提升燃料电池铂基催化剂稳定性的原理、策略与方法

doi:10.3866/PKU.WHXB202010072

Abstract

Abstract:

Proton exchange membrane fuel cells (PEMFCs) have attracted significant attention owing to their high conversion efficiency, high power density, and low pollution. Their performance is mainly governed by the oxygen reduction reaction (ORR) occurring at the cathode. Owing to the sluggish kinetics of ORR, a large amount of electrocatalysts, i.e., platinum (Pt), is required to accelerate the reaction rate and improve the performance of PEMFCs for practical applications. The use of Pt electrocatalysts inevitably increases the cost, thereby hindering the commercialization of PEMFCs. In addition, the activity and stability of the commercial Pt/C catalyst are still insufficient. Therefore, advanced electrocatalysts with high activity, good stability, and low cost are urgently needed. To date, some theoretical models, especially d-band center theory, have been proposed and guided the search for next-generation electrocatalysts with higher ORR activity. Based on these theories, several strategies and catalysts, especially Pt-based alloy catalysts, have been developed to accelerate ORR and improve the fuel cell performance. For instance, Pt–Ni octahedral nanoparticles (NPs) electrocatalysts have achieved remarkable ORR activity, with one order of magnitude higher activity than that of commercial Pt/C. However, PEMFCs are usually operated at a high voltage (0.6–0.8 V) and an acidic electrolyte, where the transition metals (M) are easily oxidized and etched away. The electronic effect induced by the introduction of M would be eliminated due to the dissolution of transition metals and the agglomeration of NPs, leading to the decay of ORR activity. Therefore, the long-term stability of oxygen reduction catalysts and fuel cells remains highly challenging. It is crucial to design an efficient and highly stable ORR catalyst to promote the application of PEMFCs. Aiming to the stability issues of fuel cell cathode catalysts, the current review summarizes the principles, strategies, and approaches for improving the stability of Pt-based catalysts. First, we introduce thermodynamic and kinetic principles that affect the stability of catalysts. Thermodynamic (such as cohesive energy, alloy formation energy, and segregation energy) and kinetic parameters (such as vacancy formation and diffusion barrier) regarding the structural stability of catalysts significantly affect the metal dissolution and atomic diffusion processes. In addition, these parameters seem to be associated with chemical bond energy to some extent, which could be employed as a descriptor for the stability of catalysts. Later, we outline some representative strategies and methods for improving catalyst stability, namely elemental doping, atomic arrangement engineering, chemical or physical confinement, and supporting material design. Finally, a brief summary and future research perspectives are provided.

Key words: Proton exchange membrane fuel cell, Electrocatalysis, Oxygen reduction reaction, Pt-based electrocatalyst, Stability

MSC2000:

O643

Jiashun Liang, Xuan Liu, Qing Li. Principles, Strategies, and Approaches for Designing Highly Durable Platinum-based Catalysts for Proton Exchange Membrane Fuel Cells[J].Acta Phys. -Chim. Sin., 2021, 37(9): 2010072.

