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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
2008 Vol. 24,No. 03
Published: 10 March 2008
Current column
Table of Contents
ARTICLE
Note
Table of Contents
Table of Contents for Vol.24 No.3
2008, 24 (03): 0.
2343
Abstract/Metrics
2395
PDF(1720KB)
ARTICLE
Microporous Silica Hollow Nanospheres Templated by Anionic Polypeptide
LI Li-Ying; WANG Jin-Gui; SUN Ping-Chuan; LIU Xiao-Hang; DING Da-Tong; CHEN Tie-Hong
Anionic polypeptide, the poly(sodium L-glutamate), was applied to fabricate microporous silica hollow nanospheres templa...
2008, 24 (03): 359-363.
DOI: 10.1016/S1872-1508(08)60014-5
5573
Abstract/Metrics
3036
PDF(1666KB)
Catalytic Combustion of Ethyl Acetate over Al
2
O
3
-Ce
0.5
Zr
0.5
O
2
Supported Metal Oxide Catalysts
YUAN Shu-Hua; SHEN Mei; GONG Mao-Chu; WANG Jian-Li; YAN Sheng-Hui; CAO Hong-Yan; CHEN Yao-Qiang
The catalysts for the combustion of ethyl acetate were prepared using Fe, Co, Cu, Cr, andMn metal oxides as active compo...
2008, 24 (03): 364-368.
DOI: 10.1016/S1872-1508(08)60015-7
5349
Abstract/Metrics
2622
PDF(210KB)
Influences of Mesoporous Structure on the NO+H
2
+O
2
Low Temperature Reaction over Pt/Si-MCM-41 Catalyst
WU Peng; LIU Yun-Xia; ZHANG Fu-Xiang; LI Lan-Dong; YANG Ya-Li; GUAN Nai-Jia
It was found that Si-MCM-41 mesoporous molecular sieves as a support of noble metal Pt could be used for the selective c...
2008, 24 (03): 369-374.
DOI: 10.1016/S1872-1508(08)60016-9
5375
Abstract/Metrics
2431
PDF(1387KB)
Synthesis, Characterization and Humidity Sensitive Properties of Nanocrystalline LaCo
x
Fe
1-
x
O
3
WANG Zhu-Yi; CHEN Cheng; FENG Cai-Hui; WANG Jin-Xing; ZOU Bo; ZHAO Meng; WU Feng-Qing
The nanocrystalline LaCoxFe1 -xO3 with different concentrations of Co was prepared by polyethylene glycol (PEG) sol-gel ...
2008, 24 (03): 375-378.
DOI: 10.1016/S1872-1508(08)60017-0
4618
Abstract/Metrics
2771
PDF(479KB)
Interactions of Quercetin with Casein and Bovine Serum Albumin as well as Effects of Coexisting Carbon Nanotubes
CHEN Dai-Wu; XIE Qing-Ji; JIANG Xue-Qin; YAO Shou-Zhuo
Fluorescence quenching and synchronous fluorescence methods were used to study the interactions of fluorescence-active q...
2008, 24 (03): 379-387.
DOI: 10.1016/S1872-1508(08)60018-2
5850
Abstract/Metrics
2923
PDF(556KB)
Electronic Structure and Formation Heat of Pu
3
Mand PuM
3
(M=Ga, In, Sn and Ge) Compounds
LUO Wen-Hua; MENG Da-Qiao; LI Gan; CHEN Hu-Chi
The equilibrium structure, electronic structure, and formation heat of Pu3M (PuM3) (M=Ga, In, Sn and Ge) compounds with ...
2008, 24 (03): 388-392.
DOI: 10.1016/S1872-1508(08)60019-4
5304
Abstract/Metrics
2547
PDF(312KB)
Corrosion Electrochemical Characteristics of X60 Pipeline Steel in SRB and CO
2
Coexistence Environment
LIU Wei; ZHAO Yan-Liang; LU Min-Xu
The corrosion morphology, the corrosion film composition, and corrosion electrochemical characteristics of X60 steel soa...
2008, 24 (03): 393-399.
DOI: 10.3866/PKU.WHXB20080307
4787
Abstract/Metrics
3050
PDF(1099KB)
Theoretical Expression and Experiment on Surface Tension in Ideal Binary Mixtures of Surfactants
TU Guo-Yun; WANG Zheng-Wu; WANG Zhong-Ni; LIU Feng; XIAO Jian-Yi
Two kinds of equations of the surface tension vs the concentration for ideal binary mixtures of surfactants were acquire...
