TiO2,Al2O3) Organic-Inorganic Hybrid Materials[J]. Acta Phys. -Chim. Sin., 1997,13(05): 407-412
160. Guan Jian-Guo,Zhao Su-Ling,Xie Hong-Quan.The Temperature and Electric Field Dependence of Properties for Hydrous Electrorheological Fluid-Lithium Polymethacrylate[J]. Acta Phys. -Chim. Sin., 1997,13(03): 242-246
161. Cao Wan-Qiang,Wang Yong,Li Jing-De.Thermally Stimulated Current of Polypropylene in Equilibrium and Non-equilibrium State[J]. Acta Phys. -Chim. Sin., 1996,12(12): 1090-1093
162. Shao Guo-Quan,Fang Wei-Hai,Chen Guang-Ju,Liu Ruo-Zhuang.Theoretical Study on Decarbonylation Reaction of Acrolein and Its Derivatives in Their Electronic Ground States[J]. Acta Phys. -Chim. Sin., 1996,12(09): 830-835
163. Zhang Jun,Luo Sheng-Cheng,Gui Lin-Lin,Tang You-Qi.Synthesisi and Characterization of New PMMA-TiO2 Organic-Lnorganic Hybrid Glasses[J]. Acta Phys. -Chim. Sin., 1996,12(04): 289-292
164. Liu Mu-Xin.Xu Gui-Ying.Li Gan-Zuo.Mao Hong-Zhi.Li Fang.The Transient Interfacial Tension between Oleic Acid-sodium Oleate Aqueous Solution and Crude Oil[J]. Acta Phys. -Chim. Sin., 1995,11(11): 1040-1043
165. Zhang Bang-Hua, Li Chuan-Gang, Song Mou-Dao, Zhou Qing-Ye, Hao Guang-Jie, Zhang Ying.Study on the Miscibility of PVC/PBD-b-PMMA Blends[J]. Acta Phys. -Chim. Sin., 1995,11(09): 807-811
166. Tang Yi, Hua Wei-Ming, Gao Zi.Acid Strength and the Framework Structure of Zeolite[J]. Acta Phys. -Chim. Sin., 1994,10(12): 1116-1120
167. Gao Zi, Hua Wei-Ming, Chen Jian-Min, Tang Yi.Characterization of Solid Superacidity by Pentane Isomerization Reaction[J]. Acta Phys. -Chim. Sin., 1994,10(10): 897-902
168. Xu Gui-Ying, Su Hong-Mei, Li Gan-Zuo, Liu Mu-Xin, Li Fang, Mao Hong-Zhi.The Interaction between Polyacrylamide and Mixed Surfactants[J]. Acta Phys. -Chim. Sin., 1994,10(10): 909-914
169. Gao Zi, Chen Jian-Min, Tang Yi, Hua Wei-Ming.Characterization of Solid Superacidity by Butane Isomerization Reaction at Ambient Temperature[J]. Acta Phys. -Chim. Sin., 1994,10(08): 698-703
170. Xie Zhi-Ming; Gao Pian; Li Zhuo-Mei.Study on the Stability of Soap-free Water-Solubilized Polyacrylic Colloidal Dispersions[J]. Acta Phys. -Chim. Sin., 1994,10(05): 438-443
171. Huang Wei-Jun, Chen Su-Ming, Tan Fu, Yang Zhen-Xiang.Study on Thermodynamic Characteristics of Cinnamic Acid Derivatives[J]. Acta Phys. -Chim. Sin., 1994,10(02): 151-153
172. Ji Yong-Qiang, Fu Xiao-Yuan.Theoretical Study on the Thermal Decomposition of 2-nitropropene[J]. Acta Phys. -Chim. Sin., 1994,10(01): 22-25
173. Fang Wei-Hai; Fang De-Cai; Liu Ruo-Zhuang.AM1 Study of the Photodecarboxylation Reaction of Acrylic acid in the Gas Phase[J]. Acta Phys. -Chim. Sin., 1993,9(06): 788-790
174. Luo Yun-Xia; Yang Hong; Yu Bin; Ding Meng-Xian; Jiang Bing-Zheng.The Effect of Mobility of Molecules on Radiation-induced Chain Scission and Racemization of iso-Poly(Methyl Methacrylate)[J]. Acta Phys. -Chim. Sin., 1993,9(05): 604-609
175. Fang Wei-Hai; Fang De-Cai; Liu Ruo-Zhuang.Theoretical Study of Pyrolysis Mechanisms of Acrylic acid in the Gas Phase[J]. Acta Phys. -Chim. Sin., 1993,9(05): 630-634
176. Liao Jian-Hui; Liu Li-Zhi; Wang Guo-Ying; Jiang Bing-Zheng.The Compatibility and Crystallization of the Mixtures of Poly (Tetrahydrofuran-b-methyl methacrylate) Diblock Copolymer with Polyvinyl Chloride Homopolymer[J]. Acta Phys. -Chim. Sin., 1993,9(05): 657-662
177. Zhang Qing-Da; Li Zhuo-Mei.Study on the Dissociation of A New Cationic Polyacrylamide[J]. Acta Phys. -Chim. Sin., 1993,9(05): 679-683
178. Zhao Dong-Yuan; Yang Ya-Shu; Guo Xie-Xian; Chen Heng-Rong; Xin Qin; Wang Guo-Jia.Preparation,Characterization and Surface Acidity of Hydroxy-Fe-Al Pillared Clays Containing Mixed-matal Complexes(II)[J]. Acta Phys. -Chim. Sin., 1993,9(03): 336-344
179. Niu Guo-Xing; Zhu Chong-Ye; Li Quan-Zhi; Xue Zhi-Yuan; Zhao Yan; Hou Yun-Duo; Li Ming-Shi.Studies on Acidic Properties of Various Reusy[J]. Acta Phys. -Chim. Sin., 1993,9(03): 374-381
180. Wang Qiu-Ying; Jian Pan-Ming; Zhu Chao; Zhai Ying-Li.Studies on Silicon-Rich PrHY Zeolites of Ultrastability by IR AND 29Si MAS NMR[J]. Acta Phys. -Chim. Sin., 1993,9(01): 50-55
181. Xu Gui-Ying; Gu Ying-Hui; Zeng Li-Rong; Zhu He-Ping; Mao Hong-Zhi.Study of the Interaction Between Polyacrylamide and Sodium Dodecyl Sulfonate by Viscosity Method[J]. Acta Phys. -Chim. Sin., 1992,8(03): 352-357
182. Song Mo; Liang Hao-Jun; Chen Yi-Yi; Jiang Bing-Zheng.Investigation of Phase Separation Behavior in Poly (Methyl Methacrylate)/Poly (Styrene-CO-Acrylonitrile) Mixtures With Pulsed Nuclear Magnetic Resonance[J]. Acta Phys. -Chim. Sin., 1991,7(05): 513-517
183. Wang Peng-Fei; Wu Shi-Kang.The Change of Absorption Spectrum of 4-Hydroxybenzylidene Malononitrile Solution Under Conditions of Different pH Value[J]. Acta Phys. -Chim. Sin., 1991,7(05): 582-585
184. Bai Tong-Chun; Wang Jian-Ji; Liu Wen-Bin; Lu Jin-Suo.Study on the Salt Effect in Nonaqueous Solutions by Gas Liquid Chromatography——For Nonelectrolyte Solute (Hydrocarbons,Aromatic Hydrocarbons,Chloro-Hydrocarbons,Ketones) in Salt (Nal, NaSCN, KSCN) and Propy-Lene Carbonate Solutions[J]. Acta Phys. -Chim. Sin., 1991,7(04): 480-484
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