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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
2006 Vol. 22,No. 10
Published: 11 October 2006
Current column
ARTICLE
Note
REVIEW
ARTICLE
Synthesis and Characteristics of ZnO-CNTs Nanocomposites
ZHU Lu-Ping;HUANG Wen-Ya;MA Li-Li;FU Shao-Yun;YU Ying;JIA Zhi-Jie
ZnO-CNTs nanocomposites were successfully synthesized by sol method using Zn(CH3COO)2•2H2O and treated multiwalled...
2006, 22 (10): 1175-1180.
DOI: 10.3866/PKU.WHXB20061001
6861
Abstract/Metrics
5450
PDF(1150KB)
Preparation and Performance Test of Ni-Fe/SDC Cell Anode
LI Chang-Yu;LÜ Zhe;LIU Li-Li;LIU Zhi-Ming;SU Wen-Hui
A series of Ni-Fe oxides with high specific area and Ce0.8Sm0.2O1.9 (SDC) electrolyte were prepared using the nitrate-ci...
2006, 22 (10): 1181-1184.
DOI: 10.1016/S1872-1508(06)60054-5
5796
Abstract/Metrics
3836
PDF(533KB)
Study on Conductive Mechanism of Composites―Sulfonated Polyphenylacetylene / Multiwalled Carbon Nanotubes
BIAN Cheng-Xiang;XU Xue-Cheng;YU Wei;CHEN Yi-Wei;CHENG Rong-Ming;SHI Yan;LI Xiang-Mei;JIN Sheng-Song
Composites—sulfonated polyphenylacetylene/multiwalled carbon nanotubes (SPPA/MWNT) were prepared by mixing SPPA with MWN...
2006, 22 (10): 1185-1190.
DOI: 10.3866/PKU.WHXB20061003
6283
Abstract/Metrics
3629
PDF(709KB)
Theoretical and Experimental Study on the Reaction Mechanism of Br
2
+Cl
2
=2BrCl
YUAN Li-Xia;YANG Guo-Ying;SUN De-Sheng;WANG Zun-Yao;CHI Qing-Qing
The gas phase reaction mechanism of Br2+Cl2=2BrCl had been investigated by (U)MP2 at 6-311G* level, and a series of four...
2006, 22 (10): 1191-1195.
DOI: 10.3866/PKU.WHXB20061004
6756
Abstract/Metrics
3459
PDF(226KB)
Theoretical Study of Excited States Properties of Au(I) Complexes with Alkynyl
JIAO Yu-Qiu;SUN Qiang;FAN Di
The structures of the Au(I) complexes were fully optimized by using the MP2 method for the ground states and the CIS met...
2006, 22 (10): 1196-1200.
DOI: 10.3866/PKU.WHXB20061005
10221
Abstract/Metrics
3462
PDF(261KB)
Influence of HCl on the Mesostructure and Morphology of the Ordered Mesoporous Silica
ZHAO Chun-Xia;CHEN Wen;LIU Qi;TIAN Gao
Ordered mesoporous molecular sieves SBA-15 were synthesized by hydrothermal reaction with TEOS as the source of inorgani...
2006, 22 (10): 1201-1205.
DOI: 10.3866/PKU.WHXB20061006
5874
Abstract/Metrics
4332
PDF(2586KB)
Thermal Decomposition Mechanisms of a Three-dimensional Framework Coordination Polymer [Cu(HCOO)
2
(H
2
O)
2
]
∞
GUO Jin-Yu;ZHANG Jian-Guo;ZHANG Tong-Lai;WU Rui-Feng;YU Wei
The crystal of [Cu(HCOO)2(H2O)2]∞ (polymer 1) has been synthesized and cultured using the hydrothermal method. The...
2006, 22 (10): 1206-1211.
DOI: 10.1016/S1872-1508(06)60055-7
6430
Abstract/Metrics
4281
PDF(998KB)
Synthesis of Fe
3+
-modified SnO
2
Nanoparticles by Hydrothermal Method
FANG Li-Mei;LI Zhi-Jie;LIU Chun-Ming;ZU Xiao-Tao
Fe3+-modified SnO2 nanoparticles were directly prepared by hydrothermal method, and were characterized by X-ray diffract...
2006, 22 (10): 1212-1216.