2008, 24 (03): 400-404.
DOI: 10.3866/PKU.WHXB20080308
6611
Abstract/Metrics
3024
PDF(221KB)
Structure and Stability of Endohedral Complexes X@(HAlNH)
12
(X=Be,Mg, Ca, Zn, Al+, Ga+)
ZHANG Cai-Yun; CUI Li-Ya; WU Hai-Shun
Based on our previous researchwork of closo-hedral cluster (HAlNH)12, the geometries, natural bond orbital, vibrational ...
2008, 24 (03): 405-410.
DOI: 10.3866/PKU.WHXB20080309
5414
Abstract/Metrics
2649
PDF(693KB)
Influence of Electrolytes on the Micellar Growth of Amphiphilic Drug Chlorpromazine Hydrochloride
ALAMMd. Sayem; KABIR-UD-DIN
The effect of electrolytes on the micellar behavior of an amphiphilic drug, chlorpromazine (CPZ) hydrochloride, was stud...
2008, 24 (03): 411-415.
DOI: 10.1016/S1872-1508(08)60020-0
5141
Abstract/Metrics
3125
PDF(167KB)
Codeposition and Costripping Models for Bimetal on the Boron-Doped Diamond Surface
TONG Xi-Li; ZHAO Guo-Hua; XIAO Xiao-E; HU Hui-Kang
Codeposition and costripping models for bimetal from Ag+, Cu2+, Pb2+, Sn2+, and Cd2+, on boron-doped diammond (BDD) surf...
2008, 24 (03): 416-422.
DOI: 10.3866/PKU.WHXB20080311
5030
Abstract/Metrics
2580
PDF(994KB)
Influence of Ti-Zr Catalysts on Reversible Hydrogen Storage Characteristics of NaH/Al Composite
XIAO Xue-Zhang; CHEN Li-Xin; FAN Xiu-Lin; GE Hong-Wei; LI Shou-Quan; YING Tiao; WANG Xin-Hua; CHEN Chang-Pin
The NaAlH4 complex hydride was prepared by hydrogenation of the ball-milled (NaH/Al+Ti) and (NaH/Al+Ti-Zr) composites. T...
2008, 24 (03): 423-427.
DOI: 10.3866/PKU.WHXB20080312
5326
Abstract/Metrics
2551
PDF(225KB)
Molecular Dynamics Simulations on the Special System of TFE Aqueous Solution
ZHANG Rong; TAN Zai-You; ZHENG Dun-Sheng; LUO San-Lai; LI Hao-Ran
2,2,2-trifluoroethanol (TFE) aqueous solution is a special associate system. Molecular dynamics (MD) simulations combine...
2008, 24 (03): 428-432.
DOI: 10.3866/PKU.WHXB20080313
6186
Abstract/Metrics
3023
PDF(429KB)
Rheological Behaviors of SiO
2
/PEG Suspension under Dynamic Shear
YANG Hai-Lin; RUAN Jian-Ming; WU Qiu-Mei; ZHOU Zhong-Cheng; ZOU Jian-Peng
Fumed silica suspensions in polyethylene glycol (PEG200) exhibited shear-thickening behavior under dynamic oscillatory s...
2008, 24 (03): 433-436.
DOI: 10.3866/PKU.WHXB20080314
5156
Abstract/Metrics
2747
PDF(195KB)
Adsorption and Vibration of Oxygen Atomon Al(100), (110), (111) Planes
DIAO Zhao-Yu; WU Hong-Zhang; WANG Ze-Xin; ZHANG Xue-Na; ZHANG Yan
Adsorption of O atom on Al low index surfaces was inverstigated with the 5-parameter Morse potential (5-MP). All critica...
2008, 24 (03): 437-442.
DOI: 10.3866/PKU.WHXB20080315
5882
Abstract/Metrics
2705
PDF(768KB)
Adsorption Characteristics of Self-assembled 1-Octadecanol Layer on HOPG
QIAN Li-Ping; DENG Wen-Li
Long-chain alkanol, 1-C18H37OH, adsorbed from solution onto highly oriented pyrolytic graphite (HOPG) and formed ordered...
2008, 24 (03): 443-447.
DOI: 10.3866/PKU.WHXB20080316
5969
Abstract/Metrics
2697
PDF(2263KB)
Electronic Structure and Magnetism of Double Perovskite Sr
2-
x
La
x
CrReO
6
MIAO Yue; YUAN Hong-Kuan; CHEN Hong
The ultrasoft pseudopotential wave method with the generalized gradient approximation to the density functional theory w...