Figures/Tables 13

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References 91

1	Yang T. Y. ; Cui C. ; Rong H. P. ; Zhang J. T. ; Wang D. S. Acta Phys. -Chim. Sin. 2020, 36, 2003047.
	杨天怡; 崔铖; 戎宏盼; 张加涛; 王定胜. 物理化学学报, 2020, 36, 2003047. doi: 10.3866/PKU.WHXB202003047
2	Gasteiger H. A. ; Markovic N. M. Science 2009, 324, 48. doi: 10.1126/science.1172083
3	Debe M. K. Nature 2012, 486, 43. doi: 10.1038/nature11115
4	Bashyam R. ; Zelenay P. Nature 2006, 443, 63. doi: 10.1038/nature05118
5	Kojima K. ; Fukazawa K. ECS Trans. 2015, 69, 213.
6	Konno N. ; Mizuno S. ; Nakaji H. ; Ishikawa Y. SAE Int. J. Alt. Power 2015, 4, 123. doi: 10.4271/2015-01-1175
7	Yoshida T. ; Kojima K. Electrochem. Soc. Inter. 2015, 24, 45.
8	Miao Z. P. ; Wang X. M. ; Tsai M. C. ; Jin Q. Q. ; Liang J. S. ; Ma F. ; Wang T. Y. ; Zheng S. J. ; Hwang B. J. ; Huang Y. H. ; et al Adv. Energy Mater. 2018, 8, 1801226. doi: 10.1002/aenm.201801226
9	He D. S. ; He D. P. ; Wang J. ; Lin Y. ; Yin P. Q. ; Hong X. ; Wu Y. ; Li Y. D. J. Am. Chem. Soc. 2016, 138, 1494. doi: 10.1021/jacs.5b12530
10	Liang J. ; Ma F. ; Hwang S. ; Wang X. ; Sokolowski J. ; Li Q. ; Wu G. ; Su D. Joule 2019, 3, 956. doi: 10.1016/j.joule.2019.03.014
11	Li J. R. ; Xi Z. ; Pan Y. T. ; Spendelow J. S. ; Duchesne P. N. ; Su D. ; Li Q. ; Yu C. ; Yin Z. Y. ; Shen B. ; et al J. Am. Chem. Soc. 2018, 140, 2926. doi: 10.1021/jacs.7b12829
12	US Department of Energy, DOE Technical Targets for Polymer Electrolyte Membrane Fuel Cell Components. https: //www.energy.gov/eere/fuelcells/doe-technicaltargets-polymer-electrolyte-membrane-fuelcell-components
13	Stamenkovic V. ; Mun B. S. ; Mayrhofer K. J. J. ; Ross P. N. ; Markovic N. M. ; Rossmeisl J. ; Greeley J. ; Norskov J. K. Angew. Chem. Int. Ed. 2006, 45, 2897. doi: 10.1002/anie.200504386
14	Stamenkovic V. R. ; Fowler B. ; Mun B. S. ; Wang G. ; Ross P. N. ; Lucas C. A. ; Markovic N. M. Science 2007, 315, 493. doi: 10.1126/science.1135941
15	Stamenkovic V. R. ; Mun B. S. ; Arenz M. ; Mayrhofer K. J. J. ; Lucas C. A. ; Wang G. F. ; Ross P. N. ; Markovic N. M. Nat. Mater. 2007, 6, 241. doi: 10.1038/nmat1840
16	Greeley J. ; Stephens I. E. L. ; Bondarenko A. S. ; Johansson T. P. ; Hansen H. A. ; Jaramillo T. F. ; Rossmeisl J. ; Chorkendorff I. ; Norskov J. K. Nat. Chem. 2009, 1, 552. doi: 10.1038/Nchem.367
17	Chen C. ; Kang Y. ; Huo Z. ; Zhu Z. ; Huang W. ; Xin H. L. ; Snyder J. D. ; Li D. ; Herron J. A. ; Mavrikakis M. ; et al Science 2014, 343, 1339. doi: 10.1126/science.1249061
18	Becknell N. ; Kang Y. J. ; Chen C. ; Resasco J. ; Kornienko N. ; Guo J. H. ; Markovic N. M. ; Somorjai G. A. ; Stamenkovic V. R. ; Yang P. D. J. Am. Chem. Soc. 2015, 137, 15817. doi: 10.1021/jacs.5b09639