DOI: 10.3866/PKU.WHXB20061008
5957
Abstract/Metrics
3486
PDF(458KB)
Reaction of H
2
and N
+
Ion under Titan′s Atmosphere
GE Su-Hong;DONG Guang-Xing;CHENG Xin-Lu;YANG Xiang-Dong
The thermochemical properties of reaction N++H2→NH++H have been computed under Titan′s atmosphere conditions....
2006, 22 (10): 1217-1221.
DOI: 10.1016/S1872-1508(06)60056-9
5864
Abstract/Metrics
3097
PDF(176KB)
Corrosion Behaviour of Pure Magnesium in a Simulated Body Fluid
SONG Guang-Ling;SONG Shi-Zhe
The corrosion behaviour of pure magnesium in Hank′s simulated body fluid (SBF) was investigated. It was found that the p...
2006, 22 (10): 1222-1226.
DOI: 10.3866/PKU.WHXB20061010
6716
Abstract/Metrics
4683
PDF(549KB)
Solid-state Electrochemistry of Gadolinium Hexacyanoferrate Modified Electrode and Its Electrocatalytic Property
SHI Yan-Mao;WU Ping;DU Pan;CAI Chen-Xin
A new electroactive polynuclear inorganic compound of rare earth metal, gadolinium hexacyanoferrate (GdHCF), was prepare...
2006, 22 (10): 1227-1232.
DOI: 10.1016/S1872-1508(06)60057-0
5336
Abstract/Metrics
3372
PDF(532KB)
Base-induced Brönsted Acid Sites on Dealuminated HY Zeolite: A Solid-state NMR Spectroscopy Study
HU Wei;LUO Qing;LI Shen-Hui;SHEN Wan-Ling;YUE Yong;DENG Feng
Using trimethylphosphine(TMP) and d5-pyridine (deuterated pyridine) as the basic probe molecules, the concentrations of ...
2006, 22 (10): 1233-1237.
DOI: 10.1016/S1872-1508(06)60058-2
6410
Abstract/Metrics
3268
PDF(251KB)
Electrocatalytic Oxidation of Ethanol on Pt/nanoTiO2-CNT Complex Catalysts
CHU Dao-Bao;YIN Xiao-Juan;FENG De-Xiang;LIN Hua-Shui;TIAN Zhao-Wu
Pt/nanoTiO2-CNT complex catalysts were prepared by direct hydrolysis of Ti(OEt)4 and electrochemical scan electrodeposit...
2006, 22 (10): 1238-1242.
DOI: 10.3866/PKU.WHXB20061013
7758
Abstract/Metrics
3953
PDF(361KB)
Modeling of Cyclic Peptides by the ABEEM/MM Fluctuating Charge Force Field
ZHANG Qiang;ZHANG Xia;YANG Zhong-Zhi
The ABEEM/MM (atom-bond electronegativity equalization fused into molecular mechanic) fluctuating charge model was appli...
2006, 22 (10): 1243-1247.
DOI: 10.3866/PKU.WHXB20061014
7401
Abstract/Metrics
3738
PDF(190KB)
In situ EIS Study on Titanium/Living Cells Interface
HU Ren;LIN Li-Wen;ZHANG Fan;LIN Chang-Jian
Using a home-made in situ electrochemical cell of electrochemical impedance spectroscop(EIS), the impedance behaviors of...
2006, 22 (10): 1248-1252.
DOI: 10.3866/PKU.WHXB20061015
6860
Abstract/Metrics
3457
PDF(359KB)
Study on the Structure and Property of the Neutral Ga
x
P
y
(x+y=8) and Anionic Gallium Phosphide Clusters Using DFT
GUO Cai-Hong;JIA Jian-Feng;GUO Ling;WU Hai-Shun
Structure, electronic state, and energy of semiconductor binary micro-clusters, GaxPy and GaxPy−, having eight ato...
2006, 22 (10): 1253-1259.
DOI: 10.1016/S1872-1508(06)60059-4
7440
Abstract/Metrics
3612
PDF(194KB)
Kinetic Study of the Gas-phase Ozonolysis of Propylene
JIA Long;XU Yong-Fu;GE Mao-Fa;DU Lin;WANG Geng-Chen;ZHUANG Guo-Shun
Kinetics of the reaction of ozone with propylene under real atmospheric environmental conditions with an ozone concentra...