2008, 24 (03): 448-452.
DOI: 10.3866/PKU.WHXB20080317
5652
Abstract/Metrics
2814
PDF(412KB)
Kinetic Behaviour of the Exothermic Decomposition Reaction of
N
-Guanylurea Dinitramide
GAO Hong-Xu; ZHANG Hai; ZHAO Feng-Qi; HU Rong-Zu; MA Hai-Xia; XU Kang-Zhen; YI Jian-Hua; XU Si-Yu; GAO Yin
The kinetic behaviour of the exothermic decomposition reaction and the specific heat capacity of N-guanylurea dinitramid...
2008, 24 (03): 453-458.
DOI: 10.3866/PKU.WHXB20080318
5843
Abstract/Metrics
2523
PDF(284KB)
Effect of Gold Doping on the Photocatalytic Activity of the Anatase TiO
2
LU Han-Feng; ZHOU Ying; XU Bo-Qing; CHEN Yin-Fei; LIU Hua-Zhang
Combined with supercritical ethanol drying, anatase Au/TiO2 and Au-TiO2 with 0.2%(atom fraction) Au content were synthes...
2008, 24 (03): 459-464.
DOI: 10.3866/PKU.WHXB20080319
7673
Abstract/Metrics
3254
PDF(973KB)
Influence of Interphase Distribution of Reactants on Preparation of Nano-CuO by Adsorption Phase Technique
LI Yuan-Pu; JIANG Xin
CuO nanoparticles were synthesized in a nanoreactor formed by adsorption layer on silica surface. Adsorption capacity me...
2008, 24 (03): 465-470.
DOI: 10.3866/PKU.WHXB20080320
5151
Abstract/Metrics
2687
PDF(469KB)
Metastable Phase Equilibria of the Quaternary System Na
+
, K
+
//Cl
-
, B
4
O
2-
7
-H
2
O at 273 K
ZENG Ying; WANG Rui-Lin; LIN Xiao-Feng; PENG Yun
The metastable phase equilibria of the quaternary system Na+, K+//Cl-, B4O2- 7-H2O were studied at 273 K by isothermal e...
2008, 24 (03): 471-474.
DOI: 10.3866/PKU.WHXB20080321
5175
Abstract/Metrics
2693
PDF(183KB)
Structural Characteristics and Humidity Sensing of Mesoporous SnO
2
LIU Xiao-Lei; HE Jian-Ping; DANG Wang-Juan; JI Ya-Jun; ZHAO Gui-Wang; ZHANG Chuan-Xiang
Adouble-template (DT)method using hexadecyl trimethyl ammoniumbromide (CTAB) and dodecylamine (ODA) as templates and a h...
2008, 24 (03): 475-480.
DOI: 10.3866/PKU.WHXB20080322
5192
Abstract/Metrics
2872
PDF(735KB)
Effect of (NaPO
3
)
6
on Electrochemical Corrosion Characteristic of Micro-arc Oxidation Ceramic Coatings Formed on AZ91DMg Alloy
LUO Hai-He; CAI Qi-Zhou; WEI Bo-Kang; YU Bo; HE Jian; LI Ding-Jun
(NaPO3)6 was added to Na2SiO3-KOH electrolyte system, and in-situ ceramic coatings were prepared on AZ91D magnesium allo...
2008, 24 (03): 481-486.
DOI: 10.3866/PKU.WHXB20080323
5691
Abstract/Metrics
2955
PDF(1054KB)
Deposition of Pd Nano-Particles in W/O Microemulsion by Chemical Demulsifying
ZHOU Yong-Hua; YE Hong-Qi
Palladium nano-particles were synthesized by W/O microemulsion composed of nonionic surfactant (alkylpolyglycol ethers) ...
2008, 24 (03): 487-491.
DOI: 10.3866/PKU.WHXB20080324
5603
Abstract/Metrics
2700
PDF(301KB)
Synthesis of Mercaptopropyl Functionalized Nanosized Mesoporous Silica
MA Xue-Hui; ZHAO Yan-Bao; XIAO Gao-Feng; WU Zhi-Shen
Thiol-functionalized nanosized mesoporous silica particles with a diameter of 50-200 nm were prepared and characterized ...
2008, 24 (03): 492-496.
DOI: 10.3866/PKU.WHXB20080325
6138
Abstract/Metrics
3938
PDF(2280KB)
Note
Application of Gaussian Multi-Peak Fitting to Radial Distribution Function
FENG Wang-Sheng; FANG Yan; XU Ji-Xiang; FANG Chun-Hui; JIA Quan-Jie; WANG Huan-Hua; JIANG Xiao-Ming
Aqueous structures with salt to water molar ratios of 1:30 (Rb2SO4) and 1:14 (Cs2SO4) were measured by X-ray scattering ...