19	Luo M. C. ; Sun Y. J. ; Qin Y. N. ; Yang Y. ; Wu D. ; Guo S. J. Acta Phys. -Chim. Sin 2018, 34, 361.
	骆明川; 孙英俊; 秦英楠; 杨勇; 吴冬; 郭少军. 物理化学学报, 2018, 34, 361. doi: 10.3866/PKU.WHXB201708312
20	Greeley J. ; Mavrikakis M. Nat. Mater. 2004, 3, 810. doi: 10.1038/nmat1223
21	Nørskov J. K. ; Bligaard T. ; Logadottir A. ; Kitchin J. R. ; Chen J. G. ; Pandelov S. ; Stimming U. J. Electrochem. Soc. 2005, 152, J23. doi: 10.1149/1.1856988
22	Strasser P. ; Koh S. ; Anniyev T. ; Greeley J. ; More K. ; Yu C. F. ; Liu Z. C. ; Kaya S. ; Nordlund D. ; Ogasawara H. ; et al Nat. Chem. 2010, 2, 454. doi: 10.1038/Nchem.623
23	Luo M. C. ; Guo S. J. Nat. Rev. Mater. 2017, 2, 17059. doi: 10.1038/natrevmats.2017.59
24	Liu M. L. ; Zhao Z. P. ; Duan X. F. ; Huang Y. Adv. Mater. 2019, 31, 1802234. doi: 10.1002/adma.201802234
25	Chung D. Y. ; Yoo J. M. ; Sung Y. E. Adv. Mater. 2018, 30, 1704123. doi: 10.1002/adma.201704123
26	Wang X. X. ; Swihart M. T. ; Wu G. Nat. Catal. 2019, 2, 578. doi: 10.1038/s41929-019-0304-9
27	Borup R. ; Meyers J. ; Pivovar B. ; Kim Y. S. ; Mukundan R. ; Garland N. ; Myers D. ; Wilson M. ; Garzon F. ; Wood D. ; et al Chem. Rev. 2007, 107, 3904. doi: 10.1021/cr050182l
28	Pourbaix M. NACE 1974, 307.
29	Jinnouchi R. ; Toyoda E. ; Hatanaka T. ; Morimoto Y. J. Phys. Chem. C 2010, 114, 17557. doi: 10.1021/jp106593d
30	Tetteh E. B. ; Lee H. Y. ; Shin C. H. ; Kim S. H. ; Ham H. C. ; Tran T. N. ; Jang J. H. ; Yoo S. J. ; Yu J. S. ACS Energy Lett. 2020, 5, 1601. doi: 10.1021/acsenergylett.0c00184
31	Yoo S. J. ; Hwang S. J. ; Lee J. G. ; Lee S. C. ; Lim T. H. ; Sung Y. E. ; Wieckowski A. ; Kim S. K. Energy Environ. Sci. 2012, 5, 7521. doi: 10.1039/c2ee02691k
32	Hwang S. J. ; Kim S. K. ; Lee J. G. ; Lee S. C. ; Jang J. H. ; Kim P. ; Lim T. H. ; Sung Y. E. ; Yoo S. J. J. Am. Chem. Soc. 2012, 134, 19508. doi: 10.1021/ja307951y
33	Tang H. L. ; Su Y. ; Zhang B. S. ; Lee A. F. ; Isaacs M. A. ; Wilson K. ; Li L. ; Ren Y. G. ; Huang J. H. ; Haruta M. ; et al Sci. Adv. 2017, 3, e1700231. doi: 10.1126/sciadv.1700231
34	Zhang J. ; Wang H. ; Wang L. ; Ali S. ; Wang C. ; Wang L. ; Meng X. ; Li B. ; Su D. S. ; Xiao F. S. J. Am. Chem. Soc. 2019, 141, 2975. doi: 10.1021/jacs.8b10864
35	Xiong Y. ; Yang Y. ; DiSalvo F. J. ; Abruña H. D. ACS Nano 2020, 14, 13069. doi: 10.1021/acsnano.0c04559
36	Chong L. ; Wen J. G. ; Kubal J. ; Sen F. G. ; Zou J. X. ; Greeley J. ; Chan M. ; Barkholtz H. ; Ding W. J. ; Liu D. J. Science 2018, 362, 1276. doi: 10.1126/science.aau0630
37	Ao X. ; Zhang W. ; Zhao B. T. ; Ding Y. ; Nam G. ; Soule L. ; Abdelhafiz A. ; Wang C. D. ; Liu M. L. Energy Environ. Sci. 2020, 13, 3032. doi: 10.1039/d0ee00832j
38	Greeley J. ; Norskov J. K. Electrochim. Acta 2007, 52, 5829. doi: 10.1016/j.electacta.2007.02.082