2006, 22 (10): 1260-1265.
DOI: 10.1016/S1872-1508(06)60060-0
6807
Abstract/Metrics
3667
PDF(392KB)
Theoretical Study on the Mechanisms of the Reaction of Peroxynitrous Acid and Phenol
WANG Yun-Hai;LIU Yong-Dong;LUO Yun-Jing;ZHANG Wei;ZHONG Ru-Gang
The mechanisms of the reactions of the radicals (•OH and •NO2) derived from peroxynitrous acid with phenol hav...
2006, 22 (10): 1266-1271.
DOI: 10.1016/S1872-1508(06)60061-2
7458
Abstract/Metrics
3722
PDF(1973KB)
Carbonylation of Aryl Halide Catalyzed by Active-carbon Supported Ionic Liquid-phase Palladium Catalyst
LIN Qi;FU Hai-Yan;YUAN Mao-Lin;CHEN Hua;LI Xian-Jun
Highly dispersed supported ionic liquid-phase palladium catalyst was prepared and its catalytic performances for carbony...
2006, 22 (10): 1272-1276.
DOI: 10.1016/S1872-1508(06)60062-4
5734
Abstract/Metrics
3626
PDF(1091KB)
Note
Thermodynamic Properties of Dilution of Myo-inositol in Pure Water and Aqueous Sodium Halide Solutions
ZHENG Wen-Qing;SUN De-Zhi;QU Xiu-Kui
The dilution enthalpies of myo-inositol in water and in aqueous sodium halide solutions have been determined with flow-m...
2006, 22 (10): 1277-1280.
DOI: 10.3866/PKU.WHXB20061020
6881
Abstract/Metrics
2881
PDF(188KB)
Determination of Electrochemical Kinetic Parameters in a Mixture Controlled Corrosion System
ZHAO Yong-Tao;GUO Xing-Peng
A transient analysis method, based on the coulostatic impulse technique, is developed. This method can compute the polar...
2006, 22 (10): 1281-1286.
DOI: 10.3866/PKU.WHXB20061021
5796
Abstract/Metrics
3912
PDF(270KB)
Dissolution Kinetics of Calcined Ulexite in Ammonium Chloride Solutions at High Solid-to-Liquid Ratios
GÜR Aycan
The dissolution kinetics of calcined ulexite in ammonium chloride solutions at high solid-to-liquid ratios were investig...
2006, 22 (10): 1287-1290.
DOI: 10.3866/PKU.WHXB20061022
6461
Abstract/Metrics
3587
PDF(114KB)
Photoluminescent and Electroluminescent Characteristics of ZnGa
2
O
4
:Cr
3+
Red Phosphor
QIAO Bin;TANG Zi-Long;ZHANG Zhong-Tai;CHEN Lei
ZnGa2O4:Cr3+ red phosphors were synthesized by citric-gel method. Typical spinel-phase ZnGa2O4 could be attained after c...
2006, 22 (10): 1291-1295.
DOI: 10.3866/PKU.WHXB20061023
6015
Abstract/Metrics
4487
PDF(575KB)
Patterned Ag Film with Superhydrophobic Properties
BAI Shuo;YANG Ling-Lu;ZHANG Mao-Feng;YANG Zhao-Hui;ZHANG Zhi-Feng;CAO Wei-Xiao
Patterned DR(diazoresin)/PAA(polyacrylic acid) SA(self-assembly) film was used as template on which a patterned DNA film...
2006, 22 (10): 1296-1299.
DOI: 10.3866/PKU.WHXB20061024
7144
Abstract/Metrics
3472
PDF(1167KB)
REVIEW
“Second Organized Structures” of Nanoscale Inorganic Polyoxomolybdate Compounds
JIA Xiang-Feng;FAN Da-Wei;TANG Pei-Qin;HAO Jing-Cheng;MA Li-Ying;LIU Tian-Bo
Growth of polyoxomolybdate (POM) clusters and the main role of pentagonal {(Mo)Mo5}-type building blocks in the construc...
2006, 22 (10): 1300-1304.
DOI: 10.1016/S1872-1508(06)60063-6
4755
Abstract/Metrics
3357
PDF(1108KB)