2008, 24 (03): 497-501.
DOI: 10.3866/PKU.WHXB20080326
6793
Abstract/Metrics
3895
PDF(397KB)
Topological Analysis of Electron Density on the Halogen-Bond between H2CO and Dihalogen Molecules
ZHAO Ying; ZENG Yan-Li; SUN Zheng; ZHENG Shi-Jun; MENG Ling-Peng
Theoretical studies on the halogen-bond in complexes of H2CO and dihalogen molecules (F2, Cl2, Br2, ClF, BrF, BrCl) were...
2008, 24 (03): 502-506.
DOI: 10.3866/PKU.WHXB20080327
4785
Abstract/Metrics
2535
PDF(462KB)
Molecular Recognition of Chiral Zinc Porphyrin with Amino Acid Ester Derivatives
WANG Shu-Jun; ZANG Na; RUAN Wen-Juan; ZHU Zhi-Ang
Molecular recognition of chiral zinc porphyrin [p-(L-Leu)C2O-TPPZn] with amino acid ester derivatives was investigated b...
2008, 24 (03): 507-512.
DOI: 10.3866/PKU.WHXB20080328
4921
Abstract/Metrics
2832
PDF(373KB)
Synthesis of LiNi
1/3
Co
1/3
Mn
1/3
O
2
Cathode Material by Eutectic Molten Salt LiOH-LiNO
3
CHANG Zhao-Rong; CHEN Zhong-Jun; WU Feng; TANG Hong-Wei; ZHU Zhi-Hong
The powder of LiNi1/3Co1/3Mn1/3O2 were prepared directly without artificial grinding and washing by a eutectic molten-sa...
2008, 24 (03): 513-519.
DOI: 10.3866/PKU.WHXB20080329
5764
Abstract/Metrics
3916
PDF(3531KB)
Investigation of Chlor-Alkali Electrolysis Intensified by Super Gravity
WANG Ming-Yong; XING Hai-Qing; WANG Zhi; GUO Zhan-Cheng
The super gravity field was applied to chlor-alkali electrolysis. The effects of super gravity on hydrogen evolution rea...
2008, 24 (03): 520-526.
DOI: 10.3866/PKU.WHXB20080330
4758
Abstract/Metrics
2717
PDF(743KB)
Influence of Addition of Carbon Nanotubes in the Hydrogen Storage Alloy Electrode on the Performance of SC High Power Batteries
CHEN Yu-Ting; ZHANG Hai-Yan; ZHANG Guo-Qing; CHEN Yi-Ming; ZHU Qing-Feng
The carbon nanotubes were added to the cathode to prepare SC high-power Ni/MH batteries. The capacity, large-current dis...
2008, 24 (03): 527-532.
DOI: 10.3866/PKU.WHXB20080331
5663
Abstract/Metrics
2649
PDF(530KB)
Effect of Pore Structure of Activated Carbon on the Photocatalytic Activity of TiO
2
/AC Composite Photocatalyst
LIU Shou-Xin; CHEN Xiao-Yun
With the aim of investigating the effect of pore structure of activated carbon (AC) on the photocatalytic activity of Ti...
2008, 24 (03): 533-538.
DOI: 10.3866/PKU.WHXB20080332
5989
Abstract/Metrics
3250
PDF(663KB)
Synthesis of Hexagonal Cone-Shaped ZnO Nanoparticles Using Solvothermal Reaction and Its Photoluminescence Property
HAN Dong; ZHANG Shu-Chao
Hexagonal cone-shaped ZnO nanoparticles were synthesized by the esterification between zinc acetate and alcohol with non...
2008, 24 (03): 539-542.
DOI: 10.3866/PKU.WHXB20080333
5642
Abstract/Metrics
3137
PDF(758KB)
Interaction between Cinnamic Acid and Bovine Serum Albumin and the Influence of Alcohol
YAN Hua; YANG Jian-Guo; LIANG Hua-Ding; PAN Fu-You; ZHAO Song-Lin; LI Jing-Jing
The interaction between cinnamic acid and bovine serumalbumin (BSA) has been studied with fluorimeter under physiologica...
2008, 24 (03): 543-546.
DOI: 10.3866/PKU.WHXB20080334
5217
Abstract/Metrics
2801
PDF(213KB)