39	Marcus R. A. J. Electroanal. Chem. 1997, 438, 251. doi: 10.1016/S0022-0728(97)00091-0
40	David A. ; Porter K. E. E. ; Mohamed S. Phase Transformations in Metals and Alloys 3rd ed London: Chapman & Hall, 2009.
41	Mullin J. W. ; Mohamed S. Crystallization 3rd ed Oxford: Oxford University Press, 1997.
42	Vej-Hansen U. G. ; Rossmeisl J. ; Stephens I. E. L. ; Schiotz J. Phys. Chem. Chem. Phys. 2016, 18, 3302. doi: 10.1039/c5cp04694g
43	Liang J. S. ; Zhao Z. L. ; Li N. ; Wang X. M. ; Li S. Z. ; Liu X. ; Wang T. Y. ; Lu G. ; Wang D. L. ; Hwang B. J. ; et al Adv. Energy Mater. 2020, 10, 2000179. doi: 10.1002/aenm.202000179
44	Zhang J. ; Yang H. Z. ; Fang J. Y. ; Zou S. Z. Nano Lett. 2010, 10, 638. doi: 10.1021/nl903717z
45	Choi S. I. ; Xie S. F. ; Shao M. H. ; Odell J. H. ; Lu N. ; Peng H. C. ; Protsailo L. ; Guerrero S. ; Park J. H. ; Xia X. H. ; et al Nano Lett. 2013, 13, 3420. doi: 10.1021/nl401881z
46	Cui C. H. ; Gan L. ; Li H. H. ; Yu S. H. ; Heggen M. ; Strasser P. Nano Lett. 2012, 12, 5885. doi: 10.1021/nl3032795
47	Chan Q. W. ; Xu Y. ; Duan Z. Y. ; Xiao F. ; Fu F. ; Hong Y. M. ; Kim J. ; Choi S. I. ; Su D. ; Shao M. H. Nano Lett. 2017, 17, 3926. doi: 10.1021/acs.nanolett.7b01510
48	Wu J. B. ; Gross A. ; Yang H. Nano Lett. 2011, 11, 798. doi: 10.1021/nl104094p
49	Huang X. Q. ; Zhao Z. P. ; Cao L. ; Chen Y. ; Zhu E. B. ; Lin Z. Y. ; Li M. F. ; Yan A. M. ; Zettl A. ; Wang Y. M. ; et al Science 2015, 348, 1230. doi: 10.1126/science.aaa8765
50	Jia Q. Y. ; Zhao Z. P. ; Cao L. ; Li J. K. ; Ghoshal S. ; Davies V. ; Stavitski E. ; Attenkofer K. ; Liu Z. Y. ; Li M. F. ; et al Nano Lett. 2018, 18, 798. doi: 10.1021/acs.nanolett.7b04007
51	Beermann V. ; Gocyla M. ; Willinger E. ; Rudi S. ; Heggen M. ; Dunin-Borkowski R. E. ; Willinger M. G. ; Strasser P. Nano Lett. 2016, 16, 1719. doi: 10.1021/acs.nanolett.5b04636
52	Lim J. ; Shin H. ; Kim M. ; Lee H. ; Lee K. S. ; Kwon Y. ; Song D. ; Oh S. ; Kim H. ; Cho E. Nano Lett 2018, 18, 2450. doi: 10.1021/acs.nanolett.8b00028
53	Zhang C. L. ; Sandorf W. ; Peng Z. M. ACS Catal. 2015, 5, 2296. doi: 10.1021/cs502112g
54	Li Y. J. ; Quan F. X. ; Chen L. ; Zhang W. J. ; Yu H. B. ; Chen C. F. RSC Adv. 2014, 4, 1895. doi: 10.1039/c3ra46299d
55	Zhang J. ; Sasaki K. ; Sutter E. ; Adzic R. R. Science 2007, 315, 220. doi: 10.1126/science.1134569
56	Wu Z. F. ; Su Y. Q. ; Hensen E. J. M. ; Tian X. L. ; You C. H. ; Xu Q. J. Mater. Chem. A 2019, 7, 26402. doi: 10.1039/c9ta08682j
57	Lu B. A. ; Sheng T. ; Tian N. ; Zhang Z. C. ; Xiao C. ; Cao Z. M. ; Ma H. B. ; Zhou Z. Y. ; Sun S. G. Nano Energy 2017, 33, 65. doi: 10.1016/j.nanoen.2017.01.003
58	Kuttiyiel K. A. ; Kattel S. ; Cheng S. B. ; Lee J. H. ; Wu L. J. ; Zhu Y. M. ; Park G. G. ; Liu P. ; Sasaki K. ; Chen J. G. G. ; et al ACS Appl. Energy Mater. 2018, 1, 3771. doi: 10.1021/acsaem.8b00555
59	Sun S. H. ; Murray C. B. ; Weller D. ; Folks L. ; Moser A. Science 2000, 287, 1989. doi: 10.1126/science.287.5460.1989
60	Chen M. ; Kim J. ; Liu J. P. ; Fan H. Y. ; Sun S. H. J. Am. Chem. Soc. 2006, 128, 7132. doi: 10.1021/ja061704x
61	Kim J. ; Rong C. B. ; Lee Y. ; Liu J. P. ; Sun S. H. Chem. Mater. 2008, 20, 7242. doi: 10.1021/cm8024878
62	Zhang L. ; Roling L. T. ; Wang X. ; Vara M. ; Chi M. ; Liu J. ; Choi S. I. ; Park J. ; Herron J. A. ; Xie Z. ; et al Science 2015, 349, 412. doi: 10.1126/science.aab0801
63	Qi Z. Y. ; Xiao C. X. ; Liu C. ; Goh T. W. ; Zhou L. ; Maligal-Ganesh R. ; Pei Y. C. ; Li X. L. ; Curtiss L. A. ; Huang W. Y. J. Am. Chem. Soc. 2017, 139, 4762. doi: 10.1021/jacs.6b12780
64	Kim J. M. ; Rong C. B. ; Liu J. P. ; Sun S. H. Adv. Mater. 2009, 21, 906. doi: 10.1002/adma.200801620
65	Kang S. S. ; Miao G. X. ; Shi S. ; Jia Z. ; Nikles D. E. ; Harrell J. W. J. Am. Chem. Soc. 2006, 128, 1042. doi: 10.1021/ja057343n
66	Yi D. K. ; Selvan S. T. ; Lee S. S. ; Papaefthymiou G. C. ; Kundaliya D. ; Ying J. Y. J. Am. Chem. Soc. 2005, 127, 4990. doi: 10.1021/ja0428863
67	Lee D. C. ; Mikulec F. V. ; Pelaez J. M. ; Koo B. ; Korgel B. A. J. Phys. Chem. B 2006, 110, 11160. doi: 10.1021/jp060974z
68	Wang T. ; Liang J. ; Zhao Z. ; Li S. ; Lu G. ; Xia Z. ; Wang C. ; Luo J. ; Han J. ; Ma C. ; et al Adv. Energy Mater. 2019, 9, 1803771. doi: 10.1002/aenm.201803771
69	Chung D. Y. ; Jun S. W. ; Yoon G. ; Kwon S. G. ; Shin D. Y. ; Seo P. ; Yoo J. M. ; Shin H. ; Chung Y. H. ; Kim H. ; et al J. Am. Chem. Soc. 2015, 137, 15478. doi: 10.1021/jacs.5b09653
70	Du X. X. ; He Y. ; Wang X. X. ; Wang J. N. Energy Environ. Sci. 2016, 9, 2623. doi: 10.1039/C6EE01204C
71	Jung C. ; Lee C. ; Bang K. ; Lim J. ; Lee H. ; Ryu H. J. ; Cho E. ; Lee H. M. ACS Appl. Mater. Inter. 2017, 9, 31806. doi: 10.1021/acsami.7b07648
72	Chen H. ; Wang D. ; Yu Y. ; Newton K. A. ; Muller D. A. ; Abruna H. ; DiSalvo F. J. J. Am. Chem. Soc. 2012, 134, 18453. doi: 10.1021/ja308674b
73	Dong A. G. ; Chen J. ; Ye X. C. ; Kikkawa J. M. ; Murray C. B. J. Am. Chem. Soc. 2011, 133, 13296. doi: 10.1021/ja2057314
74	Zhang S. ; Zhang X. ; Jiang G. M. ; Zhu H. Y. ; Guo S. J. ; Su D. ; Lu G. ; Sun S. H. J. Am. Chem. Soc. 2014, 136, 7734. doi: 10.1021/ja5030172
75	Wang D. L. ; Xin H. L. L. ; Hovden R. ; Wang H. S. ; Yu Y. C. ; Muller D. A. ; DiSalvo F. J. ; Abruna H. D. Nat. Mater. 2013, 12, 81. doi: 10.1038/Nmat3458
76	Li J. ; Sharma S. ; Liu X. ; Pan Y. T. ; Spendelow J. S. ; Chi M. ; Jia Y. ; Zhang P. ; Cullen D. A. ; Xi Z. ; et al Joule 2019, 3, 124. doi: 10.1016/j.joule.2018.09.016
77	Liang J. S. ; Li N. ; Zhao Z. L. ; Ma L. ; Wang X. M. ; Li S. Z. ; Liu X. ; Wang T. Y. ; Du Y. P. ; Lu G. ; et al Angew. Chem. Int. Ed. 2019, 58, 15471. doi: 10.1002/anie.201908824
78	Wang X. X. ; Hwang S. ; Pan Y. T. ; Chen K. ; He Y. ; Karakalos S. ; Zhang H. ; Spendelow J. S. ; Su D. ; Wu G. Nano Lett. 2018, 18, 4163. doi: 10.1021/acs.nanolett.8b00978
79	Gimenez-Lopez M. D. ; Kurtoglu A. ; Walsh D. A. ; Khlobystov A. N. Adv. Mater. 2016, 28, 9103. doi: 10.1002/adma.201602485
80	Cheng N. C. ; Banis M. N. ; Liu J. ; Riese A. ; Li X. ; Li R. Y. ; Ye S. Y. ; Knights S. ; Sun X. L. Adv. Mater. 2015, 27, 277. doi: 10.1002/adma.201404314
81	Jiang K. Z. ; Zhao D. D. ; Guo S. J. ; Zhang X. ; Zhu X. ; Guo J. ; Lu G. ; Huang X. Q. Sci. Adv. 2017, 3, e1601705. doi: 10.1126/sciadv.1601705
82	Gao F. ; Zhang Y. P. ; Song P. P. ; Wang J. ; Yan B. ; Sun Q. W. ; Li L. ; Zhu X. ; Du Y. K. Nanoscale 2019, 11, 4831. doi: 10.1039/c8nr09892a
83	Song P. P. ; Xu H. ; Wang J. ; Zhang Y. P. ; Gao F. ; Guo J. ; Shiraishi Y. ; Du Y. K. Nanoscale 2018, 10, 16468. doi: 10.1039/c8nr04918a
84	Huang H. W. ; Li K. ; Chen Z. ; Luo L. H. ; Gu Y. Q. ; Zhang D. Y. ; Ma C. ; Si R. ; Yang J. L. ; Peng Z. M. ; et al J. Am. Chem. Soc. 2017, 139, 8152. doi: 10.1021/jacs.7b01036
85	Li K. ; Li X. X. ; Huang H. W. ; Luo L. H. ; Li X. ; Yan X. P. ; Ma C. ; Si R. ; Yang J. L. ; Zeng J. J. Am. Chem. Soc. 2018, 140, 16159. doi: 10.1021/jacs.8b08836
86	Jung S. M. ; Yun S. W. ; Kim J. H. ; You S. H. ; Park J. ; Lee S. ; Chang S. H. ; Chae S. C. ; Joo S. H. ; Jung Y. ; et al Nat. Catal. 2020, 3, 681. doi: 10.1038/s41929-020-00501-0
87	Liu Y. ; Mustain W. E. J. Am. Chem. Soc. 2013, 135, 530. doi: 10.1021/ja307635r
88	Jimenez-Morales I. ; Haidar F. ; Cavaliere S. ; Jones D. ; Roziere J. ACS Catal. 2020, 10, 10399. doi: 10.1021/acscatal.0c02220
89	He C. ; Sankarasubramanian S. ; Matanovic I. ; Atanassov P. ; Ramani V. ChemSusChem 2019, 12, 3468. doi: 10.1002/cssc.201900499
90	Park C. ; Lee E. ; Lee G. ; Tak Y. Appl. Catal. B-Environ. 2020, 268, 118414. doi: 10.1016/j.apcatb.2019.118414
91	Qiao Z. ; Hwang S. ; Li X. ; Wang C. Y. ; Samarakoon W. ; Karakalos S. ; Li D. G. ; Chen M. J. ; He Y. H. ; Wang M. Y. ; et al Energy Environ. Sci. 2019, 12, 2830. doi: 10.1039/c9ee01899a

No.	Electrode process	E⁰/V
1	Fe²⁺ + 2e^- ═ Fe	-0.447
2	Fe³⁺ + 3e^- ═ Fe	-0.037
3	Ni²⁺ + 2e^- ═ Ni	-0.257
4	Co²⁺ + 2e^- ═ Co	-0.28
5	Pt²⁺ + 2e^- ═ Pt	1.18
6	[PtCl₆]^2- + 2e ═ [PtCl₄]^2- + 2Cl^-	0.68
7	Pd²⁺ + 2e^- ═ Pd	0.915
8	PdBr₄^2- + 2e^- ═ Pd + 4Br^-	0.6
9	Au⁺ + e^- ═ Au	1.692
10	Au³⁺ + 3e^- ═ Au	1.498

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Principles, Strategies, and Approaches for Designing Highly Durable Platinum-based Catalysts for Proton Exchange Membrane Fuel Cells

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